DE2341555A1 - HERBICIDE - Google Patents

HERBICIDE

Info

Publication number
DE2341555A1
DE2341555A1 DE19732341555 DE2341555A DE2341555A1 DE 2341555 A1 DE2341555 A1 DE 2341555A1 DE 19732341555 DE19732341555 DE 19732341555 DE 2341555 A DE2341555 A DE 2341555A DE 2341555 A1 DE2341555 A1 DE 2341555A1
Authority
DE
Germany
Prior art keywords
triazine
spp
substituted
chloro
ethylamino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19732341555
Other languages
German (de)
Inventor
Adolf Dr Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE19732341555 priority Critical patent/DE2341555A1/en
Priority to NL7410015A priority patent/NL7410015A/en
Priority to NO74742745A priority patent/NO742745L/no
Priority to IL45424A priority patent/IL45424A0/en
Priority to FR7427724A priority patent/FR2240687A1/en
Priority to DK435874A priority patent/DK435874A/da
Priority to BR6732/74A priority patent/BR7406732D0/en
Priority to DD180518A priority patent/DD112341A5/xx
Priority to JP49092866A priority patent/JPS5042048A/ja
Priority to SE7410427A priority patent/SE7410427L/xx
Priority to ZA00745268A priority patent/ZA745268B/en
Priority to LU70746A priority patent/LU70746A1/en
Priority to BE147681A priority patent/BE818932A/en
Priority to EG339/74A priority patent/EG11774A/en
Publication of DE2341555A1 publication Critical patent/DE2341555A1/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C07D285/01—Five-membered rings
    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/14—Thiadiazoles; Hydrogenated thiadiazoles condensed with carbocyclic rings or ring systems

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

in der X Methoxy und Y Chlor bedeutet, wenn R Wasserstoff und R, Methoxy bedeutet und wenn R einen Cycloalkenylrest bedeutet, bedeutet R1 Wasserstoff, Methoxy, Methyl und Y und X bedeuten Halogen, Methyl, Methoxy, Trifluormethyl und Wasserstoffin which X denotes methoxy and Y denotes chlorine, when R denotes hydrogen and R denotes methoxy and when R denotes a cycloalkenyl radical, R 1 denotes hydrogen, methoxy, methyl and Y and X denote halogen, methyl, methoxy, trifluoromethyl and hydrogen

und
b) einer Verbindung der Formeland
b) a compound of the formula

in der X Chlor, Brom, Cyan, Hydroxy, Methoxy, Thiomethyl, Thioäthyl, Azide, R, R1 gleich oder verschieden sind und Wasserstoff, einen gegebenenfalls durch Cyan, Halogen, Alkoxy, Hydroxy substituierten geraden oder verzweigten Alkyl-, Alkenyl- oder Alkinylrest mit bis zu 7 C-Atomen, Cycloalkyl, Acetyl, Alkylacetyl, Y dieselben Bedeutungen hat wie R und R1 und Y außerdem Thioalkyl oder Amino bedeutet,in which X is chlorine, bromine, cyano, hydroxyl, methoxy, thiomethyl, thioethyl, azides, R, R 1 are identical or different and are hydrogen, a straight or branched alkyl, alkenyl or substituted by cyano, halogen, alkoxy or hydroxy Alkynyl radical with up to 7 carbon atoms, cycloalkyl, acetyl, alkylacetyl, Y has the same meanings as R and R 1 and Y also denotes thioalkyl or amino,

391/73 509809/1118 /2 391/73 509809/1118 / 2

und gegebenenfalls c) einer Verbindung der Formeland optionally c) a compound of the formula

!I! I

Ri R i

in der R einen niederen Alkylrest, R, Wasserstoff und dessen Salze bedeutet,in which R is a lower alkyl radical, R is hydrogen and its salts,

eine bessere herbizide Wirkung als die Einzelwirkstoffe hat.has a better herbicidal effect than the individual active ingredients.

Die Mischungen können eine oder mehrere Verbindungen der Formel a und b und gegebenenfalls c enthalten.The mixtures can contain one or more compounds of the formulas a and b and optionally c.

Die Mischungsverhältnisse können beliebig gewählt werden. Das Mischungsverhältnis der Wirkstoffe a zu b und/oder c beträgt 0,1 bis 10 Gewichtsteile a zu 1 Gewichtsteil b und/oder c, vorzugsweise 0,3 bis 3 Gewichtsteile a zu 1 Gewichtsteil b und/oder c.The mixing ratios can be chosen as desired. The mixing ratio of the active ingredients a to b and / or c is 0.1 to 10 parts by weight of a to 1 part by weight of b and / or c, preferably 0.3 to 3 parts by weight of a to 1 part by weight of b and / or c.

Die erfindungsgemäßen Mittel können in ihrer aufgewandten Menge schwanken. Die aufgewandte Menge hängt hauptsächlich von der Art des gewünschten Effektes ab. Die Aufwandmenge liegt im allgemeinen zwischen 0,1 und 30 oder mehr, vorzugsweise 0,2 bis 6 kg Wirkstoff pro Hektar. Die erfindungsgemäßen Mittel können u. a. im Vorpflanz-, Nachpflanz-, Vorsaat-, Vorauflauf-, Nachauf lauf verfahren oder während des Auflaufens der Kulturpflanzen oder unerwünschten Pflanzen ein- oder mehrmals angewandt werden.The agents according to the invention can vary in the amount used. The amount used mainly depends on the The type of effect you want. The application rate is generally between 0.1 and 30 or more, preferably 0.2 to 6 kg of active ingredient per hectare. The agents according to the invention can inter alia. in pre-planting, post-planting, pre-sowing, pre-emergence, post-emergence run away or during emergence of the crops or unwanted plants are applied one or more times.

Die Mischungen sind geeignet in Nutzpflanzen, z. B. Triticum spp., Hordeum vulgäre, Seeale cereale, Gossypium hirsutum, Zea mays, Solanum tuberosum, Pisum sativum, Daucus carota, Phaseolus vulgaris, Nicotiana tabacum, Soja max., Vitis vinifera, unerwünschte Pflanzen zu bekämpfen.The mixtures are useful in crops, e.g. B. Triticum spp., Hordeum vulgare, Seeale cereale, Gossypium hirsutum, Zea mays, Solanum tuberosum, Pisum sativum, Daucus carota, Phaseolus vulgaris, Nicotiana tabacum, soy max., Vitis vinifera, undesirable Combat plants.

Außerdem können die Mischungen als Totalmittel an Gräben, Gewässern, Gleisanlagen, auf Kahlflächen, Ödland etc. angewandtIn addition, the mixtures can be used as a total mean in ditches, bodies of water, Track systems, applied to bare areas, wasteland, etc.

werden.will.

/3 509809/1 118/ 3 509809/1 118

- 3 - 0·Ζ. 30 054- 3 - 0. 30 054

Die Anwendung erfolgt ζ. B. in Form von direkt versprühbaren Lösungen, Pulvern, Suspensionen oder Dispersione, Emulsionen, öldispersionen, Pasten* Stäubemitteln, Streumitteln, Granulaten durch Versprühen, Vernebeln, Verstäuben, Verstreuen oder Gießen. Die Anwendungsformen richten sich ganz nach den Verwendungszwecken;; sie sollten in jedem Fall möglichst die feinste Verteilung der erfindungsgemäßen Wirkstoffe gewährleisten.The application takes place ζ. B. in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes * dusts, grit, granules by spraying, misting, dusting, scattering or watering. The forms of application depend entirely on the intended use ;; in any case, they should ensure the finest possible distribution of the active ingredients according to the invention.

Zur Herstellung von direkt versprühbaren Lösungen, Emulsionen, Pasten und öldispersionen kommen Mineralölfraktionen von mittlerem bis hohem Siedepunkt, wie Kerosin oder Dieselöl, ferner Kohlenteeröle usw., sowie öle pflanzlichen oder tierischen Ursprungs, aliphatische, cyclische und aromatische Kohlenwasserstoffe, ζ. B. Benzol, Toluol, Xylol, Paraffin, Tetrahydronaphthalin, alkylierte Naphthaline oder deren Derivate, ζ. Β. Methanol, Äthanol, Propanol, Butanol, Chloroform, Tetrachlorkohlenstoff, Cyclohexanol, Cyclohexanon, Chlorbenzol, Isophoron usw., stark polare Lösungsmittel, wie z. B. Dimethylformamid, Dimethylsulfoxid, N-Methylpyrrolidon, Wasser usw. in Betracht.For the production of directly sprayable solutions, emulsions, pastes and oil dispersions, mineral oil fractions are used by medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils etc., as well as oils of vegetable or animal origin Origin, aliphatic, cyclic and aromatic hydrocarbons, ζ. B. benzene, toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, ζ. Β. Methanol, ethanol, propanol, butanol, chloroform, carbon tetrachloride, cyclohexanol, cyclohexanone, chlorobenzene, isophorone etc., strongly polar solvents such as. B. dimethylformamide, Dimethyl sulfoxide, N-methylpyrrolidone, water, etc. into consideration.

Wäßrige Anwendungsformen können aus Emulsionskonzentraten, Pasten oder netzbaren Pulvern (Spritzpulvern), öldispersionen durch Zusatz von Wasser bereitet werden. Zur Herstellung von Emulsionen, Pasten oder öldispersionen können die Substanzen als solche oder in einem öl oder Lösungsmittel gelöst, mittels Netz-, Haft-, Dispergier- oder Emulgiermittel in Wasser homogenisiert werden. Es können aber auch aus wirksamer Substanz, Netz-, Haf-t-, Dispergier- oder Emulgiermittel land eventuell Lösungsmittel oder öl bestehende Konzentrate hergestellt werden, die zur Verdünnung mit Wasser geeignet sind.Aqueous application forms can be obtained from emulsion concentrates, pastes or wettable powders (wettable powders), oil dispersions can be prepared by adding water. For the production of emulsions, Pastes or oil dispersions can use the substances as such or dissolved in an oil or solvent, by means of wetting, adhesive, Dispersants or emulsifiers are homogenized in water. But it can also consist of active substances, network, Haf-t, Dispersants or emulsifiers may be used to produce concentrates consisting of solvents or oils, which are then used for dilution with water are suitable.

An oberflächenaktiven Stoffen sind zu nennen: Alkali-, Erdalkali-, Ammoniumsalze von Ligninsulfonsäure, NaphthaTinsulfonsäuren, Phenolsulfonsäuren, Alkylarylsulfonate, Alkylsulfate, Alkylsulfonate, Alkali- und Erdalkalisalze der Dibutylnaphthalinsulfonsäure, Lauryläthersulfat, Fettalkoholsulfate, fettsaure Alkali- und Erdalkalisalze, Salze sulfatierter Hexadecanole, Heptadecanole, Octadecanole, Salze von sulfatiertem Fettalkoholglykoläther, Kondensationsprodukte von sulfoniertem NaphthalinThe following surface-active substances should be mentioned: alkali, alkaline earth, Ammonium salts of ligninsulphonic acid, naphthatinsulphonic acids, phenolsulphonic acids, alkylarylsulphonates, alkylsulphates, alkylsulphonates, Alkali and alkaline earth salts of dibutylnaphthalene sulfonic acid, lauryl ether sulfate, fatty alcohol sulfates, fatty acid Alkali and alkaline earth salts, salts of sulfated hexadecanols, heptadecanols, octadecanols, salts of sulfated fatty alcohol glycol ethers, Sulfonated naphthalene condensation products

509809/1118 Λ509809/1118 Λ

- 4 - O9Z. 30 Üij4- 4 - O 9 Z. 30 Üij4

und Naphthalinderivaten mit Formaldehyd, Kondensationsprodukte des Naphthalins bzw. der Naphthalinsulfonsäuren mit Phenol und Formaldehyd, Polyoxyäthylen-octylphenoläther, äthoxyliertes Isooctylphenol, - Octylphenol, - Nonylphenol, Alkylphenolpolyglykoläther, Tributylphenylpolyglykoläther, Alkylarylpolyätheralkohole, Isotridecylalkohol, Fettalkoholäthylenoxid-Kondensate, äthoxyliertes Rizinusöl, Polyoxyäthylenalkyläther, äthoxyliertes Polyoxypropylen, Laurylalkoholpolyglykolätheracetal, Sorbitester, Lignin, Sulfitablaugen und Methylcellulose.and naphthalene derivatives with formaldehyde, condensation products of naphthalene or naphthalene sulfonic acids with phenol and Formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, - octylphenol, - nonylphenol, alkylphenol polyglycol ether, Tributylphenyl polyglycol ethers, alkylaryl polyether alcohols, isotridecyl alcohol, fatty alcohol ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, Sorbitol esters, lignin, sulphite waste liquors and methyl cellulose.

Pulver, Streu- und Stäubemittel können durch Mischen oder gemeinsames Vermählen der wirksamen Substanzen mit einem festen Trägerstoff hergestellt werden.Powder, grit and dust can be mixed or mixed together Milling of the active substances with a solid carrier.

Granulate, z. B. Umhüllungs-, Imprägnierungs- und Homogengranulate, können durch Bindung der Wirkstoffe an feste Trägerstoffe hergestellt werden. Feste Trägerstoffe sind z. B. Mineralerden wie Silicagel, Kieselsäuren, Kieselgele, Silikate, Talkum, Kaolin, Attaclay, Kalkstein, Kalk, Kreide, Bolus, Löß, Ton, Dolomit, Diatomeenerde, Calcium- und Magnesiumsulfat, Magnesiumoxid, gemahlene Kunststoffe, Düngemittel, wie z. B. Ammoniumsulfat, Ammoniumphosphat, Ammoniumnitrat, Harnstoffe und pflanzliche Produkte, wie Getreidemehle, Baumrinden-, Holz- und Nußschalenmehl, Cellulosepulver und andere feste Trägerstoffe.Granules, e.g. B. coating, impregnation and homogeneous granules, can be produced by binding the active ingredients to solid carriers. Solid carriers are e.g. B. Mineral earths like silica gel, silicas, silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, Dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, fertilizers, such as. B. ammonium sulfate, Ammonium phosphate, ammonium nitrate, ureas and vegetable products such as flour, tree bark, wood and nut shell flour, Cellulose powder and other solid carriers.

Die Formulierungen enthalten zwischen 0,1 und 95 Gewichtsprozent Wirkstoff, vorzugsweise zwischen 0,5 und 90 Gewichtsprozent.The formulations contain between 0.1 and 95 percent by weight of active ingredient, preferably between 0.5 and 90 percent by weight.

Zu den Mischungen oder Einzelwirkstoffen können öle verschiedenen Typs, Herbizide, Fungizide, Nematozide, Insektizide, Bakterizide, Spurenelemente, Düngemittel, Antischaummittel (z. B. Silikone), Wachstumsregulatoren, Antidotmittel oder andere herbizid wirksame Verbindungen, wie z. B.
substituierte Aniline
substituierte Aryloxycarbonsäuren sowie deren Salze, Ester undThe mixtures or individual active ingredients can include oils of various types, herbicides, fungicides, nematocides, insecticides, bactericides, trace elements, fertilizers, antifoams (e.g. silicones), growth regulators, antidotes or other herbicidally active compounds, such as. B.
substituted anilines
substituted aryloxycarboxylic acids and their salts, esters and

AmideAmides

substituierte Äthersubstituted ethers

substituierte Arsonsäuren sowie deren Salze, Ester und Amide substituierte Benzimidazolesubstituted arsonic acids and their salts, esters and amides substituted benzimidazoles

5 0 9 8 0 9/1118 /5 5 0 9 8 0 9/1118 / 5

- 5 - O.Z. ^o 054- 5 - O.Z. ^ o 054

substituierte Benzisothiazole substituierte Benzthiadiazinondioxide substituierte Benzoxazine substituierte Benzoxazinone substituierte Benzthiadiazole substituierte Biurete substituierte Chinoline substituierte Carbamatesubstituted benzisothiazoles substituted benzthiadiazinone dioxides substituted benzoxazines substituted benzoxazinones substituted benzthiadiazoles substituted biurets substituted quinolines substituted carbamates

substituierte aliphatische Carbonsäuren sowie deren Salze,substituted aliphatic carboxylic acids and their salts,

Ester und Amide
substituierte aromatische Carbonsäuren sowie deren Salze,Esters and amides
substituted aromatic carboxylic acids and their salts,

Ester und AmideEsters and amides

substituierte Carbamoylalkyl-thiol- oder -dithiophosphate substituierte Chinazoline
substituierte Cycloalkylamidocarbonthiolsäuren sowie derensubstituted carbamoylalkyl thiol or dithiophosphates substituted quinazolines
substituted Cycloalkylamidocarbonthiolsäuren and their

Salze, Ester und AmideSalts, esters and amides

substituierte Cycloalkylcarbonamido-thiazole substituierte Dicarbonsäuren sowie Salze, Ester und Amide substituierte Dihydrobenzofuranylsulfonate substituierte Disulfide
substituierte Dipyridyliumsalze
substituierte Dithiocarbamate
substituierte Dithiophosphorsäuren sowie deren Salze, Estersubstituted cycloalkylcarbonamidothiazoles substituted dicarboxylic acids and salts, esters and amides substituted dihydrobenzofuranylsulfonates substituted disulfides
substituted dipyridylium salts
substituted dithiocarbamates
substituted dithiophosphoric acids and their salts, esters

und Amideand amides

substituierte Harnstoffe substituierte Hexahydro-IH-carbothioate substituierte Hydantoine substituierte Hydrazide substituierte Hydrazoniumsalze substituierte Isooxazolpyrimidone substituierte Imidazole substituierte Isothiazolpyrimidone substituierte Ketone substituierte Naphtochinone substituierte aliphatische Nitrile substituierte aromatische Nitrile substituierte Oxadiazole substituierte Oxadiazinone substituierte Oxadiazolidindionesubstituted ureas substituted hexahydro-IH-carbothioate substituted hydantoins substituted hydrazides substituted hydrazonium salts substituted isooxazole pyrimidones substituted imidazoles substituted isothiazole pyrimidones substituted ketones substituted naphthoquinones substituted aliphatic nitriles substituted aromatic nitriles substituted oxadiazoles substituted oxadiazinones substituted oxadiazolidinediones

509809/1118509809/1118

- 6 - O.Z. 30 054- 6 - O.Z. 30 054

substituierte Oxadiazindione substituierte Phenole sowie deren Salze und Estersubstituted oxadiazinediones substituted phenols and their salts and esters

substituierte Phosphonsäuren sowie deren Salze, Ester und Amidesubstituted phosphonic acids and their salts, esters and amides

substituierte Phosphoniumchloride substitui erte Phosphonalkylglyzine substituierte Phosphitesubstituted phosphonium chlorides substituted phosphonalkylglyzines substituted phosphites

substituierte Phosphorsäuren sowie deren Salze, Ester und Amidesubstituted phosphoric acids and their salts, esters and amides

substituierte Piperidine substituierte Pyrazolesubstituted piperidines substituted pyrazoles

substituierte Pyrazolalkylcarbonsäuren sowie deren Salze, Estersubstituted pyrazole alkyl carboxylic acids and their salts, esters

und Amideand amides

substituierte Pyrazoliumsalze substituierte Pyrazoliumalkylsulfate substituierte Pyridazine substituierte Pyridazone substituierte Pyridinearbonsäuren sowie deren Salze, Ester undsubstituted pyrazolium salts substituted pyrazolium alkyl sulfates substituted pyridazines substituted pyridazones substituted pyridinearboxylic acids and their salts, esters and

AmideAmides

substituierte Pyridine substituierte Pyridincarboxylate substituierte Pyridinone substituierte Pyrimidine substituierte Pyrimidone substituierte Pyrrolidincarbonsäure sowie deren Salze, Estersubstituted pyridines substituted pyridine carboxylates substituted pyridinones substituted pyrimidines substituted pyrimidones substituted pyrrolidinecarboxylic acids and their salts, esters

und Amideand amides

substituierte Pyrrolidine substituierte Pyrrolidone substituierte Arylsulfonsäuren sowie deren Salze, Ester und Amidesubstituted pyrrolidines substituted pyrrolidones substituted arylsulfonic acids and their salts, esters and Amides

substituierte Styrole substituierte Tetrahydro-oxadiazindione substituierte Tetrahydro-oxadlazoldione substituierte Tetrahydromethanoindene substituierte Tetrahydro-diazol-thione substituierte Tetrahydro-thiadiazin-thione substituierte Tetrahydro-thiadiazoldione substituierte aromatische Thiocarbonsäureamide substituierte Thiocarbonsäuren sowie deren Salze, Ester undsubstituted styrenes substituted tetrahydro-oxadiazinediones substituted tetrahydro-oxadlazoldiones substituted tetrahydromethanoindenes substituted tetrahydro-diazole-thiones substituted tetrahydro-thiadiazine-thiones substituted tetrahydro-thiadiazole-diones substituted aromatic thiocarboxamides substituted thiocarboxylic acids and their salts, esters and

Amide
substituierte ThiolcarbamateAmides
substituted thiol carbamates

509809/1113 /7 509809/1113 / 7

- 7 - O.Z. 30 054- 7 - O.Z. 30 054

23A155523A1555

substituierte Thioharnstoffesubstituted thioureas

substituierte Thiophosphorsäure sowie deren Salze, Ester undsubstituted thiophosphoric acid and its salts, esters and

AmideAmides

substituierte Triazine
substituierte Triazole
substituierte Uracile
substituierte Uretidindionesubstituted triazines
substituted triazoles
substituted uracils
substituted uretidinediones

gegebenenfalls auch erst unmittelbar vor der Anwendung (Tankmix) zugesetzt werden. Die zuletzt genannten herbiziden Verbindungen können auch vor oder nach den erfindungsgemäßen Einzelwirkstoffen oder Mischungen zur Anwendung gebracht werden.if necessary, only added immediately before use (tank mix). The last-mentioned herbicidal compounds can also be used before or after the individual active ingredients or mixtures according to the invention.

