DE547987C - Process for the preparation of derivatives of high molecular weight aliphatic amines - Google Patents
Process for the preparation of derivatives of high molecular weight aliphatic aminesInfo
- Publication number
- DE547987C DE547987C DE1930547987D DE547987DA DE547987C DE 547987 C DE547987 C DE 547987C DE 1930547987 D DE1930547987 D DE 1930547987D DE 547987D A DE547987D A DE 547987DA DE 547987 C DE547987 C DE 547987C
- Authority
- DE
- Germany
- Prior art keywords
- aliphatic amines
- derivatives
- preparation
- molecular weight
- high molecular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aliphatic amines Chemical class 0.000 title claims description 5
- 150000001350 alkyl halides Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical group 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 150000003139 primary aliphatic amines Chemical class 0.000 claims description 2
- 150000005619 secondary aliphatic amines Chemical class 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- KAJZYANLDWUIES-UHFFFAOYSA-N heptadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCN KAJZYANLDWUIES-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YMDNODNLFSHHCV-UHFFFAOYSA-N 2-chloro-n,n-diethylethanamine Chemical compound CCN(CC)CCCl YMDNODNLFSHHCV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- 150000001723 carbon free-radicals Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/14—Derivatives of phosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/04—Sulfonates or sulfuric acid ester salts derived from polyhydric alcohols or amino alcohols or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Description
DEUTSCHES REICHGERMAN EMPIRE
AUSGEGEBEN AM
1. APRIL 1932ISSUED ON
APRIL 1, 1932
REICHSPATENTAMTREICH PATENT OFFICE
PATENTSCHRIFTPATENT LETTERING
JVl 547987 KLASSE 12 q GRUPPEJVl 547987 CLASS 12 q GROUP
Patentiert im Deutschen Reiche vom 7. Mai 1930 abPatented in the German Empire on May 7, 1930
Es wurde gefunden, daß man durch Umsetzung von primären oder sekundären aliphatischen Aminen als solche oder im Gemisch, welche mindestens einen Kohlenstoffrest mit mehr als 8 Kohlenstoffatomen enthalten, mit Alkylhalogeniden der allgemeinen FormelIt has been found that by reacting primary or secondary aliphatic Amines as such or in a mixture, which contain at least one carbon radical with more than 8 carbon atoms, with alkyl halides of the general formula
,- R2
X.RX-N<, - R 2
XR X -N <
worin X ein Halogen ist und R1, R2 und R3 gleiche oder verschiedenartige aliphatische Reste bedeuten, Substanzen erhalten kann, die saponinartige Eigenschaften besitzen. Die neuen Verbindungen lösen sich in Form ihrer Salze in Wasser auf und bilden seifenartige, stark schäumende Lösungen. Infolge ihrer außerordentlich hohen Schaumkraft eignenwherein X is a halogen and R 1 , R 2 and R 3 are identical or different aliphatic radicals, substances can be obtained which have saponin-like properties. The new compounds dissolve in the form of their salts in water and form soap-like, strongly foaming solutions. Due to their extraordinarily high foaming power, they are suitable
ao sich die Produkte zur Erzeugung eines beständigen Schaumes, ferner auch als Textilhilfsprodukte, wie z. B. als Emulgierungs-, Wasch- und Reinigungsmittel, insbesondere für die tierische Faser.ao the products for the production of a permanent foam, also as textile auxiliary products, such as B. as emulsifying agents, detergents and cleaning agents, especially for animal fibers.
chlorids und Heptadecylamin unter Rühren ι Stunde auf 150 bis i8o°. Das Reaktionsprodukt stellt eine fast farblose wachsartige Masse dar, die sich in Wasser löst. An Stelle des Diäthylaminoäthylchlorids kann man auch die entsprechende Dimethylverbindung oder andere Alkylchloride verwenden, welche basische Gruppen enthalten. An Stelle des Heptadecylamins können dessen am Stickstoff monoalkylsubstituierte Derivate Anwendung finden.chloride and heptadecylamine with stirring for ι hour to 150 to 180 °. The reaction product is an almost colorless, waxy mass that dissolves in water. Instead of diethylaminoethyl chloride you can also use the corresponding dimethyl compound or other alkyl chlorides, which contain basic groups. Instead of the heptadecylamine, its monoalkyl-substituted on the nitrogen can be used Derivatives are used.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE547987T | 1930-05-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE547987C true DE547987C (en) | 1932-04-01 |
Family
ID=6561771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1930547987D Expired DE547987C (en) | 1930-05-07 | 1930-05-07 | Process for the preparation of derivatives of high molecular weight aliphatic amines |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE547987C (en) |
FR (1) | FR714029A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2742504A (en) * | 1953-03-23 | 1956-04-17 | Nepera Chemical Co Inc | Heptadecyl amine compound |
DE1024977B (en) * | 1953-02-25 | 1958-02-27 | Nepera Chemical Co Inc | Process for the production of tertiary diamines |
US2908714A (en) * | 1956-09-20 | 1959-10-13 | Ciba Pharm Prod Inc | Process for the preparation of a diamine |
US3079436A (en) * | 1955-11-25 | 1963-02-26 | Rohm & Haas | Bis-quaternary ammonium compounds |
-
1930
- 1930-05-07 DE DE1930547987D patent/DE547987C/en not_active Expired
-
1931
- 1931-03-30 FR FR714029D patent/FR714029A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1024977B (en) * | 1953-02-25 | 1958-02-27 | Nepera Chemical Co Inc | Process for the production of tertiary diamines |
US2742504A (en) * | 1953-03-23 | 1956-04-17 | Nepera Chemical Co Inc | Heptadecyl amine compound |
US3079436A (en) * | 1955-11-25 | 1963-02-26 | Rohm & Haas | Bis-quaternary ammonium compounds |
US2908714A (en) * | 1956-09-20 | 1959-10-13 | Ciba Pharm Prod Inc | Process for the preparation of a diamine |
Also Published As
Publication number | Publication date |
---|---|
FR714029A (en) | 1931-11-06 |
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