DE21837C - Process for the liberation of the luminous gas from ammonia and the associated extraction of sulfuric acid ammonia - Google Patents
Process for the liberation of the luminous gas from ammonia and the associated extraction of sulfuric acid ammoniaInfo
- Publication number
- DE21837C DE21837C DENDAT21837D DE21837DA DE21837C DE 21837 C DE21837 C DE 21837C DE NDAT21837 D DENDAT21837 D DE NDAT21837D DE 21837D A DE21837D A DE 21837DA DE 21837 C DE21837 C DE 21837C
- Authority
- DE
- Germany
- Prior art keywords
- ammonia
- sulfuric acid
- liberation
- luminous gas
- associated extraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims description 6
- BIGPRXCJEDHCLP-UHFFFAOYSA-N Ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 title claims description 4
- 238000000605 extraction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000010881 fly ash Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 5
- NJYFRQQXXXRJHK-UHFFFAOYSA-N (4-aminophenyl) thiocyanate Chemical class NC1=CC=C(SC#N)C=C1 NJYFRQQXXXRJHK-UHFFFAOYSA-N 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 235000015450 Tilia cordata Nutrition 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000002426 superphosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
von schwefelsaurem Ammoniak.from sulfuric acid ammonia.
In den meisten Gasanstalten wird das Leuchtgas von den darin enthaltenen Ammoniakverbindungen nur unvollständig befreit, weil man zu seiner Reinigung aufser der Waschung bisher fast ausnahmslos Kalk und Eisenoxyd anwendete. Ein Versuch, Schwefelsäure zum Reinigen des Gases anzuwenden, welche man in Form von damit getränktem Sägemehl in die Fabrikation einführte, ist wieder aufgegeben worden, weil das in dem Sägemehl gebildete schwefelsaure Ammoniak zu reich war an humosen und theerigen Substanzen, sowie an Rhodanverbindungen. Auch die Anwendung des Superphosphates zur Aufnahme des Ammoniaks aus dem Leuchtgase, wie sie in jüngster Zeit vorgeschlagen ist, leidet an dem Uebelstande, dafs hierdurch der werthvolle wasserlösliche phosphorsaure Kalk in geringwertigen unlöslichen präcipitirten phosphorsauren Kalk verwandelt wird, sowie daran, dafs das von dem Superphosphat aufgenommene Rhodanammonium daraus ohne weitere Wertriverminderung des Phosphates nicht entfernt werden kann.In most gas stations, the luminous gas is made up of the ammonia compounds it contains only incompletely liberated, because one has hitherto been cleansed besides washing almost without exception used lime and iron oxide. An attempt to use sulfuric acid for cleaning of the gas, which is used in the manufacture in the form of sawdust soaked in it introduced has been abandoned because the sulfuric acid formed in the sawdust Ammonia was too rich in humic and tarry substances and rhodan compounds. Also the use of the superphosphate to absorb the ammonia from the Luminous gases, as it has recently been proposed, suffers from the disadvantage that this results in them valuable water-soluble phosphoric acid lime in insoluble, insoluble, precipitated phosphoric acid Lime is transformed, as well as the fact that the rhodanammonium absorbed by the superphosphate from it without any further reduction in value of the phosphate cannot be removed.
Wir haben beide Uebelstande vermieden durch Anwendung mineralischer Substanzen, welche Schwefelsäure aufsaugen und zu gleicher Zeit, ohne zerlegt zu werden, eine geringe Glühtemperatur aushalten.We have avoided both inconveniences by using mineral substances, which Soak up sulfuric acid and at the same time, without being decomposed, a low annealing temperature endure.
Als solche wendeten wir Infusorienerde und auch Flugasche an; es finden sich aber wahrscheinlich noch sonstige mineralische Stoffe (Infusorienerde nimmt 150 pCt. Schwefelsäure auf, ohne die erforderliche lockere Eigenschaft zu verlieren), welche für unsere Zwecke brauchbar sind.As such, we used infusoric soil and also fly ash; but they are likely to be found other mineral substances (infusor earth takes 150 pCt. sulfuric acid without losing the required loose quality), which are useful for our purposes are.
Die mit Schwefelsäure getränkte mineralische Substanz wird behufs Aufnahme des Ammoniaks aus dem Gase auf Gashorden ausgebreitet. Diese werden vor oder nach den zur Entfernung des Schwefels mit Eisenerz oder dergleichen beschickten Horden eingeschaltet und verbleiben in den Reinigungsapparaten, bis die Schwefelsäure nahezu gesättigt ist.The mineral substance soaked with sulfuric acid is used to absorb ammonia from the gases spread on gas cords. These are placed before or after the Sulfur with iron ore or the like charged hordes switched on and remain in the cleaning equipment until the sulfuric acid is almost saturated.
Sodann wird die Substanz ausgewechselt und, wenn sie rhodanhaltig ist, in einem geschlossenen, -mit Abzug für die entwickelten Gase versehenen eisernen Gefäfs oder Ofen einer gelinden Glühhitze ausgesetzt. Hierbei entweicht, falls Rhodanverbindungen und aufserdem ein geringer Schwefelsäureüberschufs vorhanden sind, Rhodanwasserstoffsäure und die theerigen Producte verkohlen. Bei Auslaugen der Masse und Eindampfen der Lauge erhält man ein sehr reines und schönes schwefelsaures Ammoniak; es kann aber auch unter Umständen die unausgelaugte Masse zur Düngerfabrikation verwendet werden, wenn Rhodangehalt nicht vorhanden ist. Die Leuchtkraft des Gases wird, wie dies die Erfahrung gelehrt hat, durch oben beschriebene Reinigungsmethode nicht beeinträchtigt.The substance is then exchanged and, if it contains rhodan, in a closed, - With a deduction for the evolved gases, iron vessel or furnace of a mild one Exposed to glowing heat. This escapes, if rhodan compounds and also a a slight excess of sulfuric acid are present, hydrothodic acid and the mineral products char. When the mass is leached out and the lye is evaporated, a very pure and beautiful sulfuric acid ammonia is obtained; however, under certain circumstances, the undrained mass can also be used for the manufacture of fertilizer if there is no rhodan content. The luminosity of the gas will be like this experience has taught, is not affected by the cleaning method described above.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE21837C true DE21837C (en) |
Family
ID=298503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT21837D Active DE21837C (en) | Process for the liberation of the luminous gas from ammonia and the associated extraction of sulfuric acid ammonia |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE21837C (en) |
-
0
- DE DENDAT21837D patent/DE21837C/en active Active
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