Die Zumischung dieser Mittel zu den erfindungsgemäßen Herbiziden kann im Gewichtsverhältnis 1 : 10 bis 10 : 1 erfolgen. Das Gleiche gilt für öle, Fungizide, Nematozide, Insektizide, Bakterizide, Antidotmittel und Wachstumsregulatoren.These agents can be admixed with the herbicides according to the invention in a weight ratio of 1:10 to 10: 1. That The same applies to oils, fungicides, nematocides, insecticides, bactericides, antidotes and growth regulators.

Die Mittel weisen einen starken herbiziden Effekt auf und können deshalb als Unkräutvernichtungsmittel bzw. zur Bekämpfung unerwünschten Pflanzenwuchses verwendet werden. Ob die Mittel als totale oder selektive Mittel wirken, hängt hauptsächlich von der Wirkstoffmenge je Flächeneinheit ab.The compositions have a strong herbicidal effect and can therefore be used as weed killers or for combating undesirable Plant growth can be used. Whether the remedies act as total or selective agents depends mainly on the Amount of active ingredient per unit area.

Unter Unkräuter bzw. unerwünschten Pflanzenwuchses sind alle monokotylen und dikotylen Pflanzen zu verstehen, die an Orten aufwachsen, wo sie nicht erwünscht sind.Weeds or unwanted vegetation are to be understood as meaning all monocotyledonous and dicotyledonous plants that are in places grow up where they are not wanted.

So können mit den erfindungsgemäßen Mitteln beispielsweise Gramineen, wieFor example, Gramineae, such as

Cynodon spp. Dactylis spp.Cynodon spp. Dactylis spp.

Digitaria spp. Avena spp.Digitaria spp. Avena spp.

Echinochloa spp. Bromus spp.Echinochloa spp. Bromus spp.

Setaria spp. Uniola spp.Setaria spp. Uniola spp.

Panicum spp. Poa spp.Panicum spp. Poa spp.

Alopecurus spp. Leptochloa spp.Alopecurus spp. Leptochloa spp.

Lolium spp. Brachiaria spp.Lolium spp. Brachiaria spp.

Sorghum spp. Eleusine spp.Sorghum spp. Eleusine spp.

Agropyron spp. Cenchrus spp.Agropyron spp. Cenchrus spp.

Phalaris spp. Eragrostis spp.Phalaris spp. Eragrostis spp.

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2 3 4 15 52 3 4 15 5

Apera spp. und andereApera spp. and other

Cyperaceae, wie Carex spp. Cyperus spp. und andereCyperaceae such as Carex spp. Cyperus spp. and other

dikotyle Unkräuter, wie Malvaceae, ζ. Β. Abutilon theoprasti Sida spp. und anderedicot weeds, such as Malvaceae, ζ. Β. Abutilon theoprasti Sida spp. and other

Compositae, wie Ambrosia spp. Lactuca spp. Senecio spp. Sonchus spp. Xanthium spp. Iva spp.
Galinsoga spp. Taraxacum spp. Chrysanthemum spp. Cirsium spp.Compositae such as Ambrosia spp. Lactuca spp. Senecio spp. Sonchus spp. Xanthium spp. Iva spp.
Galinsoga spp. Taraxacum spp. Chrysanthemum spp. Cirsium spp.

Convolvulaceae, wie Convolvulus spp. Ipomoea spp. und andereConvolvulaceae such as Convolvulus spp. Ipomoea spp. and other

Cruciferae, wie Barbarea vulgaris Brassica spp. Capsella spp. Sisymbrium spp. Thlaspi spp. Sinapis arvensis und andereCruciferae such as Barbarea vulgaris Brassica spp. Capsella spp. Sisymbrium spp. Thlaspi spp. Sinapis arvensis and others

Geraniaceae, wie Erodium spp. und andere Phragmites communisGeraniaceae such as Erodium spp. and other Phragmites communis

Eleocharis spp. Scirpus spp.Eleocharis spp. Scirpus spp.

Hibiscus spp. Malva spp.Hibiscus spp. Malva spp.

Centaurea spp. Tussilago spp. Lapsana communis Tagetes spp. Erigeron spp. Anthemis spp. Matricaria spp. Artemisia spp. Bidens spp. und andereCentaurea spp. Tussilago spp. Lapsana communis Tagetes spp. Erigeron spp. Anthemis spp. Matricaria spp. Artemisia spp. Bidens spp. and other

Cuscuta spp. Jaquemontia tamnifoliaCuscuta spp. Jaquemontia tamnifolia

Arabidopsis thaliana Descurainia spp. Draba spp. Coronopus didymus Lepidium spp. Raphanus spp.Arabidopsis thaliana Descurainia spp. Draba spp. Coronopus didymus Lepidium spp. Raphanus spp.

Geranium spp.Geranium spp.

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Portulacaceae, wie Portulaca spp.Portulacaceae such as Portulaca spp.

Primulaceae, wie Anagallis arvensis und anderePrimulaceae such as Anagallis arvensis and other

Rubiaceae, wie Richardia spp. Galium spp.Rubiaceae such as Richardia spp. Galium spp.

Scrophulariaceae, wie Linaria spp. Veronica spp.Scrophulariaceae such as Linaria spp. Veronica spp.

Solanaceae, wie Physalis spp. Solanum spp. und andereSolanaceae such as Physalis spp. Solanum spp. and other

Urticaceae, wie Urtica spp.Urticaceae such as Urtica spp.

Violaceae/ wie Viola spp.Violaceae / like Viola spp.

Zygophyllaceae, wie Tribulus terrestisZygophyllaceae such as Tribulus terrestis

Euphorbiaceae, wie Mercurialis annuaEuphorbiaceae such as Mercurialis annua

Umbelliferae, wie Daucus carota Aethusa cynapiumUmbelliferae such as Daucus carota Aethusa cynapium

Commelinaeae, wie Comtnelina spp.Commelinaeae such as Comtnelina spp.

Labiatae, wie Lamium spp. und andereLabiatae such as Lamium spp. and other

Leguminpsae, wie Medicago spp. Trifolium spp. Vicia spp. und andereLeguminpsae such as Medicago spp. Trifolium spp. Vicia spp. and other

und andere Lysimachia spp.and other Lysimachia spp.

Diodia spp. und andereDiodia spp. and other

Digitalis spp. und andereDigitalis spp. and other

Nicandra spp. Datura spp.Nicandra spp. Datura spp.

und andere und andere Euphorbia spp.and other and other Euphorbia spp.

Ammi majus und andere und andere Galeopsis spp.Ammi majus and others and others Galeopsis spp.

Sesbania exaltata Cassia spp. Lathyrus spp.Sesbania exaltata Cassia spp. Lathyrus spp.

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Plantaginaceae, wie Plantago spp.Plantaginaceae such as Plantago spp.

Polygonaceae, wie Polygonum spp. Rumex spp.Polygonaceae such as Polygonum spp. Rumex spp.

Aizoaceae, wie Mollugo verticillataAizoaceae, such as Mollugo verticillata

Amaranthaceae, wie Araaranthus spp.Amaranthaceae such as Araaranthus spp.

Boraginaceae, wie Amsinckia spp. Myostis spp. und andereBoraginaceae such as Amsinckia spp. Myostis spp. and other

Caryophyllaceae, wie Stellaria spp. Spergula spp. Saponaria spp. Scleranthus annuusCaryophyllaceae such as Stellaria spp. Spergula spp. Saponaria spp. Scleranthus annuus

Chenopodiaceae, wie Chenopodium spp. Kochia spp. Salsola KaliChenopodiaceae such as Chenopodium spp. Kochia spp. Salsola potash

Lythraceae, wie Cuphea spp.Lythraceae such as Cuphea spp.

Oxalidaceae, wie Oxalis spp.Oxalidaceae such as Oxalis spp.

Ranuneulaeeae, wie Ranunculus spp. Delphinium spp.Ranuneulaeeae such as Ranunculus spp. Delphinium spp.

Papaveraceae, wie Papaver spp. und anderePapaveraceae such as Papaver spp. and other

Onagraceae, wie Jussiaea spp. und andereOnagraceae such as Jussiaea spp. and other

Fagopyrum spp. und andereFagopyrum spp. and other

und andere und andereand others and others

Anchusa spp. Lithospermum spp.Anchusa spp. Lithospermum spp.

SiIene spp. Cerastium spp. Agrostemma githago und andereSiIene spp. Cerastium spp. Agrostemma pallida and others

Atriplex spp. Monolepsis nuttalliana und andereAtriplex spp. Monolepsis nuttalliana and other

und andereand other

Adonis spp. und andereAdonis spp. and other

Fumaria officinalis und andereFumaria officinalis and others

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Rosaceae, wie Alchemillia spp. und andereRosaceae such as Alchemillia spp. and other

Potamogetonaceae, wie Potamogeton spp.Potamogetonaceae such as Potamogeton spp.

Najadaceae, wie Najas spp.Najadaceae such as Najas spp.

Marsileaceae, wie Marsilea quadrifoliaMarsileaceae, such as Marsilea quadrifolia

Polypodiaceae, wie Pteridium aguilinumPolypodiaceae such as Pteridium aguilinum

Alismataceae, wie Alisma spp. und andereAlismataceae such as Alisma spp. and other

Equisetaceae, wie Equisetaceae spp.Equisetaceae such as Equisetaceae spp.

bekämpft werden.be fought.

Potentilla spp.Potentilla spp.

und andere und andere und andereand others and others and others

Sagittaria sagittifoliaSagittaria sagittifolia

und andereand other

Im Gewächshaus und im Freiland wurden die Verbindungen 2-Chlor-4-allylamino-6-(P-methoxypropyl)-amino-1,3,5-triazin 2-Chlor-4-allylamino-6-n-propylamino-l,3,5-triazin 2-Chlor-4-allylamino-6-isopropylamino-1,3*5-triazin 2- Chlor- 4-allylamino-6-ß-methoxyäthylamino-1,3,5- triazin 2-Chlor-4-isopropylamino-6-hydroxymethylamino-l,3,5-triazin 2-Ghlor-4-cyclopropylamino-6-isopropylamino-l,3,5-triazin 2-Chlor-4,6-bis-(diäthylamino)-l,3*5-triazin 2-Chlor-4-isopropylamino-6-n-propylamino-1,3,5-triazin 2-Chlor-4-äthylamino-6-sec-butylamino-l,3,5-triazin 2-Chlor-4-äthylamino-6-butin-(l)-yl-(3)-amino~1,3,5-triazin 2-Chlor-4,6-diäthylamino-l,3»5-triazin 2-Chlor-4-äthylamino-6-isopropylamino-l,3>5-fcriazin 2-Chlor-4-äthylamino-6-tert.-butylamino-l,3*5-triazin 2-Chlor-4-äthylamino-6-diäthylamino-1,3,5-triazin 2-Chlor-4-diäthylamino-6-i sopropylamino-1,3,5-triazin 2-Chlor-4,6-diisopropylamino-l,3,5-triazin 2-Chlor-4-äthylamino-6-J^-niethoxypropylamino-1,3,5-triazinIn the greenhouse and in the field, the compounds 2-chloro-4-allylamino-6- (P-methoxypropyl) -amino-1,3,5-triazine 2-chloro-4-allylamino-6-n-propylamino-1,3,5-triazine 2-chloro-4-allylamino-6-isopropylamino-1,3 * 5-triazine 2-chloro-4-allylamino-6-ß-methoxyethylamino-1,3,5-triazine 2-chloro-4-isopropylamino-6-hydroxymethylamino-1,3,5-triazine 2-chloro-4-cyclopropylamino-6-isopropylamino-1,3,5-triazine 2-chloro-4,6-bis (diethylamino) -l, 3 * 5-triazine 2-chloro-4-isopropylamino-6-n-propylamino-1,3,5-triazine 2-chloro-4-ethylamino-6-sec-butylamino-1,3,5-triazine 2-chloro-4-ethylamino-6-butyn- (1) -yl- (3) -amino ~ 1,3,5 -triazine 2-chloro-4,6-diethylamino-1,3 »5-triazine 2-chloro-4-ethylamino-6-isopropylamino-1,3> 5-fcriazine 2-chloro-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine 2-chloro-4-ethylamino-6-diethylamino-1,3,5-triazine 2-chloro-4-diethylamino-6-isopropylamino-1,3,5-triazine 2-chloro-4,6-diisopropylamino-1,3,5-triazine 2-chloro-4-ethylamino-6-1-4 -niethoxypropylamino-1,3,5-triazine

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2-Chlor-4-isopropylamino-ö-methylamino-1,3,5-triazin 2-Chlor-4-isopropylamino-6-/L-methoxypropylamino-l,3*5-triazin 2-Chlor-4-äthylamino-6-ß-(f-methoxy-propylamino-1,3,5-triazin 2-(2-Chlor-4-methylamino-l,3,5-triazin-6-yl-amino)-2-methyl-2-chloro-4-isopropylamino-δ-methylamino-1,3,5-triazine 2-chloro-4-isopropylamino-6- / L- methoxypropylamino-1,3 * 5-triazine 2-chloro-4-ethylamino-6 -ß- (f-methoxy-propylamino-1,3,5-triazine 2- (2-chloro-4-methylamino-1,3,5-triazin-6-yl-amino) -2-methyl-

propionitril
2-(2-Chlor-4-äthylamino-l,3,5-triazin-6-yl-amino)-2-methyl-propionitrile
2- (2-chloro-4-ethylamino-1,3,5-triazin-6-yl-amino) -2-methyl-

propionitrilpropionitrile

2-Methoxy-4-methylamino-6-isopropylan^ino-l, 3,5-triazin 2-Methoxy-4-äthylamino-6-tert.-butylaraino-l,3,5-triazin 2-Me thoxy-4, 6-di- (3-methoxypropylamino)-1,3*5- triazin 2-Methoxy-4,6-bis-(äthylamino)-1,3,5-triazin a-Methoxy-^-äthylamino-ö- sec. -butylatnino-1,3,5- triazin 2-Methoxy-4-ß-methoxyäthylamino-6-isopropylamino-1,3,5-triazin 2-Methoxy-4-äthylamino-6-isopropylaInino-1,3, 5- triazin 2-Methoxy-il-,6-diisopropylamino-l,3,5-triazin 2-Methoxy-4-isopropylamino-6-diäthylamino-l,3,5-triazin 2-Methoxy-il-methylamino-6- sec. -butylatnino-1,3,5-triazin 2-Methoxy-4-isopropylamino-6-acetylatnino-l,3,5-triazin 2-Methoxy-4-isopropylamino-6-äthylacetylamino-l,3,5-triazin K 2-Me thoxy-4- (J -methoxypropyl) -amino-6- isoamylamino-1,3,5- triazin 2-Methylthio-4-isopropylamino-6-sec.-butylamino-l,3,5-triazin 2-Methylthio-4-isopropylatnino-6-tert.-butylatnino-1,3,5-triazin 2-Methylthio-4- (3-methoxy-propyl-amino) -6-isopropylamino-2-methoxy-4-methylamino-6-isopropylan ^ ino-1,3,5-triazine 2-methoxy-4-ethylamino-6-tert.-butylaraino-1,3,5-triazine 2-methoxy-4, 6-di- (3-methoxypropylamino) -1,3 * 5-triazine 2-methoxy-4,6-bis (ethylamino) -1,3,5-triazine a-methoxy - ^ - ethylamino-6-sec. -butylatnino-1,3,5-triazine 2-methoxy-4-ß-methoxyethylamino-6-isopropylamino-1,3,5-triazine 2-methoxy-4-ethylamino-6-isopropylainino-1,3,5-triazine 2-methoxy-i l, 6-diisopropylamino-l, 3,5-triazine 2-methoxy-4-isopropylamino-6-diethylamino-l, 3,5-triazine 2-methoxy-i l-methylamino-6- sec -butylatnino-1,3,5-triazine 2-methoxy-4-isopropylamino-6-acetylatnino-1,3,5-triazine 2-methoxy-4-isopropylamino-6-ethylacetylamino-1,3,5-triazine K 2-methoxy-4- (J- methoxypropyl) -amino-6- isoamylamino-1,3,5-triazine 2-methylthio-4-isopropylamino-6-sec.-butylamino-1,3,5-triazine 2- Methylthio-4-isopropylamino-6-tert-butylamino-1,3,5-triazine 2-methylthio-4- (3-methoxy-propyl-amino) -6-isopropylamino-

1*3,5-triazin1 * 3,5-triazine

2-Methylthio-4,6-di-(3-methoxy-propyl-amino)-l,3,5-triazin 2-Methylthio-4-methylamino-6-isopropylamino-l,3,5-triazin 2-Methylthio-4-äthylanlino-6-isopropylamino-1,3,5- triazin 2-Methylthio-4-äthylamino-6- sec. -butylamino-1,3,5-triazin 2-Methylthio-4-äthylamino-6-tert.-butylamino-1,3,5-triazin 2-Methylthlo-4,6-diisopropylamino-1,3,5-triazin 2-Methylthio-4-äthylamino-6-*,ß-dimethylpropylamino-1,3,5-triazin 2-methylthio-4,6-di- (3-methoxy-propyl-amino) -1,3,5-triazine 2-methylthio-4-methylamino-6-isopropylamino-1,3,5-triazine 2-methylthio-4-ethylanino-6-isopropylamino-1,3,5-triazine 2-methylthio-4-ethylamino-6-sec-butylamino-1,3,5-triazine 2-methylthio-4-ethylamino-6-tert-butylamino-1,3,5-triazine 2-methylthlo-4,6-diisopropylamino-1,3,5-triazine 2-methylthio-4-ethylamino-6 - *, ß-dimethylpropylamino-1,3,5-triazine

2-Methylthio-4-πlethylamino-6-n-propylamino-l, 3,5-triazin 2-Methylthio-4-methylamino-6- sek. -butylatnino-1,3,5-triazin 2-Methyl thio-4,6-bi s-(f-methoxypropylamino)-1,3,5-triazin 2-Methylthio-4-allylamino-6-n-propylamino-1,3,5-triazin 2-Methylthio-4-allylamino-6-isopropylatnino-l, 3,5-triazin 2-Methylthio-4,6-bis-(allylamino)-l,3,5-triazin 2-Methylthio-4-amino-6-isopropylamino-1,3,5-triazin2-methylthio-4-πlethylamino-6-n-propylamino-1,3,5-triazine 2-methylthio-4-methylamino-6 sec. -butylatnino-1,3,5-triazine 2-methyl thio-4,6-bis- (f-methoxypropylamino) -1,3,5-triazine 2-methylthio-4-allylamino-6-n-propylamino-1,3,5-triazine 2-methylthio-4-allylamino-6-isopropylatnino-1,3,5-triazine 2-methylthio-4,6-bis (allylamino) -1,3,5-triazine 2-methylthio-4-amino-6-isopropylamino-1,3,5-triazine

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2-Methylthio-4-amino-6-n-propylamino-l,3,5-triazin2-methylthio-4-amino-6-n-propylamino-1,3,5-triazine

2-Methylthio-4-diäthylamino·■■6-isopropylamino-l,3,5-triazin2-methylthio-4-diethylamino · ■■ 6-isopropylamino-1,3,5-triazine

2-Me thylthio^-äthylamino-ö-methylthio-1,3,5-· triazin 2-Methylthio-4,6-bis-(äthylamino-l,3,5-triazin 2-Methylthio-4-äthylamino-6-n-propylamino-l,3,5-triazin2-methylthio ^ -ethylamino-ö-methylthio-1,3,5- · triazine 2-methylthio-4,6-bis (ethylamino-1,3,5-triazine 2-methylthio-4-ethylamino-6-n-propylamino-1,3,5-triazine

2-Methylthio-4-äthylamino-6-/-methoxypropylamino-1,3,5-triazin 2-(2-MethyltMo-4-isopropylamino-l,3,5-triazin-6-yl-amino)-2-methylthio-4-ethylamino-6 - / - methoxypropylamino-1,3,5-triazine 2- (2-MethyltMo-4-isopropylamino-1,3,5-triazin-6-yl-amino) -

