DE291456C - - Google Patents
Info
- Publication number
- DE291456C DE291456C DENDAT291456D DE291456DA DE291456C DE 291456 C DE291456 C DE 291456C DE NDAT291456 D DENDAT291456 D DE NDAT291456D DE 291456D A DE291456D A DE 291456DA DE 291456 C DE291456 C DE 291456C
- Authority
- DE
- Germany
- Prior art keywords
- wool
- parts
- salts
- acid
- aminooxynaphthalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 210000002268 Wool Anatomy 0.000 claims description 8
- 150000001879 copper Chemical class 0.000 claims description 5
- FCZNYKVABFECER-UHFFFAOYSA-N 2-aminooxynaphthalene-1-sulfonic acid Chemical class C1=CC=CC2=C(S(O)(=O)=O)C(ON)=CC=C21 FCZNYKVABFECER-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 241000790917 Dioxys <bee> Species 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 3
- 239000010446 mirabilite Substances 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- JBUKJLNBQDQXLI-UHFFFAOYSA-N Sodium perborate Chemical compound [Na+].[Na+].O[B-]1(O)OO[B-](O)(O)OO1 JBUKJLNBQDQXLI-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 244000061775 Olea africana Species 0.000 description 1
- 235000002852 Olea africana Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241001584775 Tunga penetrans Species 0.000 description 1
- 230000002378 acidificating Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- -1 chromium potassium Chemical compound 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009963 fulling Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/10—Metal complexes of organic compounds not being dyes in uncomplexed form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/008—Preparing dyes in situ
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
■KAISERLICHES■ IMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 291456 KLASSE 8 m. GRUPPE- M 291456 CLASS 8 w. GROUP
Es wurde die bemerkenswerte Beobachtung gemacht, daß man durch Behandeln der Wollfaser mit Dioxy- bzw. Aminooxynaphtalinsulfosäuren und Kupfersalzen mit oder ohne Anwendung von anderen Metallsalzen wertvolle Töne, besonders wertvolle Khakinuancen, erhalten kann. Die so erzeugten Töne sind sehr lichtecht, echt gegen Wäsche und Walke. Auch ist das Egalisierungsvermögen dieser Produkte sehr gut. Die Faser ist außerdem gut durchgefärbt und die Färbung reibecht.The remarkable observation was made that by treating the wool fiber with dioxy or aminooxynaphthalene sulfonic acids and copper salts with or without the use of other metal salts are valuable Tones, especially valuable khaki nuances. The sounds so generated are very lightfast, resistant to laundry and fulling. The ability to equalize is also this Products very well. The fiber is also well dyed and the dye is rub-resistant.
Man kann das Verfahren auch unter Zusatz von anderen Salzen neben den Kupfersalzen ausführen und zweckmäßig auch oxydierende Stoffe, wie Wasserstoffsuperoxyd oder Natriumperborat, der Flotte zusetzen.The process can also be used with the addition of salts other than the copper salts carry out and expediently also oxidizing substances such as hydrogen peroxide or sodium perborate, add to the fleet.
Die verwendeten Produkte lassen sich auch, wie gefunden wurde, mit den verschiedensten sauren oder Chromfarbstoffen kombinieren.The products used can also be, as has been found, with the most varied combine acidic or chrome dyes.
Von dem Verfahren der Patentschrift 157489 unterscheidet sich das vorliegende wesentlich dadurch, daß danach keine Körper, wie Basen oder Phenole oxydiert, sondern Dioxy- und Aminooxynaphtalinsulfosäuren mit Kupfersalzen behandelt werden, wobei die Verwendung eines Oxydationsmittels nicht nötig ist. Freilich kann auch hier die Operation in Gegenwart anderer Salze oder auch unter Zusatz von Oxydationsmitteln ausgeführt werden. Die Erfindungsidee beruht jedoch auf der Behandlung von Dioxy- und Aminooxynaphtalinsulfosäuren mit Kupfersalzen. Daß dabei FarbThe present method differs significantly from the method of patent specification 157489 in that afterwards no bodies, such as bases or phenols, are oxidized, but dioxy and Aminooxynaphthalene sulfonic acids are treated with copper salts, with the use an oxidizing agent is not necessary. Of course, the operation can also be carried out here in the present other salts or with the addition of oxidizing agents. the However, the idea of the invention is based on the treatment of dioxy- and aminooxynaphthalene sulfonic acids with copper salts. That color
stoffbildung stattfinden und man derart zu wertvollen Tönen gelangen würde, war in keiner Weise vorauszusehen.there was no formation of matter and one would come to such valuable tones Way to foresee.
ioo Teile Wolle, gleichviel ob loses Material oder Stückware, werden in einem Bottich oder Jigger bei Anwesenheit von:100 parts of wool, regardless of whether it is loose material or piece goods, are put in a vat or Jigger in the presence of:
3 Teilen i-Amino-8-naphtol-4-sulfosäure, io - Glaubersalz,
6 - Essigsäure oder Ameisensäure, ι Teil Schwefelsäure,3 parts of i-amino-8-naphthol-4-sulfonic acid, io - Glauber's salt,
6 - acetic acid or formic acid, ι part sulfuric acid,
2 Teilen Kupfervitriol2 parts of blue vitriol
eine Stunde gekocht. Die Wolle wird dabei braunolive angefärbt.cooked for an hour. The wool is dyed brown olive.
ioo Teile Wolle werden eine Stunde gekocht bei Anwesenheit von:100 parts of wool are boiled for one hour in the presence of:
3 Teilen i-Amino-8-naphtol-5-sulfosäure, . io - Glaubersalz,3 parts of i-amino-8-naphthol-5-sulfonic acid,. io - Glauber's salt,
2 - Oxalsäure, 2 - Kupfervitriol,2 - oxalic acid, 2 - vitriol,
ι Teil Natriumperborat, ι - Schwefelsäure.ι part of sodium perborate, ι - sulfuric acid.
Die Wolle nimmt eine bläulichbraune Farbnuance an.The wool takes on a bluish brown shade.
100 Teile Wolle werden eine Stunde gekocht in Gegenwart von:100 parts of wool are boiled for one hour in the presence of:
3 Teilen 2 · 8-dioxynaphtalin-6-sulfosaurem3 parts of 2 x 8-dioxynaphthalene-6-sulfonic acid
Natrium, |Sodium, |
- Glaubersalz, :- Glauber's salt,:
6 - Essigsäure,6 - acetic acid,
2 - Kupfervitriol,2 - blue vitriol,
V2 Teil Chromkali, jV 2 part chromium potassium, j
ι - Schwefelsäure. Iι - sulfuric acid. I.
Man erhält eine grünlichgelbe Khakinuance, jA greenish-yellow khakinuance is obtained, j
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE291456C true DE291456C (en) |
Family
ID=546335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT291456D Active DE291456C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE291456C (en) |
-
0
- DE DENDAT291456D patent/DE291456C/de active Active
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