DE2137662A1 - Process for the production of labels, signs, boards or other surfaces that have display symbols or motifs - Google Patents

Description

The invention relates to a method of manufacture of labels and other display surfaces such as signs.

It is known that labels and signs, where the text can be composed in front of the user, are highly valued for their flexibility of use.

In particular, self-adhesive labels of the aforementioned type are already known, which are on a wide variety of üeoieten, as with administrative and commercial service parts or the like, as well as can be used by individuals.

Such labels or signs allow an effective and at the same time aesthetic and very visible representation because of the possibilities they offer to achieve contrasts in colors.

In a general way, labels of the aforementioned type are made plastic by manually driving a malleable material produced at skin temperature.

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This driving is done by applying pressure to a realized a selected motif, which, by acting on a skin made of plastic material, causes permanent disorientation of the molecules. This leads to the plastic material undurol "void and a light Eelie impression - is formed, which corresponds to the selected motif

This disorientation can only be achieved by putting on of high pressure causes, thus increasing the dimension-the embossed motifs is limited, which is obtained either by hand or with devices of simple execution can be.

For example, the actually known, easily manageable devices do not allow formation of characters the largest dimension of which is more than 8 mm If it is desired to produce motifs of large dimensions, damn it on relatively extensive devices used, which develop very high pressures Now experience shows that it is with the * actually known Methods and devices is very tricky to realize characters whose dimensions are more than 12 mm.

These labels are generally made from complex materials that have the embossable skin is relatively thick in order to achieve an opacity which enables a good contrast effect · Furthermore, lacks the flexibility of the labels obtained makes it difficult to apply them to certain substrates the local deformations produced by the embossing reduce the area of contact with the receiving ones Wearers, which in certain cases leads to very moderate behavior over time.

Furthermore, the labels obtained can only be used in a limited temperature interval, because especially above 50 ° C the impressions produced by physical modification of the plastic material disappear pretty quickly.

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In addition, only light impressions can be made by embossing can be obtained on a colored substrate.

There are also known labels in which the. Imprints can be obtained by heat transfer · However The motifs on these labels can only be used under the simultaneous effect of high pressures and high temperatures be achieved.

On the other hand, transfer materials have already been described, those of skins or pre-cut ones Motifs are formed, which are detachably worn by a temporary carrier and not a pressure-sensitive one Adhesive are provided to enable their attachment to a receiving surface after transfer.

The transfer skins, especially used for decals or decoration and composition work can be cut according to a specific contour using either scissors or a knife will. On the other hand, however, it is impossible to cut any motif in advance by simply printing it.

The object of the invention is to remedy the above-mentioned disadvantages and, for this purpose, a method for the production of labels, signs or the like. To create which, except that it is of a remarkable one Simplicity is leading to vast compositional possibilities.

The method for producing labels, panels, signs or other surfaces bearing indicative motifs or characters is essentially characterized in that a first strip is formed which has a carrier which is covered on at least one side with a layer of a pressure-sensitive adhesive is clothed in that a second Obertragungsstreifen is formed which comprises a support having a transferable skin wearing that the two strips are combined so that the adhesive layer and the transferable skin face each other, that subsequently to this

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composite structure a predetermined motif is applied locally under a given pressure in such a way that a cutting of a corresponding motif in the transferable skin and at the same time a transfer of the motif cut in this way to the adhesive layer to which it adheres, and that then the initially formed strips be separated from each other, wherein the strip carrying the print can then optionally be covered with a protective skin according to the later use.

According to a first embodiment of the method According to the invention, said motif is applied to the composite structure on which the transferable skin is carried Side applied and then the second strip with the non-transferred parts of the skin removed.

According to a second embodiment of the invention, the aforementioned motif is applied to the zusej-nongeseLosed structure on the cell carrying the adhesive layer and then the first strip with the transferred skin parts is removed.

Depending on the desired end result, there are various options.

When working according to the first embodiment, the printed motif is obtained on the first strip or the adhesive strip.

The label or sign produced in this way can be used directly, simply by applying it to Objects or other surfaces or transparent articles by means of the visible adhesive side of the first starting strip.

A tape provided with adhesive on both sides can be used as the first strip, whereby the one side receives a protective strip intended to be used at the time of attachment of the label or Shield to be removed.

The products thus obtained can be attached to various objects by gluing.

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In a modified embodiment, a tape provided with adhesive on one side can be used which, as before, takes up a transfer strip on the adhesive side on which a pressure is applied is exercised according to a predetermined motive, whereby the "cutting" and at the same time the setting on the adhesive surface of the created motif is brought about, after which the strip is removed so that the subject is allowed to appear, and finally a protective film is applied applied, which is at least non-stick Has area. .

However, if desired, no protective film can also be used can be applied to the adhesive surface, and the latter is then used to secure the To ensure labels on a suitable mounting surface, in the obvious case in which the receiving surface is transparent.

According to a further modification, as before, a pressure-sensitive adhesive is applied on the eir-.fcü side provided band a transferable "! is applied, then a motif is applied with a predetermined pressure, what ensures the "cutting", the transfer and the definition of the motif on the adhesive, then that Transfer tape removed what was on the adhesive side lets the motifs appear, and then a transparent cover film is applied to this adhesive side Adhesive tape applied or not.

The label or label thus obtained is particular intended to be introduced into fittings, especially those in the form of sliding or application devices for labeling of the known type.

V / hen worked according to the second embodiment the printed motif is obtained on the aforesaid second tape or transfer tape.

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BATH ORIGINAL

With such a process, a background is obtained, the color of which is that of the skin from transferable Is dye, the motifs obtained after printing the appearance and color of the Carrier of the communicable skin.

It is therefore easy to understand. da £ when you get that The appearance of the tint and decoration of the transferable skin and its wearer can be changed, one great Variety of products, such as signs and labels »can produce the desired printed Carrying off what was previously difficult to achieve. ·

For example, a carrier for a transparent transferable skin can be provided, and in this case the imprints themselves are transparent and stand out from a colored background, which corresponds to the transferable skin. It should be noted that such a Carrying out the procedure is a special case, since as will appear from the description below, the carrier of the transferable skin of any kind and any appearance.

A carrier can be used for the transferable skin with a layer of a on one side pressure-sensitive adhesive covered with a skin that can be removed at the time of use, and on the other side has the transferable skin, which after the removal of the first adhesive tape is transparent Absorbs protective skin.

