DE19622742C1 - Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid - Google Patents
Verfahren zur Schaumherstellung mittels unter Druck gelöstem KohlendioxidInfo
- Publication number
- DE19622742C1 DE19622742C1 DE19622742A DE19622742A DE19622742C1 DE 19622742 C1 DE19622742 C1 DE 19622742C1 DE 19622742 A DE19622742 A DE 19622742A DE 19622742 A DE19622742 A DE 19622742A DE 19622742 C1 DE19622742 C1 DE 19622742C1
- Authority
- DE
- Germany
- Prior art keywords
- pressure
- carbon dioxide
- dissolved
- polyol
- mixing chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 88
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 44
- 239000001569 carbon dioxide Substances 0.000 title claims description 30
- 239000006260 foam Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 10
- 230000008569 process Effects 0.000 title claims description 5
- 229920005862 polyol Polymers 0.000 claims description 29
- 150000003077 polyols Chemical class 0.000 claims description 29
- 239000012948 isocyanate Substances 0.000 claims description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 150000002513 isocyanates Chemical class 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 239000004604 Blowing Agent Substances 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 238000010924 continuous production Methods 0.000 claims description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate Chemical compound [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 description 8
- 230000003068 static effect Effects 0.000 description 7
- 229920005830 Polyurethane Foam Polymers 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003570 air Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- -1 chlorofluorocarbons Natural products 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000013012 foaming technology Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000008258 liquid foam Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
- B29C44/3446—Feeding the blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/46—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length
- B29C44/461—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length dispensing apparatus, e.g. dispensing foaming resin over the whole width of the moving surface
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19622742A DE19622742C1 (de) | 1996-06-07 | 1996-06-07 | Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| US09/194,784 US6127442A (en) | 1996-06-07 | 1997-05-26 | Process for foam production using dissolved under pressure carbon dioxide |
| PCT/EP1997/002688 WO1997047453A1 (de) | 1996-06-07 | 1997-05-26 | Verfahren zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
| DE59704801T DE59704801D1 (de) | 1996-06-07 | 1997-05-26 | Verfahren zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
| AT97927040T ATE206346T1 (de) | 1996-06-07 | 1997-05-26 | Verfahren zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
| HK99105708.4A HK1021159B (en) | 1996-06-07 | 1997-05-26 | Process for foam production using dissolved under pressure carbon dioxide |
| BR9709771A BR9709771A (pt) | 1996-06-07 | 1997-05-26 | Processo para a produção de espuma por meio de dióxido de carbono dissolvido sob pressão |
| CN97195299A CN1102886C (zh) | 1996-06-07 | 1997-05-26 | 用加压溶解的二氧化碳生产泡沫材料的方法 |
| JP10501116A JP2000511839A (ja) | 1996-06-07 | 1997-05-26 | 加圧下に溶解された二酸化炭素によるフォーム製造方法 |
| EP97927040A EP0907478B1 (de) | 1996-06-07 | 1997-05-26 | Verfahren zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
| TW086107657A TW402617B (en) | 1996-06-07 | 1997-06-04 | A process for the continuous production of polyurethane block foam using carbon dioxide which is physically dissolved under pressure as a foaming agent |
| ZA9705008A ZA975008B (en) | 1996-06-07 | 1997-06-06 | A process for the production of foam by means of carbon dioxide dissolved under pressure. |
| ARP970102481A AR007521A1 (es) | 1996-06-07 | 1997-06-06 | Procedimiento para la produccion de espuma mediante dioxido de carbono disuelto a presion |
| NO19985627A NO312843B1 (no) | 1996-06-07 | 1998-12-02 | Fremgangsmåte for skumproduksjon ved bruk av opplöst karbondioksid under trykk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19622742A DE19622742C1 (de) | 1996-06-07 | 1996-06-07 | Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19622742C1 true DE19622742C1 (de) | 1998-03-12 |
Family
ID=7796314
