DE274347C - - Google Patents
Info
- Publication number
- DE274347C DE274347C DENDAT274347D DE274347DA DE274347C DE 274347 C DE274347 C DE 274347C DE NDAT274347 D DENDAT274347 D DE NDAT274347D DE 274347D A DE274347D A DE 274347DA DE 274347 C DE274347 C DE 274347C
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen peroxide
- boric acid
- borax
- solutions
- perborates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004327 boric acid Substances 0.000 claims description 7
- 239000004328 sodium tetraborate Substances 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- PNIJRIIGBGFYHF-UHFFFAOYSA-N perborate(2-) Chemical compound O[B-]1(O)OO[B-](O)(O)OO1 PNIJRIIGBGFYHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000005712 crystallization Effects 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 22
- 239000000243 solution Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-M Sodium percarbonate Chemical compound [Na+].OOC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-M 0.000 description 2
- PFUVRDFDKPNGAV-UHFFFAOYSA-N Sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000004965 peroxy acids Chemical class 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/12—Peroxyhydrates; Peroxyacids or salts thereof containing boron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- A* 274347 KLASSE 12«. GRUPPE- A * 274347 CLASS 12 «. GROUP
Verfahren zur Darstellung von Perboraten. Patentiert im Deutschen Reiche vom 19. April 1913 ab.Procedure for the representation of perborates. Patented in the German Empire on April 19, 1913.
Nach den bisherigen technisch ausgeführten Verfahren zur Darstellung von Perboraten und Perborax geht man von sehr teuren Rohstoffen aus, vom Natriumsuperoxyd, Natriumpercarbonat oder Perhydrol, oder man arbeitet mit dem technischen, nur 3 Prozent enthaltenden, unreinen Wasserstoffsuperoxyd und erhält eine Unmenge an Lösungen.According to the previous technically executed method for the representation of perborates and Perborax is based on very expensive raw materials, sodium peroxide and sodium percarbonate or Perhydrol, or you work with the technical, only 3 percent containing, impure hydrogen peroxide and contains a vast number of solutions.
Nach vorliegender Erfindung benutzt man dagegen das billigste, reinste und konzentrierteste Wasserstoffsuperoxyd, das überhaupt herzustellen geht — das Wasserstoffsuperoxyd in Gasform.According to the present invention, on the other hand, the cheapest, purest and most concentrated is used Hydrogen peroxide that can ever be manufactured - the hydrogen peroxide in gaseous form.
Das gasförmige Wasserstoffsuperoxyd kann durch Destillation seiner wäßrigen Lösungen unter Vakuum ,hergestellt werden; dies Verfahren erfordert jedoch viel Heizmittel und ist mit großen Verlusten verbunden; oder man entbindet aus Persulfaten oder anderen Wasserstoffsuperoxyd liefernden Salzen das Wasserstoffsuperoxyd mittels Säuren und saugt unter Vakuum oder durch einen Luftstrom das Gas im statu nascendi ab. Das einfachste und billigste Verfahren dagegen besteht darin, daß man Persäuren der Destillation unterwirft und das entbundene gasförmige Wasserstoffsuperoxyd direkt in die Lösung von Boraten oder Lösung von Borsäure unter Zugabe des nötigen Alkalis einleitet bzw. durch diese Lösungen durchsaugt, wenn nötig unter Kühlung.The gaseous hydrogen peroxide can be obtained by distilling its aqueous solutions under vacuum; however, this method requires a lot of heating means and is associated with great losses; or one releases from persulfates or other hydrogen peroxide supplying salts the hydrogen peroxide by means of acids and sucks the under vacuum or through a stream of air Gas off in statu nascendi. The simplest and cheapest way to counter this is to that one subjects peracids to the distillation and the released gaseous hydrogen peroxide introduced directly into or through the solution of borates or solution of boric acid with the addition of the necessary alkali Solutions sucked through, if necessary with cooling.