The labels or signs obtained in this way can have the carrier side on any desired surface are attached, with inscriptions of the same color as the carrier appearing that differ from stand out from a substrate, which is the transfer skin is equivalent to. According to a modification, the carrier is transparent and the non-transferred parts of the skin are with a pressure-sensitive adhesive on both sides

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covered with fabric provided tape, one side of which adheres to these skin parts, while the other side is a Absorbs skin that may be removed at the time of use.

According to this modified embodiment of the method Labels or signs obtained can be with the side carrying the transferable skin and with the interposition of the aforementioned tape with adhesive on both sides on any opaque one or transparent surface, through the transparent support, which in this case is the The role of the protective skin is played, inscriptions of the same color as the receiving surface are left visible, that stand out from a substrate that corresponds to the transferable skin.

This procedure enables in a general way starting from its transmissible skin, an infinite one To achieve a variety of imprint effects, through the sole modification of the wearer, whose color effect can be any.

In all cases, regardless of the type of implementation chosen, the type of materials used, i.e., the adhesive tape, the transferable skin backing, the transferable skin and the protective skin will receive a wide variety of products. Furthermore, according to the method according to the Invention obtained products, for example display signs, represent printed motifs, the dimensions of which cover a very extensive area, well a relatively small compressive force is sufficient to generate and fix the print.

It has been found that in the method according to the invention, a force of the order of 100 kg is sufficient to cut and define characters which have an area of 9 c «2 ^ _y while the same force is not sufficient to move in embossing a skin of polyvinyl chloride mark of 11 mm height, an area of

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BAD OR (GINAL

Cover 10 to 30 mm

The force that is required to produce an imprint • by embossing is therefore 30 to 90 times the force required to form prints by the method according to the invention

Since it is possible to produce motifs, characters and letters of large dimensions, this can be done PdId of the use of labels or the like formed in this way by the user.

The invention also makes it possible to produce labels or the like of the desired thickness and flexibility. Be? .- * For example, according to the first embodiment, it is possible to determine the type and thickness of the receiving adhesive tape and / or the type and thickness of the transparent cover skin can be changed without increasing the compressive force appreciably. In addition, since the components of the label are given, it is possible to have an unlimited number of more or less contrasting combinations Depending on the need Put them together by simply changing the coloring and appearance of the various elements.

The compositions of the various elements can also be based on various parameters, which are required by the subsequent use, are chosen in order to obtain products of high quality. P Further features and advantages of the invention emerge from the following description, in which the invention is explained with reference to the drawing, for example.

Pig. 1 to 4- illustrate schematically a first embodiment of the method according to the invention.
Pig. 5 illustrates a possible modification of FIG

first embodiment.

Pig. 6 illustrates a second embodiment of the method according to FIG. Invention.

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7 illustrates a possible modification of the second embodiment.

8 illustrates a further possible modification of the second embodiment.

In order to produce labels, signs or the like of high quality according to the invention, the very clean prints have, the adhesive tape and the transfer tape must meet certain conditions.

First, the adhesive attachment of the transferable skin to the pressure sensitive adhesive is just under the Influence of a certain pressure effective, which is of the order of magnitude of that which is applied to the composite Structure must be exercised * in order to ensure that the imprinted motif is cut into the transferable skin, and the pressure-sensitive adhesive must have little affinity for the simple touch Have dye skin. Indeed, it is venial that after the pressure has been applied, these parts of the transferable skin surrounding the cut motif are slightly removed from the Adhesives can be separated without being damaged and remain attached to the carrier.

It has been found that these conditions are met when used as pressure sensitive adhesive tapes Adhesive tapes with the following characteristics are used:

poor gripping ability,

an adhesive capacity that develops under the influence of pressure,

a low tack,

good internal cohesion and sufficient elasticity.

Each of these characteristics is discussed in detail below.

A.) The low gripping power is essential, so that the bond between the transferable skin and the adhesive tape is not created by a simple touch

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can occur, but only becomes effective under the influence of a given pressure. The! Peile that the Pressure not be subjected, can then easily be separated · For this purpose can be beneficial Adhesive tapes are used that, according to the AJERA standards measured, a griffin between 5 and 150 and preferably of less than 100 centinewtons / cm

B.) A low tack is necessary to prevent the transferable skin and the pressure-sensitive adhesive due to the low gripping power conditioned, with a simple touch

fc extended in time. The value should be one that the transferable skin with simple contact with a pressure sensitive adhesive during a minimal Time that corresponds at least to the full working cycle of the creation of the print motif is not transferred will,

That which develops under the effect of the leak Adhesiveness is a necessary condition for the motif cut into the transferable skin at the same time is set on the tape. The adhesive strength of the adhesive tape is advantageously 40 to 400 centinewtons / cm, to enable a good separation of the cut motif.

w D.) The inner cohesion conditions the permanent

Plague hanging of the adhesive on its support, this sticking in the course of the various subsequent Operations of the method and in particular in the course of the application of the pressure and in the course of the separation of the Adhesive tape and the transferable skin should not be changed. Internal cohesion should have a fourth, which is sufficient to cover the entire removal of the cut motif with the adhesive tape at the moment of separation of the Adhesive tape and the dye skin to allow.

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Ε ·) The elasticity should be sufficient so that the adhesive follows the possible deformations of the transferable skin when the pressure is applied, which is a ' better adhesion of the transferable skin due to the adhesive on the entire surface of the cut motif . enables · It should also enable the adhesive to to follow the deformations imparted to its wearer when separating from the transmissible skin, in order to avoid any return to avoid on the transmissible skin. The elasticity also plays an important role in the Distribution of the pressure over the surface of the motif, this distribution having a direct influence on the Has quality of cut. *

The affinity for the transferable skin is determined by the compatibility between the adhesive and the transferable Skin determined.

According to a further feature of the invention, the adhesive components which are those mentioned above Fulfill conditions, advantageously selected from the substances listed below:

I. Polyurethane-based adhesives made from polyether polyols with a high OH index and polyether polyols with a relatively low OH index are prepared in such proportions that the mean index of the mixture is between 50 and 100. This polyether device contributes, on the one hand, to a low gripping power and a low stickiness on the surface to obtain and on the other hand to achieve a relatively high internal adhesion, the effect of which developed under the application of pressure.

II Adhesives based on silicones which are crosslinked by means of peroxides, amines or metal cations, the crosslinking being carried out in such a way that the above -mentioned characteristics are obtained, and where the choice of catalyst is also determined by the loading

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conditions of preparation of the adhesive and the conditions of behavior of the carrier at working temperatures is determined.

III Adhesives based on acrylic derivatives, which are crosslinked by means of peroxides, amines, metal cations or isocyanates.

IV · Adhesives on the base *; of polyvinyl ether.

