DE2860140D1 - Zeolite zsm-11, a method for preparing it, and a process of catalytic conversion using a catalyst comprising it - Google Patents

Zeolite zsm-11, a method for preparing it, and a process of catalytic conversion using a catalyst comprising it

Info

Publication number
DE2860140D1
DE2860140D1 DE7878300219T DE2860140T DE2860140D1 DE 2860140 D1 DE2860140 D1 DE 2860140D1 DE 7878300219 T DE7878300219 T DE 7878300219T DE 2860140 T DE2860140 T DE 2860140T DE 2860140 D1 DE2860140 D1 DE 2860140D1
Authority
DE
Germany
Prior art keywords
catalyst
preparing
catalytic conversion
zeolite zsm
zsm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE7878300219T
Other languages
German (de)
English (en)
Inventor
Louis Dean Rollmann
Ernest William Valyocsik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Application granted granted Critical
Publication of DE2860140D1 publication Critical patent/DE2860140D1/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/365—Type ZSM-8; Type ZSM-11; ZSM 5/11 intermediate
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/222—Catalytic processes not covered by C07C5/23 - C07C5/31 with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/29—MEL, e.g. ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE7878300219T 1977-08-01 1978-08-01 Zeolite zsm-11, a method for preparing it, and a process of catalytic conversion using a catalyst comprising it Expired DE2860140D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/820,992 US4108881A (en) 1977-08-01 1977-08-01 Synthesis of zeolite ZSM-11

Publications (1)

Publication Number Publication Date
DE2860140D1 true DE2860140D1 (en) 1980-12-11

Family

ID=25232222

Family Applications (1)

Application Number Title Priority Date Filing Date
DE7878300219T Expired DE2860140D1 (en) 1977-08-01 1978-08-01 Zeolite zsm-11, a method for preparing it, and a process of catalytic conversion using a catalyst comprising it

Country Status (9)

Country Link
US (1) US4108881A (enrdf_load_stackoverflow)
EP (1) EP0000669B1 (enrdf_load_stackoverflow)
JP (1) JPS5452699A (enrdf_load_stackoverflow)
AU (1) AU515825B2 (enrdf_load_stackoverflow)
CA (1) CA1119146A (enrdf_load_stackoverflow)
DE (1) DE2860140D1 (enrdf_load_stackoverflow)
IT (1) IT1097569B (enrdf_load_stackoverflow)
NZ (1) NZ188025A (enrdf_load_stackoverflow)
ZA (1) ZA784360B (enrdf_load_stackoverflow)

Families Citing this family (52)

