DE246337C - - Google Patents
Info
- Publication number
- DE246337C DE246337C DENDAT246337D DE246337DA DE246337C DE 246337 C DE246337 C DE 246337C DE NDAT246337 D DENDAT246337 D DE NDAT246337D DE 246337D A DE246337D A DE 246337DA DE 246337 C DE246337 C DE 246337C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- red
- brown
- yellow
- vat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000843 powder Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 229960000583 Acetic Acid Drugs 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 239000012362 glacial acetic acid Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N Martius yellow Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- IBFXOWJTDUNEFS-UHFFFAOYSA-N (1-aminocyclohexa-2,4-dien-1-yl)-(4-aminophenyl)methanone Chemical compound C1=CC(N)=CC=C1C(=O)C1(N)C=CC=CC1 IBFXOWJTDUNEFS-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/24—Anthraquinone dyes or anthracene nucleus containing vat dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
Patentiert im Deutschen Reiche vom 10. November 1910 ab.Patented in the German Empire on November 10, 1910.
Es wurde die auffallende Beobachtung gemacht, daß die substituierten Coeramidonine (s. H. Decker, Ann. 348, S. 243), die keine Sulfogruppe enthalten, wertvolle, sowohl für Wolle wie für Baumwolle geeignete Küpenfarbstoffe sind. Dies war um so weniger zu erwarten, als die einfachen, in der Patentschrift 126444 beschriebenen Körper dieser Reihe dort nur als Ausgangsmaterialien zur Darstellung von Farbstoffen bezeichnet werden und an und für sich keinen färberischen Wert besitzen.The striking observation was made that the substituted coeramidonines (see H. Decker, Ann. 348, p. 243), which do not contain a sulfo group, are valuable, both for Wool are like vat dyes suitable for cotton. This was all the less true expect than the simple bodies described in patent 126444 this Number can only be referred to there as starting materials for the representation of dyes and in and of themselves have no coloring value.
I. ι Teil 14-Chlorcoeramidonin, erhalten z. B. durch Behandeln von 4-Chlor phenyl-α-aminoanthrachinon mit Kondensationsmitteln, wird mit 2,5 Teilen Natronlauge 400 Be., 2 Teilen Hydrosulfitpulver und 100 Teilen Wasser verrührt, V4 Stunde kalt stehen gelassen und in eine Färbeküpe gegeben, die 400 Teile Wasser und 20 Teile Glaubersalz kristallisiert enthält. Die Färbeküpe ist rot. Das Baumwollgarn wird Y2 Stunde lang bei gewöhnlicher Temperatur unter der Flotte gefärbt, abgewunden und an der Luft der Oxydation ausgesetzt. Es entsteht eine klare, goldgelbe Färbung von guter Chlorechtheit.I. ι part 14-Chlorcoeramidonin obtained z. B. by treating 4-chloro phenyl-α-aminoanthraquinone with condensing agents, is mixed with 2.5 parts of sodium hydroxide 40 0 Be., 2 parts of hydrosulfite powder and 100 parts of water, V left to stand for 4 hours and placed in a dye vat, the Contains 400 parts of water and 20 parts of Glauber's salt in crystallized form. The dye vat is red. The cotton yarn is dyed under the liquor for 2 hours at ordinary temperature, unwound and exposed to oxidation in the open air. The result is a clear, golden yellow color with good chlorine fastness.
Das 14-Chlorcoeramidonin bildet ein braungelbes, in Eisessig leicht mit braungelber Farbe lösliches Pulver, die Lösung in konzentrierter Schwefelsäure ist bordeauxrot.The 14-Chlorcoeramidonin forms a brownish yellow, in glacial acetic acid slightly with a brownish yellow color soluble powder, the solution in concentrated sulfuric acid is burgundy.
In ähnlicher Weise gefärbt werden z. B. das 12 · 14-Dichlorcoeramidonin aus 2 · 4-Dichlorphenyl-a-aminoanthrachinon (braungelbes, in Eisessig etwas schwerer als das obige Monochlorderivat lösliches Pulver) und das Benzocoeramidonin aus a-Naphtyl-a-aminoanthrachinon (gelbes Pulver, in konzentrierter Schwefelsäure grün, in Eisessig mit rotgelber Farbe löslich). Die Nuance ist nur wenig verschieden. In a similar way, z. B. the 12 · 14-dichloro-coeramidonine from 2 · 4-dichlorophenyl-a-aminoanthraquinone (brown-yellow powder that is slightly more difficult to dissolve in glacial acetic acid than the above monochloro derivative) and benzocoeramidonine from a-naphthyl-a-aminoanthraquinone (yellow powder, in concentrated sulfuric acid green, soluble in glacial acetic acid with a red-yellow color). The nuance is only slightly different.