2-methyl-propionitril
2-(2-Methylthio-4-äthylamino-1,3*5-triazin-6-yl-amino)-2-methyl-2-methyl-propionitrile
2- (2-methylthio-4-ethylamino-1,3 * 5-triazin-6-yl-amino) -2-methyl-

propionitril
2-(2-Methylthlo-4-methylamino-l,3,5-triazin-6-yl-amino)-2-methyl-propionitrile
2- (2-methylthlo-4-methylamino-1,3,5-triazin-6-yl-amino) -2-methyl-

propionitrilpropionitrile

2-Äthylthio-4-äthylamino-6-isopropylamino-l,3>5-triazin 2-Äthylthio-4, 6-bis- (isopropylamino-)-l,3,5-triazin 2-Äthylthio-4,6-bis-(äthylamino)-1,3,5-triazin 2-Azido-4-äthylamino-6-sec.-butylämino-l,3,5-triazin 2-Azido-4-see.-butylamino-6-methylthio-l,3j5-triazin 2-Azido-4-äthylamino-6-tert.-butylamino-l,3,5-triazin 2-Azido-4-isopropylaraino-6-methylthio-1,3,5-triazin 2-Cyan-4-äthylamino-6-isopropylamino-1,3,5-triazin 2-Hydroxy-4-amino-6-äthylamino-1,3,5-triazin 2-Hydroxy-4-amino-6-isopropylamino-l,3,5-triazin 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethyl-2-ethylthio-4-ethylamino-6-isopropylamino-1,3> 5-triazine 2-ethylthio-4, 6-bis (isopropylamino -) - 1,3,5-triazine 2-ethylthio-4,6-bis- (ethylamino) -1,3,5-triazine 2-Azido-4-ethylamino-6-sec-butylamino-1,3,5-triazine 2-Azido-4-see-butylamino-6-methylthio-1,3j5-triazine 2-Azido-4-ethylamino-6-tert-butylamino-1,3,5-triazine 2-Azido-4-isopropylaraino-6-methylthio-1,3,5-triazine 2-cyano-4-ethylamino-6-isopropylamino-1,3,5-triazine 2-hydroxy-4-amino-6-ethylamino-1,3,5-triazine 2-Hydroxy-4-amino-6-isopropylamino-1,3,5-triazine 3-Isopropyl-2,1,3-benzothiadiazinone- (4) -2,2-dioxide 3-Isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide, sodium salt 3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethyl-

aminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanol-amine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethanol-

aminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Methylamin-amine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-methylamine-

salz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Trimethyl-salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-trimethyl-

aminsalzamine salt

3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Äthylaminsalz 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthylamin-3-Isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-ethylamine salt 3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethylamine-

salz
3-Isopropyl-2,1,3-benzothiadiazinon- (4)-2,2-dioxid-Ä'thanolamin-salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-ethanolamine-

salzsalt

3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Anilinsalz 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Pyridinsalz 3- Isopropyl-2,1,3-benzothiadiazinone- (4) -2,2-dioxide-aniline salt, 3-Isopropyl-2,1,3-benzothiadiazinone- (4) -2,2-dioxide-pyridine salt

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2 3 4 '! 5 5 52 3 4 '! 5 5 5

3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Phenylen-3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-phenylene-

diaminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Cyclohexyl-diamine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-cyclohexyl-

aminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dodecyl-amine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dodecyl-

hexamethyleniminsalzhexamethyleneimine salt

3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Hydrazinsalz 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Magnesium-3-Isopropyl-2,1,3-benzothiadiazinone (4) -2,2-dioxide hydrazine salt 3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-magnesium-

salzsalt

3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Calciumsalz 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Ammonium-3-Isopropyl-2,1,3-benzothiadiazinone (4) -2,2-dioxide calcium salt 3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-ammonium-

salzsalt

3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Kaliumsalz 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Lithium-3-Isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide, potassium salt 3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-lithium-

salzsalt

3-Isobutyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid 3-Isobutyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz 3-Isobutyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethyl-3-Isobutyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide, 3-Isobutyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide, sodium salt 3-isobutyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethyl-

aminsalz
3-Isobutyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanol-amine salt
3-isobutyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethanol-

aminsalzamine salt

3-sec.-Butyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid 3-sec.-Butyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natrium-3-sec-butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide 3-sec-butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-sodium-

salz
3-sec.-Butyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethyl-salt
3-sec-butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethyl-

aminsalz
3-sec. -Butyl-2,1,3-benzothiadiazinon- (4)-2,2-dioxid-Diäthanol-amine salt
3-sec. -Butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethanol-

aminsalzamine salt

3-n-Butyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid 3-n-Butyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz 3-n-Butyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethyl-3-n -Butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide 3-n -Butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide sodium salt 3-n-butyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethyl-

aminsalz 3-n-Butyl-2,Iy3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanolaminsalz amine salt 3-n-butyl-2, ly3-benzothiadiazinon- (4) -2,2-dioxide-diethanolamine salt

3-n-Propyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid 3-n-Propyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz 3-n-Propyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethyl-3-n-Propyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide 3-n-Propyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide, sodium salt 3-n-propyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethyl-

aminsalzamine salt

509809/1118 /15 509809/1118 / 15

- 15 - O.Z. 50 054- 15 - O.Z. 50 054

3-n-Propyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanol-3-n-propyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethanol-

aminsalzamine salt

3-Äthyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid 3-Äthyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz 3-Äthyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethylamin-3-ethyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide 3-ethyl-2,1,3-benzothiadiazinon- (4 ) -2,2-dioxide sodium salt 3-ethyl-2, 1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethylamine-

salz
3-Äthyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxId-Diäthanol-salt
3-ethyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxId-diethanol-

arainsalzarainsalz

3-Methyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid 3-Methy1-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz 3-Methyl-2,1,3- benzothiadiazinon-(4)-2,2-dioxid-Dimethyl-3-methyl-2,3-benzothiadiazinon- (4) -2,2-dioxide 3-Methy1-2,1,3-benzothiadiazinon- (4) -2,2-dioxide, sodium salt 3-methyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethyl-

aminsalz
3-Methyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanol-amine salt
3-methyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethanol-

aminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid- T- Iso-amine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide- T- iso-

propoxypropylarainsalz
3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-ß-Sthyl-propoxypropyl arain salt
3-isopropyl-2, l, 3-benzothiadiazinon- (4) -2,2-dioxide-ß-ethyl-

hexylaniinsalzhexylaniine salt

3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-N,N-Dime thy lpyridinsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-N-Methyl-3-Isopropyl-2,3-benzothiadiazinon- (4) -2,2-dioxide-N, N-dimethyl pyridine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-N-methyl-

N-butyl-piperidinsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Stearyl-N-butyl piperidine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-stearyl-

aminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Hexylamin-amine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-hexylamine-

salz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-ß-(Butyl)-salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-ß- (butyl) -

butoxyhexylaminsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Phenyl-butoxyhexylamine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-phenyl-

hydrazinsalz
3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Äthanol-hydrazine salt
3-isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-ethanol-

aminsalzamine salt

N-3-Chlorphenyl-N-cyclohexyl-l-enyl-N',Nf-dimethylharnstoff N-Phenyl-N-cyclohexyl-1-enyl-N1,NT-dimethylharnstoff N-3-Chlorphenyl-N-cyclohexyl-l-enyl-N-methylharnstoff N-Phenyl-N-cyclohex-l-enyl-N'-methylharnstoff N-4-Pluorphenyl-N-cyclohex-l-enyl-N'-methylharnstoff N-3-Chlor-4-methoxyphenyl-N-cyclohex-l-enyl-N-methylharnstoff N-3-Chlor-4-methylphenyl-N-cyclohex-l-enyl-N',N!-dimethyl-N-3-chlorophenyl-N-cyclohexyl-l-enyl-N ', N f -dimethylurea N-phenyl-N-cyclohexyl-1-enyl-N 1 , N T -dimethylurea N-3-chlorophenyl-N-cyclohexyl- 1-enyl-N-methylurea N-phenyl-N-cyclohex-1-enyl-N'-methylurea N-4-fluorophenyl-N-cyclohex-1-enyl-N'-methylurea N-3-chloro-4-methoxyphenyl -N-cyclohex-l-enyl-N-methylurea N-3-chloro-4-methylphenyl-N-cyclohex-l-enyl-N ', N ! -dimethyl-

509809/1118 /16509809/1118 / 16

- i6 - ο.ζ. 30- i6 - ο.ζ. 30th

harnstoffurea

N-3-Trif luormethylphenyl-N-cyclohex-l-enyl-N' ,N' -dime thy !harnstoff N-3-trifluoromethylphenyl-N-cyclohex-1-enyl-N ', N'-dimethyl urea

N-3-Trifluormethylphenyl-N-cyclohex-l-enyl-N'-methylharnstoff N-Ji^Dicnlorphenyl-N-cyclohex-l-enyl-N1,N1-dimethylharnstoff N-J-Chlor-^-methoxyphenyl-N-cyclohex-l-enyl-N' ,N1 -dimethylharnstoff N-3-Trifluoromethylphenyl-N-cyclohex-l-enyl-N'-methylurea N-Ji ^ Dicnlorphenyl-N-cyclohex-l-enyl-N 1 , N 1 -dimethylurea NJ-chloro - ^ - methoxyphenyl-N-cyclohex -l-enyl-N ', N 1 -dimethylurea

N-4-Chlorphenyl-N-cyclohex-l-enyl-N'-methylharnstoff N-3-Chlor-ii-methoxyphenyl-Nt -methyl-N1 -methoxyharnstof fN-4-chlorophenyl-N-cyclohex-l-enyl-N'-methyl urea N-3-chloro-i i-methoxyphenyl-N-methyl-N 1 t f -methoxyharnstof

in Mischung untereinander an den bereits genannten Pflanzen geprüft. Die aufgeführten Mittel haben eine entsprechende biologische Wirkung wie die in den Beispielen aufgeführten Mischungen.tested in a mixture with each other on the plants already mentioned. The means listed have a corresponding biological effect like the mixtures listed in the examples.

Beispiel 1example 1

Im Freiland wurden verschiedene Pflanzen bei einer Wuchshöhe von 2 bis 30 cm mit folgenden Einzelwirkstoffen und deren Mischungen als Öldispersion behandelt:In the field, various plants were grown to a height of 2 to 30 cm with the following individual active ingredients and their Mixtures treated as an oil dispersion:

I N-3-Chlor-4-methoxyphenyl-Nf-methyl-N'-methoxyharnstoffI N -3-chloro-4-methoxyphenyl-N f -methyl-N'-methoxyurea

II 2-Chlor-4-äthylamino-6-isopropylamino-l,3*5-triazinII 2-chloro-4-ethylamino-6-isopropylamino-1,3 * 5-triazine

III 2-(2-Chlor-4-methylamino-l,3,5-triazin-6-yl-amino)-2-methylpropionitril III 2- (2-Chloro-4-methylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

IV 2-Chlor-4,6-diäthylamino-1,3,5-triazinIV 2-chloro-4,6-diethylamino-1,3,5-triazine

V 2-Chlor-4-äthylamino-6-tert.butylamino-l,3,5-triazinV 2-chloro-4-ethylamino-6-tert-butylamino-1,3,5-triazine

VI 2-(2-Chlor-4-äthylamino-l,3J5-triazin-6-yl-amino)-2-methyl-propionitril VI 2- (2-chloro-4-ethylamino-l, 3 J 5-triazin-6-yl-amino) -2-methyl-propionitrile

VII 2-Methylthio-4-äthylamino-6-tert.butylamino-1,3,5-triazin VII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3,5-triazine

VIII 2-Methylthio-4,6-dlisopropylamino-l,3,5-triazinVIII 2-Methylthio-4,6-dlisopropylamino-1,3,5-triazine

IX 2-Methylthio-4-(4-methoxypropylamino)-6-isopropylamino-l,3,5-triazin IX 2-methylthio-4- (4-methoxypropylamino) -6-isopropylamino-1,3,5-triazine

X 2-Azido-4-äthylamino-6-tert.butylamino-1,3,5-triazinX 2-Azido-4-ethylamino-6-tert-butylamino-1,3,5-triazine

XI 2-Chlor-4-isopropylamino-6-cyclopropylamino-1,3,5-triazinXI 2-chloro-4-isopropylamino-6-cyclopropylamino-1,3,5-triazine

XII 2-Methylthio-4-äthylamino-6- «,, ß-dimethylpropylamino-1,3,5-triazin XII 2-methylthio-4-ethylamino-6- «,, ß-dimethylpropylamino-1,3,5-triazine

mit je 0,25, 0,5, 0,75 und 1 kg/ha aktive Substanzwith 0.25, 0.5, 0.75 and 1 kg / ha of active substance

/17 509809/1118/ 17 509809/1118

I+II, I+III, I+IV, I+V, I+VI, I+VII, I+VIII, I+IX, I+X, I+XI, I+XIII + II, I + III, I + IV, I + V, I + VI, I + VII, I + VIII, I + IX, I + X, I + XI, I + XII

mit je 0,25+0,75, 0,75+0,25 und 0,5+0,5 kg/ha aktivewith 0.25 + 0.75, 0.75 + 0.25 and 0.5 + 0.5 kg / ha active

Substanz.Substance.

Nach 8 bis 12 Tagen wurde festgestellt, daß die Mischungen eine bessere herbizide Wirkung bei gleicher Verträglichkeit an den Kulturpflanzen zeigten als die Einzelwirkstoffe.After 8 to 12 days it was found that the mixtures had a better herbicidal effect with the same tolerance to the Cultivated plants showed as the single active ingredients.

Das Versuchsergebnis ist aus nachfolgender Tabelle zu ersehen.The test result can be seen from the following table.

509809/1118 /l8 509809/1118 / l8

Ul
O Ul
O WirkstoffActive ingredient 0,250.25 0,50.5 rr 0,750.75 0,750.75 11 0,250.25 IIII 0,50.5 VV 0,750.75 11 0,250.25 IIIIII 0,750.75 VIVI 0,50.5 0,750.75 1 ■1 ■ ho
COho
CO 11 -- co
00co
00 kg/hakg / ha 00 0,50.5 0,50.5 55 77th -O--O- 1—*1-* OO Nutzpflanzen:Useful plants: 00 00 00 00 00 00 00 1010 00 00 00 ■■ 00 1010 1212th 00 cn
cncn
cn co
"V.co
"V. Trlticum aestivumTrlticum aestivum 00 00 00 00 00 00 00 55 00 55 00 00 00 1010 1212th 00 —X—X Hordeum vulgäreHordeum vulgar 00 00 00 6363 00 00 00 1010 00 1010 00 00 00 4040 4747 00 ~m~ m Seeale cerealeSeeale cereale 6868 4545 00 3131 3737 unerwünschte Pflanzen:unwanted plants: 2424 4040 5050 1515th 7070 4545 5555 3030th 7070 8787 4040 5555 2020th 2828 7575 Alopecurus myosuroidesAlopecurus myosuroides 1515th 2525th 3030th 4242 3535 5050 6565 2323 8080 9090 1515th 5050 3535 6565 7575 4545 Poa annuaPoa annua 55 1111 1414th 1515th 2525th 4040 3535 5050 6060 1515th 3030th 4040 5555 y^
N y ^
N Galium aparineGalium aparine 2020th 2727 3030th 4040 2020th 4040 4545 5050 1010 3030th 3636 4545 OO Lamium araplexicauleLamium araplexicaule 3030th O
UiO
Ui IVIV WirkstoffActive ingredient 0,250.25 0,50.5 11 0,250.25 0,750.75 11 0,250.25 11 kg/hakg / ha 00 00 00 00 1212th 1515th 00 1010 Triticum aestivumTriticum aestivum 00 00 55 00 77th 1010 55 1515th Hordeum vulgäreHordeum vulgar 00 00 1010 00 1111 1313th 44th 1515th Seeale cerealeSeeale cereale 4040 5555 7070 4040 5050 5555 3030th 5555 Alopecurus myosuroidesAlopecurus myosuroides 4545 5555 7575 2525th 3535 4040 1717th 5050 Poa annuaPoa annua 00 1010 2020th 1515th 2525th 2727 55 3535 Galium aparineGalium aparine 2020th 3535 5050 1515th 4040 5050 5050 8080 Lamium araplexicauleLamium araplexicaule

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

VII 0,25 0,5 0,75VII 0.25 0.5 0.75

VIII
0,25 0,5 0,75 1VIII
0.25 0.5 0.75 1

IX 0,25 0,5 0,75IX 0.25 0.5 0.75

Triticum aestlvum Hordeum vulgäre Secale cereale Triticum aestlvum Hordeum vulgar Secale cereale

Alopecurus myosuroides Poa annua Galium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparine Lamium amplexicaule

0 0 00 0 0

0 0 00 0 0

0 0 00 0 0

45 55 7145 55 71

30 35 3830 35 38

26 40 5026 40 50

22 4 4722 4 47

0 5 100 5 10

0 5 100 5 10

0 0 60 0 6

45 55 60 45 55 60

45 50 55 45 50 55

42 50 57 42 50 57

55 60 65 55 60 65

0 0 0 θ0 0 0 θ

0 0 00 0 0

0 0 00 0 0

44 55 61 44 55 61

18 35 4018 35 40

20 35 5020 35 50

15 32 4015 32 40

WirkstoffActive ingredient 0,250.25 XX 0,50.5 0,750.75 11 0,250.25 0,0, XIXI 11 0,250.25 XIIXII 0,750.75 11 kg/ha a. S.kg / ha a. S. 00 00 00 00 00 00 5 0,755 0.75 00 00 0,50.5 00 00 Triticum aestivumTriticum aestivum 00 00 00 00 00 00 00 00 00 00 00 00 Hordeum vulgäreHordeum vulgar 00 00 00 00 00 00 00 00 00 00 00 00 Secale cerealeSecale cereale 2525th 4545 6060 7777 4040 5555 00 8585 2020th 00 6565 7777 Alopecurus myosuroldesAlopecurus myosuroldes 3535 4343 6060 8080 2020th 4545 7070 7575 2525th 5050 7777 8080 Poa annuaPoa annua 1010 2020th 2828 3535 2525th 4545 6060 6060 1515th 5050 3030th 3535 Galium aparineGalium aparine 4646 7070 7575 8080 1010 2525th 5555 4040 6060 2424 7070 8282 Lamium amplexlcauleLamium amplexlcaule 3535 6868

0 = ohne' Schädigung 100 - totale Schädigung0 = no damage 100 - total damage

COCO

»—λ»—Λ

cn cn cncn cn cn

CO O COCO O CO

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

I+III + II

0,25+ 0,75+ 0,5+ 0,75 0,25 0,50.25+ 0.75+ 0.5+ 0.75 0.25 0.5

I+IIII + III

0,25+ 0,75+ 0,5+
0,75 0,25 0,50.25+ 0.75+ 0.5+
0.75 0.25 0.5

I+IVI + IV

0,25+ 0,75+ 0,5+ 0,75 0,25 0,50.25+ 0.75+ 0.5+ 0.75 0.25 0.5

Triticum aestivumTriticum aestivum 00 00 00 00 00 00 00 00 00 Hordeutn vulgäreExtremely vulgar 00 00 00 00 00 00 00 00 00 Secale cerealeSecale cereale 00 00 00 00 00 00 00 00 00 Alopecurus myosuroidesAlopecurus myosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 100100 100100 9090 8585 9595 100100 100100 100100 Galium aparineGalium aparine 9292 7676 8888 8585 6969 8181 6060 5454 6161 Lamium amplexicauleLamium amplexicaule 100100 8686 100100 9696 8080 9797 100100 9090 100100 WirkstoffActive ingredient I+VI + V I+VII + VI I+VIII + VII

Triticum aestivum Hordeutn vulgäre Secale cerealeTriticum aestivum Hordeutn vulgar Secale cereale

Alopecurus myosuroides Poa annua Galium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparine Lamium amplexicaule

1212th 00 1010 77th 00 55 00 00 00 77th 00 55 1212th 55 1010 00 00 00 1111 00 1010 1212th 44th 1010 00 00 00 100100 100100 100100 100100 100100 100100 100100 100100 100100 9090 9595 9595 8787 8282 9292 100100 100100 100100 7070 6969 7474 7373 5959 7171 9090 7676 8787 9797 8080 9898 100100 100100 100100 100100 8888 100100

cn cn cncn cn cn

WirkstoffActive ingredient I+VIIII + VIII 0,75+0.75+ 0,5+0.5+ I+IXI + IX 0,75+0.75+ 00 0,5+0.5+ 00 I+XI + X 0,75+0.75+ 0,5+0.5+ kg/ha a. S.kg / ha a. S. 0,25+0.25+ 0,250.25 0,50.5 0,25+0.25+ 0,250.25 00 0,50.5 00 0,25+0.25+ 0,250.25 0,50.5 0,750.75 00 00 0,750.75 00 00 00 00 0,750.75 00 00 Triticum aestivumTriticum aestivum 55 00 00 00 00 100100 00 100100 00 00 00 Hordeum vulgäreHordeum vulgar 55 00 00 00 00 9595 00 100100 00 00 00 Secale cerealeSecale cereale 00 100100 100100 00 100100 6969 100100 7575 00 100100 100100 Alopecurus myosuroidesAlopecurus myosuroides 100100 8o8o 100100 100100 8484 100100 9797 100100 100100 100100 100100 Poa annuaPoa annua 100100 7474 9393 9090 7070 8282 100100 6464 7171 Galium aparineGalium aparine 9595 100100 100100 9090 8282 9494 7373 100100 100100 Laraium amplexicaialeLaraium amplexicaiale 100100 9797 100100 WirkstoffActive ingredient I+XII + XI 00 00 I+XIII + XII Triticum aestivumTriticum aestivum 00 00 00 00 Hordeum vulgäreHordeum vulgar 00 00 00 00 Secale cerealeSecale cereale 00 100100 100100 00 Alopecurus myosuroidesAlopecurus myosuroides 100100 9090 100100 100100 Poa annuaPoa annua 100100 7575 9292 100100 Galium aparineGalium aparine 9797 8080 9090 7575 9595 100100

0 = ohne Schädigung 100 * totale Schädigung0 = without damage 100 * total damage

ro ιro ι

COCO

cn
Cncn
Cn

cncn

UiUi

-tr-tr

ro roro ro

- 22 - O.Z. 30 054- 22 - O.Z. 30 054

Beispiel 2Example 2

Im Freiland wurden verschiedene Pflanzen bei einer Wuchshöhe von.2 bis 28 cm mit folgenden Einzelwirkstoffen und deren Mischungen als Dispersion behandelt:In the field, various plants were grown to a height of 2 to 28 cm with the following individual active ingredients and their mixtures treated as a dispersion:

I N-^-Chlor-^-methoxy-phenyl-N'-methyl-N1-methoxyharnstoffI N - ^ - chlorine - ^ - methoxy-phenyl-N'-methyl-N 1 -methoxyurea

II 2-Chlor-4-äthylamino-6-isopropylamino-l,3*5-triazinII 2-chloro-4-ethylamino-6-isopropylamino-1,3 * 5-triazine

III 2- (2-Chlor-il-methylamino-1,3, 5- triazin-6-yl-amino) -2-methylpropionitril III 2- (2-chloro- i l-methylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

IV 2-Chlor-4,6-diäthylamino-l,3,5-triazinIV 2-chloro-4,6-diethylamino-1,3,5-triazine

V 2-Chlor-4-äthylamino-6-tert.butylamino-l,3*5-triazinV 2-chloro-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine

VI 2-(2-Chlor-4-äthylamino-l,3,5-triazin-6-yl-amino)-2-methylpropionitril VI 2- (2-chloro-4-ethylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

VII 2-Methylthio-4-äthylamino-6-tert.butylamino-l,3,5-triazin VII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3,5-triazine

VIII 2-Methylthio-4,6-diisopropylamino-l,3,5-triazinVIII 2-methylthio-4,6-diisopropylamino-1,3,5-triazine

IX 2-Methyl thio-4- (3-methoxypropylamino) -6-isopropylamino-1,3,5-triazin IX 2-methyl thio-4- (3-methoxypropylamino) -6-isopropylamino-1,3,5-triazine

X 2-Azido-4-äthylamino-6-tert.butylamino-l,3*5-triazinX 2-Azido-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine

XI 2-Chlor-4-isopropylamino-6-cyclopropylamino-l,3,5-triazinXI 2-chloro-4-isopropylamino-6-cyclopropylamino-1,3,5-triazine

XII 2-Methylthio-4-äthylamino-6- cc, ß-dimethylpropylamino-1,3,5-triazin XII 2-methylthio-4-ethylamino-6- cc, β-dimethylpropylamino-1,3,5-triazine

mit je 0,5, 1, 1,5 und 2 kg/ha aktive Substanzwith 0.5, 1, 1.5 and 2 kg / ha of active substance

I+II, I+III, I+IV, I+V, I+VI, I+VII, I+VIII, I+IX, I+X, I+XI und I+XIII + II, I + III, I + IV, I + V, I + VI, I + VII, I + VIII, I + IX, I + X, I + XI and I + XII

mit je 0,5+1*5* 1*5+0,5 und 1+1 kg/ha aktive Substanz.each with 0.5 + 1 * 5 * 1 * 5 + 0.5 and 1 + 1 kg / ha of active substance.