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DE2830787B2 (de) * 1978-07-13 1981-02-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von stickstoffhaltigen kirstallinen Metallsilikaten mit Zeolithstniktur
BR8000226A (pt) * 1979-01-15 1980-10-07 Mobil Oil Corp Zeolito zsm-11, processo para sua preparacao, e processo para conversao de uma carga organica
NZ192909A (en) * 1979-02-21 1982-03-30 Mobil Oil Corp Crystalline zeolite designated zsm-48 useful as organic conversion catalyst
DE2909929A1 (de) * 1979-03-14 1980-09-25 Basf Ag Verfahren zur herstellung eines zeolithen vom strukturtyp zsm-5
US4229424A (en) * 1979-04-09 1980-10-21 Mobil Oil Corporation Crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
US4423021A (en) * 1979-08-08 1983-12-27 Mobil Oil Corporation Method of preparing silico-crystal ZSM-48
US4259306A (en) * 1979-10-15 1981-03-31 Mobile Oil Corporation Synthesis of ZSM-39
EP0031675B1 (en) * 1979-12-31 1983-02-09 Mobil Oil Corporation Conversion of olefin containing mixtures to gasoline
DE3006471A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
CA1167071A (en) * 1980-03-15 1984-05-08 William J. Ball Process for the production of aromatic hydrocarbons
US4324940A (en) * 1980-04-09 1982-04-13 Mobil Oil Corporation Shape selective acid catalyzed reactions of olefins over crystalline zeolites
EP0042226B1 (en) * 1980-06-12 1984-08-08 Imperial Chemical Industries Plc Zeolite eu-1
AU542052B2 (en) * 1980-06-12 1985-02-07 Imperial Chemical Industries Ltd. Zeoliteeuz and its use as a catalyst
JPS577820A (en) * 1980-06-18 1982-01-16 Mitsubishi Heavy Ind Ltd Novel crystalline silicate and its manufacture
DE3031557C2 (de) * 1980-08-21 1986-05-22 Basf Ag, 6700 Ludwigshafen Kristalliner Borsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung
US4371457A (en) * 1980-10-29 1983-02-01 Mobil Oil Corporation Zeolites modified with group VA metals
DE3172377D1 (en) 1980-12-12 1985-10-24 Exxon Research Engineering Co Composite zeolite
DE3268503D1 (en) * 1981-05-20 1986-02-27 Ici Plc Zeolites
CA1185953A (en) * 1981-06-30 1985-04-23 Muin S. Haddad Method for manufacture of ams-1b crystalline borosilicate molecular sieve
NZ202099A (en) * 1981-10-21 1986-07-11 Ici Plc Preparation of zeolite nu-10
JPS58219130A (ja) * 1982-06-14 1983-12-20 シエブロン・リサ−チ・コンパニ− ベンゼンの合成法
US4495166A (en) * 1982-07-19 1985-01-22 Mobil Oil Corporation Synthesis of ZSM-5 utilizing a mixture of quaternary ammonium ions and amines
US4481173A (en) * 1982-11-22 1984-11-06 Mobil Oil Corporation Manufacture of low sodium zeolite
DE3361440D1 (en) * 1982-12-30 1986-01-16 Asahi Chemical Ind A crystalline aluminosilicate, a process for producing the same, and a catalyst comprising the crystalline aluminosilicate
US4732747A (en) * 1983-04-11 1988-03-22 The Dow Chemical Company Magnesium silicate compositions and process for making
JPH0739357B2 (ja) * 1983-10-28 1995-05-01 三菱化学株式会社 ジメチルナフタレン類の異性化方法
GB2167052B (en) * 1984-11-17 1988-09-07 Laporte Industries Ltd Synthetic crystalline molecular sieve materials and a method for their preparation
US4894212A (en) * 1987-07-20 1990-01-16 Mobil Oil Corp. Synthesis of crystalline silicate ZSM-11
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
US5213786A (en) * 1991-12-20 1993-05-25 Mobil Oil Corp. Synthesis of crystalline silicate ZSM-11
DE4323774A1 (de) * 1993-07-15 1995-02-09 Basf Ag Hohlkugelartig agglomerierte Pentasilzeolithe
EP0721427A1 (en) * 1993-10-01 1996-07-17 Chevron U.S.A. Inc. Zeolite zsm-11 and a process for preparing zeolite zsm-11 using a 3,5-dimethylpiperidinium templating agent
US5840264A (en) * 1994-08-22 1998-11-24 Board Of Trustees Operating Michigan State University Crystalline inorganic oxide compositions prepared by neutral templating route
US6162414A (en) 1994-08-22 2000-12-19 Board Of Trustees Operating Michigan State University Quasi crystalline inorganic oxide compositions prepared by neutral templating route
US5785946A (en) * 1994-08-22 1998-07-28 Board Of Trustees Operating Michigan State University Crystalline inorganic oxide compositions prepared by neutral templating route
CN1041399C (zh) * 1994-12-30 1998-12-30 中国石油化工总公司 一种含稀土的结晶硅酸铝沸石
US5622684A (en) * 1995-06-06 1997-04-22 Board Of Trustees Operating Michigan State University Porous inorganic oxide materials prepared by non-ionic surfactant templating route
US5800799A (en) * 1996-05-02 1998-09-01 Board Of Trustees Operating Michigan State University Porous inorganic oxide materials prepared by non-ionic surfactant and fluoride ion
CN1048655C (zh) * 1996-06-24 2000-01-26 中国石油化工总公司 一种烷基化催化剂及其应用
US6027706A (en) * 1998-05-05 2000-02-22 Board Of Trustees Operating Michigan State University Porous aluminum oxide materials prepared by non-ionic surfactant assembly route
US6277355B1 (en) 1999-07-13 2001-08-21 Exxonmobil Chemical Patents Inc. Synthesis of ZSM-5 and ZSM-11
US6649083B1 (en) 1999-08-12 2003-11-18 Board Of Trustees Of Michigan State University Combined porous organic and inorganic oxide materials prepared by non-ionic surfactant templating route
DE19955557A1 (de) * 1999-11-18 2001-05-23 Basf Ag Oxidischer Katalysator mit Zeolithstruktur und Verfahren zu dessen Herstellung
FR2914635B1 (fr) 2007-04-05 2009-11-20 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mel
RU2346930C1 (ru) * 2007-11-08 2009-02-20 Государственное образовательное учреждение высшего профессионального образования "Российский химико-технологический университет им. Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) Способ получения мононитротолуола с повышенным содержанием п-изомера
CN106672999B (zh) * 2015-11-09 2018-10-23 中国石油化工股份有限公司 含卤素和稀土金属的zsm-11/zsm-5复合分子筛的合成方法及其合成的复合分子筛
CN106673002B (zh) * 2015-11-09 2018-11-20 中国石油化工股份有限公司 Zsm-11/zsm-5复合分子筛的合成方法及其合成的复合分子筛
CN106673000B (zh) * 2015-11-09 2018-10-23 中国石油化工股份有限公司 含稀土金属的zsm-11分子筛的合成方法及其合成的分子筛
CN106673001B (zh) * 2015-11-09 2018-11-20 中国石油化工股份有限公司 Zsm-11分子筛的合成方法及其合成的zsm-11分子筛
CN106944080B (zh) * 2016-01-07 2018-11-06 中国石油化工股份有限公司 一种用于乙烷氧化脱氢制乙烯催化剂的制备方法
US20220134318A1 (en) 2019-03-29 2022-05-05 Exxonmobil Chemical Patents Inc. Mel-Type Zeolite for Converting Aromatic Hydrocarbons, Process for Making and Catalytic Composition Comprising Said Zeolite
KR102747277B1 (ko) 2019-03-29 2024-12-27 엑손모빌 케미칼 패턴츠 인코포레이티드 신규한 제올라이트, 이의 제조 방법, 및 방향족 탄화수소의 전환에서의 이의 용도

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Also Published As

Publication number Publication date
CA1119146A (en) 1982-03-02
EP0000669B1 (en) 1980-09-03
ZA784360B (en) 1980-03-26
IT1097569B (it) 1985-08-31
IT7826376A0 (it) 1978-08-01
NZ188025A (en) 1980-11-28
AU515825B2 (en) 1981-04-30
EP0000669A1 (en) 1979-02-07
AU3848978A (en) 1980-02-07
JPS5452699A (en) 1979-04-25
US4108881A (en) 1978-08-22
JPS6215488B2 (enrdf_load_stackoverflow) 1987-04-08

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