DE202005010761U1 - Cosmetic composition, useful for decorative cosmetics e.g. in coloring, lips, eyelids, eyelashes and eyebrows, comprises a combination of water-soluble and lipid soluble active agent - Google Patents

Abstract

Cosmetic composition, useful for decorative cosmetics in coloring, beautifying and caring keratin fibers and skin, submucosa and mucous membranes, lips, eyelids, eyelashes and eyebrows, comprises a combination of water-soluble and lipid soluble active agent.

Description

The The invention relates to a preparation, in particular a cosmetic Preparation according to claim 1, especially in the form of a pencil or a smooth paste, which are for cosmetic applications, in particular in the field of decorative Cosmetics, for dyeing, beautify and maintaining keratinic materials such as e.g. of the skin, of semi-mucous membranes and mucous membranes, lips, eyelids, eyelashes and eyebrows and their environment, is suitable. Examples include lipstick, lip rouge, Cheek rouge, lipliner, eyeliners, eyebrow pencils, khol, kohl, Makeup, Effect Party Makeup, Hair Dye, Mascara, Hair Mascara, Concealer, concealer or eye shadow.

she Can also be used as a lip balm, lip balm, lip gloss, as a fixing basis for the lips, as a care base for the care of the skin or as a sunscreen be used. The preparation according to the invention preferably contains especially cosmetic preparation a combination of water-soluble, especially slightly water-soluble and lipid-soluble Active ingredients which are in the form of a specially tailored in the effect Complex of active ingredients, a so-called "active ingredient cocktail" may be present water-soluble "are thereby Active ingredients, of which at room temperature - ie at 23 +/- 2 ° C - at least Dissolve 10 g per 100 g of water to let. Preferably, the preparation, in particular cosmetic Preparation in anhydrous form before.

the People naturally inherit the desire, beautiful and attractive look as well as possible on his fellow human beings and vital to act. The beauty ideal is in the course of times a multiple change and the most diverse Fashion trends have been subjected - goal but man was always, at least, an immaculate ideal to get close. Besides clothes and ornaments, therefore, the look played and the condition of the skin and the appendages is an essential one Role. Already in ancient times, as from ancient Egyptian murals and known from grave finds, lay to man - especially the female Share - in it, the outside through to optimize creative color designs. In the past was the color effect - believes the analyzes of old finds - apparently a higher meaning attributed as the compatibility and today's toxicological considerations - probably true to the Motto: "Who be beautiful wants, must suffer. "National and international legal regulations have become more recent time for the consumer as dangerous recognized ingredients of such preparations eliminated.

Preparations of the type mentioned usually contain lipids, such as fats, oils, oil-soluble plant extracts, saturated line are and / or branched medium to long chain fatty alcohols with chain lengths between C ₆ and C ₄₀ , saturated linear and / or branched medium to long chain fatty acids Chain lengths between C ₆ and C ₄₀ or those having at least one double bond whose esters and waxes, which may be of vegetable or animal origin, derived from mineral sources, such as petroleum, or obtained by synthesis or chemical modification of said substances. Also known is the use of organosilicon compounds, such as dimethicones, phenyltrimethicones, diphenyldimethicones, volatile cyclomethicones, silicone waxes and the like and / or mixtures thereof.

Besides For example, a solid phase or solid phase may be included from finely divided fillers and coloring or mixtures thereof. In the case of sunscreen can particularly finely divided pigments, so-called nanopigments with an average Particle size between 5 and 25 nm, find application which have a transparent effect on the skin and do not color them anymore. Examples include silicon dioxide, titanium dioxide and Zinc oxide.

Known is also preparations, especially cosmetic preparations of the type mentioned, to add active ingredients that have positive topical effects exercise capital or at least one says such an effect. According to the legal Requirements for cosmetics must be the effect of such agents Although scientifically verifiable, they must not predominantly destined to alleviate or cure pathological conditions. The relevant engaged professional thus converts to a recognizable very narrow Burr and is required, very intense for suitable drugs for its purposes to do research and against mostly to delineate medicinal substances.

In the production and processing of preferably anhydrous and lipid-containing preparations of the type mentioned is to be considered that they can be exposed to higher temperatures in the range of 70 to 110 ° C for a long time - on the one hand, when the raw materials are melted and together with colorants and other Additives are homogenized and secondly, when they are in their final form to be brought. The raw materials used are not allowed to change chemically, or only to a very limited extent, by the action of heat and atmospheric oxygen. Raw materials of plant or animal origin, especially if they contain double bonds or conjugated double bonds in the carbon chain, tend to rearrange, build up, peroxide formation and the like, which can lead to negative odor changes. By the presence of certain pigments such changes can be induced or accelerated in the sense of a catalyst effect.

