DE2652588A1 - Permanent image formation on ceramics, glass, wood, metal etc. - by lacquering, drying, freezing, applying photographic emulsion, imaging and glazing - Google Patents

Permanent image formation on ceramics, glass, wood, metal etc. - by lacquering, drying, freezing, applying photographic emulsion, imaging and glazing

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Publication number
DE2652588A1
DE2652588A1 DE19762652588 DE2652588A DE2652588A1 DE 2652588 A1 DE2652588 A1 DE 2652588A1 DE 19762652588 DE19762652588 DE 19762652588 DE 2652588 A DE2652588 A DE 2652588A DE 2652588 A1 DE2652588 A1 DE 2652588A1
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DE
Germany
Prior art keywords
image
drying
wood
glass
emulsion layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19762652588
Other languages
German (de)
Inventor
Ilse Hackbarth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE19762652588 priority Critical patent/DE2652588A1/en
Publication of DE2652588A1 publication Critical patent/DE2652588A1/en
Pending legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C11/00—Auxiliary processes in photography
    • G03C11/08—Varnishing, e.g. application of protective layers on finished photographic prints
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
    • G03C1/93—Macromolecular substances therefor

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

Method involves (a) lacquering, drying and freezing the surface; (b) applying and drying a special emulsion; (c) engraving the image in the emulsion layer from the negative; and (d) fixing, washing and glazing image. The images are insol. in water at low to medium temps. and resistant to mechanical stress. They can be applied to any surface, e.g. the inside or outside of an ordinary ceramic dish, which can even be of inferior quality. No surface pretreatment is necessary.

Description

Verfahren zum dauerhaften Entwickeln von fotografischen Bildern auf Keramik, Glas, etall, Holz od.dgl.Process for the permanent development of photographic images Ceramic, glass, metal, wood or the like.

Die Erfindung betrifft ein Verfahren zur Behandlung und Beschichtung von glatten und trockenen Oberflächen aus Keramik, Glas, Metall, Holz od.dgl., um auf diesen fotografische Bilder dauerhaft zu entwickeln, die bei niedrigen bis mittleren Temperaturen wasserunlöslich und auch gegen mechanische Beanspruchung widerstandsfähig sind.The invention relates to a method of treatment and coating of smooth and dry surfaces made of ceramic, glass, metal, wood or the like. To to develop permanently on these photographic images at low to medium Temperatures insoluble in water and also resistant to mechanical stress are.

Das erfindungsgemäße Verfahren besteht aus mehreren Verfahrensschritten.The method according to the invention consists of several method steps.

Anfänglich wird die zu behandelnde Oberfläche mit einem Lack- oder Plastikprodukt grundiert, das im Sprüh- oder Spritzverfahren zu einer dünnen aber dichten Schicht auf der Oberfläche aufgetragen, anschließend langsam (ca. 50 Stunden) getrocknet und schließlich in einer Tiefkühlkammer eingefroren wird.Initially, the surface to be treated is covered with a varnish or Primed plastic product that is sprayed or sprayed into a thin but applied in a thick layer on the surface, then slowly (approx. 50 hours) dried and finally frozen in a freezer.

Sobald die geeignete Einfrierung erreicht ist, wird die Grundierungsschicht in einer Klimakammer bei etwa 18 -19°C mit einer Emulsionsschicht bezw. Positivierungsschicht von besonderer Zusammensetzung versehen, die mit einer geeigneten Sprüh- oder Spritzvorrichtung gleichmäßig aufgetragen und in der Klimakammer bei ebenfalls 18 - 190 G getrocknet wird.Once the appropriate freezing is achieved, the primer layer is applied BEZW in a climatic chamber at about 18 -19 ° C with an emulsion layer. Positive layer of special composition provided with a suitable spray or spray device applied evenly and dried in the climatic chamber at 18-190 G as well will.