Nach 8 bis 10 Tagen wurde festgestellt, daß die Mischungen eine bessere Verträglichkeit an den Kulturpflanzen und eine bessere herbizide Wirkung zeigten als die Einzelwirkstoffe mit 2 kg/ha aktive Substanz.After 8 to 10 days it was found that the mixtures were better tolerated by the crop plants and better herbicidal effect showed as the individual active ingredients with 2 kg / ha of active substance.

Das Versuchsergebnis ist aus nachfolgender Tabelle zu ersehen.The test result can be seen from the following table.

/23 509809/1 1 18 / 23 509809/1 1 18

WirkstoffActive ingredient 0,50.5 11 II. 1,51.5 IVIV 22 0,50.5 IIII 11 1,51.5 VV 1,51.5 22 22 0,50.5 11 IIIIII VIVI 1,51.5 22 kg/ha a. S.kg / ha a. S. . 1*5. 1 * 5 2020th 2525th 1,51.5 1515th Nutzpflanzen:Useful plants: 00 00 00 2020th 00 00 00 2020th 1515th 3030th 2020th 00 00 2020th 1010 Triticum aestivumTriticum aestivum 00 00 00 2222nd 00 00 55 2323 1818th 3535 2121 00 00 00 1919th 1515th Hordeum vulgäreHordeum vulgar 00 00 00 2525th 00 00 1010 2626th 3232 00 00 00 1010 Seeale cerealeSeeale cereale 00 unerwünschte Pflanzen:unwanted plants: 4040 7070 8787 100100 5555 8787 9292 100100 5050 7575 9090 CXTCXT Alopecurus myosuroidesAlopecurus myosuroides 2525th 3535 4242 6565 6565 9090 100100 100100 3030th 4545 8585 7575 O
f ftO
f ft Poa annuaPoa annua 1111 1515th 2020th 2525th 4040 6o6o 8080 9595 3030th 5555 6060 8585 UD
OOUD
OO Galium aparineGalium aparine 2727 4040 6565 8282 4040 5050 6565 8080 3030th 4545 7575 7070 α
coα
co Lamium amplexicauleLamium amplexicaule 5555 WirkstoffActive ingredient 0,50.5 11 22 0,50.5 11 0,50.5 11 22 0000 kg/ha a. S.kg / ha a. S. 00 00 3030th 1010 1515th 55 1010 2o2o Triticum aestivumTriticum aestivum 00 55 3535 55 1010 1010 1515th 2424 HordQum vulgäreHordQum vulgar 00 1010 3030th 1010 1313th 1010 1515th 2323 Seeale cerealeSeeale cereale

Alopecurus myosuroides 55 70 80 95 45 55 65 80 40 55 65 75Alopecurus myosuroides 55 70 80 95 45 55 65 80 40 55 65 75

Poa annua 55 75 90 100 30 40 50 65 31 50 70 85 pPoa annua 55 75 90 100 30 40 50 65 31 50 70 85 p

Oalium aparine 10 20 30 50 23 27 35 55 20 35 50 70 £J .N Oalium aparine 10 20 30 50 23 27 35 55 20 35 50 70 £ J. N

Lamium amplexicaule 35 50 60 80 35 50 62 75 65 80 85 95 ·>· οLamium amplexicaule 35 50 60 80 35 50 62 75 65 80 85 95 ·> · ο

ro -fr ro -fr

cncn

cn ο cocn o co

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

VII
0,5 1 1,5 2VII
0.5 1 1.5 2

VIII
0,5 1 1,5 2VIII
0.5 1 1.5 2

IX
0,5 1 1,5 2IX
0.5 1 1.5 2

Triticutn aestivum Hordeum vulgäre Secale cerealeTriticutn aestivum Hordeum vulgar Secale cereale

Alopecurus myosuroides Poa annua Gal Ium aparlne Lamlum amplexicauleAlopecurus myosuroides Poa annua Gal Ium aparlne Lamlum amplexicaule

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

0 0 0 00 0 0 0

0 0 0 00 0 0 0

0 0 0 00 0 0 0

55 80 94 10055 80 94 100

35 40 50 8535 40 50 85

40 62 81 9640 62 81 96

41 53 70 8541 53 70 85

0,5 1 1,5 20.5 1 1.5 2

10 14 2010 14 20

10 15 2210 15 22

6 10 156 10 15

60 75 9060 75 90

55 70 8555 70 85

57 70 8057 70 80

65 80 9565 80 95

XIXI

0,5 1 1,5 20.5 1 1.5 2

0 0 5 100 0 5 10

0 0 5 120 0 5 12

0 0 6 110 0 6 11

55 78 90 10055 78 90 100

35 50 65 8535 50 65 85

35 60 77 9035 60 77 90

32 50 65 8032 50 65 80

XIIXII

0,5 1 1,5 20.5 1 1.5 2

Tritlcum aestivum Hordeum vulgäre Secale cerealeTritlcum aestivum Hordeum vulgar Secale cereale

Alopecurus myosuroides Poa annua Galium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparine Lamium amplexicaule

0 = ohne Schädigung 100 = totale Schädigung0 = no damage 100 = total damage

0 0 0 00 0 0 0

0 0 0 00 0 0 0

0 0 0 00 0 0 0

45 77 90 10045 77 90 100

43 80 95 10043 80 95 100

20 35 60 8020 35 60 80

70 80 95 10070 80 95 100

Ö 0 0Ö 0 0

0 0 00 0 0

0 0 00 0 0

85 93 10085 93 100

75 90 10075 90 100

60 80 9560 80 95

40 57 7540 57 75

0 0 0 00 0 0 0

0 0 0 00 0 0 0

0 0 0 00 0 0 0

50 77 92 10050 77 92 100

50 80 90 10050 80 90 100

24 35 58 7824 35 58 78

68 82 95 10068 82 95 100

O CO Vvl O CO Vvl

UlUl cn cn cncn cn cn

cn ο co co ο cocn ο co co ο co

WirkstoffActive ingredient I+III + II 1,5+1.5+ 1+11 + 1 I+IIII + III 1,5+1.5+ 1+11 + 1 i+rvi + rv 1,5+1.5+ I+VIII + VII 00 1+11 + 1 kg/ha a. S.kg / ha a. S. 0,5+0.5+ 0,50.5 0,5+0.5+ 0,50.5 0,5+0.5+ 0,50.5 00 00 1,51.5 2020th 00 1,51.5 00 00 1,51.5 00 00 00 00 Triticum aestlvumTriticum aestlvum 55 2323 55 00 00 00 2020th 00 00 100100 55 Hordeum vulgäreHordeum vulgar 55 2626th 1010 00 00 00 2222nd 00 100100 100100 1010 Secale cerealeSecale cereale 66th 100100 100100 00 100100 100100 2525th 100100 100100 9898 100100 Alopecurus myosuroidesAlopecurus myosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 9898 100100 100100 9595 100100 100100 7474 100100 7575 Galium aparineGalium aparine 100100 100100 100100 100100 100100 100100 8181 100100 100100 Lamium amplexicauleLamium amplexicaule 100100 100100 100100 WirkstoffActive ingredient I+VI + V 1010 1515th I+VII + VI 55 1010 00 Triticum aestivumTriticum aestivum 2020th 55 1010 1515th 1010 1515th 00 Hordeum vulgäreHordeum vulgar 1515th 1010 1313th 2020th 1010 1515th 00 Secale cerealeSecale cereale 1818th 100100 100100 1919th 100100 100100 100100 Alopecurus myosuroidesAlopecurus myosuroides 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 9393 8787 100100 8080 9090 100100 Galium aparineGalium aparine 9696 100100 100100 100100 100100 100100 100100 Lamium amplexicauleLamium amplexicaule 100100 100100

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

I+VIIII + VIII

0,5+ 1,5+ 1+1
1,5 0,50.5+ 1.5+ 1 + 1
1.5 0.5

I+IXI + IX

0,5+ 1,5+ 1+1 1,5 0,50.5+ 1.5+ 1 + 1 1.5 0.5

0,5+ 1,5+ 1+1
1,5 0,50.5+ 1.5+ 1 + 1
1.5 0.5

Triticum aestivumTriticum aestivum 1515th 00 1010 55 00 I+XIII + XII 00 00 00 00 Hordeum vulgäreHordeum vulgar 1010 00 1010 55 00 00 00 00 00 Secale cerealeSecale cereale 100100 00 66th 66th 00 00 00 00 00 Alopecurus rayosuroidesAlopecurus rayosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 100100 100100 100100 100100 100100 100100 100 ·100 · 100100 Galium aparlneGalium aparlne 100100 100100 100100 100100 9494 100100 100100 8686 9494 Trfimtum amplexicauleTrfimtum amplexicaule I+XII + XI 100100 100100 100100 100100 100100 100100 100100 100100 WirkstoffActive ingredient

Triticum aestivum Hordeum vulgäre Secale cerealeTriticum aestivum Hordeum vulgar Secale cereale

Alopecurus myosuroides Poa annua Galium aparlne Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparlne Lamium amplexicaule

0 « ohne Schädigung 100 = totale Schädigung0 «without damage 100 = total damage

00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 9090 9696 100100 100100 100100 100100 100100 100100

ίο 4ίο 4

COCO

cn cn cncn cn cn

- 27 - 0.Z. 30- 27 - 0.Z. 30th

Beispiel 3Example 3

Im Freiland wurden verschiedene Pflanzen bei einer Wuehshöhe von 2 bis 18 cm mit folgenden Einzelwirkstoffen undderen Mischungen als Dispersion-Emulsion-Tankmix behandelt:In the field, various plants with a height of 2 to 18 cm with the following individual active ingredients and theirs were grown Mixtures treated as a dispersion-emulsion-tank mix:

I N-3-Chlor-4-methoxy-phenyl-N'-methyl-N1-methoxyharnstoffI N-3-chloro-4-methoxyphenyl-N'-methyl-N 1 -methoxyurea

II 2-Chlor-4-äthylamino-6-isopropylamino-l,3i5-triazinII 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine

III 2-(2-Chlor-4-methylamino-l,3,5-triazin-6-yl-amino)-2-methylpropionitril III 2- (2-Chloro-4-methylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

IV 2-Chlor-4,6-diäthylamino-l,3,5-triazinIV 2-chloro-4,6-diethylamino-1,3,5-triazine

V 2-Chlor-4-äthylamino-6-tert.butylamino-l,3*5-triazinV 2-chloro-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine

VI 2-(2-Chlor-4-äthylamino-l,3,5-triazin-6-yl-amino)-2-methylpropionitril VI 2- (2-chloro-4-ethylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

VII 2-Methylthio-4-äthylamino-6-tert.butylamino-1,3*5-triazinVII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine

VIII 2-Methylthio-4,6-diisopropylamino-1,3,5-triazinVIII 2-methylthio-4,6-diisopropylamino-1,3,5-triazine

IX 2-Methylthio-4-(3-methoxypropylamino)-6-isopropylamino-1,3,5-triazin IX 2-methylthio-4- (3-methoxypropylamino) -6-isopropylamino-1,3,5-triazine

X 2-Azidio-4-äthylamino-6-tert.butylamino-l,3,5-triazinX 2-Azidio-4-ethylamino-6-tert-butylamino-1,3,5-triazine

XI 2-Chlor-4-i sopropylamino-6-cyclopropylamino-1,3,5-triazinXI 2-chloro-4-isopropylamino-6-cyclopropylamino-1,3,5-triazine

XII 2-Methylthio-4-äthylamino-6-α,ß-dimethylpropylamino-1,3,5-triazin XII 2-methylthio-4-ethylamino-6-α, β-dimethylpropylamino-1,3,5-triazine

XIII 3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxidXIII 3-Isopropyl-2,3-benzothiadiazinon- (4) -2,2-dioxide

XIV 3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz XIV 3-Isopropyl-2,3-benzothiadiazinon- (4) -2,2-dioxide sodium salt

XV 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethylaminsalz XV 3-Isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-dimethylamine salt

XVI 3-Isopropyl-2,1,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanolaminsalz XVI 3-Isopropyl-2,1,3-benzothiadiazinon- (4) -2,2-dioxide-diethanolamine salt

mit Je 0,25, 0,5, 1 und 1,5 kg/ha aktive Substanzwith 0.25, 0.5, 1 and 1.5 kg / ha of active substance

I+II+XIII, I+III+XV, I+IV+XIV, I+V+XVI, I+VI+XIV, I+VII+XVI, I+VIII+XIII, I+IX+XV, I+X+XVI, I+XI+XIV, I+XII+XIV mit je 0,25+0,25+0,5, 0,25+0,5+0,25, 0,5+0,25+0,25, 0,25+0,25+1, 0,25+1+0,25, 1+0,25+0,25 kg/ha aktive Substanz.I + II + XIII, I + III + XV, I + IV + XIV, I + V + XVI, I + VI + XIV, I + VII + XVI, I + VIII + XIII, I + IX + XV, I + X + XVI, I + XI + XIV, I + XII + XIV with 0.25 + 0.25 + 0.5, 0.25 + 0.5 + 0.25, 0.5 + 0.25 + 0.25, 0.25 + 0.25 + 1, 0, 25 + 1 + 0.25, 1 + 0.25 + 0.25 kg / ha active Substance.

Nach 8 bis 14 Tagen wurde festgestellt, daß die Mischungen eine bessere herbizide Wirkung bei gleicher Verträglichkeit an den Kulturpflanzen zeigten als die Einzelwirkstoffe. Das Versuchsergebnis ist aus nachfolgender Tabelle zu ersehen.After 8 to 14 days it was found that the mixtures had a better herbicidal action with the same tolerance on the crop plants showed as the individual active ingredients. The test result can be seen from the following table.

5 0 9809/1118 /28 5 0 9809/1118 / 28

WirkstoffActive ingredient 0,250.25 0,50.5 II. 11 11 00 1,51.5 0,250.25 0,50.5 IIII 11 VV 11 1,51.5 0,250.25 0,50.5 IIIIII VIVI 11 1,51.5 Ni
CONi
CO I
ro
00I.
ro
00 kg/ha a. S.kg / ha a. S. 55 1515th 11 1010 cn
cn
cncn
cn
cn II. Nutzpflanzen:Useful plants: 00 00 00 00 00 00 00 00 1010 55 00 00 1515th 00 Triticum aestivumTriticum aestivum 00 00 00 7070 00 00 00 00 1313th 55 00 00 00 1515th 00 Hordeum vulgäreHordeum vulgar 00 00 00 7575 00 00 00 00 5555 66th 00 00 00 5555 00 Secale cerealeSecale cereale 2020th 4040 00 5050 unerwünschte Pflanzen:unwanted plants: 2424 4040 7070 5050 8787 4545 5555 8787 2727 9292 4040 5050 3535 8585 cncn Alopecurus myosuroidesAlopecurus myosuroides 1515th 2525th 3535 4242 5050 6565 9090 5050 100100 1515th 3030th 7575 8080 6060 CDCD Poa annuaPoa annua 55 1111 1515th 2020th 2525th 4040 6060 8080 1515th 3030th 4545 7575 co
coco
co Galium aparineGalium aparine 2020th 2727 4040 6565 2020th 4040 5050 6565 1010 3030th 5555 5555 O
*
•
O
UlO
*
•
O
Ul O
coO
co Lamium amplexicauleLamium amplexicaule IVIV 4545 WirkstoffActive ingredient 0,250.25 0,50.5 1,51.5 0,250.25 0,50.5 1,51.5 0,250.25 0,50.5 1,51.5 kg/ha a. S.kg / ha a. S. 00 0 '0 ' 2020th 00 1010 2020th 00 55 1515th Triticum aestivum ·Triticum aestivum 00 00 2222nd 00 55 1515th 55 1010 2020th Hordeum vulgäreHordeum vulgar 00 1010 2525th 00 1010 1818th 44th 1010 1919th Secale cerealeSecale cereale 4040 5555 8080 4040 4545 6565 3030th 4444 6565 Alopecurus myosuroidesAlopecurus myosuroides 4545 5555 9090 2525th 3030th 5050 1717th 3131 7070 Poa annuaPoa annua 00 1010 3030th 1515th 2323 3535 '5'5 2020th 5050 Galium aparineGalium aparine 2020th 3535 6060 1515th 3535 6262 5050 6565 8585 Lamium amplexicauleLamium amplexicaule

cn ο co co ο co cn ο co co ο co

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

VII 0,25 0,5 1VII 0.25 0.5 1

1*51 * 5

VIII
0,25 0,5 1VIII
0.25 0.5 1

IX
1,5 0,25 0,5 1IX
1.5 0.25 0.5 1

Tritieum aestivum Hordeutn vulgäre Secale cerealeTritieum aestivum Very vulgar Secale cereale

Alopecurus myosuroidesAlopecurus myosuroides

Foa annuaFoa annua

Galium aparlneGalium aparlne

τJtmi \\ψ[\ amplexicauleτJtmi \\ ψ [\ amplexicaule

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

00 0 0 00000 0 0 000

0000 0000000 000

45 77 90 40 55 85 93 20 50 7745 77 90 40 55 85 93 20 50 77

43 80 95 20 45 75 90 25 50 8043 80 95 20 45 75 90 25 50 80

20 35 60 25 45 60 80 15 24 3520 35 60 25 45 60 80 15 24 35

70 80 95 10 25 40 57 60 68 8270 80 95 10 25 40 57 60 68 82

1*51 * 5

Tritieum aestivumTritieum aestivum 00 00 00 11 00 00 00 1010 XIXI 1414th 00 00 00 55 Hordeum vulgäreHordeum vulgar 00 00 00 00 00 00 1010 5 15 1 1515th 00 00 00 55 Secale cerealeSecale cereale 00 00 00 00 00 00 66th 1010 00 00 00 66th Alopecurus myosuroidesAlopecurus myosuroides 4545 5555 8888 9494 2525th 4545 6060 7575 4444 5555 7878 9090 Foa annuaFoa annua 3030th 3535 4040 5050 1010 4545 5555 7070 1818th 3535 5050 6565 Galium aparineGalium aparine 2626th 4040 6262 8181 2020th 4242 5757 7070 2020th 3535 6060 7777 Lamlum amplexicauleLamlum amplexicaule 2222nd 4141 5353 70 .70. 3030th 5555 6565 8080 1515th 3232 5050 6565 WirkstoffActive ingredient XX XIIXII kg/ha a. S.kg / ha a. S. 0,250.25 0,50.5 1*51 * 5 0,250.25 0,0, 1,51.5 0,250.25 0,0, 5 15 1 1,51.5