A The object of the invention was therefore, preferably anhydrous and lipid-containing preparation, in particular in the form of a stick or a supple paste suitable for cosmetic applications, especially in the field of decorative cosmetics, for dyeing and beautify keratinic materials such as e.g. of the skin, of semi-mucous membranes and mucous membranes, the lips and eyelids and their surroundings, lends itself easily can be applied, sticks well and lasts a long time, and from the original one Job location not or only minimally in the immediate area immigrate to provide. The preparation should - if they in pen form - at different storage temperatures, based on the different Transport routes and the user himself can give, storage stable be and - if It is present as a supple paste - no syneresis effects after prolonged storage demonstrate.

Further should this preparation be soft and supple, on keratinic materials such as e.g. the skin, the semi-mucous membranes and mucous membranes, do not tighten the lips and eyelids and do not dry them out stick well and persistently, if possible not on objects and textiles or other skin areas transmitted and in immediate eyes close Do not cause irritation or other negative sensations.

A Another object of the invention was the aforementioned preparation simultaneously with a selected one and in the intended effect balanced drug combination in the form of a "drug cocktail" equip and in its effect continues by cleverly selected lipidic herbal Ingredients to supplement. Ultimately, a preparation of the type mentioned should result, the in addition to decorative properties pronounced nourishing moments in the sense from sustained vitalizing, energizing, and microcirculation and thus has the substance transport of the skin stimulating effect. These Effects should ultimately positively influence the overall appearance of the skin, the fine structure of the skin surface improve, reduce the depth of wrinkles as well as fatigue and the counteract premature skin aging. In modern usage These intended effects are also called "vitalizing", "energizing", "anti-wrinkle" and "anti-age".

Suitable raw materials for the production of said preparations are, as already stated, lipids which are listed below with the names known to the person skilled in the art according to the "International Nomenclature of Cosmetic Ingredients" (the so-called INCI name) and which are also described in at least Examples include fats and oils of plant, animal, mineral or synthetic origin such as Hydrogenated Jojoba Oil, (Hydrogenated) Cottonseed Oil, (Hydrogenated) Castor Oil, (Hydrogenated) Vegetable Oil, (Hydrogenated) Rapeseed Oil , Hydrogenated Coconut Glycerides Hydrogenated Palm Kernel Oil Hydrogenated Sweet Almond Oil Hydrogenated Peanut Oil Magnifera Indica Mango Seed Oil Limnanthes Alba Meadowfoam Oil), Butyrosperum Parkii (Shea Butter), Macadamia Ternifolia Nut Oil (Macadamia Nut Oil), Buxus Chinensis Oil (Jojoba Oil), P ersea Gratissima Oil (Avocado Oil), Avocado Extract (Phytosterols and Persea Gratissima Oil), Calendula Oil, Hypericum Oil, (Hydrogenated) Stearyl Olive Esters, Theobroma Grandiflorum (Capuacu Butter), Shark Liver Oil, Squalane, Squalene, Caprylic / Capric Triglyceride , (Hydrogenated) Polybutene, Mineral Oil, oil-soluble plant extracts and mixtures of these substances. Of the medium to long-chain fatty alcohols with chain lengths between C ₆ and C ₄₀ , medium to long-chain fatty acids with chain lengths between C ₆ and C ₄₀ and their esters with a chain length between C ₆ and C _{40 of} the alcohol radical and with a chain length between C ₆ and C _{40 of} the carboxylic acid radical, have proven particularly advantageous, for example octyldodecanol, myristyloctadecanol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, melissinyl alcohol, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, erucic acid, Behenic Acid, Cerotinic Acid, Melissinic Acid, Isopropyl Myristate, Isopropyl Palmitate, Butyl Stearate, Hexyl Oleate, Myristyl Lactate, Myristyl Myristate, Myristyl Isostearate, Myristyl Stearate, Isostearyl Isostearate, Cetyl Palmitate, Behenyl Erucate, Behenyl Behenate, Behenyl Stearate, Behenyl Isostearate , C20-40 alkyl stearates and mixtures thereof. Among the waxes, Copernicia Cerifera (Carnauba), Euphorbia Cerifera (Candelilla Wax), Cera Alba (Beeswax), Rhus Succedanea Fruit Wax (Japan Wax), Oryza Sativa Bran Wax, (Rice Bran Wax), Ouricury Wax , Polyglyceryl-3 Beeswax (Cera Bellina), Synthetic Beeswax, Synthetic Wax, Polyethylene, Cera Microcristallina, Paraffin Wax, waxes from the Fischer-Tropsch synthesis and mixtures thereof.