V. Adhesives based on natural rubbers or preferably synthetic rubbers, the latter generally making it possible to obtain adhesives of better purity and if the first embodiment of the method is chosen to have better stability against aging of the motif-adhesive complex formed.

The transfer tape should also meet certain conditions to od labels, signs. Like. To received, which have very clean motifs and a flawless finish.

In particular, according to a further feature of the invention, it should have a structure that gives it the options listed below.

I. Sufficient plasticity of the transmissible skin to allow a clean cut under the action of the To enable pressure without a jagging or tearing or to cause tearing, which would deprive the printed motif of any cleanliness.

II. Various stretches for the transmissible skin and for its wearer to prevent the Avoid the carrier when the pressure is applied and the separation between the carrier and that on the pressure sensitive Glue to facilitate set motif.

III. Characteristics of the sticking between the transmissible skin and its wearer, which the good behavior of the composite structure in the various manipulations and at the same time the easy one Separation of the wearer and that from the transferable skin

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cut motif after it has been laid down on the adhesive.

IV. Sufficient resistance of the transmissible skin to tension to prevent damage in transit and to avoid during the various operations that it ■ may be charged with.

A transferable skin which corresponds to the aforementioned various parameters may advantageously be formed from a film-forming organic polymer which _v fillers mad / or added pigment, coloring agent and, if necessary, plasticizers and / or waxes and / or resins.

In order to ensure the stability of the motifs formed over time, it is necessary that the products, which introduced into the composition of the transferable skin are insoluble in the pressure-sensitive adhesive at application temperatures, to any To prevent emigration.

It has also been found that, de n & aa used the Adhesive, the granulometry of the pigments and fillers used have a certain influence on the adhesion in the absence of any pressure between the transfer skin and the pressure sensitive adhesive. For example, when using fillers and pigments with a grain size between 10 and 100 microns have obtained a skin that has micro-protuberances on the surface that have a continuous Contact between the surface of the transfer skin and prevent the surface of the pressure sensitive adhesive when the skin is applied to the adhesive will. This makes it possible to limit the adhesion between the two surfaces and to facilitate their separation.

Under the action of the pressure applied at the time the motif was formed, the adhesive is forced to penetrate in_ all irregularities of the surface of the transferable skin, creating a firmer and more continuous Contact between the adhesive and the

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cut motif and thus an effective attachment is guaranteed.

Among the film-forming organic polymers that are involved in the composition of the transferable skin in can occur more satisfactorily: polyvinyl alcohols, polyvinyl ethers, Polyvinyl acetates, copolymers of vinyl acetate and vinyl chloride, acrylic derivatives, nitrocellulose, cellulose acetates, cellulose acetobutyrates, methyl celluloses, Ethyl celluloses, carboxymethyl celluloses, styrene resins, polyurethanes or their mixtures.

The plasticizers or softeners are preferably non-migrating and they can be made from Group are selected, the butyl, cyclohexyl and dioctyl phthalates, chlorinated diphenyls, chlorinated Triphenyls, tricresyl phthalate and polymeric plasticizers, such as polyester derivatives of sebacic acid or adipic acid. These plasticizers are the ones that usually used for plasticizing organic polymers.

The plasticizers are advantageously used in a proportion of 30 to 300 # with respect to the polymer applied.

The fillers can be selected from the group that includes talc, dolomite, silica, mica, Chalk, titanium oxide, zinc oxide, starches and their mixtures.

The pigments can be of a mineral, organic or metallic type

Advantageously, 2 to 11 parts of the fillers and / or pigments can be used per part of polymer.

The carrier of the transferable skin can be formed from a skin made of styrene polymex'isates or - copolymers, olefin polymers or olefin copolymers, Cellulose derivatives, polyvinyl acetal, poly-

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vinyl esters or halides, polyesters and polycarbonates is composed. The polymers forming the carrier of the transferable skin can be a contain sufficient amount of plasticizer to give them the above-mentioned elongation characteristics to rent. The carrier can check you out regenerated cellulose film, which is coated with an organic polymer, or from be formed of a paper film, which has a slightly non-stick clothing.

The transfer belt is made in that such a carrier with the components of the brought in the form of a solution, dispersion or melt transferable skin is coated by known methods in such a way that after drying or cooling a skin is formed, which has a weight of 5 to 150 u: .d before-

preferably from 10 to 50 g / m 2.

The pressure sensitive adhesive tapes used in the method according to the invention may be those that are commonly commercially available but become advantageous those of of the type specified below. However, experiments have shown that it is desirable to eliminate the To use a tape with pressure-sensitive adhesive, the backing of which has a certain flexibility, which is preferably larger than that of the "base or support of the transferable skin.

The optimal results obtained depend on the combination of the following two factors:

The weight of the transmissible skin, which can be between 5 and 40 g / m, and

the weight of the adhesive coating on the

p sensitive adhesive tape per m, where this weight between 5 and 30 g / m on each side of the tape can be.

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The combination of these two factors determines the application pressure.

All of these dispositions lead to multiple advantages, which are summarized in the following way can:

a) The adhesive allows the transfer process only low pressures are to be used.

b) The production of labels or signs of any kind by the user under very practical and / or less arduous conditions.

c) The formation of the motifs and their transfer can be realized by using standard printing signs is assumed. * *

d) Great simplicity of manufacture compared to a known process for the formation of 'Heat transfer printing due to the fact that the adhesive strength instead of thermal energy is set.

The adhesive tape and the transfer tape as defined above are then placed on top of one another, wherein the adhesive is brought into contact with the transferable skin to form a composite structure. A predetermined motif, such as the letter 'F shown in the drawing, is printed applied to this structure, either on the side of the wearer of the transferable parabola a first embodiment, or on the opposite Side, i.e. on the side of the carrier, of the adhesive layer in a second embodiment.

For a better understanding of the invention, some exemplary embodiments are given below with reference explained on the drawing.

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First embodiment of the method example 1

In a mixer, 6 parts of butyl phthalate were mixed with 4 parts of a yellow pigment such as the one called "Jaune Lumidre JN "is commercially available, and. 29 parts of a talc of a particle size that passes through a sieve of 0.063 πιπί passes through it, in the presence of 0.3 parts of a dispersing agent, such as that which is commercially available under the name "Pluronic L61" mixed together into a paste.

Thereafter, 57 parts of ethyl acetate and 4 parts of nitrocellulose, such as those listed under the Designation "Nitro-Cellulose E130" is in the trade, added. It became a complete solution the nitrocellulose mixed, wonacl- means of a With a doctor blade, the resulting color is applied in this way to a polyester film 10 (Pig. 1) of 25 micron thickness became that after drying a transferable skin 11

2, which had a weight of 50 g / m 2. the transferable skin was thus applied to the polyester film 10 which formed its backing.

