DE20144C - Innovation in the alcohol cleaning process - Google Patents
Innovation in the alcohol cleaning processInfo
- Publication number
- DE20144C DE20144C DENDAT20144D DE20144DA DE20144C DE 20144 C DE20144 C DE 20144C DE NDAT20144 D DENDAT20144 D DE NDAT20144D DE 20144D A DE20144D A DE 20144DA DE 20144 C DE20144 C DE 20144C
- Authority
- DE
- Germany
- Prior art keywords
- iron
- innovation
- cleaning process
- potash
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims description 6
- 238000004140 cleaning Methods 0.000 title description 3
- 238000000034 method Methods 0.000 title description 2
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 7
- 229940072033 potash Drugs 0.000 claims description 7
- 235000015320 potassium carbonate Nutrition 0.000 claims description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000005530 etching Methods 0.000 claims description 2
- 230000001590 oxidative Effects 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 229910052742 iron Inorganic materials 0.000 description 10
- 239000003610 charcoal Substances 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000003313 weakening Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/001—Processes specially adapted for distillation or rectification of fermented solutions
- B01D3/003—Rectification of spirit
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
Das Haupt-Patent bezieht sich darauf, die zur Absorption der im Rohspiritus enthaltenen Verunreinigungen dienende Holzkohle durch poröse Metalle zu ersetzen, besonders durch Bohr-, Hobel- oder Drehspäne der verschiedenen Gufseisenarten. Diese porösen Metalle erlahmen in ihrer Wirkung nicht so bald, als die Holzkohle und lassen sich bei eingetretener Erschöpfung auf einfachere und weniger kostspielige Weise wieder beleben. Auch ist die bei Anwendung von Holzkohle unerläfsliche Verdiinnung des Rohspiritus auf 50° Tr. bei Anwendung des neuen Filtermaterials nicht mehr erforderlich.The main patent relates to the absorption of the raw alcohol contained Replace contaminants with charcoal with porous metals, especially with Drilling, planing or turning chips of the various types of cast iron. These porous metals are weakening in their effect not as soon as the charcoal and when exhausted revive in a simpler and less costly way. Thinning is also indispensable when using charcoal of the raw alcohol to 50 ° Tr. when using the new filter material no longer necessary.
Da die porösen Metalle, wie die Industrie sie liefert, jedoch niemals rein sind, sondern stets Verunreinigungen enthalten, so ist es nothwendig, dieselben vor dem Gebrauch zu präpariren, um den schädlichen Einflufs der Verunreinigungen zu paralysiren. Die Präparation bildet den Inhalt der hiermit vorliegenden Neuerung an dem unter P. R. No. 17924 patentirten Spiritus-Reinigungsverfahren. Da die Anwendung von porösem Eisen zum Zweck der Alkoholreinigung bereits im grofsen Mafse ausgeführt wird, ist die hier weiterhin beschriebene Behandlung der porösen Metalle, namentlich für Eisen, von Wichtigkeit.Since the porous metals as supplied by industry are never pure, but always Contain impurities, it is necessary to prepare them before use, to paralyze the harmful influence of impurities. The preparation forms the content of the innovation presented here on the basis of P. R. No. 17924 patented Spirit cleaning process. As the application of porous iron for the purpose of alcohol cleaning is already carried out to a large extent, is the treatment further described here of porous metals, especially iron, of importance.
Das Gufseisen enthält stets Schwefel, Phosphor, Silicium u. a. m. Diese Elemente gehen im Contact mit Spiritus leicht Verbindungen ein, welche einen sehr üblen Geruch besitzen. Die Bildung dieser übelriechenden Verbindungen wird aber vermieden, wenn das Eisen vor dem Gebrauch mit übermangansaurem Kali behandelt worden ist, wodurch gleichzeitig, noch die Wirkungsfähigkeit des Eisens bedeutend vermehrt wird. Das übermangansaure Kali zerstört durch Oxydiren die an der Oberfläche des Eisens befindlichen genannten Verunreinigungen. Dabei wird nun auch die wirkende Oberfläche des porösen Eisens durch Anätzung vergröfsert und somit gewissermafsen die Porosität vermehrt.The cast iron always contains sulfur, phosphorus, silicon and others. m. These items go in contact with alcohol it easily incorporates compounds which have a very bad odor. The formation of these malodorous compounds is avoided if the iron before Use has been treated with super-manganese acid potash, which, at the same time, still has the Effectiveness of iron is significantly increased. The over-manganese acid potash destroyed by oxidizing the impurities mentioned on the surface of the iron. The effective surface of the porous iron is now enlarged by etching and thus, to a certain extent, increases the porosity.
Die Präparation des Filtermaterials geschieht nun in der Weise, dafs man dasselbe in den Filtern selbst mit einer Lösung von übermangansaurem Kali übergiefst und wartet, bis die rothe Lösung entfärbt worden ist. Ist die Entfärbung eingetreten, dann ist die Einwirkung des Übermangansauren Kalis auf das Eisen beendet; man wäscht alsdann mit reinem Wasser das in den Filtern befindliche präparirte Material so lange; bis das Waschwasser nicht mehr alkalisch reagirt.The preparation of the filter material is now carried out in such a way that the same is done in the Filter yourself doused with a solution of super-manganese potash and wait until the red solution has been decolorized. If the discoloration has occurred, then the action is the over-manganese potash on the iron finished; it is then washed with pure water the prepared material in the filters for so long; until the wash water is no more reacts alkaline.
Für 100 kg Eisen werden je nach Qualität desselben 1 bis ζ kg übermangansaures Kali verwendet.For 100 kg of iron, depending on its quality, 1 to ζ kg of super-manganese potash is required used.
Läfst die Wirkung des porösen Eisens auf den Spiritus mit der Zeit etwas nach und zeigtThe effect of the porous iron on the spirit diminishes somewhat over time and shows
sich von neuem die Bildung übelriechender Substanzen, dann kann das Eisen durch Wiederholung der beschriebenen Behandlung leicht regenerirt werden.If the formation of malodorous substances occurs anew, then the iron can through repetition easily regenerated after the treatment described.
Claims (1)
Die Wiederbelebung des erschöpften, aus porösem Metall bestehenden Filtermaterials durch die Behandlung desselben mit übermangansaurem Kali.i. The preparation of the porous metals for their use as filter material in alcohol rectification by oxidizing the impurities in the metal and by etching the metal surfaces themselves by means of a solution of super-manganese potash.
The revitalization of the exhausted, porous metal filter material by treating it with super-manganese potash.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE20144C true DE20144C (en) |
Family
ID=296914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT20144D Active DE20144C (en) | Innovation in the alcohol cleaning process |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE20144C (en) |
-
0
- DE DENDAT20144D patent/DE20144C/en active Active
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