The Amounts used at room temperature, i. at in the range of 23 +/- 2 ° C liquid lipid components, So on oils and liquid Esters and wax esters, lie in the range between 5 and 80 wt .-%, preferably in the range between 15 and 50% by weight, that at room temperature, at in the range of 23 +/- 2 ° C fixed Lipid components, ie fats, fatty alcohols, fatty acids whose Esters and waxes range between 1 and 65% by weight, preferably in the range between 5 and 45 wt .-%. The indication of the used and preferably used amounts, of course, with the proviso that itself the sum of all mentioned components one of the later still cited Recipes always supplemented to 100,000 wt .-%. The here and below cited Quantities can in some cases slightly under- or even exceeded and still preparations according to the invention to be obtained.

For the relevant Expert would come this in no way due to the large number of possible substances mentioned above unexpectedly - he know Therefore, in the event of such a shortfall or overshoot, the framework of the above invention would not leave.

One another constituent essential to the invention is a solid phase, which made of finely divided fillers and at least one colorant or a mixture of two or more colorants. Both coloring it is preferably inorganic and / or organic Pigments, insoluble in water and / or in the aforementioned lipid phase insoluble of organic dyes and / or glitter based on of coated mica, bismuth oxychloride, coated bismuth oxychloride, Glass, platelet-shaped, at least partially coated with other materials metal powders, at least partially coated with other materials finely divided Plastic plates, preferably PET platelets or solid solutions of dyes in suitable plastic matrices, preferably in Polyester. 3 In general, pigments are white or white Colored, inorganic or organic, in water and the respective Medium insoluble Understood particles that are to color and / or cloud the composition. It may be white or colored, inorganic and / or organic pigments in commercial size or with particle sizes in the nanometer range, the so-called "nanopigments." In this area In particular, alumina, titania, zinc oxide and ceria are to call. The choice of colorants takes place with the proviso that their use and the amount used in accordance with the Specifications by Appendix 3 of the Cosmetics Regulation for Germany is regulated, which on the for the European Union valid EC Directive is based. Comparable regulations are also available in Japan and in the U.S.A. dye should therefore be selected that they prefer the respective valid regulations worldwide correspond. Of the suitable colorants are exemplary called pigments such as titanium dioxide (C.I. No. 77891), iron oxides (C.I. 77491, 77492, 77499), ultramarine (C.I. No. 77007), Berliner Blue / Ferric Blue (C.I. No. 77510), carbon black / carbon Black (C.I. No. 77267) chrome oxide green (C.I. No. 77288), chromium oxide hydrate green (C.I. No. 77289), Manganese Violet (C.I. No. 77742), zinc oxide (C.I. No. 77947), barium sulfate (C.I. No. 77120), glitter such as e.g. Mica, at least partially coated with titanium dioxide (C.I. No. 77891) and / or with others Metal oxides, such as iron oxides, chrome oxide green or Chromoxidhydratgrün or with Ultramarine and the like coloring agents, Bismuth oxychloride and its mixtures with mica (C.I. No. 77163), at least partially coated with titanium dioxide and / or others the aforementioned metal oxides or other colorants, platelet-shaped, optionally finely divided Metal powder, e.g. Aluminum (C.I. No. 77000), copper (C.I. 77400), bronze (C.I. No. 77400), brass (C.I. No. 77400), silver (C.I. No. 77820) or gold (C.I. No. 77480). Become organic colorants favorably selected among the complex salts of carminic acid (C.I. No. 75470) and / or colorants, the selected were among the fluoresceins, monoazo dyes, disazo dyes, Indigotine dyes, pyrazole dyes, quinoline dyes, triphenylmethane dyes, Antraquinone dyes and xanthan dyes, which in suitable Insoluble by laking were made. Examples include FD & C Red no. 3 (C.I. 45430), D & C Red No. 6 (C.I. No. 15850), D & C Red No. 7 (C.I. No. 15850: 1), D & C Red No. 21 (C.I. No. 45380: 2), D & C Red No. 22 (C.I. No. 45380), D & C Red 27 (C.I. No. 45410: 1), D & C Red 28 (C.I. No. 45410), D & C Red 30 (C.I. No. 73630), D & C Red No. 33 (C.I. No. 17200), D & C Red No. 34 (C.I. No. 15880: 1), FD & C Yellow No. 5, (C.I. No. 19140), FD & C. 7 (C.I. No. 45350: 1), D & C Yellow no. 10 (C.I. No. 47005), D & C Orange No. 5 (C.I. No. 45370: 1), D & C Orange No. 10 (C.I. No. 45425: 1), FD & C Green no. 3 (C.I. No. 42053), D & C Green No. 5 (C.I. No. 61570), D & C Green No. 6 (C.I. No. 61565), FD & C Blue No.1 (C.I. No. 42090), D & C Violet No. 2 (C.I. No. 60725).