Nunmehr wird das auf übliche Weise gemachte und entwikkelte Bildnegativ in einer in der Fotografie angewandten Art auf die Emulsionsschicht übertragen und die Positivierung des Bildes in einem Entwicklungsbad von 15 - 170 C durchgeführt.Now the image made and developed in the usual way becomes negative transferred to the emulsion layer in a manner used in photography and the positive image was carried out in a developing bath at 15 - 170 ° C.

Die Fixierung des Bildes erfolgt ebenfalls in einem 15 -170 C warmen Fixierbad, die Bildwaschung bei maximal 180 C und die Bildtrocknung in natürlicher Lüftung.The image is also fixed in a 15 -170 C warm Fixing bath, picture washing at a maximum of 180 C and picture drying in a natural way Ventilation.

Im letzten abschließenden Verfahrensschritt wird die Bildoberfläche mit einer aufsprüh- oder aufspritzbaren Firnislasur überzogen, die das Bild wasserunlöslich und gegen mechanische Einflüsse widerstandsfähig macht.In the last, final process step, the image surface is created coated with a spray-on or spray-on varnish glaze, which makes the picture water-insoluble and makes it resistant to mechanical influences.

Eigentümlich für das erfindungsgemäße Verfahren ist, daß die für die Aufnahme der Fotografien vorgesehenen Oberflächen jede gewünschte Form haben können, z.B. die Innen-oder Außenfläche eines gewöhnlichen Keramiktellers, der sogar minderer Qualität sein kann; auch bedürfen die mit Fotografien zu schmückenden Oberflächen vor Anwendung der erfindungsgemäßen Beschichtung keinerlei Vorbehandlung oder Hilfsmittel.It is peculiar to the method according to the invention that the The surfaces provided for taking the photographs can have any desired shape, E.g. the inner or outer surface of an ordinary ceramic plate, which is even less Quality can be; also require the surfaces to be decorated with photographs no pretreatment or aids whatsoever prior to application of the coating according to the invention.

Claims (7)