It then became a strip of say 50 now Cut off the width and thereby obtain a transfer belt which is designated generally by 12 in the drawing is.

On one surface of a pressure-sensitive adhesive 14, 15 provided on both sides 50 mm wide adhesive tape 13 (Fig. 2) of the type such as it is on the market, and which had a carrier based on transparent polyvinyl chloride, the transfer tape 12 was applied so that the transferable skin 11 facing the adhesive and her T-beam 10 was turned outwards.

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A metal alloplastic character 16 was then arranged on the carrier 10, for example a letter represented and a height of 35 mm and a

p
Area of about 630 mm, and a force of 70 kg was exerted on this sign, which corresponded to a pressure of about 11 kg / cm.The application of this pressure enabled a motif corresponding to the sign to be cut into the transfer skin and at the same time to be attached On the pressure-sensitive adhesive. The metalloplastic mark was then removed, after which the backing 10 and the non-attached portion of the transferable skin 11 were removed (Fig. 3).

The motifs "M" were then in * the measure of the decrease of the transfer belt visible.

The resulting tape was then provided with a protective cover (FIG. 4) formed by a tape 19 made of transparent polyester, now y'J wide and 25 microns thick.

In this way, depending on the case, one can Pressure-sensitive adhesive can be produced with a label or sign that has a very high degree of flexibility and has a very clean and very bright yellow print on a transparent background.

In use, for the purpose of applying to a the anti-stick tape 18 is easily removed from a suitable surface.

Example 2

In a mixer were 7-5 parts of dioctyl phthalate with 18 parts of a talc of a particle size that will pass through a 0.063 mm sieve and 8 parts Titanium oxide of a particle size that will pass through a 0.063 mm sieve in the presence of 0.3 parts a dispersant, for example that which is commercially available under the name "Pluronic L61"

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3 parts of ethyl cellulose, such as that which is commercially available under the name "Ethyl-Gellulose H300", and 56 parts of methyl ethyl ketone were added. It was mixed until the ethyltellulose had completely dissolved, and then the color thus obtained was applied by means of a pruning knife to a polyester film 25 microns thick in such a way that, after drying, a transferable skin was obtained

which had a weight of 30 g / m. The transferable skin was attached to the polyester film in such a way that which formed its bearer.

A 19 mm strip was then cut to obtain a transfer tape.

On one surface one on both sides with pressure sensitive! Adhesive verseheneu, 19 mm wide Klebbisn & there by the manner in which it is located in the trade, and which had a support made of "Cello.piane" of red color, was the aforementioned 1 ^ ^ö rtragungsband applied such that the transferable skin facing the adhesive and the wearer was turned outward.

A metalloplastic sign with a height of 10 mm and an area of about 50 mm * "was then placed on the carrier of the transferable skin. A force of 55 kg was exerted on this metalloplastic sign, which corresponded to a pressure of about 11 kg / cm. Es a motif corresponding to the sign was then cut into the transfer tape and at the same time the sign was attached to the pressure-sensitive adhesive.After the removal of the metalloplastic sign, the carrier of the transferable skin was removed, the non-attached parts of the skin being taken with it.

The printed tape thus obtained was then coated with a commercially available pressure-sensitive tape

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Adhesive covered tape, which had a width of 19 mm and one made of undyed and transparent '"Cellophane" had existing backing. The adhesive tape was arranged so that the adhesive side came into contact with the imprint · · *

In this way there was obtained a pressure-sensitive adhesive: label having a very had a pleasant appearance, presented a white print on a red background and possessed such flexibility. that it could be applied to any carrier.

Example 3

In a mixer, 3 parts of a polyester derived from sebacic acid, such as the one which is under the name "Garbeflex HM1O" in Trade is located, with 32 parts of chalk of a particle size, which passes through a sieve of 0.063 mm, 2 parts of black dye, like the one that is is on the market under the name "Noir 84-2", and 0.3 part of a dispersant such as that commercially available under the name "Pluronic Lö1" is mixed together to form a paste.

12 parts of a copolymer of vinyl acetate and vinyl chloride, as it is commercially available under the name "Rhodopas AX", and UA parts of methyl ethyl ketone were added. Mixing was carried out until this copolymer had completely dissolved, after which the paint obtained in this way was applied to a polyester film 25 microns thick by means of a doctor blade in such a way that, after drying, a transferable skin with a weight of 4-0 g / m 2 was obtained. The transferable skin was thus attached to the polyester film that formed its backing.

A strip 12 mm wide was cut to obtain a transfer tape.

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On one of the surfaces of a pressure sensitive adhesive on both sides Commercially available tape that was 12 mm wide and had a backing made of yellow Cellulose acetate consisted, the aforementioned ^ transfer tape was applied so that the transferable Skin facing the adhesive and the carrier facing outwards.

"A metalloplastic was then placed on this carrier

2 characters with a height of b mm and an area of about 13 mm arranged. A force of 15 kg was exerted on this sign, thereby cutting out and at the same time the attachment of a motif corresponding to the mark was caused. Then became the carrier of the transferable Skin and the non-attached parts of the skin peeled off after the metalloplastic mark is removed had been.

Then, the obtained printed tape was coated with one made of transparent cellulose acetate existing tape of 12 mm wide covered. In this way, a pressure-sensitive adhesive was provided Received label with black imprints on a yellow background.

Example 4- '- ■

In a mixer, 10 parts of butyl phthalate were mixed with 2 parts of carbon black, such as the one below called "Noir de Carbone BL", and 31 parts of a talc of a particle size that passes through a 0.063 mm sieve in the presence of 0.3 part of a dispersant such as that which is under the name "Pluronic L61" in the trade is mixed together to form a paste.

There were then 53 parts of methyl ethyl ketone, 2.85 parts Ethyl cellulose, such as those that go under the designation "Ethyl Cellulose N300" is commercially available,

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and 0.5 part of polyvinyl acetate such as that used is on the market under the name "Rhodopas M", added. The ethyl cellulose and the polyvinyl acetate were mixed until completely dissolved, after which, using a doctor blade, the dye thus obtained is applied to a polyester film of 25 microns Thick dfcMrt was applied that after drying a transmissible skin weighing 50 s / ia was obtained. The transferable skin was like that on that Polyester film attached, which formed its carrier.

A strip 50 mm wide was cut off and thereby obtain a transmission band.