0 0 00 0 0

92 9092 90

5858

9595

KM O KM O

cn ο co CX) CD CD cn ο co CX) CD CD

WirkstoffActive ingredient 0,250.25 0,50.5 XIIIXIII 1,51.5 0,250.25 XIVXIV 0,50.5 11 1,51.5 0,250.25 0,50.5 XVXV 1,51.5 kg/ha a. S.kg / ha a. S. 00 00 11 00 00 00 00 00 00 00 11 00 Triticuna aestivumTriticuna aestivum 00 00 00 00 00 00 00 00 00 00 00 00 Hordeum vulgäreHordeum vulgar 00 00 00 00 00 00 00 00 00 00 00 00 Secale eerealeSecale eereale 33 55 00 1515th 00 00 1212th 1515th 00 1010 00 1616 Alopecurus myosuroidesAlopecurus myosuroides 00 00 1010 1010 00 55 1212th 1515th 00 55 1212th 1313th Poa annuaPoa annua 1515th 3030th 55 7575 1515th 3030th 6060 6060 2020th 3030th 88th 6060 Galium aparineGalium aparine 55 1010 6060 4040 55 1010 2525th 4040 55 1010 5050 45.45. Lamium amplexicauleLamium amplexicaule 2525th 4040 WirkstoffActive ingredient 0,250.25 0,50.5 XVIXVI 1,51.5 kg/ha a. S.kg / ha a. S. 11

Trlticum aestivum Hordeum vulgäre Secale eerealeTrlticum aestivum Hordeum vulgar Secale eereale

Alopecurus myosuroides Poa annua Gal ium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Gal ium aparine Lamium amplexicaule

0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0

00 1010 1212th 1515th 00 55 1010 1515th 2525th 3535 6565 8080 66th 1010 3535 5050

0 = ohne Schädigung 100 = totale Schädigung0 = no damage 100 = total damage

cn cn cncn cn cn

CTl O (O OO O CD CTl O (O OO O CD

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

I+II+XIIII + II + XIII

0,25+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5 0,25 0,25 1 0,25 0,250.25+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5 0.25 0.25 1 0.25 0.25

I+III+XVI + III + XV

0,25+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5+ 0,25+ 0,25+1+ 0,25+ 0,5 0,25 0,25 1 0,25 0,250.25+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5+ 0.25+ 0.25 + 1 + 0.25+ 0.5 0.25 0.25 1 0.25 0.25

Triticum aestlvumTriticum aestlvum 00 00 00 00 00 00 00 00 00 00 ΌΌ 00 Hordeum vulgäreHordeum vulgar 00 00 00 00 00 00 00 00 00 00 00 00 Seeale cerealeSeeale cereale 00 00 00 00 00 00 00 00 00 00 00 00 Alopecurus tnyosuroidesAlopecurus tnyosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 100100 100100 100100 100100 100100 7070 8585 8o8o 8080 100100 9090 Galium aparineGalium aparine 100100 9797 8888 100100 100100 9090 9090 9090 8181 100100 100100 8585 Lamlum araplexicauleLamlum araplexicaule 9090 100100 8686 100100 100100 100100 8080 9595 8282 9595 100100 9595 WirkstoffActive ingredient i+iv+xrvi + iv + xrv I+V+XVII + V + XVI

Triticum aestivum 0 0 0 0 0 0 0 10 0 0 15Triticum aestivum 0 0 0 0 0 0 0 10 0 0 15

Hordeum vulgäre 00 00 5 0 0 500 10Hordeum vulgar 00 00 5 0 0 500 10

Secale cereale 0 0 0 0 10 0 0 10 0 0 13Secale cereale 0 0 0 0 10 0 0 10 0 0 13

Alopecurus myosuroides 100 100 100 100 100 100 100 100 100 100 100 ICAlopecurus myosuroides 100 100 100 100 100 100 100 100 100 100 100 IC

Poa annua 100 100 100 100 100 100 85 85 95 90Poa annua 100 100 100 100 100 100 85 85 95 90

Galium aparine 55 70 66 100 80 70 95 100 91 100Galium aparine 55 70 66 100 80 70 95 100 91 100

Lamium amplexicaule 90 100 92 100 100 100 80 97 84 100Lamium amplexicaule 90 100 92 100 100 100 80 97 84 100

100 95 97 ^ °100 95 97 ^ °

cn cncn cn

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

I+VI+XIVI + VI + XIV

0,25+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5 0,25 0,25 1 0,25 0,250.25+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5 0.25 0.25 1 0.25 0.25

I+VII+XVII + VII + XVI

0,25+ 0,25+ 0,5+ 0,25+ 0,25+ 1+0.25+ 0.25+ 0.5+ 0.25+ 0.25+ 1+

0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+

0,5 0,25 0,25 1 0,25 0,250.5 0.25 0.25 1 0.25 0.25

O CD OO O CDO CD OO O CD

(it ■α m(it ■ α m

Triticum aestivumTriticum aestivum OO 55 00 00 00 1010 00 00 00 00 OO 00 00 00 00 CJCJ I
VjJI.
Previous year Hordeum vulgäreHordeum vulgar 55 1010 00 55 • 5• 5 1515th 55 00 00 00 00 00 00 00 00 LT,
cn LT,
cn l\J
Il \ J
I. Secale cerealeSecale cereale 44th 1010 00 44th 44th 1515th 44th 00 00 00 00 00 00 00 00 Alopecurus myosuroidesAlopecurus myosuroides 9494 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 7272 8181 100100 7878 7777 100100 8888 9090 9595 8686 9595 8080 9595 9595 100100 Galium aparineGalium aparine 8080 8080 100100 7171 100100 9595 7575 100100 100100 9797 9898 8888 100100 100100 100100 Lamium amplexicauleLamium amplexicaule 100100 100100 100100 100100 100100 100100 100100 8888 100100 9292 9090 8282 100100 ' 100'100 100100 WirkstoffActive ingredient I+VIII+XIIII + VIII + XIII I+IX+XVI + IX + XV OO Triticum aestivumTriticum aestivum 00 00 00 1010 00 00 00 00 00 ISIS Hordeum vulgäreHordeum vulgar 00 00 00 1010 00 00 00 00 00 VjJ
O
O
VJIPrevious year
O
O
VJI Secale cerealeSecale cereale 00 00 00 66th 00 00 00 00 00 Alopecurus myosuroidesAlopecurus myosuroides 5454 100100 9999 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 6565 7575 7070 100100 8585 7373 7777 100100 8989 Galium aparineGalium aparine 9595 8686 100100 100100 9090 9090 100100 100100 9090 Lamium amplexicaule ■Lamium amplexicaule ■ 100100 100100 100100 100100 100100 8080 100100 100100 9797

OO O CDOO O CD

Wirkstoff kg/ha a. S. Active ingredient kg / ha a. S.

I+X+XVII + X + XVI

0,25+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+ 0,5 0,25 0,25 1 0,25 0,25 I+XI+XIV0.25+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+ 0.5 0.25 0.25 1 0.25 0.25 I + XI + XIV

0,25+ 0,25+ 0,5+ 0,25+ 0,25+ 1+
0,25+ 0,5+ 0,25+ 0,25+ 1+ 0,25+
0,5 0,25 0,25 1 0,25 0,250.25+ 0.25+ 0.5+ 0.25+ 0.25+ 1+
0.25+ 0.5+ 0.25+ 0.25+ 1+ 0.25+
0.5 0.25 0.25 1 0.25 0.25

Triticum aestivum
Hordeum vulgäre
Seeale cerealeTriticum aestivum
Hordeum vulgar
Seeale cereale

Alopecurus nyosuroldes 100Alopecurus nyosuroldes 100

Poa annuaPoa annua

Galium aparineGalium aparine

Lamium amplexicauleLamium amplexicaule

OO 00 00 00 00 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 00 00 00 00 00 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 9595 9898 9898 100100 100100 100100 • 80• 80 100100 8585 8787 100100 9595 9090 9090 9090 8686 100100 9090 9797 100100 8787 100100 100100 9090 100100 100100 100100 100100 100100 100100 8ο8ο 9090 9090 • 95• 95 100100 9595

WirkstoffActive ingredient

I+XII+XIVI + XII + XIV

Triticum aeetivum
Hordeum vulgäre
Secale cerealeTriticum aeetivum
Hordeum vulgar
Secale cereale

0 0
0 0
0 00 0
0 0
0 0

Alopecurus myosuoides 84 100Alopecurus myosuoides 84 100

Poa annua 85 100Poa annua 85 100

Oalium aparine 90 84Oalium aparine 90 84

Lamium amplexlcaule 100 100Lamium amplexlcaule 100 100

0 0 00 0 0

100 90 81100 90 81

100100

0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0

96 9296 92

100 100100 100

100100

100100

95 10095 100

0 = ohne Schädigung
100 = totale Schädigung0 = without damage
100 = total damage

- 34 - O.Z. j>L> 054- 34 - OZ j>L> 054

2 3 A 1 5 5 52 3 A 1 5 5 5

Beispiel 4Example 4

Eine landwirtschaftliche Nutzfläche wurde mit verschiedenen Samen besät. Unmittelbar danach wurde der so vorbereitete Boden mit folgenden Einzelwirkstoffen und deren Mischungen als Granulat behandelt:An agricultural area was sown with various seeds. Immediately after that, the ground thus prepared was created treated as granules with the following individual active ingredients and their mixtures:

I N-jS-Chlor-^-methoxy-phenyl-N' -methyl-N' -methoxyharnstof fI N-jS-chloro - ^ - methoxy-phenyl-N'-methyl-N'-methoxyurea f

II 2-Chlor-4-äthylamino-6-isopropylamino-1,3,5-triazinII 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine

III 2-(2-Chlor-4-methylamino-l,3,5-triazin-6-yl-amino)-2-methylpropionitril III 2- (2-Chloro-4-methylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

IV 2-Chlor-4,6-diäthylamino-1,3,5-triazinIV 2-chloro-4,6-diethylamino-1,3,5-triazine

V 2-Chlor-4-äthylamino-6-tert.butylamino-1,3*5-triazinV 2-chloro-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine

VI 2-(2-Chlor-4-äthylamino-l,3,5-triazin-6-yl-amino)-2-methylpropionitril VI 2- (2-chloro-4-ethylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

VII 2-Methylthio-4-äthylamino-6-tert.butylamino-1,3,5-tri azinVII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3,5-tri azin

VIII 2-Methylthio-4,6-diisopropylamino-l,3,5-triazinVIII 2-methylthio-4,6-diisopropylamino-1,3,5-triazine

IX 2-Methylthio—4-(3-methoxypropylamino)-6-isopropylamino-1,3,5-triazin IX 2-methylthio-4- (3-methoxypropylamino) -6-isopropylamino-1,3,5-triazine

X 2-Azido-4-äthylamino-6-tert.butylamino-1,3,5-triazinX 2-Azido-4-ethylamino-6-tert-butylamino-1,3,5-triazine

XI 2-Chlor-4-isopropylamino-6-cyclopropylamino-l,3,5-triazinXI 2-chloro-4-isopropylamino-6-cyclopropylamino-1,3,5-triazine

XII 2-Methylthlo-4-äthylamino-6-Λ,ß-dimethylpropylamino-1,3,5-triazin XII 2-methylthlo-4-ethylamino-6- Λ, ß-dimethylpropylamino-1,3,5-triazine

mit Jeweils 0,25, 0,5, 0,75, 1, 1,5 und 2 kg/ha a. S.with 0.25, 0.5, 0.75, 1, 1.5 and 2 kg / ha a. S.

I+II, I+III, I+IV, I+V, I+VI, I+VII, I+VIII, I+IX, I+X, I+XI und I+XIII + II, I + III, I + IV, I + V, I + VI, I + VII, I + VIII, I + IX, I + X, I + XI and I + XII

mit je 0,25+0,75, 0,75+o,25, 0,5+0,5, 0,5+1,5, 1,5+0,5with 0.25 + 0.75, 0.75 + o, 25, 0.5 + 0.5, 0.5 + 1.5, 1.5 + 0.5 each

und 1+1 kg/ha aktive Substanz.and 1 + 1 kg / ha of active substance.

Der Versuch wurde unter trockenen Bedingungen gehalten.The experiment was kept under dry conditions.

Nach 4 bis 5 Wochen wurde festgestellt, daß die Mischungen eine bessere herbizide Wirkung bei gleicher Verträglichkeit an den Kulturpflanzen bei 1 kg/ha a. S. zeigten und eine bessere Verträglichkeit an den Kulturpflanzen und eine bessere herbizide Wirkung bei 2 kg/ha a. S. als die Wirkstoffe I bis XII zeigten.After 4 to 5 weeks the mixtures were found to have a better herbicidal effect with the same tolerance on the crop plants at 1 kg / ha a. S. showed and better tolerability on the cultivated plants and a better herbicidal effect at 2 kg / ha a. S. as the active ingredients I to XII showed.

Das Vereuchaergebnis ist aus nachfolgender Tabelle zu ersehen.The results can be seen in the following table.

5 0 9 8 0 9/11185 0 9 8 0 9/1118

WirkstoffActive ingredient 0,250.25 0,50.5 II. 11 11 1,51.5 22 0,250.25 0,50.5 IIII TVTV 11 1,51.5 22 kg/ha a. S.kg / ha a. S. 0,750.75 00 0,750.75 0,750.75 Nutzpflanzen:Useful plants: 00 00 00 00 00 00 00 00 00 55 1010 2020th Tritieum aestivumTritieum aestivum 00 00 00 00 00 55 1010 00 00 00 00 1010 1515th 2222nd Hordeum vulgäreHordeum vulgar 00 00 00 00 0 '0 ' 00 00 00 00 00 00 1515th 2020th 2525th Secale cerealeSecale cereale 00 00 00 00 7070 55 1515th 00 00 00 00 00 00 00 Zea maysZea mays 00 6868 00 5050 unerwünschte Pflanzen;unwanted plants; 2020th 3535 7575 1010 8080 9090 2525th 4040 5555 8o8o 8585 9797 CJICJI Alopecurus myosuroidesAlopecurus myosuroides 3030th 4545 5050 8080 4040 8585 9090 2525th 4040 5656 55 7575 8080 9595 CD
COCD
CO Poa annuaPoa annua 00 22 7070 1010 1616 2020th 22 55 7070 3535 1515th 2020th 3030th 0000 Galium aparineGalium aparine 1212th 2525th 55 5050 6767 9090 1818th 2727 1010 4040 5050 9090 (_>
co (_>
co Lamium amplexicauleLamium amplexicaule 3030th IIIIII 3535 —*- * WirkstoffActive ingredient 0,250.25 0,50.5 0,750.75 1,51.5 22 0,250.25 0,50.5 11 1,51.5 22 coco kg/ha a. S.kg / ha a. S. 00 00 00 00 1010 00 00 00 00 1010 Triticum aestivumTriticum aestivum 00 00 00 00 1515th 00 00 00 00 1010 Hordeum vulgäreHordeum vulgar 00 00 00 00 1919th 00 00 00 00 1010 Secale cerealeSecale cereale 00 00 00 00 00 00 00 00 00 00 Zea maysZea mays 2020th 3535 5050 8080 9090 ' 15'15 2525th 6060 7070 8585 Alopecurus myosuroidesAlopecurus myosuroides 1818th 3838 6060 7676 9090 2020th 3030th 6363 7070 9090 Poa annuaPoa annua 22 33 55 1515th 2020th 00 33 1010 1414th 1919th Galium aparineGalium aparine 1515th 2020th 3030th 4848 7575 1717th 2424 4646 5555 8080 Lamium amplexicauleLamium amplexicaule

VjJ VJlYear of year of year of

·—* cn· - * cn

VjJ
ONPrevious year
ON

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

0,25 0,5 0,75 1 1,5 20.25 0.5 0.75 1 1.5 2

VI
0,25 0,5 0,75 1 1,5 2VI
0.25 0.5 0.75 1 1.5 2

Triticum aestivumTriticum aestivum 00 00 55 1010 1515th 1818th 00 00 00 00 55 1010 Hordeum vulgäreHordeum vulgar 00 00 00 55 1010 1414th 00 00 00 55 1010 1515th Seeale cerealeSeeale cereale 00 00 55 1212th 1515th 2020th 00 00 00 55 1010 1414th Zea maysZea mays 00 00 00 00 00 00 00 00 00 00 00 00 Alopecurus myosuroidesAlopecurus myosuroides 2020th 3030th 5454 6262 7070 7979 2525th 4545 7070 8080 9090 9898 Poa annuaPoa annua 1818th 3030th 5858 6565 7575 8080 2727 4949 7575 8585 9595 9898 cncn Galium aparineGalium aparine 00 55 1010 1515th 2323 3030th 55 77th 1010 1515th 2222nd 3030th 19801980 Lamium amplexicauleLamium amplexicaule 1515th 2020th 3030th 4040 5252 7575 1515th 3030th 3535 4040 4848 8585 CDCD WirkstoffActive ingredient VII.VII. VIIIVIII »» kg/ha a. S.kg / ha a. S. 0,250.25 0,50.5 0,750.75 11 1,51.5 22 0,250.25 0,50.5 0,750.75 11 1,51.5 22

0 0 0 00 0 0 0

Triticum aestivum 0 0Triticum aestivum 0 0

Hordeum vulgäre 0 0Hordeum vulgar 0 0

Seeale cereale 0 0Seeale cereale 0 0

Zea mays 0 0Zea mays 0 0

Alopecurus myosuroides 10 20Alopecurus myosuroides 10 20

Poa annua 15 25Poa annua 15 25

Galium aparine 0 0Galium aparine 0 0

Lamium amplexlcaule 25 40Lamium amplexlcaule 25 40

0 00 0

0 50 5

0 70 7

0 00 0

0 00 0

0 00 0

0 00 0

0 00 0

0
0
0
00
0
0
0

5 5 05 5 0

50 80 9550 80 95

56 85 9856 85 98

7 10 157 10 15

75 90 9575 90 95

5 105 10

10 1510 15

15 2015 20

0 00 0

10 15 30 40 60 8510 15 30 40 60 85

15 20 40 48 75 9015 20 40 48 75 90

0 2 5 10 15 200 2 5 10 15 20

25 45 60 80 90 9525 45 60 80 90 95

COCO

cn cn cncn cn cn

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

0,25 0,50.25 0.5

IX
0,75 1IX
0.75 1

1,5 21.5 2

0,25 0,5 0,75 1 1,5 20.25 0.5 0.75 1 1.5 2

Trlticum aestivumTrlticum aestivum 00 00 00 00 XIXI 00 55 00 00 00 00 XIIXII 00 00 Hordeum vulgäreHordeum vulgar 00 00 00 00 ,75 1, 75 1 00 77th 00 00 00 00 75 175 1 00 00 Seeale cerealeSeeale cereale 00 00 00 00 55 1010 00 00 00 00 00 00 Zea maysZea mays 00 00 00 00 00 00 00 00 00 00 00 00 Alopecurus myosuroidesAlopecurus myosuroides 1212th 1818th 3535 4545 7070 8585 2323 4545 6060 7070 8585 9595 Poa annuaPoa annua 1717th 2626th 4040 5050 8o8o 9090 2525th 4646 7070 7777 8686 9797 Galium aparineGalium aparine 00 33 55 1010 1212th 1717th 00 22 55 77th 1010 1515th cn
οcn
ο Lamium amplexicaUleLamium amplexicaUle 2020th 4040 5858 7070 8585 9090 1515th 2525th 3131 3838 4747 8585 980!980! WirkstoffActive ingredient •• CD
. &CD
. & kg/ha a. S.kg / ha a. S. 0,250.25 0,50.5 00 1,51.5 22 0,250.25 0,50.5 0,0, 1,51.5 22

Triticum aestivum Hordeum vulgäre Secale cereale
Zea maysTriticum aestivum Hordeum vulgar Secale cereale
Zea mays

0 0 0 00 0 0 0

Alopecurus myosuroides 18 Poa annua 20Alopecurus myosuroides 18 Poa annua 20

Galium aparine 0 Lamium amplexicaule 14Galium aparine 0 Lamium amplexicaule 14

0 0 0 00 0 0 0

4040

4444

2020th

0 0 0 00 0 0 0

0 0 0 00 0 0 0

0 00 0

0 00 0

0 00 0

0 00 0

0 00 0

0 00 0

0 00 0

0 00 0

5555

65"65 "

55

3030th

8o8o

8585

4343

4545

2424

0
0
0
00
0
0
0

5454

63 663 6th

3535

0
0
0
00
0
0
0

0 00 0

0 00 0

0 00 0

0 00 0

65 75 9465 75 94

74 80 9074 80 90

10 14 1810 14 18

40 50 8740 50 87

ro νro ν

co ·co

■ο S^■ ο S ^

cn S cn -t=· cn cn S cn -t = · cn

cn ο co oo ο to cn ο co oo ο to

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

I + III + II

0,25+ 0,75+ 0,5+ 0,5+ 1,5+ 1+1 0,75 0,25 0,5 1,5 0,50.25+ 0.75+ 0.5+ 0.5+ 1.5+ 1 + 1 0.75 0.25 0.5 1.5 0.5

+ III+ III

0,25+ 0,75+ 0,5+ 0,5+ 1,5+ 1+1
0,75 0,25 0,5 1,5 0,50.25+ 0.75+ 0.5+ 0.5+ 1.5+ 1 + 1
0.75 0.25 0.5 1.5 0.5

Triticum aestivumTriticum aestivum 00 00 IVIV 00 1010 00 55 00 00 VV 00 9898 00 00 00 Hordeum vulgäreHordeum vulgar 00 00 00 1515th 55 1010 00 00 00 100100 00 55 00 Secale cerealeSecale cereale 00 00 00 2020th 00 1515th 00 00 00 4242 00 00 00 Zea maysZea mays 00 00 00 00 55 00 00 00 00 8787 00 55 00 Alopecurus myosuroidesAlopecurus myosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 10.010.0 100100 100100 100100 100100 100100 100100 100100 100100 100100 Galium aparineGalium aparine 5050 4545 4848 6868 6464 7070 4444 5050 7070 6565 6060 Lamium araplexicauleLamium araplexicaule 9090 9090 9393 100100 100100 100100 9090 9090 100100 100100 100100 WirkstoffActive ingredient I +I + I +I +

