DE242454C - - Google Patents

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Publication number
DE242454C
DE242454C DENDAT242454D DE242454DA DE242454C DE 242454 C DE242454 C DE 242454C DE NDAT242454 D DENDAT242454 D DE NDAT242454D DE 242454D A DE242454D A DE 242454DA DE 242454 C DE242454 C DE 242454C
Authority
DE
Germany
Prior art keywords
cement
sulfo
oleic acid
hydrocarbons
pores
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DENDAT242454D
Other languages
German (de)
Publication of DE242454C publication Critical patent/DE242454C/de
Active legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Claims (1)

KAISERLICHESIMPERIAL PATENTAMT.PATENT OFFICE. Es ist bekannt, Zementflächen, Kalksteine usw. durch Bestreichen mit Seifenlösung gegen das Eindringen von Wasser zu schützen. Dieses Verfahren hat jedoch so große Mängel, daß es sehr bald verlassen wurde. Zunächst war die Wirkung eine vorübergehende, denn die Lösungen der Seifen sind mehr oder weniger gelatinös und vermögen deshalb nicht in die Poren des Zements usw. einzudringen.It is known to counter cement surfaces, limestone, etc. by brushing with soap solution to protect the ingress of water. However, this procedure has such great flaws that it was abandoned very soon. At first the effect was temporary because the solutions of the soaps are more or less gelatinous and are therefore not capable of in penetrate the pores of the cement, etc. ίο Die Seifen der fixen Alkalien haben auch noch den Nachteil, auszuwittern und dadurch die Oberflächen unansehnlich zu machen und zu zerstören. Der Überzug wurde aus diesem Grunde bald abgewaschen und völlig unwirksam. ίο The soaps of the fixed alkalis also have nor the disadvantage of weathering and thereby making the surfaces unsightly and to destroy. For this reason the coating was soon washed off and completely ineffective. Allen diesen Übelständen begegnet das neue Verfahren; es besteht darin, daß zunächst Ölsäure durch Behandlung mit Schwefelsäure in Sulfoölsäure übergeführt wird. Die Ammonverbindung dieser Säure vermag, was bisher nicht bekannt war, infolge ihrer Leichtflüssigkeit in die Poren des Zements usw. einzudringen, so daß nicht nur die Oberfläche, sondern auch die darunter liegenden Schichten des Zements usw. durch die Bildung unlöslichen sulfoölsauren Kalks wasserundurchlässig gemacht und das Abwaschen durch Regen vermieden wird. Die Wirkung des sulfoölsauren Ammons wird wesentlich erhöht durch seine Eigenschaft, Kohlenwasserstoffe, wie Paraffin, nicht wie das einfache ölsäure Ammon nur zu emulgieren, sondern unter gewissen Bedingungen zu einer opalisierenden Flüssigkeit zu lösen. Der Vorteil dieser Eigenschaft für den beabsichtigten Zweck liegt auf der Hand. Die Kohlenwasserstoffe werden nicht wie bei einer Emulsion auf der Oberfläche der Steine usw., sondern innerhalb der Poren abgelagert und so vor dem Abwaschen geschützt. Es ist bekannt, Zement usw. mit Lösungen von Paraffin in Äther oder Benzin zu überziehen; dieses Verfahren ist aber nicht nur teuer, sondern wegen der hohen Feuergefährlichkeit, besonders in Innenräumen, unbrauchbar. The new procedure addresses all of these evils; it is that first of all Oleic acid is converted into sulfo oleic acid by treatment with sulfuric acid. The ammonium compound this acid is capable of what was previously unknown due to its light fluidity penetrate into the pores of the cement, etc., so that not only the surface but also the layers underneath of cement etc. impermeable to water due to the formation of insoluble sulfo-oleic lime and washing away by rain is avoided. The effect of sulfo oleic acid Ammons is greatly enhanced by its property of being hydrocarbons, like Paraffin, not just to emulsify like the simple oleic acid ammonium, but under certain circumstances Conditions to dissolve an opalescent liquid. The advantage of this property for the intended purpose is obvious. The hydrocarbons won't like an emulsion on the surface of the stones etc., but within the pores deposited and thus protected from washing off. It is known to use cement etc. with solutions of paraffin in ether or gasoline to cover; this process is not only expensive, but also because of the high degree of fire hazard, especially indoors, unusable. Pats ν t-An SPRU CH :Pats ν t-An SPRU CH: Verfahren, Zement, Kalksteine, Ziegel, Sandsteine usw. wasserdicht zu machen, dadurch gekennzeichnet, daß die Körper mit einer Lösung sulfoölsauren Ammons mit oder ohne Zusatz von Kohlenwasserstoffen durch Bestreichen,· Spritzen oder Eintauchen überzogen werden.Methods of waterproofing cement, limestone, brick, sandstone, etc., characterized in that the body is treated with a solution of sulfo-oil acid ammonium with or without the addition of hydrocarbons coated by brushing, spraying or dipping.
DENDAT242454D Active DE242454C (en)

Publications (1)

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DE242454C true DE242454C (en)

Family

ID=501657

Family Applications (1)

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Country Status (1)

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DE (1) DE242454C (en)

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