DE19962865C1 - Shaped polymer foam component for sound absorption purposes in automobiles is provided with perforations in its compacted surface layer - Google Patents
Shaped polymer foam component for sound absorption purposes in automobiles is provided with perforations in its compacted surface layerInfo
- Publication number
- DE19962865C1 DE19962865C1 DE19962865A DE19962865A DE19962865C1 DE 19962865 C1 DE19962865 C1 DE 19962865C1 DE 19962865 A DE19962865 A DE 19962865A DE 19962865 A DE19962865 A DE 19962865A DE 19962865 C1 DE19962865 C1 DE 19962865C1
- Authority
- DE
- Germany
- Prior art keywords
- sound absorption
- perforations
- polymer foam
- automobiles
- surface layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/34—Chemical features in the manufacture of articles consisting of a foamed macromolecular core and a macromolecular surface layer having a higher density than the core
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/172—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general using resonance effects
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/162—Selection of materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2350/00—Acoustic or vibration damping material
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Multimedia (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Soundproofing, Sound Blocking, And Sound Damping (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Die Erfindung betrifft Polymerschaum-Formteile mit erhöhtem Schallabsorptionsver mögen.The invention relates to polymer foam molded parts with increased sound absorption to like.
Polymerschaum-Formteile, insbesondere auch Polyurethanschaum-Formteile, wer den vielfältig zur Gehäuseisolation von Apparaten, insbesondere auch im Kraftfahr zeugbereich, beispielsweise als Kofferraumabdeckungen, Längssäulenabdeckungen usw. eingesetzt. Die Formschaumteile sind dabei im allgemeinen flächig ausgedehnt bei einer Dicke des Formschaumteils von 0,5 bis 5 cm. Die flächige Ausdehnung kann in der dritten Dimension gekrümmt sein.Polymer foam molded parts, in particular also polyurethane foam molded parts, who versatile for housing insulation of devices, especially in motor vehicles stuff area, for example as trunk covers, longitudinal pillar covers etc. used. The molded foam parts are generally flat with a thickness of the molded foam part of 0.5 to 5 cm. The areal extent can be curved in the third dimension.
Derartige Formschaumteile besitzen gegenüber ihrem Volumen eine äußere verdich tete Schicht, die auch als Haut bezeichnet wird. Die Verdichtung der Oberfläche geschieht bei der Formschaumherstellung durch den Kontakt der noch nicht ausge härteten Schaummasse mit der Formoberfläche, wobei oberflächig vorhandene Schaumbläschen zerstört werden. Die Oberflächenhaut ist ein inhärentes Merkmal von Formschaum. Versuche, durch Einsatz spezieller Schäummittel oder durch chemische Modifizierung der schaumbildenden Masse die Tendenz zur Ausbildung einer Oberflächenhaut zu reduzieren, haben nur graduell zum Erfolg geführt.Such molded foam parts have an outer compression compared to their volume layer, which is also called skin. The compaction of the surface happens in the production of molded foam through the contact of the not yet hardened foam mass with the mold surface, being superficial Foam bubbles can be destroyed. The surface skin is an inherent characteristic of molded foam. Attempts to use special foaming agents or chemical modification of the foam-forming mass the tendency to training reducing a surface skin has only gradually led to success.
In DE-OS-25 25 051 sind Film-Schaum-Schichtstoffe beschrieben, die aus einem offenzelligen Polyurethanschaum und einem mit diesem verbundenen deformierbaren, perforierten Film bestehen können, der zum Beispiel eine Plastik- oder eine Metallfolie sein kann.DE-OS-25 25 051 describes film-foam laminates which consists of an open-cell polyurethane foam and a associated with this deformable, perforated film can exist, for example a plastic or a Can be metal foil.
Eine Aufgabe von Formschaumteilen im Kfz-Bereich und im Bereich der Apparate isolierung ist die Schalldämpfung insbesondere im Bereich von oberhalb 1000 Hz, insbesondere oberhalb 5000 Hz.A task of molded foam parts in the automotive sector and in the field of apparatus Isolation is sound absorption, especially in the range above 1000 Hz, especially above 5000 Hz.