One provided on one side on the adhesive surface with pressure sensitive adhesive, 50 mm wide commercial tape which aufwiesr a group consisting of polyvinyl chloride backing of 50 micron thickness and white color, wu -: e applied, the transfer belt such that ^ti: .s transferable skin.! facing the adhesive and the carrier facing outwards.

A metalioplastisch.es was then placed on this carrier

ρ characters 35 meters high and about 630 mm in area arranged, and upon the sign became a force of

Exerted 70 kg, which corresponded to a pressure of about 11 kg / cm ·. The application of this pressure resulted in the cutting of a motif corresponding to the character the transferable skin and at the same time for attaching this motif to the pressure-sensitive adhesive. The metalloplastic Sign was removed, and then the wearer became the transferable skin and the non-attached Parts of the skin removed.

The resulting tape was then tied with a transparent polyester tape 20 (Fig. 5) 50 inches wide and 25 microns Thick covered.

In this way a label was obtained which was printed in black on a white background and

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possessed such rigidity that it was easy to use in labeling machines known type could be introduced.

Example 5

In a mixer were placed: 6 parts of butyl phthalate, 4.5 parts soot black, like the one that is under the name "Noir de Carbone BL" in Handol located 23 parts of a talk such as that commercially available as "Tale 10 MCTO" 0.3 part of a dispersant such as that sold under the designation "Pluronic L61" commercially available 2.8 parts of nitrocellulose, such as that known as "nitrocellulose." E130 "commercially available, and 64 parts of acetone.

It was mixed until the nitrocellulose was completely dissolved and the mass became treated in a ball mill for 24 hours to to obtain a dye of great fineness.

The dye thus obtained was then applied by a doctor blade on a polyester film of 25 microns thickness such that after drying, a transferable skin was obtained

had a weight of 25 g / m 2 and of the polyester film was worn, which formed its wearer.

A strip 50 mm wide was then cut off, to get a transmission band.

On the other hand, a pressure-sensitive adhesive tape was produced by using a ütreichmesser on one side of a tape of polyvinyl chloride of red color with a width of 50 mm and a thickness of 40 microns a toilet adhesive composition was applied, which contained the following components:

7.5 parts of a polyether polyol with an OH index of 660, such as that listed under the

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drawing "Voranol CP260" is on the market,

92.5 parts of a polyether polyol with an OH index of 53, such as the one under the name "Caradol GJOOO" in the trade,

35 parts of a resin made from one with glycerin esterified rosin ester consisted of how he himself under the name "ßesosol G" in the trade,

8.5 parts of a resin obtained from a triethylene glycol ester consisted of hydrogenated rosin, as it is called "Staybelite Ester 3" is on the market,

11.5 parts acrylic acid,

3 parts of tin octoate, such as that which is sold under the name "T 9" as Catalyst and

15.3 parts of tolylene diisocyanate, such as those found under dei. ^v Designation "Suprasec EN" is on the market.

After polymerization at 100.degree. C., the tape was coated with a pressure sensitive adhesive on, which had a weight of 30 g / m.

Its adhesive strength, measured on a steel plate according to the AFERA standards, was 300 cents ine v / t o n / cm, and his gripping ability, also measured according to the AFERA standards, was 5 centinewtons / cm.

The transfer tape was applied to the adhesive side of the tape thus obtained in such a way that the transferable Skin facing the adhesive and her Tx-ager turned outward.

A metalloplastic was then placed on this carrier Character arranged, which had a height of 35 mm and an area of about 630 mm. Was on this sign a force of 70 kg exerted, which corresponds to a pressure of about 11 kg / cm. The application of this pressure made it possible to cut a motif corresponding to the character

109887/0279

into the transferable skin of the transfer belt and at the same time the attachment of this motif to the pressure-sensitive adhesive. The metalloplastic sign was removed, and then the transferable skin backing that did not attach it was removed Took parts of the transmissible skin.

De ¹ ; tape thus obtained was covered with a tape made of a polyester 50 mm wide and 25 microns thick.

In this way a non-adhesive label was obtained, which can be inserted into a label holder Art could be introduced and had black prints on a red background.

Example 6

In a mixer were 2 parts of ethyl cellulose, such as the one y. ^ Ah under the designation "ethyl cellulose U30G "in stores, $ 2 parts talk, like the one that is commercially available under the name "Tale 10 MGTO", 4 parts of a gelVuu pigment, such as that sold under the name "Jaune TiumiSre JN", 0.3 parts a dispersant such as that which is commercially available under the name "Pluronic L61", and 70 parts of toluene were introduced. It was mixed until the ethyl cellulose was completely dissolved, and then the mass was ball milled for 60 hours to obtain a dye from great! unity.

The dye thus obtained was then applied to a polyester film of a thickness by means of a doctor blade of 25 microns so applied that after drying a transferable skin was obtained that had a weight

2
of 20 g / m. The transferable skin was carried by a polyesber folio, which forms its carrier 'e »

109887/0279

A strip 150 ^mm wide was then cut to obtain a transfer tape.

On the other hand, it became a pressure-sensitive adhesive tape produced by using a doctor blade on one side of a polyvinyl chloride Band of black color, with a width of 150 nm and a thickness of 100 microns havi-a, an adhesive solution was applied, had the following composition:

100 parts of a silicone resin, such as that 'is located under the designation ^"r Si 271 commercially in 36 #Lger solution in xylene, and 1 part of benzoyl peroxide.

After drying, the tape had a coating consisting of a pressure sensitive adhesive Had a weight of JO g / m.

The linear tack of this tape, measured on a steel plate according to the AFEKA-ETc-v ^ oti, was 320 centinewtons / cm, and its gripping power &eLt; Likewise measured according to these standards, was 90 centinewtons / em.

The other side of the adhesive tape was coated with a pressure sensitive adhesive of a known type and covered with an anti-adhesive film that was intended to be used at the moment of attachment of the label to be removed.

The transfer tape of 150 mm width was applied to the adhesive side of the tape that remained free applied so that the transferable skin was facing the adhesive and its carrier was facing outwards.

A metalloplastic was then placed on this carrier

Sign arranged, which had a height of 80 mm and area of about 18 cm, and on this sign a force of 200 kg was exerted, resulting in a pressure of about 11 kg / cm. Applying this pressure made it possible to cut out one corresponding to the character Motif in the transfer belt and at the same time the

10 9 88 7/0279 bad ORrGiNAL

Attachment of this motif to the pressure-sensitive adhesive. After removing the metalloplastic mark the transferable skin carrier was removed, which took the non-attached parts of the skin with it.

