DE289243C - - Google Patents
Info
- Publication number
- DE289243C DE289243C DENDAT289243D DE289243DA DE289243C DE 289243 C DE289243 C DE 289243C DE NDAT289243 D DENDAT289243 D DE NDAT289243D DE 289243D A DE289243D A DE 289243DA DE 289243 C DE289243 C DE 289243C
- Authority
- DE
- Germany
- Prior art keywords
- salts
- raw
- sulfonic acids
- nitro
- aromatic hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000003460 sulfonic acids Chemical class 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000002360 explosive Substances 0.000 claims description 3
- 150000007529 inorganic bases Chemical class 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- 150000002828 nitro derivatives Chemical class 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- UJOBWOGCFQCDNV-UHFFFAOYSA-N Carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- OXNIZHLAWKMVMX-UHFFFAOYSA-N Picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 2
- 230000002421 anti-septic Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- PNFSYNAUAPBVGF-UHFFFAOYSA-M sodium;phenyl sulfate Chemical compound [Na+].[O-]S(=O)(=O)OC1=CC=CC=C1 PNFSYNAUAPBVGF-UHFFFAOYSA-M 0.000 description 2
- 229950002929 trinitrophenol Drugs 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N Anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 1
- 241000031711 Cytophagaceae Species 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L Zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- -1 cresol salts Chemical class 0.000 description 1
- 125000000853 cresyl group Chemical class C1(=CC=C(C=C1)C)* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- NLLHQLPNIQGOFP-UHFFFAOYSA-N naphthalene-1-sulfonic acid;zinc Chemical compound [Zn].C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NLLHQLPNIQGOFP-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003171 wood protecting agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/38—Aromatic compounds
- B27K3/42—Aromatic compounds nitrated, or nitrated and halogenated
Description
KAISERLICHES"./.IMPERIAL "./.
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- JVl 289243 KLASSE 38 h. GRUPPE- JVl 289243 CLASS 38 h. GROUP
Patentiert im Deutschen Reiche vom 8. Februar 1914 ab.Patented in the German Empire on February 8, 1914.
Die in neuerer Zeit für die Zwecke der Holzkonservierung in Vorschlag gebrachten, mit anorganischen Basen abgesättigten Mono-, Di- und Polynitroverbindungen, insbesondereThose that have recently been proposed for the purpose of wood conservation, mono-, di- and polynitro compounds saturated with inorganic bases, in particular
.'5 die Di- und Trinitrophenol- und -kresolsalze, haben bekanntlich den Nachteil, daß sie beim Eintrocknen stark zur Explosivität neigen..'5 the di- and trinitrophenol and cresol salts, as is known, have the disadvantage that they are used in Drying out has a strong tendency to be explosive.
Diesen Übelstand hat man dadurch zu beseitigen versucht, daß man den genanntenAttempts have been made to remedy this deficiency by doing the aforementioned
ίο Nitroverbindungen indifferente Stoffe, wie Glyzerin, Seife oder Sulfitzelluloseablauge, die als Hauptbestandteil ligninsulfosaure Salze enthält, zusetzte.ίο Nitro compounds inert substances, such as Glycerine, soap or sulphite cellulose waste liquor, which contains lignosulphonic acid salts as the main component, added.
Für die Zwecke der Holzkonservierung warFor the purpose of wood preservation it was
:i5 damit jedoch ein neuer Nachteil in der Richtung verbunden, daß durch den Zusatz dieser in fungicider Hinsicht völlig unwirksamen Stoffe die antiseptische Kraft der zur Anwendung gelangten Nitroverbindungen nicht unerheblich geschwächt wurde.: i5, however, a new disadvantage in the direction connected that by the addition of these in fungicider terms completely ineffective Substances, the antiseptic power of the nitro compounds used is not insignificant was weakened.
Dieser Nachteil kann nun nach vorliegender Erfindung in der Weise vermieden werden, daß man die genannten Nitroverbindungen mit Stoffen versetzt, die sowohl die Fähigkeit besitzen, die Explosivität der Nitroverbindungen aufzuheben oder herabzumindern, als auch gleichzeitig stark antiseptisch zu wirken. This disadvantage can now be avoided according to the present invention in such a way that that the nitro compounds mentioned are mixed with substances that have both the ability have the ability to cancel or reduce the explosiveness of the nitro compounds, as well as having a strong antiseptic effect at the same time.