Patentansprüche 1) Verfahren zum dauerhaften Entwickeln von fotografischen Bildern auf Keramik, Glas, Metall, Holz od.Claims 1) Process for the permanent development of photographic Images on ceramics, glass, metal, wood or dgl., gekennzeichnet durch folgende Verfahrensschritte a) Lackieren, Trocknen und Einfrieren der Keraß!llk-, Glas, etall-, Holz- od.dgl. Flächen, b) Aufbringen und Trocknen der als Bildträger dienenden besonders zusammengesetzten Emulsionsschicht auf die gefrorene Lackierung, c) Gravieren des Bildes vom Bildnegativ in die Emulsionsschicht, d) Fixieren, Waschen und Lasieren des Bildes. Like., characterized by the following process steps a) painting, Drying and freezing the Keraß! Llk-, glass, metal, wood or the like. Areas, b) Applying and drying the specially composed components that serve as image carriers Emulsion layer on the frozen varnish, c) Engraving the image from the negative into the emulsion layer, d) fixing, washing and glazing of the image. 2) Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß zur Grundierung der Oberflächen mit einer dünnen aber dichten Schicht Lack- oder Plastikprodukte dienen, die in einem Zeitraum von etwa 50 Stunden getrocknet und anschließend in einer Tiefkühlkammer eingefroren werden.2) Method according to claim 1, characterized in that for priming the surfaces with a thin but dense layer of lacquer or plastic products serve, which are dried over a period of about 50 hours and then in frozen in a freezer. 3) Verfahren nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, daß auf die gefrorene Grundierungsschicht die Emulsionsschicht in einer Klimakammer bei etwa 10-19°C aufgesprüht oder aufgespritzt und bei ebenfalls 18-190C in der Klimakammer getrocknet wird.3) Method according to claims 1 and 2, characterized in that that on the frozen primer layer the emulsion layer in a climatic chamber at about Sprayed or splashed on at 10-19 ° C and at the same time 18-190C is dried in the climatic chamber. 1) Verfahren nach Anspruch 3, gekennzeichnet durch folgende Formel für die Emulsion : Teil A : Gelatine 50g Wasser 2 Liter Teil B : Kaliumbromid 75g Kaliumjodid-Lösung zu 103 30cm³ Teil C : Natriumchlorid-Lösung zu 25 ; 10cm³ Teil D : Silbernitrat 100g Wasser 600cm³ Ammoniak 100cm³ Teil E : Gelatine 250g Reifung während 30 Kinuten bei 45°C Teil F: Schwefelsäure Dichte 1,18 157cm3 Zitronensäure zu 50% 30cm³ waschen, umschmelzen und dann hinzufügen : Teil G: Gelatine 85g Kaliumjodid zu 0,66 25g Kaliumbromid zu 25% 1,00cm³ Natriumchlorid zu 25% 2,50cm³ Reifung während 60 Minuten bei 50°C Teil H : Zitronensäure-Lösung 5,50cm³ 1) Method according to claim 3, characterized by the following formula for the emulsion: Part A: gelatin 50g water 2 liters Part B: potassium bromide 75g Potassium iodide solution at 103 30 cm³ Part C: Sodium chloride solution at 25; 10cm³ part D: silver nitrate 100g water 600cm³ ammonia 100cm³ Part E: gelatine 250g maturation for 30 minutes at 45 ° C Part F: sulfuric acid density 1.18 157 cm3 citric acid Wash up to 50% 30cm³, remelt and then add: Part G: Gelatine 85g potassium iodide to 0.66 25g potassium bromide to 25% 1.00cm³ sodium chloride to 25% 2.50cm³ ripening 60 minutes at 50 ° C Part H: Citric acid solution 5.50 cm³ 5) Verfahren nach den Ansprüchen 1 - 4, dadurch gekennzeichnet, daß das Bild vom ttegativ in an sich bekann ter Weise auf die getrocknete Emulsionsschicht aber tragen wird und die Mildpositivierung in einem 15 - 170 C warmen Entwicklungsbad erfolgt.5) Procedure according to the Claims 1 - 4, characterized in that the image of the negative in itself is known ter way on the dried emulsion layer however will wear and the mild positivation takes place in a 15-170 C developing bath. 6) FVerfahren nach den Ansprüchen 1 - 5, dadurch gekennzeichnet, daß zur Fixierung des Bildes ein 15-17° C warmes Fixierbad dient, das Bild in einem 180 C warmen Wasserbad gewaschen und in natürlicher Lüftung getrocknet wird.6) F method according to claims 1-5, characterized in that A 15-17 ° C fixing bath is used to fix the image, the image in one 180 C warm water bath is washed and dried in natural ventilation. 7) Verfahren nach den Ansprüchen 1 - 6, d a d u r c h g e k e n nz e i c h n e t, daß die Bildoberfläche gegen Wasserlöslichkeit und mechanische Einflüsse durch eine aufsprüh-oder aufspritzbare Firnislasur geschützt wird7) Method according to claims 1-6, d a d u r c h g e k e n nz E i c h n e t that the picture surface against water solubility and mechanical influences is protected by a spray-on or spray-on varnish glaze
DE19762652588 1976-11-19 1976-11-19 Permanent image formation on ceramics, glass, wood, metal etc. - by lacquering, drying, freezing, applying photographic emulsion, imaging and glazing Pending DE2652588A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19762652588 DE2652588A1 (en) 1976-11-19 1976-11-19 Permanent image formation on ceramics, glass, wood, metal etc. - by lacquering, drying, freezing, applying photographic emulsion, imaging and glazing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762652588 DE2652588A1 (en) 1976-11-19 1976-11-19 Permanent image formation on ceramics, glass, wood, metal etc. - by lacquering, drying, freezing, applying photographic emulsion, imaging and glazing

Publications (1)

Publication Number Publication Date
DE2652588A1 true DE2652588A1 (en) 1978-05-24

Family

ID=5993463

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19762652588 Pending DE2652588A1 (en) 1976-11-19 1976-11-19 Permanent image formation on ceramics, glass, wood, metal etc. - by lacquering, drying, freezing, applying photographic emulsion, imaging and glazing

Country Status (1)

Country Link
DE (1) DE2652588A1 (en)

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