DE2922671A1 - Chewable dentifrice compsns. - comprising chewable base and abrasive particles - Google Patents

Chewable dentifrice compsns. - comprising chewable base and abrasive particles

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Publication number
DE2922671A1
DE2922671A1 DE19792922671 DE2922671A DE2922671A1 DE 2922671 A1 DE2922671 A1 DE 2922671A1 DE 19792922671 DE19792922671 DE 19792922671 DE 2922671 A DE2922671 A DE 2922671A DE 2922671 A1 DE2922671 A1 DE 2922671A1
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Germany
Prior art keywords
dental care
agent according
calcium
chewable
cleaning agent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19792922671
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German (de)
Other versions
DE2922671C2 (en
Inventor
Heinz-Joachim Dr Kinkel
Erich Robens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle Institut eV
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Battelle Institut eV
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Application filed by Battelle Institut eV filed Critical Battelle Institut eV
Priority to DE19792922671 priority Critical patent/DE2922671C2/en
Publication of DE2922671A1 publication Critical patent/DE2922671A1/en
Application granted granted Critical
Publication of DE2922671C2 publication Critical patent/DE2922671C2/en
Expired legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24Phosphorous; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/66Enzymes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/0012Galenical forms characterised by the site of application
    • A61K9/0053Mouth and digestive tract, i.e. intraoral and peroral administration
    • A61K9/0056Mouth soluble or dispersible forms; Suckable, eatable, chewable coherent forms; Forms rapidly disintegrating in the mouth; Lozenges; Lollipops; Bite capsules; Baked products; Baits or other oral forms for animals
    • A61K9/0058Chewing gums

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Zoology (AREA)
  • Nutrition Science (AREA)
  • Physiology (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Cosmetics (AREA)

Abstract

Dentifrice compsns. comprise a chewable base material contg. abrasive particles with a particle size of 0.1-100 mu m, opt. together with surfactants, anticariogenic agents and conventional additives. Regular use of the compsns. is stated to satisfy the requirements of everyday oral hygiene. The abrasive particles can comprise inorganic and/or organic materials and are pref. present in an amt. of 0.1-20 wt.%. Suitable materials include CaCO3, Ca phosphates, Ca lactate, CaSO4, Al(OH)3, Al2O3, MgO, Mg(OH)2, Mg trisilicate or pyrophosphate, SiO2, and indigestible polysaccharides (esp. ground cellulosic components of cereal grains).

Description

Zahnpflege- und Zahnreinigungsmittel Dental care and cleaning products

=p=3=======0====r===-=============-= Die Erfindung betrifft ein Zahnpflege- und Zahnreinigungsmittel in Form einer Kaumasse bestehend aus einer kaubaren Matrix und üblichen Zusatzstoffen. = p = 3 ======= 0 ==== r === - ============= - = The invention relates to a dental care and dentifrice in the form of a gum consisting of a chewable matrix and usual additives.

Die Entstehung der Zahnkaries und der marginalen Parodontopathien steht in Zusammenhang zur dento-gingivalen Plaque.The development of dental caries and marginal periodontal disease is related to dento-gingival plaque.

Die Plaque ist eine sich ständig erneuernde Anhäufung von Speichelbestandteilen und vor allem oralen Mikroorganismen.The plaque is a constantly renewed accumulation of saliva components and especially oral microorganisms.

