DE2625607A1 - Turbine blades erosion prevention - by metering specific quantities of surfactant into the (wet) steam - Google Patents

Turbine blades erosion prevention - by metering specific quantities of surfactant into the (wet) steam

Info

Publication number
DE2625607A1
DE2625607A1 DE19762625607 DE2625607A DE2625607A1 DE 2625607 A1 DE2625607 A1 DE 2625607A1 DE 19762625607 DE19762625607 DE 19762625607 DE 2625607 A DE2625607 A DE 2625607A DE 2625607 A1 DE2625607 A1 DE 2625607A1
Authority
DE
Germany
Prior art keywords
steam
esp
wet
turbine blades
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE19762625607
Other languages
German (de)
Inventor
Erwin Dipl Ing Czempik
M E Prof Dr Dejc
G A Prof Dr Filippov
A N Dipl Ing Kukuskin
A V Dr Kurschakov
Alexander Dipl Chem Dr Langner
Klaus Dipl Chem Pflugbeil
G A Dipl Ing Dr Saltanov
Kurt Dipl Ing Schindler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INST ENERGETIK RATIONAL
Moskovsky Energetichesky Institut
Original Assignee
INST ENERGETIK RATIONAL
Moskovsky Energetichesky Institut
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DD174801A external-priority patent/DD107962A1/xx
Application filed by INST ENERGETIK RATIONAL, Moskovsky Energetichesky Institut filed Critical INST ENERGETIK RATIONAL
Publication of DE2625607A1 publication Critical patent/DE2625607A1/en
Ceased legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D25/00Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
    • F01D25/007Preventing corrosion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/50Intrinsic material properties or characteristics
    • F05D2300/512Hydrophobic, i.e. being or having non-wettable properties

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

Redn. of erosion of turbine components esp. of blades in wet steam turbines is described in the parent patent. The improvement comprise determining the concn. of the surfactant materials metered (esp. film-forming amines and/or volatile alkaline materials) in combination with the press. and temp. and the nature of the steam expansion process as well as its (their) own characteristics. The process, esp. useful in conventional powder stations or in the sec. systems of nuclear power plants, enables better use to be made of the steam's thermal energy, thus enabling turbines of comparable power to be built lighter. During the expansion cycle, a film forms on the blades, protecting their surface and preventing depositions forming.

Description

Die Erfindung betrifft ein Verfahren zur Verringerung derThe invention relates to a method for reducing the

Erosion von Turbinenteilen, insbesondere von Turbinenschaufeln der Naßdampfturbinen, die in Kernkraftwerken zum Einsatz kommen nach Patent 107 962.Erosion of turbine parts, especially turbine blades of the Wet steam turbines that are used in nuclear power plants according to patent 107 962.

In dem genannten Hauptpatent ist ein Verfahren beschrieben, bei dem in den Sekundärkreislauf von Kernkraftwerken mit Druckwas serre aktoren oder in den Wasser-Dampfkreislauf konventioneller Kraftwerk filmbildende Amine allein und/ oder flüchtige Alkalisierungsmittel zudosiert werden. Als filmbildende Amine werden dabei vorzugsweise Octadecylamin bzw. als flüchtige A1 kalisierungsmittel vorzugsweise Morpholin eingesetzt. Nach dem erSindungsgemPRen Verfahren werden die filmbildenden Amine allein und/oder flüchtige Alkalisierungsmittel drucklos, beispielsweise durch Einsaugen zwischen Kondensatpumpe und Kondensator bzw. durch Zugabe in den Speisewasserbehälter, oder mittels Hochdruckpumpe zugegeben.In the main patent mentioned, a method is described in which in the secondary circuit of nuclear power plants with pressurized water actuators or in the water-steam cycle of conventional power plants film-forming amines alone and / or volatile alkalizing agents are added. Used as film-forming amines preferably octadecylamine or, as a volatile A1 calizing agent, preferably Morpholine used. According to the process according to the invention, the film-forming Amines alone and / or volatile alkalizing agents without pressure, for example by Sucking in between the condensate pump and the condenser or by adding it to the feed water tank, or added by means of a high pressure pump.