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19622742A Expired - Fee Related DE19622742C1 (de) | 1996-06-07 | 1996-06-07 | Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| DE59704801T Expired - Lifetime DE59704801D1 (de) | 1996-06-07 | 1997-05-26 | Verfahren zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59704801T Expired - Lifetime DE59704801D1 (de) | 1996-06-07 | 1997-05-26 | Verfahren zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6127442A (enExample) |
| EP (1) | EP0907478B1 (enExample) |
| JP (1) | JP2000511839A (enExample) |
| CN (1) | CN1102886C (enExample) |
| AR (1) | AR007521A1 (enExample) |
| AT (1) | ATE206346T1 (enExample) |
| BR (1) | BR9709771A (enExample) |
| DE (2) | DE19622742C1 (enExample) |
| NO (1) | NO312843B1 (enExample) |
| TW (1) | TW402617B (enExample) |
| WO (1) | WO1997047453A1 (enExample) |
| ZA (1) | ZA975008B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003035731A1 (de) * | 2001-10-24 | 2003-05-01 | Hennecke Gmbh | Verfahren zur herstellung von polyurethan-schaum |
| DE10203701C1 (de) * | 2002-01-31 | 2003-12-04 | Hennecke Gmbh | Verfahren zur Herstellung von Polyurethan-Schaum mit einstellbarer Zellstruktur |
| DE102009016730A1 (de) * | 2009-04-09 | 2010-10-14 | Hennecke Gmbh | Verfahren und Vorrichtung zur Herstellung einer gesättigten Lösung aus einer Polyurethan-Reaktionskomponente und einem darin gelösten Treibmittel |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU5566498A (en) | 1997-01-10 | 1998-08-03 | Beamech Group Limited | Apparatus and process for producing polymeric foam |
| US6326413B1 (en) | 1998-01-09 | 2001-12-04 | Beamech Group Limited | Process and apparatus for producing plastics and polymeric foam |
| AU6763800A (en) * | 1999-08-17 | 2001-03-13 | Sachchida N. Singh | Methods for improving the insulating properties of closed celled rigid polyurethane foams |
| US6458861B1 (en) | 2001-01-18 | 2002-10-01 | Bayer Antwerp N.V. | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
| GB0202349D0 (en) * | 2002-02-01 | 2002-03-20 | Beamech Group Ltd | Process and apparatus for CO2 foaming having variable pressure control |
| DE10226041A1 (de) * | 2002-06-12 | 2003-12-24 | Brugg Rohrsysteme Gmbh | Verfahren zur Herstellung eines wärmeisolierten Leitungsrohres |
| JP2006516467A (ja) | 2003-02-04 | 2006-07-06 | オステオテック,インコーポレイテッド | 骨インプラントのためのポリウレタン |
| US7985414B2 (en) * | 2003-02-04 | 2011-07-26 | Warsaw Orthopedic, Inc. | Polyurethanes for osteoimplants |
| DE10311768A1 (de) * | 2003-03-18 | 2004-09-30 | Hennecke Gmbh | Verfahren zur Herstellung von Polyurethan-Schaumstoffen |
| US6797736B1 (en) * | 2003-03-19 | 2004-09-28 | Basf Corporation | Method of forming high resilience slabstock polyurethane foam |
| US20050038132A1 (en) * | 2003-03-19 | 2005-02-17 | Raghuram Gummaraju | Composition for forming a foamed article and an article of furniture having the foamed article disposed therein |
| US6784218B1 (en) * | 2003-03-19 | 2004-08-31 | Basf Corporation | Method of forming high resilience slabstock polyurethane foam displaying latex-like characteristics |
| US8012210B2 (en) | 2004-01-16 | 2011-09-06 | Warsaw Orthopedic, Inc. | Implant frames for use with settable materials and related methods of use |
| US20060091574A1 (en) * | 2004-11-03 | 2006-05-04 | Lear Corporation | Interior vehicle trim panel having a sprayed expanded polyurethane layer and method and system of making same |
| WO2007084609A2 (en) | 2006-01-19 | 2007-07-26 | Osteotech, Inc. | Porous osteoimplant |
| WO2007084725A2 (en) | 2006-01-19 | 2007-07-26 | Osteotech, Inc. | Injectable and moldable bone substitute materials |
| US7566165B2 (en) * | 2006-04-17 | 2009-07-28 | Milliken & Company | Valved manifold and system suitable for introducing one or more additives into a fluid stream |
| JP5105900B2 (ja) * | 2007-01-29 | 2012-12-26 | 有限会社サン・イースト・リサーチ | ピンホールが無く、自由に気泡サイズを自由にコントロール可能なポリウレタンフォームの製造方法。 |
| DE102007015660A1 (de) * | 2007-03-31 | 2008-10-02 | Brugg Rohr Ag, Holding | Flexibles wärmeisoliertes Leitungsrohr |
| CN101260199B (zh) * | 2008-04-15 | 2011-05-11 | 广东工业大学 | 一种聚合物发泡成核物的制备方法 |
| ITMI20091705A1 (it) * | 2009-10-05 | 2011-04-06 | Afros Spa | Metodo e apparecchiatura per rivestire una tubazione con una schiuma termicamente isolante. |
| CN102152436B (zh) * | 2010-12-07 | 2013-01-02 | 张家港力勤机械有限公司 | 聚氨酯发泡机的原料核化装置 |
| CN103895145B (zh) * | 2012-12-25 | 2016-12-28 | 朴喜大 | 环保型pu发泡方法 |
| CN104441385A (zh) * | 2014-11-18 | 2015-03-25 | 中天日立射频电缆有限公司 | 一种用于物理发泡过程的双路注气系统及其注气方法 |