Π. ι Teil Di-14 · i4'-coeramidonylketon, erhalten z. B. durch Kondensation von Di-α· a-anthrachinonyl-p · p-diaminobenzophenon (braungelbes, in konzentrierter Schwefelsäure rotbraun, in Eisessig braungelb lösliches Pulver), wird direkt in der Färbeküpe mit 6 Teilen Natronlauge 40 ° Be., 2 Teilen Hydrosulfitpulver und 500 Teilen Wasser auf 6o° erwärmt, bis eine rote Küpe entstanden ist, dann 20 Teile kristallisiertes Glaubersalz zugegeben und die Baumwolle V2 Stunde lang bei 60 ° unter der Flotte ausgefärbt. Die Färbung wird abgewunden, verhängt, gespült, abgesäuert und kochend geseift. Man erhält eine schöne, goldgelbe, wasch- und chlorechte Färbung.Π. ι part of di-14 · i4'-coeramidonyl ketone, obtained z. B. by condensation of di-α · a-anthraquinonyl-p · p-diaminobenzophenone (brown-yellow, in concentrated sulfuric acid red-brown, in glacial acetic acid brown-yellow soluble powder), is directly in the dye vat with 6 parts sodium hydroxide 40 ° Be., 2 parts hydrosulfite powder and 500 parts of water are heated to 60 ° until a red vat has formed, then 20 parts of crystallized Glauber's salt are added and the cotton V is dyed under the liquor at 60 ° for 2 hours. The color is unwound, imposed, rinsed, acidified and soaped at the boil. A beautiful, golden yellow, wash- and chlorine-fast coloration is obtained.
III. Das 14 · I4'-Bi-I2 · i2'-methylcoeramidonyl aus Di-α · a-anthrachinonyl-o-tolidin (braunrotes, in konzentrierter Schwefelsäure grün, in Eisessig rotbraun lösliches Pulver) wird in derselben Weise, wie in Beispiel II angegeben, verküpt und auf Baumwolle gefärbt. Die erhaltene Färbung ist kupferrot und wasch- und chlorecht. Wolle wird in der Küpe rotbraun gefärbt.III. The 14 · I4'-Bi-I2 · i2'-methylcoeramidonyl from di-α a-anthraquinonyl-o-tolidine (brown-red, green in concentrated sulfuric acid, in Glacial red-brown soluble powder) is given in the same way as in Example II, tubed and dyed on cotton. The color obtained is copper-red and wash- and chlorine law. Wool is dyed reddish brown in the vat.
PateNT-AνSPRUCH :PateNT CLAIM:
Verfahren zum Färben mit substituierten, keine Sulfogruppe enthaltenden Coeramidoninen, dadurch gekennzeichnet, daß man die mit alkalischen Küpungsmitteln reduzierten Farbstoffe aus der Küpe auf der Faser auffärbt.Process for dyeing with substituted, non-sulfo-containing coeramidonines, characterized in that the dyes reduced with alkaline cooling agents are removed from the vat the fiber discolors.
BERLIN. GEDRUCKT IN DER REICHSDRUCKEREI.BERLIN. PRINTED IN THE REICHSDRUCKEREI.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE246337C true DE246337C (en) |
Family
ID=505224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT246337D Active DE246337C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE246337C (en) |
-
0
- DE DENDAT246337D patent/DE246337C/de active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE246337C (en) | ||
| DE229708C (en) | ||
| DE949649C (en) | Process for dyeing and printing polyacrylonitrile fibers | |
| DE2016862C3 (en) | Process for the preparation of I to 1 and I to 2 metal complex azo dyes | |
| DE82270C (en) | ||
| AT148470B (en) | Process for the production of etchable, green-blue dyeings and prints on cellulose esters and ethers. | |
| DE565341C (en) | Process for the preparation of halogen-3, 4, 8, 9-dibenzpyrene-5, 10-quinones | |
| DE68381C (en) | ||
| DE402643C (en) | Process for the preparation of related dyes | |
| DE643244C (en) | Process for the production of azo dyes | |
| DE582263C (en) | Process for dyeing acetate silk | |
| DE269850C (en) | ||
| DE238982C (en) | ||
| DE184445C (en) | ||
| DE261737C (en) | ||
| DE729230C (en) | Process for printing animal fibers or cellulose fibers or fiber mixtures thereof with chromium stain dyes | |
| DE538315C (en) | Process for the preparation of Kuepen dyes | |
| DE564695C (en) | Process for the production of chromium-containing azo dyes | |
| DE108546C (en) | ||
| DE738049C (en) | Process for the production of acidic dyes of the naphthophenosafranin series | |
| DE595327C (en) | Process for the preparation of dyes or their intermediate products | |
| DE586180C (en) | Process for the preparation of chromium compounds of dyes | |
| DE548830C (en) | Process for the preparation of halogen-containing compounds of the dibenz and isodibenzanthrone series | |
| DE116546C (en) | ||
| DE413738C (en) | Process for the preparation of Kuepen dyes of the dibenzanthrone series |