Als geeignet hierzu haben sich die für diesen Zweck noch nicht in Vorschlag gebrachten sulfosäuren Salze aromatischer Kohlenwasserstoffe und ihrer Derivate (Halogen-, Hydroxyl-, Nitroverbindungen usw.) sowie Mischungen der genannten Salze erwiesen. InThose that have not yet been proposed for this purpose have proven to be suitable for this purpose sulfonic acids Salts of aromatic hydrocarbons and their derivatives (halogen, hydroxyl, Nitro compounds etc.) as well as mixtures of the salts mentioned. In
■35 Betracht kommen beispielsweise ■ naphthalin--· sulfosaures Zink, Calcium, Magnesium oder phenolsulfosaures Natrium, Calcium usw. bzw. die bei der Darstellung der Sulfosäuren aus Rohnaphthalin, Rohantrazen, Rohphenanthren, Rohkarbazol, Rohphenol, Rohkresol usw. sowie Gemischen, wie sie im Teeröl vorliegen, durch Absättigen mit Zinkoxyd, Magnesia, Natronlauge usw. direkt erhaltenen Lösungen.■ 35 Consider, for example, ■ naphthalene-- · Zinc sulphate, calcium, magnesium or sodium phenol sulphate, calcium etc. or in the representation of sulfonic acids from raw naphthalene, raw anthracene, raw phenanthrene, Raw carbazole, raw phenol, raw cresol, etc. as well as mixtures such as those found in tar oil, solutions obtained directly by saturation with zinc oxide, magnesia, caustic soda, etc.
Die Mischung erfolgt derart, daß beispielsweise auf ι Teil Di- oder Trinitrophenol- oder -kresolnatrium ι bis io Teile naphthalinsulfosaures Zink, phenolsulfosaures Natrium oder Gemische aller dieser Stoffe zugesetzt werden. Soll die Explosivität nicht aufgehoben, sondern nur vermindert werden, so wird der Zusatz von sulfosäuren Salzen aromatischer Kohlenwasserstoffe und ihrer Derivate entsprechend eingeschränkt.The mixing is carried out in such a way that, for example, on ι part of di- or trinitrophenol or -cresol sodium ι to 10 parts of naphthalenesulfonic acid Zinc, sodium phenol sulfate or mixtures of all of these substances can be added. If the explosiveness is not to be abolished, but only reduced, then the addition is of sulfonic acids salts of aromatic hydrocarbons and their derivatives accordingly restricted.
Gegenüber der Patentschrift 219942, welche die Verwendung hydroxylfreier Nitrokörper, die keine Salze zu bilden vermögen, vorsieht, und gegenüber der Patentschrift 219893, welche mit organischen Basen abgesättigte Nitrokörper benutzt, unterscheidet sich vorliegendes Verfahren dadurch, daß dort Nitrokörper verwendet werden, die nach den Angaben der Patentschriften schon an und für sich unexplosiv sind, so daß der Zusatz eines anderen Holzkonservierungsmittels keine weitere explosionshemmende Wirkung ausüben kann, während im vorliegenden Falle mit anorganischen Basen abgesättigte Nitroverbindungen in Frage kommen, die im Gegensatz zu den vorhin genannten Verbindungen stark explosiv :-sind -und- d^irch den Zusatz der sulfosäurenCompared to patent 219942, which provides for the use of hydroxyl-free nitro bodies that are unable to form salts, and compared to patent 219893, which uses nitro bodies saturated with organic bases, the present process differs in that there are used nitro bodies which are specified according to the information the patents are already on and unexplosiv for themselves, so that the addition of another wood preservative can exert no further explosion-inflammatory effect, while coming in this case with inorganic bases dangling nitro compounds in question, which, unlike the previously mentioned compounds highly explosive: -are -and- d ^ irch the addition of sulfonic acids
Salze aromatischer Kohlenwasserstoffe und ihrer Derivate erst explosionssicher gemacht werden sollen.Salts of aromatic hydrocarbons and their derivatives can only be made explosion-proof should.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE289243C true DE289243C (en) |
Family
ID=544289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT289243D Active DE289243C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE289243C (en) |
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0
- DE DENDAT289243D patent/DE289243C/de active Active
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