The print obtained then became medium? a transparent polyester adhesive tape known-. ^7. Ax protected which was 150 nrai wide and 25 microns thick with the adhesive facing the print.

In this way, an adhesive label was obtained which had yellow motifs on a black background and which could easily be attached to a receiving surface after removing the anti-adhesive film.

Example 7

A transfer belt 50 m ™ wide was used prepared according to the procedure described in Example C.

Further, a pressure-sensitive adhesive tape was produced by using a knife on one side of a tape made of white polyethylene, 50 mm wide and 100 microns Thickness an adhesive solution was applied, which had the following composition:

100 parts of acrylic copolymer, such as that sold under the name "D 262" by the company Monsanto is in stores and that is a 45 # solution represents

5 parts of a solution of 10 % sodium bicarbonate in ethanol and 50 parts of ethyl acetate.

After drying, the tape had a coating of pressure sensitive adhesive that weighed 30 g / m ² .

The linear tack of this tape, measured according to the AMSBA standards, was 60 centinewtons / cm.

, 09887/0279 ^

The gripping ability, also measured according to these standards, was 10 centinewtons / cm.

The 50 mm wide transfer tape was applied to the adhesive side in such a way that the transferable skin was facing the adhesive and its carrier was facing outwards. Then, according to Example 5, a metalloplastic sign was applied (height of the sign 35 ππη> pressure 11 kg / cm). Thereafter, the tape obtained was covered n ± t with a known adhesive tape made of transparent polyester 50 mm wide and 25 microns thick, with the adhesive facing the print side.

A non-stick label was obtained, which had yellow prints on a white background.

Example 8

A transfer tape 50 mm wide was used prepared according to Example 6, and a pressure-sensitive adhesive tape was prepared by the one side of a transparent polyester tape 50 mm wide and 125 microns thick with a Adhesive solution was coated, which had the following composition:

100 parts of polyisobutylene, such as that sold under the name "Oppanol B100",

10 parts of polyisobutylene, such as that which is under the name "Oppanol B3" in the trade, and 500 parts of the essence "C".

After drying, the tape had a coating of pressure sensitive adhesive that weighed 25 g / m ² .

The linear tack of this tape, measured according to the AFERA standards, was 120 centinewtons / cm.

The gripping ability, also measured according to these standards, was 40 centinewtons / cm.

The other side of the tape was coated with a pressure sensitive adhesive of a known type and covered with an anti-adhesive protective film.

109887/0279

On the remaining adhesive side, the transfer tape was then applied in such a way that the transferable Skin facing the adhesive and then its temporary carrier was turned outwards. On this carrier a metalloplastic sign was arranged according to Example 5 (height of the sign 35-nun, "pressure 11 kg / cm).

The resulting tape was then covered with a tape made of polyester, 50 mm wide and 25 microns Thick covered.

An adhesive label was obtained which had yellow imprints on a transparent background and could be attached to a receiving surface after the anti-adhesive protective film had been removed. ^v

Example 9

A transfer tape 150 mm wide was used prepared according to Example 6, and a pressure-sensitive Adhesive tape was made by removing one side of a tape of 150 mm white paper

_S was coated width and a weight of 70 g / m with an adhesive solution had the following composition which:

100 parts of polyisoprene, as it is commercially available under the name "Natsyn 2200",

10 parts of a petroleum resin, as it is under the name "Arkon 125" in the trade, and 500 parts of the essence "0".

After drying, the tape had a coating of a pressure sensitive adhesive with a

Weight of 20 g / m. .

The linear tack of this tape, measured according to the AFERA standards, was 60 centinewtons / cnu

The gripping ability, also according to these standards measured was 20 centinewtons / cm.

The transfer tape was then applied to the adhesive side xv, as in the previous examples

10988 770279

has been described. Then a metalloplastisch.es Character applied according to Example 6 (height of the character 80 mm, pressure 11 kg / cm).

The obtained tape was covered with a known tape made of transparent polyester adhesive of I50 mm width and 25 microns Di ..- do.

It v, \ j? De so received a paper label, which one had yellow imprints on a white background.

Second embodiment of the method Example 10

Into a mixer were introduced: 3 parts of ethyl cellulose, such as that which comes under the designation "Ethyl Cellulose N300" is commercially available, 8 parts of talc, like the one who si oh under the name "Sale 10 MGTO" is commercially available, 5 'parts white pigment, such as the one which is under the name "Blanc SynthScolor 55 ^" in 6 parts of wax such as that sold under the name "Cire Waxrex 31 E" 10 parts of resin, such as that sold under the name "Nevillac Soft", 28 parts of methyl ethyl ketone, 21 parts of isopropanol and 18 parts of the essence "C".

It was up to the complete dissolution of the ethyl cellulose kneaded, and then the mass was treated in a ball mill until a dye of great size Delicacy was preserved.

In order to produce a transfer belt 4- (Pig. 6), was using a Streichmeecers the dye obtained on the back of an adhesive tape 6 of 50 mm width and known type applied, the support of which was made of red metallized polyvinyl chloride and a thickness of 30 microns would have. The applied dye skin 5 had a weight after drying; of about 25 g / m.

109887/0279

A dye skin 5 was then applied to the resulting dye skin pressure-sensitive adhesive tape 3 of 55 mm width of this type applied that the adhesive 2 with the dye skin 5 came into contact. The pressure-sensitive adhesive tape used was from a backing 1 made of "cellophane" with a thickness of 30 microns formed with a pressure sensitive. Adhesive 2 was coated, which has an adhesiveness, measured according to the AlERA Kormen, from 300 centinewtons / cm and a grip strength of 5 centinewtons / cm as above has been described.

On the visible surface of the adhesive tape 3

a metalloplastic sign 7 was placed,

2 that has a height of 35 mm and an area of about 630 mm would have. A force of 70 kg was exerted on this symbol.

o practiced, which corresponded to a pressure of about 11 kg / cm, which allowed the cutting of the motif corresponding to the character in the dye house 5 and at the same time the attachment of this motif to & em pressure-sensitive adhesive 2. After the metalloplastic mark 7 had been removed, the adhesive tape 3 on which the cut-out motif was attached was removed.

In this way an adhesive label was obtained which had metallized red motifs on a white background exhibited.

Example 11

In a mixer were placed: 3 parts of ethyl cellulose, such as that which is commercially available under the name "Ethyl Cellulose N 300", 23 parts Talc, such as that sold under the name "Tale 10 MGTO", 5 parts of a blue Pigments such as that sold under the designation "Bleu Syntheeolor 1025", 8 parts of one Weiclmachers, like the one who goes by the designation "Dephenyl chlore DP 6" is commercially available, and 30 parts of isopropanol.