| DE102016114898A1 (de) | 2016-08-11 | 2018-02-15 | Ceracon Gmbh | Vorrichtung und Verfahren zum Schäumen eines viskosen Materials |
| JP7623816B2 (ja) * | 2020-10-02 | 2025-01-29 | 積水化学工業株式会社 | 混合システム |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB803771A (en) * | 1954-06-21 | 1958-10-29 | Xetal Products Ltd | Production of cellular synthetic rubbers |
| US3181199A (en) * | 1961-12-07 | 1965-05-04 | Allied Chem | Froth applicator |
| US3184419A (en) * | 1958-02-06 | 1965-05-18 | Dunlop Rubber Co | Method for the production of polyurethane foamed material |
| EP0645226A2 (en) * | 1993-07-14 | 1995-03-29 | Foaming Technologies Cardio B.V. | Froth process and system for continuous manufacture of polyurethane foam slab-stocks |
| DE4422568C1 (de) * | 1994-06-28 | 1996-02-15 | Bayer Ag | Verfahren und Vorrichtung zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055272A (en) * | 1989-01-13 | 1991-10-08 | Sealed Air Corporation | Method for producing polyurethane foam and apparatus therefor |
| US5118720A (en) * | 1989-01-13 | 1992-06-02 | Sealed Air Corporation | Method for producing polyurethane foam and apparatus therefor |
| US5665287A (en) * | 1993-07-14 | 1997-09-09 | Foaming Technologies Cardio Bv | Froth process for continous manufacture of polyurethane foam slab-stocks |
| IT1270979B (it) * | 1993-09-30 | 1997-05-26 | Afros Spa | Procedimento e apparecchiatura per la produzione in continuo di schiume poliuretaniche in blocchi |
| DE4442256C1 (de) * | 1994-11-28 | 1996-07-25 | Hennecke Gmbh Maschf | Verfahren zum Lösen von Kohlendioxid in einem flüssigen Polymer |
-
1996
- 1996-06-07 DE DE19622742A patent/DE19622742C1/de not_active Expired - Fee Related
-
1997
- 1997-05-26 AT AT97927040T patent/ATE206346T1/de not_active IP Right Cessation
- 1997-05-26 JP JP10501116A patent/JP2000511839A/ja not_active Ceased
- 1997-05-26 EP EP97927040A patent/EP0907478B1/de not_active Expired - Lifetime
- 1997-05-26 DE DE59704801T patent/DE59704801D1/de not_active Expired - Lifetime
- 1997-05-26 US US09/194,784 patent/US6127442A/en not_active Expired - Fee Related
- 1997-05-26 CN CN97195299A patent/CN1102886C/zh not_active Expired - Fee Related
- 1997-05-26 WO PCT/EP1997/002688 patent/WO1997047453A1/de not_active Ceased
- 1997-05-26 BR BR9709771A patent/BR9709771A/pt not_active IP Right Cessation
- 1997-06-04 TW TW086107657A patent/TW402617B/zh active
- 1997-06-06 ZA ZA9705008A patent/ZA975008B/xx unknown
- 1997-06-06 AR ARP970102481A patent/AR007521A1/es active IP Right Grant
-
1998
- 1998-12-02 NO NO19985627A patent/NO312843B1/no not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB803771A (en) * | 1954-06-21 | 1958-10-29 | Xetal Products Ltd | Production of cellular synthetic rubbers |
| US3184419A (en) * | 1958-02-06 | 1965-05-18 | Dunlop Rubber Co | Method for the production of polyurethane foamed material |
| US3181199A (en) * | 1961-12-07 | 1965-05-04 | Allied Chem | Froth applicator |
| EP0645226A2 (en) * | 1993-07-14 | 1995-03-29 | Foaming Technologies Cardio B.V. | Froth process and system for continuous manufacture of polyurethane foam slab-stocks |
| DE4422568C1 (de) * | 1994-06-28 | 1996-02-15 | Bayer Ag | Verfahren und Vorrichtung zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003035731A1 (de) * | 2001-10-24 | 2003-05-01 | Hennecke Gmbh | Verfahren zur herstellung von polyurethan-schaum |
| DE10203701C1 (de) * | 2002-01-31 | 2003-12-04 | Hennecke Gmbh | Verfahren zur Herstellung von Polyurethan-Schaum mit einstellbarer Zellstruktur |
| DE102009016730A1 (de) * | 2009-04-09 | 2010-10-14 | Hennecke Gmbh | Verfahren und Vorrichtung zur Herstellung einer gesättigten Lösung aus einer Polyurethan-Reaktionskomponente und einem darin gelösten Treibmittel |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1021159A1 (en) | 2000-06-02 |
| US6127442A (en) | 2000-10-03 |
| WO1997047453A1 (de) | 1997-12-18 |
| JP2000511839A (ja) | 2000-09-12 |
| ATE206346T1 (de) | 2001-10-15 |
| NO312843B1 (no) | 2002-07-08 |
| EP0907478B1 (de) | 2001-10-04 |
| CN1221368A (zh) | 1999-06-30 |
| NO985627D0 (no) | 1998-12-02 |
| DE59704801D1 (de) | 2001-11-08 |
| TW402617B (en) | 2000-08-21 |
| BR9709771A (pt) | 1999-08-10 |
| EP0907478A1 (de) | 1999-04-14 |
| ZA975008B (en) | 1998-01-14 |
| CN1102886C (zh) | 2003-03-12 |
| NO985627L (no) | 1998-12-02 |
| AR007521A1 (es) | 1999-11-10 |
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