Provided these colorants not as insoluble Liquids application can find they also in the form of solid solutions find use in plastics. Well known and cheap in the trade available are such solid solutions, which intensively fluoresce in long-wave UV light, so-called "black light", e.g. under the INCI name "Polyester-3, Red 22 "," Polyester-3, Red 28 "," Polyester-3, Yellow 10 "or" Polyester-3, Blue 1 ", where too Mixtures of these solid solutions optionally also be used with other of the aforementioned colorants can.

The Use amount of said colorants is - ever after desired Effect and the kind of the desired Product between 0.1 and 50 wt .-%, preferably between 1 and 40 Wt .-% and most preferably between 5 and 30 wt .-%. The The amount used depends on the one hand on the color intensity of the used Pigments and on the other hand also after the later technology for the production the desired Products.

Next the aforementioned colorants the preparation, in particular cosmetic preparation in the solid phase still fillers such as. Talc, kaolin, silicas, Alumina, which may possibly also be in amorphous form, Strength, modified starch, Polytetrafluoroethylene powder ("Teflon"), polyamide powder, polyethylene powder, Polypropylene powder and other polymer powder, boron nitride, insoluble Metallic soaps such as Mg stearate, Ca stearate, Sr stearate, Zn stearate or mixtures of these substances. These finely divided or fibrous fillers, in general particle sizes between 0.1 and 10 μm are used in amounts between 0.1 and 25 wt .-%, preferably between 1 and 12% by weight. In addition, even in cosmetics conventional additives like synthetic or natural Fibers such as e.g. those of polyamides, polyesters, elastanes, polyacrylonitrile, Rayon, viscose, artificial silk, silk, wool, cotton, linen, cellulose or mixtures thereof, antioxidants, preservatives, fragrance mixtures, defoamers, Thickener, dispersing agent, emollient light stabilizer for the purpose of product protection or as protection of the human body before the harmful ones Effects of UV-A and UV-B radiation in sunlight and the like be used.

When particularly essential to the invention component contains the aforementioned preparation, in particular cosmetic preparation, which, as already stated above, as lipid-based and anhydrous mixture is present, as well Anhydrous combination of slightly water-soluble active ingredients with lipid-based Active ingredients and lipidic plant extracts in the form of a special coordinated active ingredient complex, ie a so-called "Vitalisierungskomplexes", the "active ingredient cocktail" with revitalizing, Energizing, wrinkling and visible signs the skin aging counteracting properties. As special preferably a combination of (slightly water-soluble) Magnesium Aspartate, Zinc Gluconate, Copper Gluconate, Sodium Ascorbyl Phosphates and Sodium Hyaluronate with the lipid-based extracts of Echium Plantagineum (Natterhead) with Cardiospermum Halicacabum (Balloon vine) and Helianthus annuus (Sunflower) and with tocopheryl Nicotinates proved. As this drug combination surprisingly a Effect showed that significantly over the effects of the individual substances went out, this "active substance cocktail" by a synergistic Cooperation be assumed.

magnesium Aspartate, Zinc Gluconate and Copper Gluconate act as energy donating and revitalizing and at the same time provide the skin with important benefits Trace Elements, Sodium Ascorbyl Phosphate is one over one longer Period storage-stable form of vitamin C - it acts as a radical scavenger, acts Wrinkling and the visible signs of aging and promotes the collagen synthesis in the tissue. Sodium hyaluronate is considered very effective moisturizer, thus reducing the depth of wrinkles and has a regenerating effect.

The Esters of nicotinic acid promote blood circulation - but can quite connected to a perceived as unpleasant hot flush with intense skin reddening, to lead. Esters such as ethyl nicotinate or benzyl nicotinate are outstanding Moreover, not by a special fragrance. A much milder effect on the other hand shows the tocopheryl nicotinate, which also as radical scavenger and Antioxidant is used and prefers the microcirculation in stimulates the upper layers of the skin. The combination of Echium Plantagineum (Natter head) with Cardiospermum Halicacabum (balloon vine) and Helianthus Annuus (sunflower) has a cell regenerating, balancing and harmonizing effect and serves as a very good skin protection.

The amounts of the aforementioned active ingredients in the finished product, based on the total amount of the preparation, are between 0.01 and 1.5% by weight for magnesium aspartates and zinc gluconates, and between 0.001 and 0.5% by weight for copper gluconates and sodium hyaluronates. %, for sodium ascorbyl phosphates between 0.1 and 10% by weight, for tocopheryl nicotinates between 0.01 and 2.0% by weight and for the lipidic combination of Echium Plantagineum (natterhead) with Cardiospermum halicacabum (balloon vine) and Helianthus annuus (sunflower) between 0.1 and 15% by weight. Preferably, the extraction of the plant material is carried out with a triglyceride such as Sesame Oil, Rapeseed Oil, Sunflower Oil or Caprylic / Capric Triglyceride or with Octyldodecanol, Hexyl Oleate, Jojoba Oil or mixtures thereof. It is essential to the invention that the constituents of the active ingredient complex are also present in the intended amount in the ready-to-use preparation - it is irrelevant whether they are weighed into individual portions and added individually to the mixture to be prepared or if two premixes are used to minimize the error and to improve the production process. a liquid phase containing the lipid-soluble constituents and a solid phase, which contains the water-soluble constituents in undissolved, ie solid form. Experience has shown that such a variation is of no importance for the finished end product.