1 09887/0279

It was up to the complete dissolution of the ethyl cellulose shuffled, and then the measure was turned into one Treated ball mill until a dye of great fineness was obtained.

The dye obtained in this way was applied to one side of a fJ> at 6 using a doctor blade, which was made of polyvinyl chloride of fluorescent yellow color and was 70 microns thick, such that after drying a transferable from Color existing skin 5 was obtained, which is a weight

2
The other side of the skin 6 made of polyvinyl chloride had previously been coated with a layer 9 of a pressure-sensitive adhesive of a known type, which was then covered with an anti-stick skin 21 (^ Fig. 7).

The composite structure obtained was a strip of 50 now wide cut off.

An Xlebape 3 was applied to the dye skin 5 applied according to Example 10.

On the visible, non-adhesive side of the adhesive tape 3 »which was covered with the dye skin 5, a metalloplastic sign 8 was arranged, which

a height of. 35 mm and an area of about 630 mm would have. A force of 70 kg was exerted on this sign, which corresponded to a pressure of about 11 kg / cm, what the cutting of a motif 8 'corresponding to the character in the dye skin 5 and at the same time the attachment caused this motif on the pressure-sensitive adhesive. After removing the metalloplastic At the mark, the adhesive tape 2 on which the cut-out motif 8 was attached was removed (FIG. 7).

A colorless, transparent adhesive tape, 50 mm wide and of a known type, the backing of which consisted of a polyester 25 microns thick, was then applied to the tape thus obtained, ^{bearing an inscription 8 1, in order to form a protective skin.}

109887/0279

In this way, a pressure-sensitive adhesive label was obtained which had fluorescent yellow motifs on a blue background.

Example 12

Ef. A dye according to Example 11 was prepared.

Danr. was on the uncoated side of a pressure sensitive Adhesive tape, which has a width of 150 mm and had a support made of transparent polyethylene, a coating of the dye of 140 mm Width applied so that a free piece of 5 mm was left on each of the edges of the tape.

The dye coating was such that after Drying a deposit of about 25 g / m 2 was obtained.

The dye coating was applied according to Example 11 a pressure-sensitive adhesive tape 150 mm wide .

; On the visible side of the pressure-sensitive A metalloplastisch.es sign was placed on the adhesive tape, which has a height of 80 mm and an area of

ρ
had about 18 cm. There was a force upon this sign

ρ of 200 kg, which corresponded to a pressure of about 11 kg / cm, which means the simultaneous cutting of one of the Sign the corresponding motif into the dye skin and attach this motif to the pressure-sensitive Caused glue. After removing the metalloplastic The adhesive tape on which the cut-out motif was attached was removed.

A transparent and colorless adhesive tape of a known type was then applied to the tape carrying the print applied, which had a width of 150 mm and its Backing made of a polyester with a thickness of 25 microns existed to form a protective skin.

In this way an adhesive label was obtained which had transparent inscriptions on a blue background and had transparent spare parts at the top and bottom.

109887/0279

Example 13

First, a dye was prepared according to the example. Then on a 150 mm wide carrier 6 ¹ made of transparent polyethylene (FIG. 8), a skin 5 ^{1 made} of dye 150 mm wide was deposited by deposition. The deposition of the faber was such that, after drying, a coating of

about 25 g / m 2 was obtained.

In accordance with Example 11, a pressure-sensitive adhesive tape 150 mm wide was applied to the dye coating "upset.

Afterwards, a metalloplastic mark was made on the visible side of the pressure-sensitive adhesive tape arranged and this adhesive tape removed, as described in Example 12.

A mxt adhesive was then applied over pulls 24, 25 on both sides of the tape carrying the print transparent tape 23 (Fig. 8) applied, the adhesive material over train 25 on one side of the tape 23 adhered to the visible surface of the skin 5 '* carrying the printed motif while the adhesive was applied 24 carrying side of the tape 23 was covered with a * removable anti-adhesive skin 26, which allows the label to be affixed at the time of its use.

To apply such a label, it is sufficient to remove the anti-stick skin 26 before the Label is applied to a display surface ..

In this way a sign was obtained which had transparent inscriptions on a blue background wore.

It should be noted that the invention is not restricted to the exemplary embodiments selected which rather within the scope of the invention

109887/0279 ORIGINAL BATHROOM

changes can be made.

In particular, in the second embodiment of the invention, the type and appearance of the carrier transmissible skin can be modified in any way. For example, ar "3telle of printed Carriers as described in Examples: 10 to Ί3 were, also carriers of luminescent or iridescent color, metallic and wood-like carriers and pigmented, colored and variously printed supports or supports made of wood or metal are used which allow printing effects to be achieved that were previously impossible or difficult to achieve was.

It should also be noted that the components of the adhesive label can be selected so that the Overall structure a great persistence e; ep; 2ni "u ^ r high Temperature, radiation and weather influences.

The labels can be manufactured in dimensions that allow them to be used as signal boards.

109887/0279

Claims (1)