Es wurde nun gefunden, dass die Schallabsorption im Bereich der genannten höheren Frequenzen dadurch verbessert werden kann, dass die Formschaum-Haut perforiert wird. It has now been found that the sound absorption is in the range of the higher Frequencies can be improved by perforating the molded foam skin becomes.
Gegenstand der vorliegenden Erfindung sind daher Polymerschaum-Formteile mit erhöhtem Schalladsoptionsvermögen im Frequenzbereich oberhalb 1500 Hz, die durch eine Perforierung der oberflächig vorhandenen Verdichtungsschicht gekenn zeichnet sind.The present invention therefore relates to molded polymer foam parts increased sound absorption in the frequency range above 1500 Hz, the characterized by perforation of the compression layer present on the surface are drawn.
Vorzugsweise besteht die Perforierung aus Löchern von 0,1 bis 10 mm ∅, insbeson dere bevorzugt 0,3 bis 3 mm ∅. Die erfindungsgemäße Perforierung ist jedoch nicht an kreisrunde Durchmesser gebunden. Vorteilhaft können ovale oder schlitzförmige Perforierungen eingesetzt werden. Insbesondere bevorzugt sind schlitzförmige Perfo rierungen mit einem Querschnittsverhältnis von 1 : 5 bis 1 : 100. Im Falle von schlitzförmigen Perforierungen werden diese bevorzugt in mindestens 2 Richtungen auf der Oberfläche angeordnet.The perforation preferably consists of holes of 0.1 to 10 mm ∅, in particular whose preference is 0.3 to 3 mm ∅. However, the perforation according to the invention is not tied to circular diameter. Oval or slit-shaped can be advantageous Perforations are used. Slot-shaped perfo are particularly preferred rations with an aspect ratio of 1: 5 to 1: 100. In the case of slot-shaped perforations are preferred in at least 2 directions arranged on the surface.
Ferner sind kreisförmige Schlitze in Form von geschlossenen oder unterbrochenen Kreisen geeignet.Furthermore, circular slots are in the form of closed or interrupted ones Suitable for circles.
Im Falle von nicht kreisförmig, lochartigen Perforierungen soll die kleinere Quer schnittsabmessung vorzugsweise 0,1 bis 3 mm, insbesondere bevorzugt 0,5 bis 2 mm, betragen.In the case of non-circular, hole-like perforations, the smaller cross should be cut dimension preferably 0.1 to 3 mm, particularly preferably 0.5 to 2 mm.
Die Summe der Perforationen kann bis zu 50% der verdichteten Oberfläche ausma chen. Im allgemeinen ist eine Summe der Perforationen zwischen 0,1 und 10% der verdichteten Oberfläche ausreichend. Besonders bevorzugt beträgt die Summe der Perforationen zwischen 1,5 und 4% der Oberfläche.The total number of perforations can be up to 50% of the compacted surface chen. In general, a total of the perforations is between 0.1 and 10% of the compacted surface sufficient. The sum is particularly preferably the Perforations between 1.5 and 4% of the surface.
Bevorzugt werden Polyurethanschaumstoff-Formteile mit einer Dichte von 60 bis 120 kg/m3 eingesetzt. Die Erfindung ist jedoch nicht auf die üblicherweise bei terrestrischer Anwendung bevorzugten Formschaumdichten beschränkt. Sie kommt auch zum Zuge bei üblicherweise im Flugzeugbau eingesetzten viel niedrigeren Dichten bis hinab zu weniger als 10 kg/m3. Polyurethane foam molded parts with a density of 60 to 120 kg / m 3 are preferably used. However, the invention is not restricted to the molded foam densities which are usually preferred for terrestrial use. It also comes into play at much lower densities commonly used in aircraft construction down to less than 10 kg / m 3 .
Die Perforierung soll selbstverständlich nicht das Formschaumteil durchdringen, sondern lediglich die Verdichtungsschicht der Oberfläche.The perforation should of course not penetrate the molded foam part, but only the compaction layer of the surface.