Da das Gas durch mehrere hintereinander aufgestellte Absorptionsgefäße hindurchgesaugt werden kann, ist jeder Verlust an Wasserstoffsuperoxyd ausgeschlossen. An Stelle der teuren, aus reinem Borax oder reiner Borsäure und Ätznatron hergestellten Lösungen kann man vorteilhafter verwenden die filtrierten Aufschlußlösungen der Borsäure- oder Boraxfabrikation oder noch vorteilhafter die Mutterlaugen von der Borax- und Borsäurekristallisation — es ist also am' rationellsten, die Perboratfabrikation sowohl mit der Persäure-, als auch mit der Borax- oder Borsäuredarstellung in Verbindung zu bringen.Because the gas is sucked through several absorption vessels placed one behind the other any loss of hydrogen peroxide is excluded. Instead of expensive solutions made from pure borax or pure boric acid and caustic soda it is more advantageous to use the filtered digestion solutions of boric acid or Borax production or, even more advantageously, the mother liquors from borax and boric acid crystallization - It is therefore the most rational to use the perborate production both with the peracid, as well as with the representation of borax or boric acid.
Die Vorteile des vorliegenden Verfahrens gegenüber den bisherigen sind folgende:The advantages of the present method over the previous ones are as follows:
1. Das aus dem teuren Natriumsuperoxyd oder Natriumpercarbon at oder Perhydrol gewonnene Wasserstoffsuperoxyd ist ein für technischen Gebrauch viel zu teures Präparat; billiger und vorteilhafter als nach der vorliegenden Erfindung kann das Perborat nach keinem der bisherigen Verfahren dargestellt werden.1. That obtained from the expensive sodium peroxide or sodium percarbonate or perhydrol Hydrogen peroxide is a preparation that is far too expensive for technical use; cheaper and more advantageous than according to the present invention, the perborate can none of the previous procedures are presented.
2. Nach dem vorliegenden Verfahren arbeitet man mit reinem gasförmigen Wasserstoffsuperoxyd und erhält Perborate in größter Reinheit, ohne das teure Kühlen großer Flüssigkeitsmengen nötig zu haben.2. The present process uses pure gaseous hydrogen peroxide and receives perborates in the greatest purity, without the expensive cooling of large amounts of liquid need to have.
3. Vor allem kann mit viel konzentrierteren Lösungen gearbeitet werden, man erspart daher viel an Apparatur, Lohn und Zeit.3. Above all, you can work with much more concentrated solutions, so you save a lot of equipment, wages and time.
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE274347C true DE274347C (en) |
Family
ID=530722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT274347D Active DE274347C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE274347C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE767052C (en) * | 1938-06-05 | 1951-08-09 | Heinrich Schmidt | Process for the production of pure hydrogen peroxide |
-
0
- DE DENDAT274347D patent/DE274347C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE767052C (en) * | 1938-06-05 | 1951-08-09 | Heinrich Schmidt | Process for the production of pure hydrogen peroxide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE274347C (en) | ||
| DE3782626T2 (en) | METHOD FOR SEPARATING AND RECOVERING BORON CONNECTIONS FROM A GEOTHERMAL SOLE. | |
| DE2846892C2 (en) | Process for the preparation of m-diisopropylbenzene dihydroperoxide by oxidation of m-diisopropylbenzene in the liquid phase | |
| DE507522C (en) | Process for the preparation of perborates | |
| DE947162C (en) | Process for working up the reaction mixture obtained in the nitration of cyclohexane | |
| DE2148717A1 (en) | Process for purifying lactams | |
| DE2641449C3 (en) | Process for purifying a solution of ε-caprolactam | |
| DE593385C (en) | Process for the production of alkali alcoholates | |
| DE902252C (en) | Process for the production of percarbonate | |
| DE363175C (en) | Process for the production of solutions from cellulose or cellulose-containing substances | |
| DE352186C (en) | Process for the production of hydrogen | |
| DE1054970B (en) | Process for the production of alkali peroxides | |
| DE1082254B (en) | Process for the production of high percentage hydroperoxide solutions of terpene hydrocarbons from low percentage solutions | |
| DE214040C (en) | ||
| DE566152C (en) | Manufacture of copper chloruer | |
| DE2027280A1 (en) | ||
| AT202974B (en) | Process for the production of alkali peroxides | |
| DE845346C (en) | Process for the preparation of benzene-2,4-disulfonic acid-1-carboxylic acid | |
| DE960459C (en) | Process for the preparation of 6-alkoxycyclodecanones (1) or their oximes | |
| DE544522C (en) | Process for the production of anthraquinone and anthraquinone derivatives | |
| DE628426C (en) | Process for the production of hydrogen peroxide | |
| DE520776C (en) | Manufacture of boric acid | |
| AT228743B (en) | Process for cleaning aqueous solutions from hydrogen peroxide | |
| AT221475B (en) | Process for the production of stable alkali perborate | |
| DE239075C (en) |