In der Praxis hat es sich gezeigt, daß die Anwendungsbedingungen des Verfahrens sehr unterschiedlich sind. So schwanken die Parameter Druck, Temperatur sowie die Art des Expansionsprozesses des Dampfes in starkem Maße sowohl zwischen den verschiedenen Anlagen auch bei unterschiedlicher Fahrweise des gleichen Aggregates.In practice it has been shown that the conditions of use of the Procedures are very different. The parameters pressure and temperature fluctuate as well as the type of expansion process of the steam to a large extent both between the different systems even if the same unit operates differently.

Palls diese Parameter extreme Werte annehmen, kann jedoch mit der in dem Hauptpatent angegebenen Konzentration der Dosierstoffe nicht immer ein optimales Ergebnis erzielt werden. Der Zweck der Erfindung besteht darin, die vorgenannten Mängel zu. beseitigen.However, if these parameters assume extreme values, the specified in the main patent concentration of Dosage substances not always an optimal result can be achieved. The purpose of the invention is to the aforementioned defects. remove.

Der Erfindung liegt die Aufgabe zugrunde, das Verfahren zur Verringerung der Erosion von Turbinenteilen, insbesondere von Turbinenschaufeln der Naßdampfturbinen, nach Patent 107 962 so zu verbessern, daß auch bei extremen Werten des Druckes und der Temperatur des Dampfes sowie der Art des Expansionsprozesses des Dampfes ein möglichst feines Tropfenspektrum des Dampf-WassereGemisches und eine Vermeidung bzw. Einschränkung der Ausbildung von Wasserfilmen erreicht wird.The invention is based on the object of the method for reducing the erosion of turbine parts, especially turbine blades of wet steam turbines, to improve according to patent 107 962 so that even with extreme values of the pressure and the temperature of the steam and the type of expansion process of the steam The finest possible drop spectrum of the steam-water mixture and avoidance or restriction of the formation of water films is achieved.

Es wurde gefunden, daß die Konzentration der einzusetzenden grenzflächenaktfflven Dosierstoffe in Abhängigkeit vom Druck, der Temperatur und von der Art des Expansionsprozesses sowie durch die Eigenschaften der Dosierstoffe selbst zu bestimmen ist. Die Dosierstellen für die Dosierstoffe werden für das jeweilige Aggregat so gewählt, daß die grenzflächenaktiven Dosierstoffe vor dem Epansionsprozeß in der zur Erreichung des gewEnschten Effektes erforderlichen Menge dem Dampf zugegeben werden können.It has been found that the concentration of the surfactants to be used Dosing substances depending on the pressure, the temperature and the type of expansion process as well as to be determined by the properties of the dosing substances themselves. The dosing points for the metering substances are chosen for the particular unit so that the surface-active Dosing substances before the expansion process in order to achieve the desired effect required amount can be added to the steam.

Bei Anwendung des erSindungsgemaßen Verfahrens in einem mit Wasserdampf betriebenen Turboaggregat kann die in dem Dampf enthaltene Wärmeenergie besser ausgenutzt werden. Die Turbinen können bei gleicher Leistung leichter gebaut werden und infolge der verringerten Erosion an den Durbinenschaufeln wird die Standzeit erhöht. Durch Wegfall der Kondensationssprünge treten keine Beschädigungen der Aggregate auf und die Havariegefahr wird verringert. Vv'ährend des Expansionsprozesses des Arbeitsmediums erfolgt die Kondensation der Dosierstoffe, die an den Aggregatoberflächen sehr dünne hydrophobe Schutzfllme ausbilden. Dadurch wird ein direkter Angriff der Oberflächen durch das Arbeitsmedium verhindert, was zum Beispiel zur Erosionsverminderung und Korrosionsverringerung, zur Ablösung von Ablagerungen sowie zur Verhinderung der Ausbildung neuer Ablagerungen führt.When using the inventive method in one with steam operated turbo unit can better utilize the thermal energy contained in the steam will. The turbines can be built lighter with the same output and as a result of the reduced erosion on the turbine blades, the service life will be elevated. By eliminating the cracks in condensation, there is no damage to the units and the risk of damage is reduced. Vv 'during the expansion process of the Working medium, the dosing substances condense on the unit surfaces Form very thin hydrophobic protective films. This creates a direct attack on the Surfaces prevented by the working medium, which for example to reduce erosion and corrosion reduction, deposit removal and prevention leads to the formation of new deposits.

