DE258393C - - Google Patents
Info
- Publication number
- DE258393C DE258393C DENDAT258393D DE258393DA DE258393C DE 258393 C DE258393 C DE 258393C DE NDAT258393 D DENDAT258393 D DE NDAT258393D DE 258393D A DE258393D A DE 258393DA DE 258393 C DE258393 C DE 258393C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- magnesium
- mixtures
- soap
- soaps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000344 soap Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 claims 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 241000854350 Enicospilus group Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/42—Per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 258393 KLASSE 23 e. GRUPPE- M 258393 CLASS 23 e. GROUP
Patentiert im Deutschen Reiche vom 2. März 1909 ab.Patented in the German Empire on March 2nd, 1909.
Natriumperborat ist bekanntlich in Mischung mit Seifenmasse nicht haltbar. Es ist ferner bekannt, daß die Haltbarkeit solcher Mischungen durch weiteren Zusatz von verschiedenen Salzen noch mehr herabgesetzt wird.As is well known, sodium perborate cannot be kept in a mixture with soap mass. It is further known that the shelf life of such mixtures by further addition of different Salting is reduced even more.
Es wurde nun gefunden, daß man zu haltbaren, aktiven Sauerstoff. enthaltenden Seifenmischungen gelangt, wenn man denselben in geringer Menge Salze des Magnesiums, der alkaiischen Erden oder des Zinks zusetzt.It has now been found that sustainable, active oxygen can be obtained. containing soap mixes if one arrives at it in a small amount of salts of magnesium, the alkaline ones Earth or zinc added.
Vor dem Verfahren des Patentes 249325 zeichnen sich diese Zusätze dadurch aus, daß sie die Alkalinität der Produkte nicht vermindern, was für die Verwendung für Waschzwecke von großer Wichtigkeit ist. Wertvoll ist, daß man die genannten Stoffe nicht in äquimolekularem Verhältnis anwenden muß, sondern nur einen geringen Teil davon nötig hat. Dadurch wird bei der Anwendung dieser Stoffe zum Bleichen und Waschen vermieden, daß sich schwerlösliche Seifen in nennenswerten Mengen bilden, wie dies bei solchen Bleichprozessen der Fall ist, in denen man äquimolekulare Mengen von Perborat und beispielsweise Magnesiumsalz zur Anwendung bringt.Before the process of the patent 249325, these additives are characterized in that they do not reduce the alkalinity of the products, which is suitable for use for laundry purposes is of great importance. It is valuable that you do not use the substances mentioned must apply equimolecular ratio, but only a small part of it is necessary Has. This avoids using these substances for bleaching and washing, that sparingly soluble soaps are formed in significant quantities, as is the case with such bleaching processes is the case in which one equimolecular amounts of perborate and, for example Magnesium salt applies.
Zur Erzielung von brauchbaren Produkten verfährt man beispielsweise so, daß man 1 Mol. Natriumperborat mit Ve 0(^er V12 Mol. Magnesiumsulfat mischt und hierzu Seifen oder Seifen pulver in der jeweilig gewünschten Menge zusetzt. Man kann die Produkte auch zusammenschmelzen. Statt des Magnesiumsalzes können entsprechende Mengen von Strontium-, Barium- oder Zinksalzen genommen werden.To obtain usable products, one proceeds, for example, by mixing 1 mol of sodium perborate with Ve 0 ( ^ er V12 mol of magnesium sulfate and adding soaps or soap powder in the desired amount. The products can also be melted together instead of the magnesium salt Corresponding amounts of strontium, barium or zinc salts can be used.
Geht man nicht von reinem Perborat aus, sondern von einem aktiven Borat, wie letzteres in dem Patent ,250331 beschrieben ist, so verfährt man beispielsweise so, daß man ein Schmelzprodukt, welches aus 20 Teilen Borsäure, 5 Teilen Natriumsuperoxyd, 5 Teilen Wasser, 13 Teilen Borax und 7 Teilen Seife besteht, mit 3 Teilen kristallisiertem Magnesiumchlorid vermischt.If one does not start from pure perborate, but from an active borate, like the latter is described in patent 250331, the procedure is, for example, that one a melt product which consists of 20 parts of boric acid, 5 parts of sodium peroxide, 5 parts Water, 13 parts borax and 7 parts soap, with 3 parts crystallized Magnesium chloride mixed.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB15213/31A GB378973A (en) | 1931-05-22 | 1931-05-22 | Improvements in the manufacture of soap powders |
Publications (1)
Publication Number | Publication Date |
---|---|
DE258393C true DE258393C (en) |
Family
ID=10055030
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT258393D Active DE258393C (en) | 1931-05-22 |
Country Status (6)
Country | Link |
---|---|
US (1) | US2004670A (en) |
BE (1) | BE388131A (en) |
DE (1) | DE258393C (en) |
FR (1) | FR736024A (en) |
GB (1) | GB378973A (en) |
NL (1) | NL37608C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE882741C (en) * | 1948-10-01 | 1953-07-13 | Henkel & Cie Gmbh | Soaking agent |
-
0
- BE BE388131D patent/BE388131A/xx unknown
- NL NL37608D patent/NL37608C/xx active
- DE DENDAT258393D patent/DE258393C/de active Active
-
1931
- 1931-05-22 GB GB15213/31A patent/GB378973A/en not_active Expired
-
1932
- 1932-04-02 US US602870A patent/US2004670A/en not_active Expired - Lifetime
- 1932-04-27 FR FR736024D patent/FR736024A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE882741C (en) * | 1948-10-01 | 1953-07-13 | Henkel & Cie Gmbh | Soaking agent |
Also Published As
Publication number | Publication date |
---|---|
NL37608C (en) | 1900-01-01 |
GB378973A (en) | 1932-08-22 |
FR736024A (en) | 1932-11-18 |
US2004670A (en) | 1935-06-11 |
BE388131A (en) |
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