Triticum aestivum Hordeum vulgäre Secale cereale Zea maysTriticum aestivum Hordeum vulgar Secale cereale Zea mays

Alopecurus myosuroides Poa annua Galium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparine Lamium amplexicaule

OO 00 9696 00 00 OO OO 55 OO OO 1515th OO 1010 roro OO 00 100100 00 00 55 OO OO OO OO 1010 55 55 coco OO 00 4242 00 00 OO OO 55 OO OO 1515th OO 1212th OO 00 9090 0 -0 - 00 55 OO OO OO OO OO 55 OO 100100 9898 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 iooioo 100100 100100 100100 100100 100100 100100 100100 100100 4545 4040 6060 6767 6060 5353 4242 5050 7070 6464 6868 9696 9292 100100 100100 100100 8787 9090 8989 100100 100100 100100

i Oi O

cn οcn ο

cn ^ cncn ^ cn

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

I + VII + VI

0,25+ 0,75+ 0,5+ 0,5+ 1,5+ 1+1 0,75 0,25 0,5 1,5 0,50.25+ 0.75+ 0.5+ 0.5+ 1.5+ 1 + 1 0.75 0.25 0.5 1.5 0.5

+ VII+ VII

0,25+ 0,75+ 0,5+ 0,5+ 1,5+ 1+1
0,75 0,25 0,5 1,5" 0,50.25+ 0.75+ 0.5+ 0.5+ 1.5+ 1 + 1
0.75 0.25 0.5 1.5 "0.5

Triticum aestivumTriticum aestivum 00 00 00 55 00 00 00 9696 00 9898 00 9595 00 00 00 VO
IVO
I. Hordeum vulgäreHordeum vulgar 00 00 00 1010 55 55 00 100100 00 100100 00 9898 00 55 00 Secale cerealeSecale cereale 00 00 00 1010 00 55 00 4242 00 4040 00 3838 00 00 00 Zea maysZea mays 00 00 00 00 55 00 00 98
I +98
I + 00 97
IX97
IX 00 9898 00 55 00 Alopecurus myosuroidesAlopecurus myosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 Poa annuaPoa annua 100100 100100 100100 100100 100100 100100 100100 100100 100100 cncn Galium aparineGalium aparine 5252 4848 5050 7171 6565 6767 5757 6o6o 6o6o 39809/39809 / Lamium amplexicaule
WirkstoffLamium amplexicaule
Active ingredient 90
I +90
I + 88
VIII88
VIII 9494 9797 100100 100100 100100 100100 100100

Triticum aestivum 0 0Triticum aestivum 0 0

Hordeum vulgäre 0 0Hordeum vulgar 0 0

Secale cereale 0 0Secale cereale 0 0

Zea mays 0 0Zea mays 0 0

Alopecurus myosuroides 90Alopecurus myosuroides 90

Poa annua 95Poa annua 95

Galium aparine 47Galium aparine 47

Lamium amplexicaule 100Lamium amplexicaule 100

0 0 0 00 0 0 0

0 00 0

5 55 5

0 50 5

5 05 0

92 100 100 10092 100 100 100

96 100 100 10096 100 100 100

40 65 70 6440 65 70 64

100 100 100 100100 100 100 100

00 9595 00 9393 00 00 00 00 00 9898 00 100100 00 00 55 00 00 4444 00 4242 00 55 00 00 00 100100 00 9090 0·0 · 00 55 00 9595 100100 100100 100100 100100 100100 100100 100100 4545 5656 6060 6363 100100 100100 100100 100100

COCO

^ O^ O

cn οcn ο

cn ^ cncn ^ cn

cn ο tocn o to

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

I + XI + X

0,25+ 0,75+ 0,5+ 0,5+ 1,5+ 1+1 0,75 0,25 0,5 1,5 0,5 I + XI0.25+ 0.75+ 0.5+ 0.5+ 1.5+ 1 + 1 0.75 0.25 0.5 1.5 0.5 I + XI

0,25+ 0,75+ 0,5+ 0,5+ 1,5+ 1+1 0,75 0,25 0,5 1,5 0,50.25+ 0.75+ 0.5+ 0.5+ 1.5+ 1 + 1 0.75 0.25 0.5 1.5 0.5

Triticum aestivum Hordeum vulgäre Seeale cereale Zea maysTriticum aestivum Hordeum vulgar Seeale cereale Zea mays

Alopecurus myosuroides Poa annua Galium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparine Lamium amplexicaule

00 00 00 00 00 00 00 00 00 00 00 00 II. 00 00 00 00 55 00 00 00 00 00 55 00 .Sr
ö.Sr
ö 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 55 00 00 00 00 00 55 00 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 iodiod 100100 4545 4242 4040 5050 6060 5757 4343 4242 4040 5858 6060 6363 4343 8888 9090 100100 100100 100100 8787 9090 8888 100100 100100 100100

WirkstoffActive ingredient

I + XIII + XII

Triticum aestivum Hordeum vulgäre Seeale cereale Zea maysTriticum aestivum Hordeum vulgar Seeale cereale Zea mays

Alopecurus myosuroides Poa annua Galium aparine Lamium amplexicauleAlopecurus myosuroides Poa annua Galium aparine Lamium amplexicaule

00 9898 00 00 00 00 00 00 100100 00 00 00 55 00 00 4747 00 00 00 00 00 00 9090 00 00 00 55 00 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 4545 4040 5858 6464 6565 9090 9292 100100 100100 100100

0 = ohne Schädigung 100 = Totale Schädigung0 = no damage 100 = total damage

roro OO coco NN VjJ
OPrevious year
O cn
cncn
cn O
VJIO
VJI

cncn

- 41 - O.Z. 30 054- 41 - O.Z. 30 054

Beispiel 5Example 5

Im Gewächshaus wurden verschiedene Pflanzen bei einer Wuchshöhe von 2 bis 20 cm mit folgenden Einzelwirkstoffen und deren Mischungen als Emulsion-Dispersion behandelt:Various plants were grown in the greenhouse at a height of 2 to 20 cm with the following individual active ingredients and their Mixtures treated as emulsion-dispersion:

XVII N^-Chlor^-methoxyphenyl-N-cyclohex-l-enyl-N' ,Nf dimethylharnstoff XVII N ^ -Chlor ^ -methoxyphenyl-N-cyclohex-1-enyl-N ', N f dimethylurea

XVIII N-^-Chlor-^-methylphenyl-N-cyclohex-l-enyl-N1,N'-dimethylharnstoff XVIII N - ^ - chlorine - ^ - methylphenyl-N-cyclohex-l-enyl-N 1 , N'-dimethylurea

II 2-Chlor-4-äthylamino-6-i sopropylamino-1,3*5-triazinII 2-chloro-4-ethylamino-6-isopropylamino-1,3 * 5-triazine

III 2-^-Chlor^-methylamino-1,3,5-triazin-6-yl-amino)-2-methylpropionitrile III 2 - ^ - chloro ^ -methylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

IV 2-Chlor-4,6-diäthylamino-l,3,5-triazinIV 2-chloro-4,6-diethylamino-1,3,5-triazine

V 2-Chlor-4-äthylamino-6-tert.butylaraino-l,3,5-triazinV 2-chloro-4-ethylamino-6-tert-butylaraino-1,3,5-triazine

VI 2- (a-Chlor-^-äthylamino-1,3,5- triazin-6-yl-amino) -2-methylpropionitril VI 2- (a-chloro - ^ - ethylamino-1,3,5-triazin-6-yl-amino) -2-methylpropionitrile

VII 2-Methylthio-4-äthylamino-6-tert.butylamino-1,3,5-triazinVII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3,5-triazine

VIII 2-Methylthio-4,6-dii sopropylamino-1,3,5-triazinVIII 2-methylthio-4,6-diisopropylamino-1,3,5-triazine

IX 2-Methylthio-4-(3-methoxypropylamino)-6-isopropylamino-1,3,5-triazin IX 2-methylthio-4- (3-methoxypropylamino) -6-isopropylamino-1,3,5-triazine

X 2-Azido-4-äthylamino-6-tert.butylamino-1,3,5-triazinX 2-Azido-4-ethylamino-6-tert-butylamino-1,3,5-triazine

XI 2-Chlor-4-isopropylamino-6-cyclopropylamino-l,3,5-triazinXI 2-chloro-4-isopropylamino-6-cyclopropylamino-1,3,5-triazine

XII 2-Methylthio-4-äthylamino-6-#,ß-dimethylpropylamino-1,3,5-triazin XII 2-methylthio-4-ethylamino-6 - #, β-dimethylpropylamino-1,3,5-triazine

mit je 0,5, 1, 1,5 und 2 kg/ha a. S.with 0.5, 1, 1.5 and 2 kg / ha a. S.

xvii+ii, xvii+ni, xvii+rv, xvii+xii, xviii+xii, xviii+xi, XVIII+X, XVIII+IX, XVIII+VIII, XVTII+VII, XVII+V, XVII+VI, XVII+VII, XVII+VIII, XVII+IX, XVII+X, XVII+XI, XVIII+VI, XVIII+V, XVIII+IV, XVIII+III, XVIII+IIxvii + ii, xvii + ni, xvii + rv, xvii + xii, xviii + xii, xviii + xi, XVIII + X, XVIII + IX, XVIII + VIII, XVTII + VII, XVII + V, XVII + VI, XVII + VII, XVII + VIII, XVII + IX, XVII + X, XVII + XI, XVIII + VI, XVIII + V, XVIII + IV, XVIII + III, XVIII + II

mit je 0,5 + 1,5, 1,5 + 0,5 und 1+1 kg/ha a. S.with 0.5 + 1.5, 1.5 + 0.5 and 1 + 1 kg / ha a. S.

Nach 12 bis 15 Tagen wurde festgestellt, daß die Mischungen eine bessere herbizide Wirkung und eine bessere Verträglichkeit an den Kulturpflanzen zeigen als die Einzelwirkstoffe.After 12 to 15 days it was found that the mixtures had a better herbicidal effect and better tolerance the crops show as the individual active ingredients.

Das Versuchsergebnis ist aus nachfolgender Tabelle zu ersehen.The test result can be seen from the following table.

509809/1118 /42509809/1118 / 42

cn ο co oo ο cocn ο co oo ο co

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

XVII 0,5 1 1,5 2XVII 0.5 1 1.5 2

XVIII
0,5 1 1,5 2XVIII
0.5 1 1.5 2

II
0,5 1 1,5 2II
0.5 1 1.5 2

Trlticum aestivum
Hordum vulgäre
Seeale cerealeTrlticum aestivum
Hordum vulgar
Seeale cereale

0 6 10 10 0 0 5 11 0 0 7 130 6 10 10 0 0 5 11 0 0 7 13

Alopecurus rayosuroides 20 30 48 60 Gal ium aparine 12 20 29 36 Lamium amplexicaule 20 36 48 62Alopecurus rayosuroides 20 30 48 60 Gal ium aparine 12 20 29 36 Lamium amplexicaule 20 36 48 62

Wirkstoff
kg/ha a. S.Active ingredient
kg / ha a. S.

III 0,5 1 1,5 2III 0.5 1 1.5 2

OOO5OOO5

0 5 7 10 00580 5 7 10 0058

40 55 70 7840 55 70 78

6 10 16 206 10 16 20

20 35 57 6520 35 57 65

IV
0,5 1 1,5 2IV
0.5 1 1.5 2

0 0 20 300 0 20 30

0 5 23 350 5 23 35

0 10 26 320 10 26 32

55 87 9255 87 92

40 60 8040 60 80

40 50 65 8040 50 65 80

0,5 1 1,5 20.5 1 1.5 2

Tritlcum aestivum
Hordeum vulgäre
Seeale cerealeTritlcum aestivum
Hordeum vulgar
Seeale cereale

0 0 0 10 0 0 0 15 0 0 0 100 0 0 10 0 0 0 15 0 0 0 10

Alopecurus myosuroides 50 75 85 90 Galium aparine 30 55 75 85 Lamium amplexicaule 30 45 55 70Alopecurus myosuroides 50 75 85 90 Galium aparine 30 55 75 85 Lamium amplexicaule 30 45 55 70

0 0 20 300 0 20 30

0 5 22 350 5 22 35

0 10 25 300 10 25 30

55 70 80 9555 70 80 95

10 20 30 5010 20 30 50

35 50 60 8035 50 60 80

10 15 20 2510 15 20 25

5 10 15 2o5 10 15 2o

10 13 18 2110 13 18 21

45 55 65 8045 55 65 80

23 27 35 5523 27 35 55

35 50 62 7535 50 62 75

Ν.· COΝ. CO

0101 SS.

cn J^cn J ^

cn ο cocn o co

σ coσ co

WirkstoffActive ingredient 0,50.5 VIVI 11 1,51.5 00 55 22 0,50.5 VIIVII 11 1,51.5 XX 00 22 0,50.5 VIIIVIII 11 1,51.5 22 0,50.5 XIIXII 11 1,51.5 22 kg/ha a. S.kg / ha a. S. 55 1010 1515th 00 55 2020th 00 00 00 00 00 00 1010 1414th 2020th 00 00 00 00 Triticum aestivumTriticum aestivum 1010 1515th 2020th 00 66th 2424 00 00 00 00 00 00 1010 1515th 2222nd 00 00 00 00 Hordeum vulgäreHordeum vulgar 1010 1515th 1919th 2323 00 00 00 00 00 66th 1010 1515th 00 00 00 00 Seeale cerealeSeeale cereale 4040 5555 6565 7575 5555 8888 9494 100100 4545 6060 7575 9090 5050 7777 9292 100100 Alopecurus myosruroidesAlopecurus myosruroides 2020th 3535 5050 7070 4040 6262 8181 9696 4242 5757 7070 8080 2424 3535 5858 7878 Galium aparineGalium aparine 6565 8080 8585 9595 4141 5353 7070 8585 5555 6565 8080 9595 6868 8282 9595 100100 Lamium amplexicauleLamium amplexicaule IXIX XIXI WirkstoffActive ingredient 00 1010 00 00 00 00 00 00 00 Triticum aestivumTriticum aestivum 00 1212th 00 00 00 00 00 00 00 Hordeum vulgäreHordeum vulgar 00 1111 00 00 00 00 00 00 00 Seeale cerealeSeeale cereale

VjJPrevious year

°° Alopecurus myosuroides 55 78 90 100 45 77 90 100 55 85 93 100 Galium aparine 35 60 77 90 20 35 60 80 45 60 80 95 Lamium amplexicaule 32 50 65 80 70 80 95 100 25 40 57 75°° Alopecurus myosuroides 55 78 90 100 45 77 90 100 55 85 93 100 Galium aparine 35 60 77 90 20 35 60 80 45 60 80 95 Lamium amplexicaule 32 50 65 80 70 80 95 100 25 40 57 75

0 β ohne Schädigung ο0 β without damage ο

100 = totale Schädigung ro N100 = total damage ro N

CO v>JCO v> J

4>· Ο4> · Ο

£ cn£ cn

Wirkstoff XVII + II XVII + III XVII + IV XVII + VActive ingredient XVII + II XVII + III XVII + IV XVII + V

kg/ha a. S. 0,5+ 1,5+ 1+1 0,5+ 1,5+ 1+1 0,5+ 1,5+1+1 0,5+ 1,5+ 1+1kg / ha a. P. 0.5+ 1.5+ 1 + 1 0.5+ 1.5+ 1 + 1 0.5+ 1.5 + 1 + 1 0.5+ 1.5+ 1 + 1

1,5 0,5 1,5 0,5 1,5 0,5 1,5 0,51.5 0.5 1.5 0.5 1.5 0.5 1.5 0.5

Triticum aestivumTriticum aestivum 2020th 1010 66th 00 1010 66th 2020th 1010 66th 2020th 2020th 2121 Hordeum vulgäreHordeum vulgar 2323 VJlVJl 55 00 55 00 2222nd 55 55 1515th 1010 1010 Secale cerealeSecale cereale 2626th 77th 1010 00 77th 00 2525th 77th 1010 1818th 1717th 1313th Alopeeurus myosuroidesAlopeeurus myosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 Galium aparineGalium aparine 100100 100100 100100 100100 100100 100100 8282 7878 8080 8484 8888 8686 Lamiutn amplexicauleLamiutn amplexicaule 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 WirkstoffActive ingredient XVIIXVII + VI+ VI XVIIXVII + VII+ VII XVIIXVII + VIII+ VIII XVIIXVII + IX+ IX

cn ο cocn o co

^» Triticura aestivum 15 15 16 0 10 6 14 10 16 5 10 It Hordeum vulgäre 20 15 15 0 5 0 15 5 10 5 5 ^ Secale cereale 19 17 15 0 7 0 10 7 6 6 7^ »Triticura aestivum 15 15 16 0 10 6 14 10 16 5 10 It Hordeum vulgar 20 15 15 0 5 0 15 5 10 5 5 ^ Secale cereale 19 17 15 0 7 0 10 7 6 6 7

Alopeeurus myosuroides 100 100 100 100 100 100 100 100 100 100 100 Galium aparine 100 84 93 100 100 100 100 100 100 100 100 Lamium amplexicaule 100 100 100 100 100 100 100 100 100 100 100Alopeeurus myosuroides 100 100 100 100 100 100 100 100 100 100 100 Galium aparine 100 84 93 100 100 100 100 100 100 100 100 Lamium amplexicaule 100 100 100 100 100 100 100 100 100 100 100

cn ο cn v£ cn cn ο cn v £ cn

o Wirkstoff
co o Active ingredient
co

Wirkstoff XVII + X XVII + XI XVII + XII XVIII + XIIActive ingredient XVII + X XVII + XI XVII + XII XVIII + XII

kg/ha a. S. 0,5+ 1,5+ 1+1 0,5+ 1,5+ 1+1 0,5+ 1,5+ 1+1 0,5+ 1,5+ 1+1kg / ha a. P. 0.5+ 1.5+ 1 + 1 0.5+ 1.5+ 1 + 1 0.5+ 1.5+ 1 + 1 0.5+ 1.5+ 1 + 1

1,5 0,5 1,5 0,5 1,5 0,5 1,5 0,51.5 0.5 1.5 0.5 1.5 0.5 1.5 0.5

Triticum aestlvum 0 10 6 0 10 6 0 10 6 000Triticum aestlvum 0 10 6 0 10 6 0 10 6 000

Hordeum vulgäre 0 50 0 50 0 50 075Hordeum vulgar 0 50 0 50 0 50 075

Seeale cereale 0 70 0 70 0 70 050Seeale cereale 0 70 0 70 0 70 050

Alopecurus myosuroides 100 100 100 100 100 100 100 100 100 100 100 100Alopecurus myosuroides 100 100 100 100 100 100 100 100 100 100 100 100

Galium aparine 100 87 93 100 100 100 100 91 92 100 79 83Galium aparine 100 87 93 100 100 100 100 91 92 100 79 83

Lamium amplexlcaule 100 100 100 100 100 100 100 100 100 100 100 100Lamium amplexlcaule 100 100 100 100 100 100 100 100 100 100 100 100

Triticum aestlvum
Hordeum vulgäre
Seeale cerealeTriticum aestlvum
Hordeum vulgar
Seeale cereale

Galium aparine
Lamium amplexicauleGalium aparine
Lamium amplexicaule

XVIIIXVIII + XI+ XI 00 00 XVIIIXVIII + X+ X 00 00 XVIIIXVIII + IX+ IX 00 00 XVIIIXVIII + VIII+ VIII 00 1010 CO
—ACO
—A II. 00 77th 55 00 77th 55 55 77th UlUl 1414th 77th 1515th cn
cncn
cn 4="
VJl4 = "
VJl 00 UlUl 00 00 UlUl 00 66th 55 00 1515th 55 66th ίί 00 100100 100100 00 100100 100100 66th 100100 100100 1010 100100 100100 100100 100100 100100 100100 8080 8585 100100 9292 100100 100100 9898 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 O
•O
• a
VjJ
Oa
Previous year
O 4=-4 = -

WirkstoffActive ingredient XVIII + VIIXVIII + VII 1,5+
0,51.5+
0.5 1+11 + 1 00 00 XVII]XVII] : + vi: + vi 1+11 + 1 XVIII + IIXVIII + II 00 00 XVIIIXVIII + V+ V 1+11 + 1 XVIIIXVIII + IV+ IV 1+11 + 1 II. kg/ha a. S.kg / ha a. S. 0,5+
1,50.5+
1.5 00 00 77th 55 0,5+
1,50.5+
1.5 1,5+
0,51.5+
0.5 00 2020th 77th 1010 0,5+
1,50.5+
1.5 1,5+
0,51.5+
0.5 1515th P,5f
1,5P, 5f
1.5 1,5+
0,51.5+
0.5 00 Trltleum aestivumTrltleum aestivum 00 77th 55 55 00 1515th 55 2020th 2323 55 1010 2020th 1010 1515th 2020th 00 1010 Hordeum vulgäreHordeum vulgar 00 55 00 2020th 1717th 1515th 2525th 1515th 1212th 1313th 2222nd 77th 1010 Secale cerealeSecale cereale 00 100100 100100 1919th 1515th 100100 1818th 1515th 100100 2525th 55 100100 Alopecurus myosuroidesAlopecurus myosuroides 100100 9797 100100 100100 100100 8282 100100 100100 7373 100100 100100 7070 Galium aparineGalium aparine 100100 100100 100100 9696 7474 100100 7777 7575 100100 7272 6666 100100 Lamiutn amplexicauleLamiutn amplexicaule 100100 XVIII + IIIXVIII + III 100100 100100 100100 100100 100100 100100 WirkstoffActive ingredient 00 Triticum aestivumTriticum aestivum 00 Hordeum vulgäreHordeum vulgar 00 Secale cerealeSecale cereale