The Tasks are solved by first entering Conventionally, from a suitable lipid phase and a just such a solid phase, a preparation, in particular a cosmetic Prepared for the preparation of products in Pen shape or in the form of supple pastes which are suitable for cosmetic Applications, in particular in the field of decorative cosmetics, for To dye, beautify and maintaining keratinic materials such as e.g. of the skin, of semi-mucous membranes and mucous membranes, the Lips and eyelids and their surroundings, and then these with a combination of slightly water-soluble and lipid-soluble Active ingredients which are in the form of a specially tailored in the effect Complex of active substances may be present equips to the preparation of the invention in addition to decorative properties pronounced nourishing moments in the sense from sustained vitalizing, energizing, and microcirculation and thus has the substance transport of the skin stimulating effect. These effects are intended to ultimately make the overall picture of the skin positive affect the fine structure of the skin surface improve the wrinkle depth reduce fatigue and fatigue and counteract the premature aging of the skin. Lipid-soluble active ingredients Naturally, they are very easy to do incorporate into a lipidic phase. Surprisingly, now found that also water-soluble, especially light water-soluble Active ingredients good and even - similar to the aforementioned solid phase in undissolved, ie in solid form - in one incorporate lipidic phase. To the slightly water-soluble active ingredients but to release it again requires moisture, which in the microclimate the skin, in the form of transpiration or steam is. It is advantageous that the aforementioned, water-soluble Active ingredients can develop a depot effect in this way, since they move from train to train by the action of moisture Removed lipid film become. Thus they stand over a longer one Period available in sufficient quantity until the reservoir is used up is. Examples include lipstick, lip rouge, cheek rouge, Lipliner, eyeliners, eyebrow pencils, hair dyeing pencils, kohl, kohl, make-up Pens, Concealer, Concealer, Effect Party Makeup, Mascara, Hair mascara or eye shadow. It can also be used as a lip balm, Lip balm, lip gloss, as a fixing foundation for the lips, as Care for the care of the skin or as a sunscreen be used.

In principle, it is possible to produce a preparation, in particular a cosmetic preparation anhydrous and lipid-based by melting the lipid components in a suitable vessel at elevated temperature, adding the solid phase by means of a high-speed stirrer and this mixture as needed once or more times by a homogenizer such as three-roll mill , Corundum disk mill, colloid mill (with heatable jacket) or kneading devices happened. In one part of the preparation, the anhydrous "cocktail of active ingredients" is incorporated and later homogenized together with the main portion of the preparation.If the preparation contains glitter, they are added only before the last passage of the three-roll mill.Aluminum disc mill or colloid mill prohibit homogenization in this particular case The preparation thus obtained can then be extruded in the usual way into mine strands which are cut to the required extent and further processed in the manner known from the manufacture of pencils into cosmetic pencils which comprise a casing made of wood, a wood substitute or a wood produced in a known manner These pins can be sharpened in a conventional manner with a commercial sharpener by machining their sleeves machined.The mine sections can also be in suitable turning mechanisms, as they are made DE 37 28 427 C2 are known or transparent sleeves, according to EP 1 464 248 A1 , be plugged. But is also known, such a preparation at elevated temperature and in the liquid state according to the in EP 0 310 799 B1 or DE 44 45 230 C2 or 44 45 231 C2 or EP 1 150 588 B1 or US 6,206,597 to introduce it into a suitable turning mechanism. If such a preparation, in particular cosmetic preparation provided in the form of a supple paste, it may, for example, in an applicator according to US 6,238,117 or EP 1 419 118 A1 or EP 1 468 937 A1 or DE 20 2004 004 567 U1 filled and metered from it and applied as needed. But they can also be filled at elevated temperature and in a liquid state in a tube or a crucible or a suitable pans made of metal. If these products are produced in the form of a mascara or hair mascara, then you are in the usual way in the provided, transparent or colored in the color of the mass or the "house color" of the provider filled containers containing a removable cap with a inserted therein Having attached to a handle applicator element.