Durch den mikrobiellen Abbau von Zucker aus der Nahrung entstehen Gärungssäuren, die den Zahn lokal entmineralisieren und die kariöse Zerstörung einleiten. Zur vorbeugenden Behandlung der Zähne ist eine regelmäßige und gründliche Reinigung erforderlich. Hierfür werden manuelle und elektrische Zahnbürsten, Zahnstocher, Zahnseide sowie Kausubstanzen herangezogen. Die Zahnbürsten erreichen jedoch selten die wesentlichen Kariesdispositionsstellen. Die bisher bekannten Kaumassen bestehen aus einer Matrix, kariesprophylaktischen Verbindungen, z.B. Fluoriden, und üblichen Zusatzstoffen, z.B. Geschmack- und Aromastoffen. Solche Zusammensetzungen haben jedoch keine ausreichende Reinigungswirkung.Formed by the microbial breakdown of sugar from food Fermentation acids that locally demineralize the tooth and initiate carious destruction. Regular and thorough cleaning is essential for preventive treatment of the teeth necessary. Manual and electric toothbrushes, toothpicks, Dental floss and chewing substances used. Reach the toothbrushes but rarely the main caries disposition points. The previously known gum masses consist of a matrix, caries prophylactic compounds, e.g. fluorides, and common additives, e.g. flavorings and aromas. Such compositions however, do not have a sufficient cleaning effect.

Der vorliegenden Erfindung liegt daher die Aufgabe zugrunde, eine Kaumasse mit zahnschützender Wirkung zu entwickeln, die bei regelmäßigem Gebrauch auch die Erfordernisse der täglichen Mundhygiene erfüllt.The present invention is therefore based on the object of a Hardly any gum with a protective effect on teeth develop with regular use also meets the requirements of daily oral hygiene.

Es hat sich nun gezeigt, daß diese Aufgabe in technisch fortschrittlicher Weise gelöst werden kann, wenn die Kaumasse außer üblichen Zusatzstoffen reinigende Reibmittelteilchen mit einer Teilchengröße von 0,1 bis 100 Xum, oberflächenaktive Stoffe und kariesprophylaktische Substanzen enthält.It has now been shown that this task is technically more advanced Way can be solved if the gum in addition to the usual cleaning additives Friction agent particles with a particle size of 0.1 to 100 μm, surface-active Contains substances and caries prophylactic substances.

Die vorteilhaften Weiterbildungen des erfindungsgemäßen Zahnreinigungsmittels sind in den Unteransprüchen 2 bis 5 beschrieben.The advantageous developments of the tooth cleaning agent according to the invention are described in the subclaims 2 to 5.

Als kaubare Matrix werden die an sich bekannten Substanzen herangezogen, z.B. hochmolekulare, natürliche oder künstliche Harze und Wachse, Kautschuk, Piccolyt-Harz, Hartparaffine, Bienenwachs, Wollfett, Carnaubawachs, Walrat und Candelillawachs. Bei den üblichen Zusatzstoffen handelt es sich im wesentlichen um Geschmack- und Aromastoffe. Als Geschmacksstoffe können Zuckeraustauschstoffe, wie Sorbit, und Süßstoffe,wie Saccharin, verwendet werden. Als Aromastoffe sind z.B. Pfefferminzöl, Spearmintöl, Anisöl, Eucalyptusöl, Gewürznelkenöl, Vanillearoma und Zimtaroma geeignet.The substances known per se are used as the chewable matrix, e.g. high molecular weight, natural or artificial resins and waxes, rubber, Piccolyt resin, Hard paraffins, beeswax, wool fat, carnauba wax, whale rat and candelilla wax. The usual additives are essentially around Flavors and aromas. Sugar substitutes such as Sorbitol, and sweeteners such as saccharin can be used. The flavoring substances are e.g. Peppermint oil, spearmint oil, anise oil, eucalyptus oil, clove oil, vanilla flavor and Cinnamon flavor suitable.