Alopecurus myosuroides 100 100 100 100 100 Galium aparine 100 86 100 100 97 Lamiura amplexicaule 100 100 100 100 100 Alopecurus myosuroides 100 100 100 100 100 Galium aparine 100 86 100 100 97 Lamiura amplexicaule 100 100 100 100 100

0 = ohne Schädigung 100 = totale Schädigung0 = no damage 100 = total damage

OO rvrv NN coco VjJ
OPrevious year
O cncn OO CTlCTl cncn

- 47 «■ O.Z. 30- 47 «■ O.Z. 30th

Beispiel 6Example 6

Im Gewächshaus wurden verschiedene Pflanzen bei einer Wuchshöhe von 2 bis 20 cm mit folgenden Einzelwirkstoffen und deren Mischungen als Dispersion behandelt:Various plants were grown in the greenhouse at a height of 2 to 20 cm with the following individual active ingredients and their Mixtures treated as a dispersion:

XVIII N-J-Chlor^-methyl-phenyl^N-cyclohex-l-enyl-N',N'-dime thylharnstoffXVIII N-J-chloro ^ -methyl-phenyl ^ N-cyclohex-1-enyl-N ', N'-dime ethylurea

XVII N-3-Chlor-4-methoxy-phenyl-N-cyclohex-l-enyl-N',Nfdimethylharnstoff XVII N-3-chloro-4-methoxyphenyl-N-cyclohex-1-enyl-N ', N f dimethylurea

XVI 3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-Diäthanolaminsalz XVI 3-Isopropyl-2,3-benzothiadiazinon- (4) -2,2-dioxide-diethanolamine salt

XV 3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-Dimethylaminsalz XV 3-Isopropyl-2,3-benzothiadiazinon- (4) -2,2-dioxide-dimethylamine salt

XIV 3-Isopropyl-2,l,3-benzothiadiazinon-(4)-2,2-dioxid-Natriumsalz XIV 3- I sopropyl-2,3-benzothiadiazinon- (4) -2,2-dioxide sodium salt

XIII 3-Isopropyl-2,l,3-benzothiadlazinon-(4)-2,2-dioxidXIII 3-Isopropyl-2,3-benzothiadlazinone- (4) -2,2-dioxide

XII 2-Methylthio-4-äthylamino-6~A,ß-dimethylpropylamino-l,3*5-XII 2-Methylthio-4-ethylamino-6 ~ A, ß-dimethylpropylamino-1,3 * 5-

triazintriazine

XI 2-Chlor-4-isopropylamino-6-cyclopropylamino-l,3»5-triazin X 2-Azido-4-äthylamino-6-tert.butylamino-l,3j 5-triazin IX 2-Methylthio-4-(3-methoxy-propylamino)-6-isopropylamino-XI 2-chloro-4-isopropylamino-6-cyclopropylamino-1,3 »5-triazine X 2-Azido-4-ethylamino-6-tert-butylamino-1,3j 5-triazine IX 2-methylthio-4- (3-methoxy-propylamino) -6-isopropylamino-

1,3*5-triazin1,3 * 5-triazine

VIII 2-Methylthio-4,6-diisopropylamino-1,3*5-triazin VII 2-Methylthio-4-äthylamino-6-tert.butylamino-1,3*5-triazin VI 2-(2-Chlor-4-äthylamino-l,3,5-triazin-6-yl-amino)-2-VIII 2-methylthio-4,6-diisopropylamino-1,3 * 5-triazine VII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine VI 2- (2-chloro-4-ethylamino-1,3,5-triazin-6-yl-amino) -2-

methylpropionitrilmethylpropionitrile

V 2-Chlor-4-äthylamino-6-tert.butylamino-1,3*5-triazin IV 2-Chlor-4,6-diäthylamino-l,3,5-triazin III 2-(2-Chlor-4-methylamino-1,3,5-triazin-6-yl-amino)-2-V 2-chloro-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine IV 2-chloro-4,6-diethylamino-1,3,5-triazine III 2- (2-chloro-4-methylamino-1,3,5-triazin-6-yl-amino) -2-

methylpropionitril
II 2-Chlor-4-äthylamino-6-isopropylamino-l,3*5-triazinmethylpropionitrile
II 2-chloro-4-ethylamino-6-isopropylamino-1,3 * 5-triazine

mit Je 0,25, 1* 1*5 kg/ha aktive Substanzwith 0.25, 1 * 1 * 5 kg / ha of active substance each

XVIII+XIII+VI, XVIII+XIV+VII, XVIII+XV+VIII, XVIII+XVI+IX, XVIII+XIII+X, XVIII+XIV+XI, XVIII+XV+XII, XVII+Xill+XII, XVII+XIV+XI, XVII+XV+X, XVII+XVI+IX, XVII+XIII+VIII, XVII+XIV+VIII, xvii+xrv+vn, xvii+xv+vi, xvii+xvi+v, xvii+xv+iv, xvii+xiv+iii, XVII+XIII+II, XVIII+II+XIII, XVIII+XIV+III, XVIII+XV+IV und XVIII+XVI+VXVIII + XIII + VI, XVIII + XIV + VII, XVIII + XV + VIII, XVIII + XVI + IX, XVIII + XIII + X, XVIII + XIV + XI, XVIII + XV + XII, XVII + Xill + XII, XVII + XIV + XI, XVII + XV + X, XVII + XVI + IX, XVII + XIII + VIII, XVII + XIV + VIII, xvii + xrv + vn, xvii + xv + vi, xvii + xvi + v, xvii + xv + iv, xvii + xiv + iii, XVII + XIII + II, XVIII + II + XIII, XVIII + XIV + III, XVIII + XV + IV and XVIII + XVI + V

509809/1118 /48509809/1118/48

- 48 - O.Z. 50 054- 48 - O.Z. 50 054

mit je 0,25 + 0,25 + 1, 0,25 + 1 + 0,25 und 1 + 0,25 + 0,25 kg/ha aktive Substanz.each with 0.25 + 0.25 + 1, 0.25 + 1 + 0.25 and 1 + 0.25 + 0.25 kg / ha of active substance.

Nach 13 bis l6 Tagen wurde festgestellt, daß die Mischungen eine bessere herbizide Wirkung bei gleicher Verträglichkeit an den Kulturpflanzen zeigten als die Einzelwirkstoffe.After 13 to 16 days it was found that the mixtures showed a better herbicidal action than the individual active ingredients with the same compatibility with the crop plants.

Das Versuchsergebnis ist aus nachfolgender Tabelle zu ersehen.The test result can be seen from the following table.

509809/1118509809/1118

Wirkstoff XVIII XVII XVI XVActive ingredient XVIII XVII XVI XV

kg/ha a. S. 0,25 1 1,5 0,25 1 1,5 0,25 1 1,5 0,25 1 1,5kg / ha a. P. 0.25 1 1.5 0.25 1 1.5 0.25 1 1.5 0.25 1 1.5

Triticum aestivumTriticum aestivum 00 00 00 11 1,51.5 00 66th 1010 77th XIIIXIII 1,51.5 00 00 00 00 00 00 00 11 00 Hordeum vulgäreHordeum vulgar 00 55 77th 00 00 55 4848 11 00 2525th 00 00 00 2020th 00 00 Secale cerealeSecale cereale 00 00 55 00 00 2929 00 66th 00 00 00 55 00 00 Alopecurus myosuroidesAlopecurus myosuroides 3030th 5555 7070 1010 3030th 4848 1212th 1515th 1212th 1616 Galium aparineGalium aparine 00 1010 1616 1515th 2020th 6565 8080 •• 5050 6060 cn
οcn
ο Lamium amplexLcauleLamium amplexLcaule 1010 3535 5757 1010 3636 0,250.25 3535 5050 0,250.25 4040 4545 coco 00
ο00
ο WirkstoffActive ingredient XIVXIV XIIXII XIXI coco kg/ha a. S.kg / ha a. S. 0,250.25 0,250.25 11 1,51.5 1,51.5

_» Triticum aestivum 000 000 000 000 ,_ »Triticum aestivum 000 000 000 000,

^ Hordeum vulgäre 000 000 000 000^ Hordeum vulgar 000 000 000 000

Secale cereale 000 000 000 000Secale cereale 000 000 000 000

Alopecurus myosuroides 0 12 15 3 10 15 20 77 92 40 85 93Alopecurus myosuroides 0 12 15 3 10 15 20 77 92 40 85 93

Galium aparine 15 60 60 15 60 75 15 35 58 26 60 80Galium aparine 15 60 60 15 60 75 15 35 58 26 60 80

Lamium amplexicaule 5 25 40 5 25. 40 60 82 95 10 40 57Lamium amplexicaule 5 25 40 5 25. 40 60 82 95 10 40 57

—Λ VjJ—Λ PYY

cn ° Cn οcn ° Cn ο

Wirkstoff X IX VIII VIIActive ingredient X IX VIII VII

kg/ha a. S. 0,25 1 1,5 0,25 1 1,5 0,25 1 1,5 0,25 1 1,5kg / ha a. P. 0.25 1 1.5 0.25 1 1.5 0.25 1 1.5 0.25 1 1.5

Triticum aestivumTriticum aestivum 00 00 11 00 00 00 5 15 1 55 00 1010 11 1414th 00 00 00 Hordeum· vulgäreHordeum vulgar 00 00 00 00 00 55 00 1010 1515th 00 00 00 Secale cerealeSecale cereale 00 00 00 00 00 66th 00 66th 1010 00 00 00 Alopecurus myosuroidesAlopecurus myosuroides 2525th 7777 9090 4444 7878 9090 2525th 6060 7575 4545 8888 9494 Galium aparlneGalium aparlne 1010 3535 6060 2020th 6060 7777 2020th 5757 7070 2626th 6262 8181 Lamium amplexicaüleLamium amplexicaüle 4646 8080 9595 1515th 5050 6565 3030th 6565 8080 2222nd 5353 7070 cncn O
coO
co WirkstoffActive ingredient VIVI VV IVIV IIIIII OO
OOO
O kg/ha a. S.kg / ha a. S. 0,250.25 1,51.5 0,2f0.2f 1,51.5 0,250.25 1,51.5 0,250.25 11 1,51.5

^ Triticum aestivum 0 10 15 0 15 20 0 0 20 0 0 0^ Triticum aestivum 0 10 15 0 15 20 0 0 20 0 0 0

^ Hordeum vulgäre 5 15 20 0 10 15 0 5 22 0 0 0^ Hordeum vulgar 5 15 20 0 10 15 0 5 22 0 0 0

-» Seeale cereale 4 15 19 0 13 18 0 0 25 0 0 0- »Seeale cereale 4 15 19 0 13 18 0 0 25 0 0 0

Alopecurus myosuroides 30 55 65 40 55 65 40 70 80 40 75 85Alopecurus myosuroides 30 55 65 40 55 65 40 70 80 40 75 85

Galium aparine 5 35 50 ' 15 27 35 0 20 30 15 55 75Galium aparine 5 35 50 '15 27 35 0 20 30 15 55 75

Lamium amplexicaüle 50 80 85 15 50 62 20 50 60 10 45 55Lamium amplexicaule 50 80 85 15 50 62 20 50 60 10 45 55

-t>- VjJ-t> - PYY

WirkstoffActive ingredient 0,250.25 IIII 00 1+
0,25+
0,251+
0.25+
0.25 XVIII+XIV+IIIXVIII + XIV + III 0,25+
1 +
0,250.25+
1 +
0.25 1+
0,25+
0,251+
0.25+
0.25 xvTii+xv+rvxvTii + xv + rv 0,25+
1+
0,250.25+
1+
0.25 1+
0,25+
0,251+
0.25+
0.25 ## ιι kg/ha a. S.kg / ha a. S. 00 1 1,51 1.5 00 00 0,25+
0,25+
10.25+
0.25+
1 00 00 0,25+
0,25+
10.25+
0.25+
1 00 00 II. Triticum aestivumTriticum aestivum 00 0 50 5 00 55 00 00 55 00 00 55 Hordeum vulgäreHordeum vulgar 00 0 50 5 100100 00 00 00 00 55 00 00 Seeale cerealeSeeale cereale 4545 0 60 6 100100 100100 00 100100 100100 00 100100 100100 Alopecurus rayosuroidesAlopecurus rayosuroides 2525th 87 9287 92 100100 9090 100100 100100 8080 100100 9090 7070 Galium aparineGalium aparine 2020th 6o 806o 80 100100 100100 8585 9090 8080 100100 100100 CaJ
J>CaJ
J> OO Lamium amplexieauleLamium amplexieaule 50 6550 65 100100 100100 ——Λ
cn
CJl
cn——Λ
cn
CJl
cn *
VjJ
O*
Previous year
O cncn O
uiO
ui ο
toο
to WirkstoffActive ingredient XVIII+II+XIIXVIII + II + XII 1809/1809 / kg/ha a. S.kg / ha a. S. 0,25+ 0,25+
0,25+ 1+
1 0,250.25+ 0.25+
0.25+ 1+
1 0.25 Triticum aestivumTriticum aestivum 00 COCO Hordeum vulgäreHordeum vulgar 00 Seeale cerealeSeeale cereale 00 Alopecurus myosuroidesAlopecurus myosuroides 100100 Galium aparineGalium aparine 100100 Lamium amplexicauleLamium amplexicaule 95 '95 '

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

XVIII+XVI+VXVIII + XVI + V

0,25+ 0,25+ 1+ 0,25+ 1+ 0,25+ 1 0,25 0,250.25+ 0.25+ 1+ 0.25+ 1+ 0.25+ 1 0.25 0.25

XVIII+XIII+VIXVIII + XIII + VI

0,25+0,25+ 1+
0,25+ 1+ 0,25+
0,25 0,250.25 + 0.25 + 1+
0.25+ 1+ 0.25+
0.25 0.25

XVIII+XIV+VIIXVIII + XIV + VII

0,25+ 0,25+ 1+
0,25+ 1+ 0,25+
0,25 0,250.25+ 0.25+ 1+
0.25+ 1+ 0.25+
0.25 0.25

Triticum aestivumTriticum aestivum 1515th 00 00 XVIII+XV+VIIIXVIII + XV + VIII 1010 00 00 XVIII+XVI+IXXVIII + XVI + IX 00 00 00 XVIII+XIII+XXVIII + XIII + X Hordeum vulgäreHordeum vulgar 1010 00 55 1515th 55 1010 00 00 55 Seeale cerealeSeeale cereale 1313th 00 00 1515th 44th 44th 00 00 00 Älopecurus myosuroidesAlopecurus myosuroides 100100 100100 100100 100100 100100 100100 100100 100100 100100 Galium aparineGalium aparine 9191 100100 9090 8989 100100 7575 100100 100100 9191 Lamium amplexieauleLamium amplexieaule 100100 100100 9494 100100 100100 100100 100100 100100 100100 WirkstoffActive ingredient

Triticum aestivum Hordeum vulgäre Seeale cerealeTriticum aestivum Hordeum vulgar Seeale cereale

Älopecurus myosuroides Galium aparine Lamium amplexicauleÄlopecurus myosuroides Galium aparine Lamium amplexicaule

1010 00 00 00 00 00 00 00 00 1010 00 55 00 00 55 00 00 55 66th 00 00 00 00 00 00 00 00 100100 100100 100 .100. 100100 100100 100100 100100 100100 100100 100100 100100 9090 100100 100100 9595 8787 100100 7575 100100 100100 100100 100100 100100 9696 100100 100100 100100

UlUl

cn cn cncn cn cn

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

XVIII+XIV+XIXVIII + XIV + XI

0,25+ 0,25+ 1+ 0,25+ 1+ 0,25+ 1 0,25 0,?50.25+ 0.25+ 1+ 0.25+ 1+ 0.25+ 1 0.25 0,? 5

XVIII+XV+XIIXVIII + XV + XII

0,25+ 0,25+ 1+ 0,25+ 1+ 0,25+ 0,25 0,250.25+ 0.25+ 1+ 0.25+ 1+ 0.25+ 0.25 0.25

XVII+XIII+XIIXVII + XIII + XII

0,25+ 0,25+ 1+ 0,25+ 1+ 0,25+ 1 0,25 0,250.25+ 0.25+ 1+ 0.25+ 1+ 0.25+ 1 0.25 0.25

Trlticura aestivumTrlticura aestivum 00 00 00 XIXI 00 00 00 00 00 8585 66th 9494 Hordeum vulgäreHordeum vulgar 00 00 55 00 00 VJlVJl 00 00 100100 00 8686 Seeale cerealeSeeale cereale 00 00 00 00 00 00 00 00 100100 00 100100 Alopecurus tnyosuroidesAlopecurus tnyosuroides 100100 100100 100100 100100 100100 100100 100100 XVII+XVI+IXXVII + XVI + IX Galium aparineGalium aparine 100100 100100 9090 9292 100100 8383 100100 Lamium amplexicauleLamium amplexicaule 9393 8585 8888 100100 100100 100100 100100 WirkstoffActive ingredient XVII+XIV +XVII + XIV + XVII+XV+XXVII + XV + X

Triticum aestivum Hordeum vulgäre Seeale cerealeTriticum aestivum Hordeum vulgar Seeale cereale

0 0 0 0 0 00 0 0 0 0 0

Alopecurus myosuroides 100 100 Galium aparine 100 100 Lamium amplexieaule 91 83 006 0 0 0 0Alopecurus myosuroides 100 100 Galium aparine 100 100 Lamium amplexieaule 91 83 006 0 0 0 0

90 95 100 88 10090 95 100 88 100

006 0 0 0 0006 0 0 0 0

100 100 100 100100 100 100 100

100 100100 100

Ul ■Ja-Ul ■ Yes-

cn ςπ cncn ςπ cn

£8 0OT ΟΟΤ 0OT ΟΟτ L6 ΟΟτ Οοτ aitreopcsxduiB ran-purei£ 8 0OT ΟΟΤ 0OT ΟΟτ L6 ΟΟτ Οοτ aitreopcsxduiB ran-purei

0OT ΟΟτ 08 ΟΟτ £6 ΟΟτ ΟΟΤ 00Τ eufj-edB ακνρχ«{)0OT ΟΟτ 08 ΟΟτ £ 6 ΟΟτ ΟΟΤ 00Τ eufj-edB ακνρχ «{)

ΟΟτ ΟΟτ ΟΟτ ΟΟΤ 00Τ ΟΟτ ΟΟτ ΟΟτ ΟΟτ sapToansojCra snanosdoxvΟΟτ ΟΟτ ΟΟτ ΟΟΤ 00Τ ΟΟτ ΟΟτ ΟΟτ ΟΟτ sapToansojCra snanosdoxv

000 000 OO ST »τββτ=^ ^-r„^„ co 000 OOS OO OT000 000 OO ST »τββτ = ^ ^ -r" ^ " co 000 OOS OO OT

900 900 90 ST900 900 90 ST

ΙΙΙ+ΛΙΧ+ΙΙΛΧΙΙΙ + ΛΙΧ + ΙΙΛΧ 0OT0OT 0OT0OT οοτοοτ ΟΟΤΟΟΤ ΧΙ+ΔΧ+ΙΙΙΛΧΧΙ + ΔΧ + ΙΙΙΛΧ οοτοοτ οοτοοτ Λ+ΙΛΧ+ΙΙΛΧΛ + ΙΛΧ + ΙΙΛΧ ΟΟΤΟΟΤ JJOWVWiJJOWVWi 0808 οοτοοτ οοτοοτ οοτοοτ S6S6 ΟΟΤΟΟΤ S6S6 οοτοοτ οοτοοτ aitveopcsxdurB αίητυτΒΊaitveopcsxdurB αίητυτΒΊ 0OT0OT 0606 οοτοοτ οοτοοτ οοτοοτ οοτοοτ 9696 οοτοοτ οοτοοτ ©ufJredB mriTiBQ© ufJredB mriTiBQ frfr STST 00 ΟΟΤΟΟΤ 00 00 S8S8 99 sapfoansojCm snanosdoxvsapfoansojCm snanosdoxv SS. SS. STST 00 00 00 OO 00 οτοτ θχΒβαθο 0XB09SθχΒβαθο 0XB09S 99 OO OTOT 99 00 00 99 OO OTOT θαΒ3χπΛ mnspaoHθαΒ3χπΛ mnspaoH 00 OO

3 SsΌ τ Ss'o SsΌ τ Ss'o SsO τ3 SsΌ τ Ss'o SsΌ τ Ss'o SsO τ

D +τ +Ss'o +SsO +τ +Ss'o +Ss'o +τ +Ss'oD + τ + Ss'o + SsO + τ + Ss'o + Ss'o + τ + Ss'o

+τ +Ss'o +Ss'o +τ +Ss'o +Ss'o +τ +Ss'o +Ss'o *s "β «q/s^+ τ + Ss'o + Ss'o + τ + Ss'o + Ss'o + τ + Ss'o + Ss'o * s "β« q / s ^

ΙΛ+ΛΧ+ΙΙΛΧ ΙΙΛ+ΛΙΧ+ΙΙΙΛΧ ΙΙΙΛ+ΙΙΙΧ+ΙΙΛΧΙΛ + ΛΧ + ΙΙΛΧ ΙΙΛ + ΛΙΧ + ΙΙΙΛΧ ΙΙΙΛ + ΙΙΙΧ + ΙΙΛΧ

GO O COGO O CO

Wirkstoff XVII+XIII+IIActive ingredient XVII + XIII + II

kg/ha a. S. 0,25+ 0,25+ 1+kg / ha a. P. 0.25+ 0.25+ 1+

0,25+ 1+ 0,25+ 1 0,25 0,250.25+ 1+ 0.25+ 1 0.25 0.25

Triticum aestivum Hordeum vulgäre Seeale cerealeTriticum aestivum Hordeum vulgar Seeale cereale