The preparation according to the invention, in particular cosmetic preparation, will now be explained in detail with reference to the following examples, which, however, do not exhaustively describe or limit them. The quantities are given in weight percent (wt .-%), based in each case on the total weight of the preparation, the description of the raw materials is carried out with the relevant subject Generally known "INCI names." Example 1 (vitalizing active complex) Active substance complex lipid phase 1.1 Tocopheryl nicotinates 10,000 Octyldodecanol + Echium Plantagineum + Cardiospermurn Halicacabum + Helianthus annuus 90,000 Active substance complex solid phase 1.2 Magnesium Aspartates 8,000 Zinc Gluconate 5,500 Copper gluconate 0.900 Sodium ascorbyl phosphate 81.100 Sodium hyaluronate 4,500

Example 2 (Eyeliner)

To prepare the preparation, the ingredients of the phase (A) are placed in a suitable vessel and clearly melted with heating, then the ingredients of the phase (C) with good stirring with a sprocket or the like. Dispersed therein. This mixture is now passed twice through a three-roll mill. The components of the phase (D) are now distributed as evenly as possible over the rolling stock, this mixed again and passed through the three-roll chair again. The resulting mixture is then melted again in a vacuum process plant with heating, then the cyclopentasiloxane and the dimethicone and finally the active complex lipid phase 1.2 are added. The mixture is briefly homogenized, vented and filled into tightly closed storage containers or provided directly for hot filling in rotary mechanisms. The result is a blue-green mine with light pearlescent, which can be very easily and evenly applied to the edge of the lid, where it adheres well and extremely long, does not emigrate from the job site and can be easily removed with a commercial make-up remover. With multiple applications of this eyeliners, the skin is in the sense of vitalization excited. Increasing the microcirculation improves the mass transfer, the fine structure of the skin surface by reducing the wrinkle depth and smoothing the fine wrinkles. The preparation thus counteracts premature skin aging.

Example 3 (Eyeliner)

The Production of the preparation and processing takes place in analogy for example 2. One receives one in the casting process moss-green to be produced Mine, which can be very easily and evenly applied to the edge of the lid, there good and extraordinary is liable for a long time, does not emigrate from the place of work and settles with one commercial Make-up remover easily removed again. For multiple use This eyeliner stimulates the skin in the sense of a vitalization. By increasing the microcirculation, the mass transfer improves, the fine structure of the skin surface by reducing the depth of wrinkles and smoothing the fine folding. The preparation thus counteracts premature skin aging.

Example 4 (Lipliner)

to Preparation of the preparation is the phase (A) in a suitable Vessel under Heat clearly melted. Then with stirring with a sprocket stirrer Phase (C) homogeneously incorporated. The mixture is now going through twice passed a three-roll chair. The phase (B) is optionally homogeneous with gentle heating solved and distributed homogeneously over the rolling stock together with the phase (D). After that will the approach again passed through a three-roll chair. The crowd is now pressed to an extrudable body and thereby vented and subsequently under high pressure - at 40 to 60 MPa (400 to 600 bar) - pressed into strands that are cut to length and be processed in a known manner to wood pencils. You get a brownish red mine with good opacity, which works well on the lip edge can be applied, does not blur, long sticks, not on objects or transfers other materials and not walk away from the job site into finer skin folds. With multiple Application of this lipliner is the skin in the sense of a vitalization stimulated. By increasing the microcirculation improves the mass transfer, the fine structure of the skin surface Reduction in wrinkle depth and smoothing fine-tuning. The preparation thus counteracts premature skin aging.

Example 5 (Lipliner)

to Preparation of the preparation are the components of phase (A) under heating and stirring melted, Care must be taken to ensure that the trimethylsiloxysilicate Completely dissolves in the lipid phase. It then sets the components of the solid phase (C) and works stirring them homogeneous. The mixture is now passed twice through a three-roll mill happens. The phase (D) is now as evenly as possible over the Walzgut distributed, then the approach again by a three-roll chair happens and then again in a suitable vessel under Heat melted. Meanwhile, the components of phase (B) dissolved in cyclopentasiloxane, then the phase (B) is combined with the batch and stirred well. The The resulting mixture can then be mixed with appropriate equipment be poured into the above-described rotary mechanisms. You get one red mine with a slight brownish hue and good opacity which are very good and even apply the lip border, not blurred, very long liable, not on objects or transfers other materials and not walk away from the job site into finer skin folds. With multiple Application of this lipliner is the skin in the sense of a vitalization stimulated. By increasing the microcirculation improves the mass transfer, the fine structure of the skin surface Reduction in wrinkle depth and smoothing fine-tuning. The preparation thus counteracts premature skin aging.