Das erfindungsgemäße Zahnreinigungsmittel enthält von 0,1 bis 20 Gew.-% anorganische oder organische Reibmittelteilchen mit einer Teilchengröße von 0,1 bis 100 /um. Die anorganischen Reibmittelteilchen können aus Calciumcarbonat, Dicalciumphosphat, Tricalciumphosphat, Calciumpyrophosphat Calciumlactat, Calciumsulfat, Aluminiumhydroxid, Aluminiumoxid, Magnesiumoxid, Magnesiumhydroxid, Magnesiumtrisilicat, Magnesiumcarbonat, Magnesiumpyrophosphat und Siliciumdioxid bestehen. Als organische Reibmittelteilchen können unverdauliche Polysaccharide, insbesondere gemahlene, cellulosehaltige Gerüstbestandteile aus Getreidekörnern verwendet werden. Diese Reibmittelteilchen bewirken bei der Kaubewegung eine mechanische Reinigung des Zahnes, können aber auch durch Auflösung im Speichel zahnprophylaktisch wirken. Gegebenenfalls werden auch kariesprophylaktische Substanzen in die Kaumasse einverleibt. Hierfür sind z.B. lösliche Calciumphosphate, wie Dicalciumphosphat, Fluoride wie Zinnfluorid, Aminfluorid, Dinatriummonofluorophosphat, Harnstoff, Pepsin, Pankreatin,Papain und Lipase geeignet. Vorteilhaft sind vor allem lösliche Calciumphosphate, insbesondere das Dicalciumphosphat. Diese prophylaktischen Zu- sätze weisen zunächst eine Scheuerwirkung auf. Nach ihrer Auflösung im Speichel während der üblichen durchschnittlichen Kauzeit von etwa 10 Minuten wirken sie karieshemmend (H.R. Mühlemann, Schweizerische medizinische Wochenschrift 91, 1961, 8, 221-224; H.W. Cremer, W. Büttner, Ernährungsumschau, 9, 68-72, 1962).The tooth cleaning agent according to the invention contains from 0.1 to 20% by weight inorganic or organic friction agent particles with a particle size of 0.1 up to 100 / µm. The inorganic friction agent particles can be made from calcium carbonate, dicalcium phosphate, Tricalcium phosphate, calcium pyrophosphate, calcium lactate, calcium sulfate, aluminum hydroxide, Aluminum oxide, magnesium oxide, magnesium hydroxide, magnesium trisilicate, magnesium carbonate, Magnesium pyrophosphate and silicon dioxide are made up. As organic friction agent particles can indigestible polysaccharides, especially ground, cellulose-containing structural components made from cereal grains. These friction agent particles cause the Chewing movement is a mechanical cleaning of the tooth, but can also be done by dissolving it have a tooth prophylactic effect in the saliva. If necessary, prophylactic measures against caries are also used Substances incorporated into the chewing mass. For this purpose e.g. soluble calcium phosphates, such as dicalcium phosphate, fluorides such as tin fluoride, amine fluoride, disodium monofluorophosphate, Urea, pepsin, pancreatin, papain and lipase are suitable. Are especially beneficial soluble calcium phosphates, especially dicalcium phosphate. This prophylactic To- sets initially have an abrasive effect. After their dissolution in saliva during the usual average chewing time of about 10 minutes they have a caries-inhibiting effect (H.R. Mühlemann, Swiss Medical Weekly 91, 1961, 8, 221-224; H.W. Cremer, W. Büttner, Ernahrungumschau, 9, 68-72, 1962).

Die Reinigungswirkung der Reibmittelteilchen kann unterstützt werden durch Verwendung von verträglichen Tensiden, wie Natriumlaurylsulfat, Dinatriumoctylsulfosuccinat, Natriumalkylsulfoacetat, Natriumlaurylsarkosinat, Sorbitanester, Diammoniumphosphat, Borax, Glykokoll, sowie enzymatisch wirkende Reinigungsmittel.The cleaning effect of the friction agent particles can be supported by using compatible surfactants such as sodium lauryl sulfate, disodium octyl sulfosuccinate, Sodium alkyl sulfoacetate, sodium lauryl sarcosinate, sorbitan ester, diammonium phosphate, Borax, glycocolla and enzymatic cleaning agents.