Alopecurus myosuroides Galium aparine Lamium amplexicauleAlopecurus myosuroides Galium aparine Lamium amplexicaule

00 00 66th 00 00 00 00 00 00 100100 100100 100100 100100 100100 100100 100100 9292 100100

_> 0 = ohne Schädigung -* 100 = totale Schädigung cn_> 0 = no damage - * 100 = total damage cn

VJlVJl

cn ° cn ο cn ^ cn ° cn ο cn ^

- 56 - O.Z. 30 054- 56 - O.Z. 30 054

Beispiel 7Example 7

Im Gewächshaus wurden Versuchsgefäße mit lehmigen Sandboden gefüllt und mit verschiedenen Samen besät. Danach wurde der so vorbereitete Boden mit folgendon Einzelwirkstoffen und deren Mischungen behandelt:In the greenhouse, test pots were filled with loamy sandy soil and sown with various seeds. Then it became like that prepared soil with the following individual active ingredients and their Treated mixtures:

XVIII N^-Chlor^-methylphenyl-N-cyclohex-l-enyl-N' ,N' -dime thylharnstoffXVIII N ^ -Chlor ^ -methylphenyl-N-cyclohex-1-enyl-N ', N' -dime ethylurea

XVII N^-Chlor^-methoxyphenyl-N-cyclohex-l-enyl-N*,N1-dimethylharnstoff XVII N ^ -Chlor ^ -methoxyphenyl-N-cyclohex-1-enyl-N *, N 1 -dimethylurea

XII 2-Methylthio-4-äthylamino-6- et, ß-dimethylpropylamino-1, 3* 5-XII 2-methylthio-4-ethylamino-6- et, ß-dimethylpropylamino-1, 3 * 5-

triazin
XI 2-Chlor-4-isopropylamino-6-cyclopropylarnino-l,3*5-triazin X 2-Azido-4-äthylamino-6-tert.butylamino-1,3* 5-triazin IX 2-Methylthio-4- (3-methoxypropylamino)-6-isopropylamino-triazine
XI 2-chloro-4-isopropylamino-6-cyclopropylarnino-1,3 * 5-triazine X 2-azido-4-ethylamino-6-tert-butylamino-1,3 * 5-triazine IX 2-methylthio-4- ( 3-methoxypropylamino) -6-isopropylamino-

1*3*5-triazin1 * 3 * 5-triazine

VIII 2-Methylthlo-4,6-diisopropylamino-l,3*5-triazin VII 2-Methylthio-4-äthylamino-6-tert.butylamino-1,3,5-triazin VI 2-(2-Chlor-4-äthylamino-l,3*5-triazin-6-yl-amino)-2-VIII 2-methylthlo-4,6-diisopropylamino-1,3 * 5-triazine VII 2-Methylthio-4-ethylamino-6-tert-butylamino-1,3,5-triazine VI 2- (2-chloro-4-ethylamino-1,3 * 5-triazin-6-yl-amino) -2-

methylpropionitrilmethylpropionitrile

V 2-Chlor-4-äthylamino-6-1 ert.butylamino-1,3*5-triazin IV 2-Chlor-4,6-diäthylamino-1,3,5-triazin III 2-(2-Chlor-4-methylamino-l,3*5-triazin-6-yl-amino)-2-V 2-chloro-4-ethylamino-6-1 tert-butylamino-1,3 * 5-triazine IV 2-chloro-4,6-diethylamino-1,3,5-triazine III 2- (2-chloro-4-methylamino-1,3 * 5-triazin-6-yl-amino) -2-

methylpropionitril
II 2-Chlor-4-äthylamino-6-isopropylamino-l,3*5-triazinmethylpropionitrile
II 2-chloro-4-ethylamino-6-isopropylamino-1,3 * 5-triazine

mit Je 0,5, 1,5, 2 und 1 kg/ha aktive Substanzwith 0.5, 1.5, 2 and 1 kg / ha of active substance

XVIII+II, XVIII+III, XVIII+IV, XVIII+V, XVTII+VI, XVIII+VII, XVIII+VIII, XVIII+IX, XVIII+X, XVIII+XI, XVIII+XII, XVII+XII, XVIII+XI, XVII+X, XVII+IX, XVII+ VIII, XVII+ VII, XVII+ VI, XVII+V, XVII+IV, XVII+III und XVII+II mit je 0,5+1,5, 1,5+0,5 und 1+1 kg/ha aktive SubstanzXVIII + II, XVIII + III, XVIII + IV, XVIII + V, XVTII + VI, XVIII + VII, XVIII + VIII, XVIII + IX, XVIII + X, XVIII + XI, XVIII + XII, XVII + XII, XVIII + XI, XVII + X, XVII + IX, XVII + VIII, XVII + VII, XVII + VI, XVII + V, XVII + IV, XVII + III and XVII + II with 0.5 + 1.5, 1.5 + 0.5 and 1 + 1 kg / ha of active substance

Nach 3 bis 4 Wochen wurde festgestellt, daß die Mischungen eine bessere Verträglichkeit an den Kulturpflanzen und eine bessere herbizide Wirkung zeigten als die Einzelwirkstoffe.After 3 to 4 weeks it was found that the mixtures showed better tolerance to the crop plants and a better herbicidal action than the individual active ingredients.

Das Versuchsergebnis ist aus nachfolgender Tabelle zu ersehen.The test result can be seen from the following table.

509809/1118 /5T 509809/1118 / 5T

WirkstoffActive ingredient 0,0, XVIIIXVIII 1,51.5 22 0,50.5 XVIIXVII 1,1, 5 25 2 0,0, XIIXII 5 15 1 1,1, 5 25 2 kg/ha a. S.kg / ha a. S. 00 5 15 1 00 1010 00 11 00 00 00 00 00 00 Tritieum aestivumTritieum aestivum 00 00 00 1010 00 ο ■ο ■ 00 00 00 00 00 00 Hordeura vulgäreHordeura vulgar 00 00 00 55 00 00 00 00 00 00 00 00 Seeale cerealeSeeale cereale 00 00

Alopecurus myosuroides 24 40 56 80 15 35 45 60 43 65 75Alopecurus myosuroides 24 40 56 80 15 35 45 60 43 65 75

Lamium amplexicaule 30 50 70 90 21 40 60 80 24 40 50Lamium amplexicaule 30 50 70 90 21 40 60 80 24 40 50

Wirkstoff XI X IXActive ingredient XI X IX

kg/ha a. S. 0,5 1 1,5 2 , 0,5 1 1,5 2 0,5 1 1/5 2kg / ha a. P. 0.5 1 1.5 2, 0.5 1 1.5 2 0.5 1 1/5 2

Triticum aestivum 0000 0000 OOO5Triticum aestivum 0000 0000 OOO5

Hordean vulgäre 0000 000 0 OOO7Hordean vulgar 0000 000 0 OOO7

Seeale cereale 0000 0000 000 10Seeale cereale 0000 0000 000 10

Alopecurus myosuroides 40 67 80 90 45 70 85 95 18 45 70Alopecurus myosuroides 40 67 80 90 45 70 85 95 18 45 70

Lamium amplexicaule 20 35 45 80 25 38 47 85 40 70 85Lamium amplexicaule 20 35 45 80 25 38 47 85 40 70 85

cn -^ cncn - ^ cn

WirkstoffActive ingredient 0,0, VIIIVIII 5 15 1 1,51.5 CVJCVJ 0,0, VIIVII 5 15 1 1,51.5 22 0,50.5 11 VIVI 1,51.5 22 kg/ha a. S.kg / ha a. S. 00 00 55 1010 00 00 00 00 00 00 55 .10.10 Tritieum aestlvumTritieum aestlvum 00 55 1010 1515th 00 00 00 55 00 55 1010 1515th Hordeura vulgäreHordeura vulgar 00 55 1515th 2020th 00 00 00 77th 00 55 1010 1414th Seeale cerealeSeeale cereale

Alopecurus myosuroides 15 40 βθ 85 Lamium amplexicaule 45 80 90 95Alopecurus myosuroides 15 40 βθ 85 Lamium amplexicaule 45 80 90 95

20 50 80 95 40 75 90 9520 50 80 95 40 75 90 95

80 90 98
40 48 8580 90 98
40 48 85

OO
O
CDOO
O
CD

WirkstoffActive ingredient 0,50.5 11 VV 1,51.5 IIII 1,51.5 22 -- 22 0,50.5 ]] 11 CVCV 1,51.5 22 0,50.5 11 IIIIII 22 kg/ha a. S.kg / ha a. S. 00 1010 1515th 1818th 00 00 00 1010 00 00 1,51.5 1010 Tritieum äestivumTritieum aestivum 00 55 1010 1414th 00 00 00 1010 00 00 00 1515th Hordeum vulgäreHordeum vulgar 00 1212th 1515th 2020th 00 00 00 1010 00 00 00 1919th Seeale cerealeSeeale cereale 5050 6262 7070 7979 2525th 6060 7070 8585 3535 7070 00 9090 Alopecurus myosuroidesAlopecurus myosuroides 2020th 4040 5252 7575 2424 4646 5555 8080 2020th 4040 8080 7575 Lamium amplexicauleLamium amplexicaule 4848 WirkstoffActive ingredient 0,50.5 11 kg/ha a. S.kg / ha a. S.

Tritieum äestivum
Hordeum vulgäre
Seeale cerealeTritieum aestivum
Hordeum vulgar
Seeale cereale

0 5 10 20 0 10 15 22 0 15 20 250 5 10 20 0 10 15 22 0 15 20 25

Ul
VOUl
VO

Alopecurus myosuroides 40 80 85 97 Lamium amplexicaule 27 40 50 90Alopecurus myosuroides 40 80 85 97 Lamium amplexicaule 27 40 50 90

= ohne Schädigung
= totale Schädigung= without damage
= total damage

COCO

cn cn cncn cn cn

cn ο co cocn ο co co

WirkstoffActive ingredient XVIII+IIXVIII + II 1,
0,1,
0, 5+
55+
5 1+11 + 1 XVIII+IIIXVIII + III ,5+
,5, 5 +
, 5 1+11 + 1 XVIII+IVXVIII + IV .5+
,5.5+
, 5 1,5+
0,51.5+
0.5 1+1.1 + 1. XVIII+VXVIII + V 1+11 + 1 kg/ha a. S.kg / ha a. S. 0,5+
1,50.5+
1.5 00 55 0,5+ 1,
1,5 0,0.5+ 1,
1.5 0, 00 o,O, 00 00 0,5+ 1,5+
1,5 0,50.5+ 1.5+
1.5 0.5 1010 Triticum aestivumTriticum aestivum 1010 00 1010 0 00 0 00 00 00 00 15 015 0 55 Hordeum vulgäreHordeum vulgar 1515th 00 1515th 0 00 0 00 00 00 00 10 010 0 1212th Secale cerealeSecale cereale 2020th 0 00 0 00 15 015 0

Alopecurus myosuroides Lanlum ample*icauleAlopecurus myosuroides Lanlum ample * icaule

wirkstoff 100 100
100 100active ingredient 100 100
100 100

XVIII+VI 100 100
100 100XVIII + VI 100 100
100 100

XVIII+VIIXVIII + VII

100 100 100
100 100 100100 100 100
100 100 100

XVIII+VIIIXVIII + VIII

100 100 100 100 100 100100 100 100 100 100 100

XVIII+IXXVIII + IX

Triticum aestivum Hordeum vulgäre Secale cerealeTriticum aestivum Hordeum vulgar Secale cereale

Alopecurus myosuroides Lamiuat amplexicauleAlopecurus myosuroides Lamiuat amplexicaule

55 00 00 00 00 00 VJlVJl 00 00 . 0. 0 00 00 vovo 1010 00 55 00 00 00 1010 00 '5'5 00 00 00 IiIi 1010 00 55 00 00 00 1515th 00 55 55 00 00 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100

WirkstoffActive ingredient

XVIII+X XVIII+XI XVIII + X XVIII + XI

XVIII+XIIXVIII + XII

XVII+XIIXVII + XII

Triticum aestivum Hordeum vulgäre Secale cerealeTriticum aestivum Hordeum vulgar Secale cereale

0 0 0 0 0 0 0 0 0 0 0 0

Alopecurus myosuroides 100 100 Lamim amplexicaule 100 100 Alopecurus myosuroides 100 100 Lamim amplexicaule 100 100

0 0 0 0

0 0 0 0

0 00 0

100 100100 100

100 100100 100

0 0 00 0 0

0 0 00 0 0

0 0 00 0 0

100 100 100 100 100 100

100 100 100100 100 100

0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0

100 100 100 -^ 100 100 100 - ^

loo loo loo Q1 cnloo loo loo Q 1 cn

Wirkstoff kg/ha a. S.Active ingredient kg / ha a. S.

XVII+XIXVII + XI

0,5+ 1,5+ 1+1 1,5 0,50.5+ 1.5+ 1 + 1 1.5 0.5

XVII+XXVII + X

0,5+ 1,5+ 1+1
1,5 0,50.5+ 1.5+ 1 + 1
1.5 0.5

XVII+IXXVII + IX

0,5+ 1,5+ 1+1 1,5 0,50.5+ 1.5+ 1 + 1 1.5 0.5

XVII+VIIIXVII + VIII

0,5+ 1,5+ 1+1 1,5 0,50.5+ 1.5+ 1 + 1 1.5 0.5

Triticum aestivum Hordeum vulgäre Seeale cerealeTriticum aestivum Hordeum vulgar Seeale cereale

Alopecurus myosuroides Lamiutn amplexlcaule 0 0
0 0
0 0Alopecurus myosuroides Lamiutn amplexlcaule 0 0
0 0
0 0

100
100100
100

100
100100
100

0 0 00 0 0

0 0 00 0 0

0 0 00 0 0

100 100 100100 100 100

100 100 100100 100 100

0 0 00 0 0

0 0 00 0 0

5 0 05 0 0

100 100 100100 100 100

100 100 100100 100 100

5 105 10

1515th

0 0 0 50 0 0 5

0 50 5

100 100 100 100100 100 100 100

O CO CO O COO CO CO O CO

Wirkstoff XVII+VIIActive ingredient XVII + VII

XVII+VIXVII + VI

XVII+VXVII + V

XVII+IVXVII + IV

Triticum aestivum Hordeum vulgäre Secale cerealeTriticum aestivum Hordeum vulgar Secale cereale

Alopecurus rayosuroldes Lamium amplexicaüle 0 0
0 0
0 0Alopecurus rayosuroldes Lamium amplexicaüle 0 0
0 0
0 0

100
100100
100

100
100100
100

5 0
10 0
10 05 0
10 0
10 0

0
5
50
5
5

100 100 100
100 100 100100 100 100
100 100 100

15 0
10 0
15 015 0
10 0
15 0

1010

5 125 12

100 100 100 100 100 100100 100 100 100 100 100

0 0 0 0 0 00 0 0 0 0 0

0 0 00 0 0

100 100 100 100100 100 100 100

Wirkstoff XVII+IIIActive ingredient XVII + III

XVII+ΊΙXVII + ΊΙ

Triticum aestivum Hordeum vulgäre Seeale cerealeTriticum aestivum Hordeum vulgar Seeale cereale

Alopecurus myosuroides Lamium amplexicaüleAlopecurus myosuroides Lamium amplexicaüle

00 00 00 1010 00 55 00 00 00 00 1515th 00 1010 100100 00 00 00 2020th 00 1515th 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100

ohne Schädigung totale Schädigungwithout damage, total damage

Claims (2)

PatentansprücheClaims in der X Methoxy und Y Chlor bedeutet, wenn R Wasserstoff und R- Methoxy bedeutet und wenn R einen Cycloalkenylrest bedeutet, bedeutet R, Wasserstoff, Methoxy, Methyl und Y und X bedeuten Halogen, Methyl, Methoxy, Trifluormethyl,in which X denotes methoxy and Y denotes chlorine, when R denotes hydrogen and R denotes methoxy and when R denotes a cycloalkenyl radical means, R means hydrogen, methoxy, methyl and Y and X are halogen, methyl, methoxy, trifluoromethyl, Wasserstoffhydrogen undand b) einer Verbindung der Formelb) a compound of the formula in der X Chlor, Brom, Cyan, Hydroxy, Methoxy, Thiomethyl, Thioäthyl, Azido, R, R, gleich oder verschieden sind und Wasserstoff, einen gegebenenfalls durch Cyan, Halogen, Alkoxy, Hydroxy substituierten geraden oder verzweigten Alkyl-, Alkenyl- oder Alkinylrest mit bis zu 7 C-Atomen, Cycloalkyl, Acetyl, Alkylacetyl, Y dieselben Bedeutungen hat wie R und R, und Y außerdem Thioalkyl oder Amino bedeutet, in which X is chlorine, bromine, cyano, hydroxy, methoxy, thiomethyl, thioethyl, azido, R, R, are identical or different and Hydrogen, a straight or branched one which is optionally substituted by cyano, halogen, alkoxy or hydroxy Alkyl, alkenyl or alkynyl radical with up to 7 carbon atoms, cycloalkyl, acetyl, alkylacetyl, Y have the same meanings has like R and R, and Y is also thioalkyl or amino, und gegebenenfalls
c) einer Verbindung der Formeland if necessary
c) a compound of the formula in der R einen niederen Alkylrest, R, Wasserstoff und dessen Salze bedeutet.in which R is a lower alkyl radical, R is hydrogen and its salts. 509809/1118 /62509809/1118 / 62 - 62 - O.Z. 30 054- 62 - O.Z. 30 054 2. Herbizid nach Anspruch 1 enthaltend die Mischung a + b , oder a + b + c.2. Herbicide according to claim 1 containing the mixture a + b, or a + b + c. BASF AktiengesellschaftBASF Aktiengesellschaft 509809/1118509809/1118
DE19732341555 1973-08-17 1973-08-17 HERBICIDE Pending DE2341555A1 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
DE19732341555 DE2341555A1 (en) 1973-08-17 1973-08-17 HERBICIDE
NL7410015A NL7410015A (en) 1973-08-17 1974-07-24 METHOD FOR PREPARING HERBICIDES.
NO74742745A NO742745L (en) 1973-08-17 1974-07-29
IL45424A IL45424A0 (en) 1973-08-17 1974-08-07 Synergistic herbicidal compositions containing a phenylurea and an s-triazine derivative and optionally also a benzothiadiazinone
FR7427724A FR2240687A1 (en) 1973-08-17 1974-08-09 Synergistic herbicidal compsns - contg a phenylurea, an amino triazine and opt a benzothiadiazine sulphone
DK435874A DK435874A (en) 1973-08-17 1974-08-15
BR6732/74A BR7406732D0 (en) 1973-08-17 1974-08-15 SYNERGIC HERBICIDE COMPOSITES
DD180518A DD112341A5 (en) 1973-08-17 1974-08-15
JP49092866A JPS5042048A (en) 1973-08-17 1974-08-15
SE7410427A SE7410427L (en) 1973-08-17 1974-08-15
ZA00745268A ZA745268B (en) 1973-08-17 1974-08-16 Herbicide
LU70746A LU70746A1 (en) 1973-08-17 1974-08-16 PROCESS FOR PRODUCTION OF HERBICIDE
BE147681A BE818932A (en) 1973-08-17 1974-08-16 NEW COMPOSITIONS WITH SELECTIVE HERBICIDE ACTIVITY
EG339/74A EG11774A (en) 1973-08-17 1974-08-17 Herbicides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19732341555 DE2341555A1 (en) 1973-08-17 1973-08-17 HERBICIDE

Publications (1)

Publication Number Publication Date
DE2341555A1 true DE2341555A1 (en) 1975-02-27

Family

ID=5889983

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19732341555 Pending DE2341555A1 (en) 1973-08-17 1973-08-17 HERBICIDE

Country Status (14)

Country Link
JP (1) JPS5042048A (en)
BE (1) BE818932A (en)
BR (1) BR7406732D0 (en)
DD (1) DD112341A5 (en)
DE (1) DE2341555A1 (en)
DK (1) DK435874A (en)
EG (1) EG11774A (en)
FR (1) FR2240687A1 (en)
IL (1) IL45424A0 (en)
LU (1) LU70746A1 (en)
NL (1) NL7410015A (en)
NO (1) NO742745L (en)
SE (1) SE7410427L (en)
ZA (1) ZA745268B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2284600A1 (en) * 1974-09-12 1976-04-09 Ciba Geigy Ag TRIAZINES-1,3,5 SUBSTITUTES AND PESTICIDE PRODUCTS CONTAINING THEM

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2284600A1 (en) * 1974-09-12 1976-04-09 Ciba Geigy Ag TRIAZINES-1,3,5 SUBSTITUTES AND PESTICIDE PRODUCTS CONTAINING THEM

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NO742745L (en) 1975-03-17
FR2240687A1 (en) 1975-03-14
DD112341A5 (en) 1975-04-12
NL7410015A (en) 1975-02-19
ZA745268B (en) 1975-09-24
LU70746A1 (en) 1975-01-02
EG11774A (en) 1978-06-30
SE7410427L (en) 1975-02-18
IL45424A0 (en) 1974-11-29
DK435874A (en) 1975-04-14
FR2240687B3 (en) 1977-06-10
BR7406732D0 (en) 1975-06-03
BE818932A (en) 1975-02-17
JPS5042048A (en) 1975-04-16

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