Example 6 (creamy lip gloss)

Example 6 (cream lip gloss) - continue

To prepare the preparation, the components of the phase (A) are melted under heating and stirring in a suitable vessel, it being important to ensure that the trimethylsiloxysilicate dissolves completely in the lipid phase. Now take about one-quarter of this lipid phase and stir in the D & C Red 7, passing this mixture twice through a three-roll mill. Now spread the phase (D) as evenly as possible on the rolling stock, mix and pass this amount again through a three-roll mill and combines the rolling stock with the molten residue of the phase (A). Now sprinkle the pearl pigment with good stirring. In the meantime, all components of phase (B) were dissolved in isododecane. The cyclopentasiloxane is now added and the phase (B) is added to the batch with stirring. The mixture is then cooled with gentle stirring from the approach to about 35-40 ° C to prevent settling of the colorants and transferred the mass in tightly closed storage containers to bswp later. in application devices accordingly US 6,238,117 or EP 1 419 118 A1 fill and apply. The result is a creamy, glossy lip gloss, which can be applied very light and evenly and - with the listed devices - even sharp contours on the skin of the lips, where it remains long-lasting and does not emigrate from the job site. With multiple applications of this lip gloss the skin is stimulated in the sense of a vitalization. Increasing the microcirculation improves the mass transfer, the fine structure of the skin surface by reducing the wrinkle depth and smoothing the fine wrinkles. The preparation thus counteracts premature skin aging.

Example 7 (lip balm with sunscreen)

Example 7 (lip balm with sunscreen) - continue

to Preparation of the preparation is the phase (A) in a suitable Vessel melted. It takes about a quarter of it, mixed in the colorants phase (C) with the exception of the pearlescing agent and passes twice through a three-roll chair. Now you scatter the phase (D) and the pearl pigment as possible evenly over that Walzgut and happens again over a three-roll chair. In the meantime, the ingredients became the phase (B) dissolved in the isodecane. Now united with the rolling stock the rest of the phase (A) and now sets the homogeneous mixture of the phase (B) too. You fill Now the finished mixture in tightly closed storage containers or leads They directly to further processing. The mass is preferred for bottling in known spindle mechanics - they But it can also be used in lipstick making Way to mine casting be processed by machine or by hand in suitable rotary mechanisms be used. For multiple use of this lip balm The skin is stimulated in the sense of a vitalization. By the increase the microcirculation improves the mass transfer, the fine structure the skin surface by reducing the depth of wrinkles and smoothing the fine folding. The Preparation thus counteracts premature skin aging.

Claims (38)