Die Anbringung der Perforierung erfolgt vorteilhaft gleichzeitig mit der üblicher weise durchgeführten Walzung des Polymerschaum-Formteils zur Erhöhung der Offenporigkeit des Schaumes. Hierzu werden vorzugsweise die Walzen mit Nadeln oder zylinderförmigen Noppen versehen, die sich während des Walzvorganges durch die Verdichtungs-Oberflächenschicht des Polymerschaum-Formteils bohren. Bevor zugt werden zylinderförmige Hohlnoppen benutzt, die an ihrer Stirnseite offen sind und deren Außenkante eine Schneidfläche aufweist.The perforation is advantageously carried out simultaneously with the conventional one performed rolling of the polymer foam molding to increase the Open porosity of the foam. For this purpose, the rollers with needles are preferably used or cylindrical knobs, which stand out during the rolling process drill the compression surface layer of the polymer foam molding. Before Cylinder-shaped hollow knobs are used, which are open on their front side and the outer edge of which has a cutting surface.
Die Erfindung wird nachfolgend anhand der Beispiele 1 bis 3 erläutert. The invention is explained below using Examples 1 to 3.
Es wird ein Polyurethan-Schaumstoff-Formteil einer Dichte von 80 kg/m3 und einer Dicke von 25 mm eingesetzt. Aus dem ebenen, flächigen Formteil werden senkrecht zur Formteil-Oberfläche Proben von 20 mm ∅ geschnitten. Die frequenzabhängige Schallabsorption wird nach ASTM E 1050-90 in einem Schallabsorptionrohr von 20 mm ∅ gemessen. Kurve a) der beigefügten Fig. 1 zeigt die gemessene Schallabsorp tion des Probekörpers mit nicht perforierter Oberflächenhaut.A polyurethane foam molding with a density of 80 kg / m 3 and a thickness of 25 mm is used. Samples of 20 mm ∅ are cut from the flat, flat molding perpendicular to the molding surface. The frequency-dependent sound absorption is measured according to ASTM E 1050-90 in a sound absorption tube of 20 mm ∅. Curve a) of the accompanying Fig. 1 shows the measured sound absorption of the test specimen with imperforate surface skin.
Der nach Beispiel 1 hergestellte Probekörper wird oberflächig mit ca. 1 mm großen Löchern versehen, deren Flächensumme 1% der Gesamtoberfläche ausmacht. Die entsprechende Schallabsorptionskurve ist Kurve b) der Fig. 1.The test specimen produced according to Example 1 is provided on the surface with approximately 1 mm large holes, the total area of which accounts for 1% of the total surface. The corresponding sound absorption curve is curve b) of FIG. 1.
Der Probekörper wird entsprechend Beispiel 1 präpariert, wobei jedoch die Flächen summe der Perforationen 2% der Oberfläche ausmacht. Die entsprechende Schallab sorptionskurve ist Kurve c) der Fig. 2.The test specimen is prepared according to Example 1, but the area of the perforations accounts for 2% of the surface. The corresponding sound absorption curve is curve c) of FIG. 2.
Claims (6)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19962865A DE19962865C1 (en) | 1999-12-24 | 1999-12-24 | Shaped polymer foam component for sound absorption purposes in automobiles is provided with perforations in its compacted surface layer |
AU20083/01A AU2008301A (en) | 1999-12-24 | 2000-12-12 | Sound-absorbing polymer foam molded article |
JP2001548602A JP2003518538A (en) | 1999-12-24 | 2000-12-12 | Polymer foam moldings with improved sound absorption |
KR1020027008153A KR20020063920A (en) | 1999-12-24 | 2000-12-12 | Sound-Absorbing Polymer Foam Molded Article |
PCT/EP2000/012565 WO2001048069A1 (en) | 1999-12-24 | 2000-12-12 | Sound-absorbing polymer foam molded article |
BR0016698-7A BR0016698A (en) | 1999-12-24 | 2000-12-12 | Molded piece of polymeric foam with sound absorption capacity |
EP00983290A EP1244734A1 (en) | 1999-12-24 | 2000-12-12 | Sound-absorbing polymer foam molded article |
US10/168,419 US20020179367A1 (en) | 1999-12-24 | 2000-12-12 | Sound-absorbing polymer foam molded article |