Claims (2)

Patentansprüche 1. Verfahren zur Verringerung der Erosion von Turbinenteilen, insbesondere von Turbinenschaufeln der Naßdampfturbinen, nach Patent 107 962, d a d u r c h g e k e n n z e i c h n e t , daß die Konzentration der zudosierten grenzflächenaktiven Stoffe, insbesondere filmbildende Amine und/oder flUchtige Alkalisierungsmittel, in Abhängigkeit vom Druck, von der Xemperatur und von der Art des EApansionsprozesses des Dampfes sowie in Abhängigkeit ihrer Eigenschaften bec stimmt werden.Claims 1. A method for reducing the erosion of turbine parts, in particular of turbine blades of wet steam turbines, according to patent 107 962, d a d u r c h g e k e n n n z e i c h n e t that the concentration of the metered surface-active substances, especially film-forming amines and / or volatile alkalizing agents, depending on the pressure, the temperature and the type of expansion process of the steam as well as depending on their properties bec. 2. Verfahren nach Anspruch 1, d a d u r c h g e k e n n z e i c h n e t , daß die Dosierstellen für die Dosierstoffe bei dem jeweiligen Aggregat so gewählt werden, daß diese grenzflächenaktiven Stoffe vor dem ExpansionsprozeB in der erforderlichen Menge dem Arbeitsmedium zugegeben werden können.2. The method according to claim 1, d a d u r c h g e k e n n z e i c h n e t, that the metering points for the metering substances in the respective unit so be chosen that these surfactants prior to the expansion process in the required amount can be added to the working medium.
DE19762625607 1973-11-21 1976-06-08 Turbine blades erosion prevention - by metering specific quantities of surfactant into the (wet) steam Ceased DE2625607A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DD174801A DD107962A1 (en) 1973-11-21 1973-11-21
DD18929475 1975-11-06

Publications (1)

Publication Number Publication Date
DE2625607A1 true DE2625607A1 (en) 1977-05-26

Family

ID=25747512

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19762625607 Ceased DE2625607A1 (en) 1973-11-21 1976-06-08 Turbine blades erosion prevention - by metering specific quantities of surfactant into the (wet) steam

Country Status (1)

Country Link
DE (1) DE2625607A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1557539A1 (en) * 2004-01-21 2005-07-27 Siemens Aktiengesellschaft Method and arrangement for augmenting the power output and the efficiency in a gas turbine plant, as well as a gas turbine plant
EP1925782A1 (en) * 2006-11-23 2008-05-28 Siemens Aktiengesellschaft Non wetable surface coating of steam turbine parts which work in wet steam
DE102012203010A1 (en) 2012-02-28 2013-08-29 Areva Gmbh Process for cleaning and conditioning the water-steam cycle of a power plant, in particular a nuclear power plant

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1557539A1 (en) * 2004-01-21 2005-07-27 Siemens Aktiengesellschaft Method and arrangement for augmenting the power output and the efficiency in a gas turbine plant, as well as a gas turbine plant
EP1925782A1 (en) * 2006-11-23 2008-05-28 Siemens Aktiengesellschaft Non wetable surface coating of steam turbine parts which work in wet steam
WO2008062051A1 (en) * 2006-11-23 2008-05-29 Siemens Aktiengesellschaft Non wetable surface coating of steam turbine parts which work in wet steam
DE102012203010A1 (en) 2012-02-28 2013-08-29 Areva Gmbh Process for cleaning and conditioning the water-steam cycle of a power plant, in particular a nuclear power plant
WO2013127842A1 (en) 2012-02-28 2013-09-06 Areva Gmbh Method for purifying and conditioning the water-steam circuit of a power plant, especially of a nuclear power plant
WO2013127844A1 (en) 2012-02-28 2013-09-06 Areva Gmbh Method for conditioning a power-generating circulatory system of a power plant

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