Die Herstellung des erfindungsgemäßen Zahnreinigungsmittels kann in an sich bekannter Weise erfolgen. Beispielsweise werden die Bestandteile in gelöster Form vermischt und die Lösungsmittel anschließend verdampft. Ferner ist es möglich, daß die pulverförmigen Bestandteile durch Kneten der Kaumasse einverleibt werden.The tooth cleaning agent according to the invention can be produced in take place in a known manner. For example, the ingredients are dissolved in Form mixed and the solvent then evaporated. It is also possible that the powdery ingredients are incorporated by kneading the chewing mass.

Claims (5)

Patentansprüche 1. Zahnpflege- und Zahnreinigungsmittel in Form einer Kaumasse bestehend aus einer kaubaren Matrix und üblichen Zusatzstoffen, dadurch gekennzeichnet, daß es reinigende Reibmittelteilchen mit einer Teilchengröße von 0,1 bis 100 /um sowie gegebenenfalls oberflächenaktive Stoffe und kariesprophylaktische Substanzen enthält. Claims 1. Dental care and cleaning agents in the form of a The chewing mass consists of a chewable matrix and the usual additives characterized in that it contains detergent abrasive particles with a particle size of 0.1 to 100 μm and optionally surface-active substances and caries prophylactic Contains substances. 2. Zahnpflege- und Zahnreinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß die Reibmittelteilchen aus anorganischen und/oder organischen Substanzen bestehen und in einer Menge von 0,1 bis 20 Gew.-% bezogen auf das Gesamtgewicht enthalten sind.2. Dental care and tooth cleaning agent according to claim 1, characterized in that that the friction agent particles consist of inorganic and / or organic substances and contained in an amount of 0.1 to 20% by weight based on the total weight are. 3. Zahnpflege- und Zahnreinigungsmittel nach Anspruch 1 und 2, dadurch gekennzeichnet, daß als Reibmittelteilchen Calciumcarbonat, Dicalciumphosphat, Tricalciumphosphat, Calciumpyrophosphat, Calciumlactat, Calciumsulfat, Aluminiumhydroxid, Aluminiumoxid, Magnesiumoxid, Magnesiumhydroxid, Magnesiumtrisilicat, Magnesiumpyrophosphat, Siliciumdioxid, unverdauliche Polysaccharide,insbesondere gemahlene, cellulosehaltige Gerüstbestandteile aus Getreidekörnern verwendet werden.3. Dental care and tooth cleaning agent according to claim 1 and 2, characterized characterized in that calcium carbonate, dicalcium phosphate, tricalcium phosphate, Calcium pyrophosphate, calcium lactate, calcium sulfate, aluminum hydroxide, aluminum oxide, Magnesium oxide, magnesium hydroxide, magnesium trisilicate, magnesium pyrophosphate, silicon dioxide, indigestible polysaccharides, in particular ground, cellulose-containing structural components made from cereal grains. 4. Zahnpflege- und Zahnreinigungsmittel nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß als oberflächenaktive Stoffe Natriumlaurylsulfat, Dinatriumoctylsulfosuccinat, Natriumalkylsulfoacetat, Natriumlaurylsarkosinat, Sorbitanester, Diammoniumphophat, Borax, Glykokoll, sowie enzymatisch wirkende Verbindungen verwendet werden.4. Dental care and tooth cleaning agent according to one of claims 1 up to 3, characterized in that sodium lauryl sulfate, Disodium octyl sulfosuccinate, sodium alkyl sulfoacetate, sodium lauryl sarcosinate, sorbitan ester, Diammoniumphophat, Borax, Glykocoll, as well as enzymatically acting compounds are used will. 5. Zahnpflege- und Zahnreinigungsmittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß als kariesprophylaktische Mittel lösliche Calciumphosphate, wie Dicalciumphosphat, Fluoride, wie Zinnfluorid, Aminfluorid, Dinatriummonofluorophosphat, Harnstoff, Pepsin, Pankreatin, Papain und Lipase verwendet werden.5. Dental care and tooth cleaning agent according to one of claims 1 up to 4, characterized in that soluble calcium phosphates, such as dicalcium phosphate, fluorides such as tin fluoride, amine fluoride, disodium monofluorophosphate, Urea, pepsin, pancreatin, papain and lipase can be used.
DE19792922671 1979-06-02 1979-06-02 Dental care and cleaning products Expired DE2922671C2 (en)

