DE295203C - - Google Patents
Info
- Publication number
- DE295203C DE295203C DENDAT295203D DE295203DA DE295203C DE 295203 C DE295203 C DE 295203C DE NDAT295203 D DENDAT295203 D DE NDAT295203D DE 295203D A DE295203D A DE 295203DA DE 295203 C DE295203 C DE 295203C
- Authority
- DE
- Germany
- Prior art keywords
- metals
- catalysts
- carbon
- carbides
- chips
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 240000000800 Allium ursinum Species 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- -1 rare earth carbides Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/20—Carbon compounds
- C07C2527/22—Carbides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
Bei der Behandlung von Kohlenoxyd und Wasserstoff enthaltenden Gasgemischen unter Druck mit Katalysatoren gemäß dem Verfahren der Patente 293787 und 295202 treten mitunter, insbesondere bei Verwendung von metallischen Katalysatoren Reaktionsverzögerungen ein, indem die Einwirkung zunächst gering ist und erst allmählich an Stärke zunimmt. Es wurde nun gefunden, daß man von vornherein mit Sicherheit eine befriedigende Wirkung erzielt, wenn man metallische Kontaktmassen verwendet, die Kohlenstoff in chemisch gebundener oder gelöster Form enthalten. Es kommen in dieser Beziehung praktisch namentlieh die Carbide der Metalle der Eisengruppe in Betracht, sowie auch die genannten Metalle in nur teilweise carburierter Form, wie man sie z. B. durch Behandlung von Eisen mit Kohlenwasserstoffen oder Kohlenoxyd in der Hitze leicht erhält; ferner kann man auch z. B. Gußeisen, kohlenstoff reichen Stahl u. dgl. in Form von Spänen, Schnitzeln usw. verwenden oder Carbide des Molybdäns, WoIf-When treating gas mixtures containing carbon monoxide and hydrogen Pressure with catalysts according to the method of patents 293787 and 295202 may occur Delays in reaction particularly when using metallic catalysts in that the effect is initially small and only gradually increases in strength. It has now been found that a satisfactory effect is guaranteed from the outset achieved when using metallic contact masses that chemically convert carbon contained in bound or dissolved form. In this respect they are practically borrowed by name the carbides of the metals of the iron group into consideration, as well as the metals mentioned in only partially carburized form, as you can z. B. by treating iron easily gets with hydrocarbons or carbon monoxide in heat; furthermore one can also z. B. cast iron, carbon-rich steel and the like. In the form of chips, chips, etc. use or carbides of molybdenum, WoIf-
*) Früheres Zusatzpatent: 295202.*) Previous additional patent: 295202.
rams und anderer geeigneter Metalle benutzen. Die Massen können noch durch Alkali u. dgl. aktiviert werden. Beispielsweise geht man von einem Gasgemisch aus, das neben Wasserstoff gleiche oder überragende Mengen Kohlenoxyd enthält, und behandelt dieses bei 300 bis 400 ° unter einem Druck von 50 bis 100 Atmo-Sphären. Use rams and other suitable metals. The masses can still be replaced by alkali and the like. to be activated. For example, one assumes a gas mixture that, in addition to hydrogen contains equal or superior amounts of carbon oxide, and treats this at 300 to 400 ° under a pressure of 50 to 100 atmospheres.
Man hat schon bei der synthetischen Herstellung von Ammoniak aus den Elementen unter Verwendung der Carbide der seltenen Erden gearbeitet. Dies bot aber noch keine Anhaltspunkte dafür, daß es bei der vorliegenden völlig andersartigen Katalyse vorteilhaft sein würde, als Katalysatoren kohlenstoffhaltige Metalle anzuwenden.One has already seen the synthetic production of ammonia from the elements worked using the rare earth carbides. But none of this offered yet Evidence that it is advantageous in the present completely different type of catalysis would be to use carbonaceous metals as catalysts.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE295203C true DE295203C (en) |
Family
ID=549702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT295203D Active DE295203C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE295203C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE923425C (en) * | 1951-01-30 | 1955-02-28 | Du Pont | Process for the production of high molecular weight hydrocarbons |
| DE972657C (en) * | 1949-07-12 | 1959-09-03 | Ruhrchemie Ag | Process for the production of liquid, oxygen-containing products with a high content of esters by carbohydrate hydrogenation |
| EP0355229A1 (en) * | 1988-08-25 | 1990-02-28 | Exxon Research And Engineering Company | Production of alcohols and olefins |
-
0
- DE DENDAT295203D patent/DE295203C/de active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE972657C (en) * | 1949-07-12 | 1959-09-03 | Ruhrchemie Ag | Process for the production of liquid, oxygen-containing products with a high content of esters by carbohydrate hydrogenation |
| DE923425C (en) * | 1951-01-30 | 1955-02-28 | Du Pont | Process for the production of high molecular weight hydrocarbons |
| EP0355229A1 (en) * | 1988-08-25 | 1990-02-28 | Exxon Research And Engineering Company | Production of alcohols and olefins |
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