Preparation, in particular cosmetic preparation, which are suitable for cosmetic applications, particularly in the field of decorative cosmetics, for dyeing, Beautify and care of keratin materials such as the skin, semi-mucous membranes and mucous membranes, lips, eyelids, eyelashes and eyebrows, characterized in that in that it contains a combination of water-soluble and lipid-soluble active substances. Preparation according to claim 1, characterized in that the water-soluble active substances are readily soluble in water and that their solubility at least 10 g per 100 g of water. Preparation according to claim 1 or 2, characterized in that the combination of water-soluble, especially slightly water-soluble and lipid-soluble Active ingredients in the form of a specially tailored complex of active substances, a so-called "active ingredient cocktail" is present. Preparation according to one of the preceding claims, characterized characterized in that the slightly water-soluble active ingredients of the active substance complex in the form of an anhydrous combination. Preparation according to claim 3 or 4, characterized that the drug complex is a combination of magnesium aspartates, Zinc Gluconate, Copper Gluconate, Sodium Ascorbyl Phosphate and Sodium hyaluronate as slightly water-soluble active ingredients and lipid-based Extracts of Echium Plantagineum (Natterhead), Cardiospermum halicacabum (Balloon Vine) and Helianthus Annuus (Sunflower) and tocopheryl Nicotinates as lipid-soluble Active ingredients. Preparation according to claim 3 or 4, characterized in that the amount used of the active ingredients Magnesium aspartates and zinc gluconates between 0.01 and 1.5 wt .-%, based on the total weight of the preparation is. Preparation according to Claim 3, 4 or 5, characterized that the amount of the active ingredients Copper Gluconate and Sodium Hyaluronates between 0.001 and 0.5 wt .-%, based on the total weight of Preparation is. Preparation according to Claim 3, 4 or 5, characterized that the amount of active ingredient sodium ascorbyl phosphates between 0.1 and 10% by weight, based on the total weight of the preparation. Preparation according to Claim 3, 4 or 5, characterized that the amount of the active ingredient tocopherol nicotinate between 0.01 and 2.0% by weight, based on the total weight of the preparation, is. Preparation according to Claim 3, 4 or 5, characterized that the amount of active substance Echium Plantagineum (Natterkopf), Cardiospermum Halicacabum (Balloon Vine and Helianthus Annuus (Sunflower) between 0.1 and 15% by weight, based on the total weight of the preparation, is. Preparation according to Claim 3, 4 or 5, characterized that the slightly water-soluble Constituents of the active substance complex, prepared in the form of a premix, present in the preparation. Preparation according to Claim 3, 4 or 5, characterized that the components of the active substance complex, in single portions weighed and added individually to the mixture to be prepared. Preparation according to one of the preceding claims, characterized in that it is in the form of a pen. Preparation according to one of the preceding claims 1 to 12, characterized in that they are in the form of a supple Paste is present. Preparation according to one of the preceding claims, characterized in that it is in anhydrous form. Preparation according to one of the preceding claims, characterized in that it comprises at least one lipid phase and contains a solid phase. Preparation according to one of the preceding claims, characterized in that the lipid phase is selected from fats, oils, oil-soluble plant extracts, saturated linear and / or branched chain medium to long-chain fatty alcohols saturated linear and / or branched medium to long-chain fatty acids with chain lengths between C ₆ and C ₄₀ , or those having at least one double bond and / or their esters and / or waxes and / or mixtures thereof. Preparation according to one of the preceding claims, characterized in that the liquid at room temperature lipid components in the range between 5 and 80 wt .-%, preferably in the range between 15 and 50 wt .-% are used. Preparation according to one of the preceding claims, characterized in that the solid at room temperature lipid components in the range between 1 and 65 wt .-%, preferably in the range between 5 and 45 wt .-% are used. Preparation according to one of the preceding claims, characterized in that the solid phase of finely divided fillers and at least one colorant or mixtures thereof. Preparation according to one of the preceding claims, characterized in that the finely divided fillers of the solid phase selected were talc, kaolin, starch, modified starch, Polytetrafluoroethylene powder ("Teflon"), polyamide powder, Polyethylene powder, polypropylene powder and other polymer powders, Boron nitride, insoluble Metallic soaps such as Mg stearate, Ca stearate, Sr stearate, Zn stearate or mixtures of these substances. Preparation according to one of the preceding claims, characterized in that in addition to a lipid phase and a Solid phase optionally still in cosmetics usual additives such as synthetic or natural Fibers, e.g. those made of polyamides, polyesters, elastane, Polyacrylonitrile, rayon, viscose, rayon, silk, wool, cotton, Linen, cellulose or mixtures thereof, antioxidants, preservatives, Fragrance mixtures, defoamers, Thickeners, dispersing agents, emollients, light stabilizers or mixtures thereof. Preparation according to one of the preceding claims, characterized in that the colorants of the solid phase selected were under inorganic and / or organic pigments, in water or insoluble in the lipid phase Laking organic dyes and / or glitter on Base of coated mica, bismuth oxychloride, coated Bismuth oxychloride, glass, platy, at least partially coated with other materials metal powders, at least partially coated with other materials finely divided plastic platelets, preferably PET platelets or solid solutions of Dyes in suitable plastic matrices, preferably in polyester-3 and mixtures of the aforementioned colorants. Preparation according to claim 23, characterized in that it is in the solid solutions of dyes in polyester-3 to fluoresce intensively in long-wave UV light solid solutions is. Preparation according to one the claims 23 or 24, characterized in that these in the long-wave UV light strongly fluorescent solid solutions selected were under "polyester-3, Red 22 "," Polyester-3, Red 28 "," Polyester-3, Yellow 10 "or" Polyester-3, Blue 1 ", possibly also in mixtures with other of the aforementioned colorants. Preparation according to one of the preceding claims 21 to 25, characterized in that the colorants in an amount between 0.1 and 45 wt .-%, preferably in an amount between 1 and 40 wt .-% and most preferably in an amount between 5 and 30 wt .-% be used. Preparation according to one of the preceding claims 21 to 26, characterized in that the finely divided fillers the solid phase in an amount between 0.1 and 25 wt .-%, preferably in an amount between 1 and 12 wt .-% are used. Preparation according to one of the preceding claims, characterized in that it is in the form of a cast mine. Preparation according to one of the preceding claims, characterized in that it is in the form of an extruded mine is present. Preparation according to claim 28 or 29, characterized in that they are in the rotary mechanism a pivot pin is introduced. Preparation according to claim 28 or 29, characterized in that the mine from a sleeve of wood, a wooden substitute or a plastic is surrounded. Preparation according to claim 28 or 29, characterized in that the sleeve of a machined made of sharpenable material. Preparation according to claim 14, characterized in that they are introduced into a dispenser mechanism is. Preparation according to claim 14, characterized in that it is filled into a tube or a crucible. Preparation according to claim 14, characterized in that it is filled into a pan of metal. Preparation according to one the claims 1 to 33, characterized in that they are in the form of a cosmetic pencil is present. Composition according to Claim 36, characterized in that it is a lipstick, Lipliner, eyeliner, eyeshadow, kohl, kohl, eyebrow pencil, concealer, cheek rouge, make-up pen or hair dye. A preparation according to any one of claims 14, 33, 34 or 35, characterized characterized in that it is a lip rouge, cheek rouge, Make-up, effect party makeup, mascara, hair mascara, concealer or Eye shadow acts.