DE235668C - - Google Patents
Info
- Publication number
- DE235668C DE235668C DENDAT235668D DE235668DA DE235668C DE 235668 C DE235668 C DE 235668C DE NDAT235668 D DENDAT235668 D DE NDAT235668D DE 235668D A DE235668D A DE 235668DA DE 235668 C DE235668 C DE 235668C
- Authority
- DE
- Germany
- Prior art keywords
- green
- reserve
- real
- salt
- lye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 16
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims 1
- 238000006011 modification reaction Methods 0.000 claims 1
- 239000000276 potassium ferrocyanide Substances 0.000 claims 1
- OCPOWIWGGAATRP-UHFFFAOYSA-N potassium hexacyanoferrate(4-) Chemical compound [K+].[K+].[K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N OCPOWIWGGAATRP-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 210000004369 Blood Anatomy 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- 229940097275 Indigo Drugs 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 description 1
- XMOKRCSXICGIDD-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O XMOKRCSXICGIDD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical compound [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- VRWKTAYJTKRVCU-UHFFFAOYSA-N iron(6+);hexacyanide Chemical compound [Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] VRWKTAYJTKRVCU-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Color Printing (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
In der Patentschrift 231392 ist ein Verfahren zur Entwicklung von Echtdruckgrün auf der Faser mittels Natronlauge beschrieben. Während nun das in bekannter Weise durch Dämpfen entwickelte Echtdruckgrün mittels Hydrosulfit reserviert werden kann, war für das Laugeentwicklungsverfahren eine geeignete Reserve bisher nicht vorhanden.In patent specification 231392 there is a method for developing true print green written on the fiber using caustic soda. While now through this in a known manner Steaming developed real pressure green can be reserved by means of hydrosulfite was for the lye development process does not yet have a suitable reserve.
Es ist nun gefunden worden, daß sich für die Entwicklung des Echtdruckgrüns mittels Lauge Ferrocyankalium · als Reserve sehr gut eignet, dessen reservierende Wirkung vermutlich darauf beruht, daß das Eisenoxydulsalz der Echtdruckgrünfarbe in ferrocyanwasserstoffsaures Eisenoxydulkalium übergeführt und infolgedessen als Beize unwirksam gemacht wird.It has now been found that for the development of the true printing green means Potassium ferrocyanine lye · very well suited as a reserve, presumably its reserving effect is based on the fact that the iron oxide salt of the fast printing green color is in ferrocyanhydric acid Ferric oxide sulfate is transferred and is consequently rendered ineffective as a stain.
Eine solche Reserve setzt sich beispielsweise folgendermaßen zusammen:
150 g Ferrocyankalium,Such a reserve is composed, for example, as follows:
150 g ferrocyanic potassium,
550 g Wasser,
300 g British Gum550 g water,
300 g British Gum
ι 000 g.ι 000 g.
Man druckt die Reserve vor, überflatscht mit einer Echtdruckgründruckfarbe, passiert durch Natronlauge, wäscht, malzt und seift.You preprint the reserve, overflat it with a real printing green ink, pass through Caustic soda, washes, malts and soaps.
Die Reserve eignet sich nicht nur für den grünen Eisenlack, sondern auch für die ebenfalls nach dem Laugeverfahren herstellbaren orangenen bis braunen Töne, welche man erhält, wenn man essigsaures Nickel oder essigsaures Kobalt als Beize verwendet.The reserve is not only suitable for the green iron lacquer, but also for that too orange to brown shades that can be produced using the lye process and are obtained when using nickel acetic acid or cobalt acetic acid as the pickling agent.
Setzt man der gelben Blutlaugensalzreserve Indigosalz zu, so lassen sich unter den grünen, orangenen und braunen Echtdruckgrünlacken sehr hübsche Blaureserven erzielen. Man druckt in diesem Falle beispielsweise folgende Blaureserve vor:If indigo salt is added to the yellow blood liquor salt reserve, the green, orange and brown real printing green varnishes achieve very pretty blue reserves. Man In this case, for example, pre-prints the following blue reserve:
150 g Ferrocyankalium,
40 g Indigosalz,
60 g Bisulfit 38 ° Be.,
450 g Wasser,
300 g British Gum150 g ferrocyanic potassium,
40 g indigo salt,
60 g bisulfite 38 ° Be.,
450 g water,
300 g British Gum
4040
ι 000.ι 000.
Dann überflatscht man mit Echtdruckgrün und passiert durch Natronlauge.Then you overflat it with real printing green and pass through caustic soda.
Die auf diese Weise erzielbaren weißen und blauen Reservagen bilden eine willkommene Bereicherung des Echtdruckgrünlaugeartikels.The white and blue reserves that can be achieved in this way form a welcome one Enrichment of the real print green liquor article.
Für das durch Dämpfen entwickelte Echtdruckgrün eignet sich die Blutlaugensalzreserve nicht so gut; sie reserviert wohl, aber nicht genügend weiß.The blood liquor salt reserve is suitable for the real pressure green developed by steaming not so good; she does make reservations, but does not know enough.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE235668C true DE235668C (en) |
Family
ID=495415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT235668D Active DE235668C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE235668C (en) |
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0
- DE DENDAT235668D patent/DE235668C/de active Active
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