Claims 1. Process for the production of labels, panels, signs or other surfaces that display signs or - have motifs, characterized in that a first band is formed which has a carrier which is coated on at least one side with a layer of a pressure-sensitive adhesive that a second ■ Transfer tape is formed which has a carrier bearing a transferable skin that the two Tapes are combined so that the adhesive layer and the transferable skin are facing each other that then on this composite structure a predetermined one Motif is applied locally under a given pressure in such a way that the cutting of a corresponding Motif into the transferable skin and at the same time the transfer of the cut out motif to the adhesive layer is effected to which it adheres, and that thereafter the two initially formed ligaments from each other are separated, the tape carrying the print then optionally covered with a protective skin can be. 2. The method according to claim 1, characterized in that the motif on the composite structure on the Side of the carrier of the transferable skin is applied -and that then the second tape with the non-transferred Parts of the skin are removed. 3. The method according to claim 1, characterized in that that the motif is applied to the composite structure on the side of the carrier of the adhesive off layer and that afterwards the first band with the transferred parts of the skin is removed 109887/02 7 9 4. The method according to claim 2, characterized in that that the adhesive carrier used is one which is provided with adhesive on both sides, the one side receives a protective film which is removable at the time of use, while the other side takes up the transfer tape, which is removed after printing, with the printed adhesive side one absorbs transparent protective skin. 5. The method according to claim 2, characterized in that such is used as the adhesive carrier, the - is only provided with adhesive on one side, whereby the printed adhesive side takes up a protective film To form labels, signs or the like that can be inserted into metal devices. 6. The method according to claim 2, characterized in that such an adhesive is used as the adhesive iPrp ^ is only provided with adhesive on one side, and that the printed adhesive side is used for the Ensure attachment to a transparent surface. 7. Method uaoh claim 1, characterized in that that the protection of the side carrying the print is effected by means of a transparent skin, which is an adhesive May have side which is intended to be brought into a position facing the imprint in the cover to become. 8. The method according to claim 1, characterized in that as a pressure-sensitive adhesive material, which the adhesive layer, an adhesive composition is used which is selected from the group consisting of the following Substances include: polyurethanes, silicones, crosslinkable acrylic derivatives, polyvinyl ethers, natural rubbers, synthetic Rubbers or mixtures of them, to which adhesive resins, plasticizers or fillers may be added are. 109887/0279 9. The method according to claim 8, characterized in that that the pressure-sensitive adhesive material used is one which has a gripping power between 5 and 150 and preferably below 100 centinewtons / cm. 10. The method according to claim 8 or 9, characterized in that the pressure-sensitive adhesive material has an adhesive strength between +0 and 400 centinewtons / cm. 11. The method according to any one of claims 8 to 10, characterized in that the pressure-sensitive adhesive material one which has a low "tack" is used. 12. The method according to any one of claims 8 to 11, characterized in that a .solches as the adhesive material is used, which consists of a polyurethane adhesive, which consists of a mixture, which auo WauÄgstens a polyether polyol of high OH-Inde> and at least one polyether polyol of low OH index in such Is prepared proportions that the mean OH index of the mixture is between 50 and 100, at least a polyisocyanate, at least one catalyst, acrylic acid, optionally with the addition of adhesive resins, plasticizers or fillers. 13 · method according to one of claims 8 to 11, P characterized in that such an adhesive material is used, which is formed by acrylic derivatives, which are crosslinked in the presence of agents selected from the group comprising: peroxides, Amines, metal cations "and isocyanates, to which adhesive resins, plasticizers or fillers may be added are. 14 ·. Method according to one of Claims 8 to 11, characterized in that such a is used, which consists of at least one adhesive silicone that crosslinks in the presence of agents 109887/0279 selected from the group comprising peroxides, amines and metal cations optionally adhesive resins, plasticizers or fillers are added. 15 · The method according to any one of claims 8 to 11, characterized in that a that is used which consists of at least one polyvinyl ether, the optionally adhesive Resins, plasticizers or fillers are added * 16. The method according to any one of claims 8 to 11, characterized in that as an adhesive material such is used, which consists of natural and / or synthetic rubbers, which optionally adhesive resins, plasticizers or fillers are added. Are τwendet 17 · The method of any of claims 8 to 16, characterized in that adhesive resins _t ν · <?, The check ö.oj ^0? Cr-'appe are selected including rosin ester, petroleum resins, terpene resins, ketone resins, resinous esters or mixtures of these. -. ■ 18. The method according to any one of claims 8 to 17 »characterized in that a pressure-sensitive adhesive is used in which the amount of adhesive resin is between 0 and 50 % . 19 · The method according to any one of claims 8 to 18, characterized in that the carrier of the first Tape is coated with the pressure-sensitive adhesive material in an amount between 5 and 30 g. 20. The method according to claim 3 »characterized in that the carrier for the transferable skin is transparent. 21. The method according to claim 3, characterized in that the carrier for the transferable skin luminescent, iridescent, metallized, printed, pigmented or colored. 109887/0279 22. The method according to claim 3 »characterized in that the carrier for the transferable skin made of wood or metal. 23. The method according to any one of claims 1 to 3 » characterized in that the component of the carrier for the transferable skin is selected from the group which includes: styrene polymers or styrene copolymers, Polymers or copolymers of olefins, cellulose derivatives, polyvinyl acetate, polyvinyl esters or halides, polyesters, polycarbonates and papers. 24. The method according to any one of claims 3 and 20 to 23 »characterized in that as a carrier for the transferable skin is used that has a layer of pressure-sensitive adhesive on one side, which are removable with a sum of time of use Skin needf. 'Clcü is, and on the other hand the transmissible skin that wears after the abn & iirue of the first Tape takes up a transparent protective skin - 25. The method according to any one of claims 1 to 3, characterized in that a transferable skin is used which is made of an organic polymer, Plasticizers, fillers and / or pigments and / or waxes and resins. 26. The method according to claim 25, characterized in that that the organic polymer is selected from the group comprising: polyvinyl alcohols, polyvinyl ethers, Polyvinyl acetates, copolymers of Vinyl acetate and vinyl chloride, acrylic derivatives, nitrocelluloses, Cellulose acetates, cellulose acetobutyrates, methyl celluloses, ethyl celluloses, carboxymethyl celluloses, Styrene resins, polyurethanes and their mixtures. 109887/0279 27. The method according to claim 25, characterized in that that the plasticizers used are those which are usually used for plastic materials and which are selected from the group consisting of; Butyl, cyclohexyl or dioctylpb + halates, chlorinated di- and triphenyls,! T ^ i'trt / sylpliosphat and polymeric plasticizers, such as polyesters derived from sebacic acid and adipic acid, 28 · The method according to claim 23, characterized in that the transferable skin contains 30 to 300 % plasticizer in relation to the polymer. 29 · The method according to claim 25, characterized in that that fillers are used which are selected from the group consisting of talc, dolomite, Silica, mica, chalks, titanium oxide, zinc oxide, amidones and their mixtures. 30. The method according to claim 25, characterized in that that the transferable skin is 2 to 30 parts Contains fillers and / or pigments to 1 part of the polymer. 31. The method according to claim 25, characterized in that pigments are used which can be of a mineral » » organic or metallic type · 32. Piping according to claims 3 and 20, characterized in that the non-transferred parts of the skin are covered with an adhesive tape which is rarely provided with pressure-sensitive adhesive on both, and one side of which adheres to said parts and the other side accommodates a removable skin at the time of use. 33 transmission belt, characterized in that that there is a carrier according to any one of claims 20 to 109887/0279 24 and a transferable skin according to any one of the claims 25 to 31. 34. Labels, boards, signs or other! "Laugh that according to the method according to one of the claims; 1 to 32 are manufactured and on which display symbols or motifs see α en. 35. Labels, boards, signs or other Surfaces according to claim 34, characterized in that they present a surface which is more pressure sensitive Has adhesive for attachment to a receiving surface. 109887/0279 _pAD original NAL . * ⁵ · ♦ Blank page