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DE2922671C2 DE2922671C2 (en) 1982-08-19

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2922671A1 (en) 1979-06-02 1980-12-04 Battelle Institut E V Chewable dentifrice compsns. - comprising chewable base and abrasive particles
US4446135A (en) * 1982-06-07 1984-05-01 Sterling Drug Inc. Chewable antacid tablets
US4915936A (en) * 1988-10-31 1990-04-10 United States Gypsum Company Dental hygiene composition for reducing periodontal disease
EP0396226A2 (en) * 1989-05-02 1990-11-07 ADM Agri-Industries, Ltd. Glass-like polysaccharide abrasive grit
US5013728A (en) * 1990-05-04 1991-05-07 Colgate - Palmolive Company Composition for treating osteoporosis and hormonal imbalance
WO1995034275A1 (en) * 1994-06-16 1995-12-21 The Boots Company Plc Oral hygiene composition
US6159257A (en) * 1998-10-21 2000-12-12 Adm Agri-Industries, Ltd. Water-resistant, glass-like, polysaccharide abrasive grits and method of making same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2320083A1 (en) * 1975-08-07 1977-03-04 Sigma Tau Ind Farmaceuti Medicated chewing gum - contg. e.g. cetylpyridinium chloride as antiseptic and pref. guaiazulene decongestant
DE2922671A1 (en) 1979-06-02 1980-12-04 Battelle Institut E V Chewable dentifrice compsns. - comprising chewable base and abrasive particles

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2320083A1 (en) * 1975-08-07 1977-03-04 Sigma Tau Ind Farmaceuti Medicated chewing gum - contg. e.g. cetylpyridinium chloride as antiseptic and pref. guaiazulene decongestant
DE2922671A1 (en) 1979-06-02 1980-12-04 Battelle Institut E V Chewable dentifrice compsns. - comprising chewable base and abrasive particles

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2922671A1 (en) 1979-06-02 1980-12-04 Battelle Institut E V Chewable dentifrice compsns. - comprising chewable base and abrasive particles
US4446135A (en) * 1982-06-07 1984-05-01 Sterling Drug Inc. Chewable antacid tablets
US4915936A (en) * 1988-10-31 1990-04-10 United States Gypsum Company Dental hygiene composition for reducing periodontal disease
EP0396226A2 (en) * 1989-05-02 1990-11-07 ADM Agri-Industries, Ltd. Glass-like polysaccharide abrasive grit
FR2646621A1 (en) * 1989-05-02 1990-11-09 Ogilvie Flour Mills Co Ltd GLASS-LIKE POLYSACCHARIDE, PROCESS FOR ITS PREPARATION AND USE AS ABRASIVE PARTICLES
EP0396226A3 (en) * 1989-05-02 1991-12-27 ADM Agri-Industries, Ltd. Glass-like polysaccharide abrasive grit
US5360903A (en) * 1989-05-02 1994-11-01 Adm Agri-Industries, Ltd. Glass-like polysaccharide abrasive grit
US5367068A (en) * 1989-05-02 1994-11-22 Adm Agri-Industries, Ltd. Glass-like polysaccharide abrasive grit
US5013728A (en) * 1990-05-04 1991-05-07 Colgate - Palmolive Company Composition for treating osteoporosis and hormonal imbalance
WO1995034275A1 (en) * 1994-06-16 1995-12-21 The Boots Company Plc Oral hygiene composition
US6159257A (en) * 1998-10-21 2000-12-12 Adm Agri-Industries, Ltd. Water-resistant, glass-like, polysaccharide abrasive grits and method of making same

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