MXPA02006238A MXPA02006238A (en) | 1999-12-24 | 2000-12-12 | Soundabsorbing polymer foam molded article. |
CA002394760A CA2394760A1 (en) | 1999-12-24 | 2000-12-12 | Sound-absorbing polymer foam molded article |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19962865A DE19962865C1 (en) | 1999-12-24 | 1999-12-24 | Shaped polymer foam component for sound absorption purposes in automobiles is provided with perforations in its compacted surface layer |
Publications (1)
Publication Number | Publication Date |
---|---|
DE19962865C1 true DE19962865C1 (en) | 2001-02-15 |
Family
ID=7934390
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19962865A Revoked DE19962865C1 (en) | 1999-12-24 | 1999-12-24 | Shaped polymer foam component for sound absorption purposes in automobiles is provided with perforations in its compacted surface layer |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1244734A1 (en) |
JP (1) | JP2003518538A (en) |
KR (1) | KR20020063920A (en) |
AU (1) | AU2008301A (en) |
BR (1) | BR0016698A (en) |
CA (1) | CA2394760A1 (en) |
DE (1) | DE19962865C1 (en) |
MX (1) | MXPA02006238A (en) |
WO (1) | WO2001048069A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10310907B3 (en) * | 2003-03-13 | 2004-01-08 | Bayer Ag | Sound- and heat-insulating construction element |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018140553A (en) * | 2017-02-28 | 2018-09-13 | パナソニックIpマネジメント株式会社 | Composite materials and devices using such composite materials |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2525051A1 (en) * | 1974-06-04 | 1976-04-29 | Scott Paper Co | PERFORATED, PROFILED FILM-FOAM LAMINATES |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69210997T3 (en) * | 1991-04-30 | 1999-12-16 | Dow Chemical Co | PERFORATED PLASTIC FOAM AND ITS PRODUCTION PROCESS |
ATE149910T1 (en) * | 1992-12-15 | 1997-03-15 | Scriptoria Nv | FOAM SHEETS MADE OF POLYOLEFINS |
HUP0103869A3 (en) * | 1998-09-17 | 2003-05-28 | Dow Global Technologies Inc Mi | Perforated foams |
-
1999
- 1999-12-24 DE DE19962865A patent/DE19962865C1/en not_active Revoked
-
2000
- 2000-12-12 MX MXPA02006238A patent/MXPA02006238A/en not_active Application Discontinuation
- 2000-12-12 BR BR0016698-7A patent/BR0016698A/en not_active Application Discontinuation
- 2000-12-12 EP EP00983290A patent/EP1244734A1/en not_active Withdrawn
- 2000-12-12 WO PCT/EP2000/012565 patent/WO2001048069A1/en not_active Application Discontinuation
- 2000-12-12 CA CA002394760A patent/CA2394760A1/en not_active Abandoned
- 2000-12-12 AU AU20083/01A patent/AU2008301A/en not_active Abandoned
- 2000-12-12 JP JP2001548602A patent/JP2003518538A/en active Pending
- 2000-12-12 KR KR1020027008153A patent/KR20020063920A/en not_active Application Discontinuation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2525051A1 (en) * | 1974-06-04 | 1976-04-29 | Scott Paper Co | PERFORATED, PROFILED FILM-FOAM LAMINATES |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10310907B3 (en) * | 2003-03-13 | 2004-01-08 | Bayer Ag | Sound- and heat-insulating construction element |
EP1457611A2 (en) | 2003-03-13 | 2004-09-15 | Bayer MaterialScience AG | Sound and heat insulating building element |
EP1457611A3 (en) * | 2003-03-13 | 2006-09-06 | Bayer MaterialScience AG | Sound and heat insulating building element |
Also Published As
Publication number | Publication date |
---|---|
JP2003518538A (en) | 2003-06-10 |
CA2394760A1 (en) | 2001-07-05 |
MXPA02006238A (en) | 2003-01-28 |
AU2008301A (en) | 2001-07-09 |
KR20020063920A (en) | 2002-08-05 |
EP1244734A1 (en) | 2002-10-02 |
WO2001048069A1 (en) | 2001-07-05 |
BR0016698A (en) | 2002-09-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8100 | Publication of the examined application without publication of unexamined application | ||
D1 | Grant (no unexamined application published) patent law 81 | ||
8363 | Opposition against the patent | ||
8331 | Complete revocation |