DE19531828A1 - Recovering highly viscous prods., e.g. oils, from storage areas - Google Patents
Recovering highly viscous prods., e.g. oils, from storage areasInfo
- Publication number
- DE19531828A1 DE19531828A1 DE1995131828 DE19531828A DE19531828A1 DE 19531828 A1 DE19531828 A1 DE 19531828A1 DE 1995131828 DE1995131828 DE 1995131828 DE 19531828 A DE19531828 A DE 19531828A DE 19531828 A1 DE19531828 A1 DE 19531828A1
- Authority
- DE
- Germany
- Prior art keywords
- highly viscous
- oils
- storage areas
- prods
- recovering highly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003921 oil Substances 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 7
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract 2
- 239000004571 lime Substances 0.000 claims abstract 2
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims 1
- 239000002253 acid Substances 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 235000011116 calcium hydroxide Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- -1 hydroraffinates Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B1/00—Dumping solid waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/02—Extraction using liquids, e.g. washing, leaching, flotation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C1/00—Working-up tar
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Die Erfindung betrifft ein verbessertes Verfahren zur Bergung hochviskoser Produkte gemäß
Patentanmeldung P 44 269.3-24
In der Patentanmeldung P 44 38 269.3-24 wird ein Verfahren zur Bergung hochviskoser
Produkte, die insbesondere bei der Verarbeitung von Mineralölen, Hydroraffinaten, Altölen,
Teeren und anderen Kohlenwasserstoffen entstehen und als Abfallprodukte in Becken, Gruben,
Behältern u. a. deponiert oder gelagert werden, beschrieben, bei dem durch Einbringung von
Zusatzmittel eine pumpfähige Konsistenz dieser Produkte erreicht wird. Als Zusatzmittel
werden dazu flüssige Kohlenwasserstoffgemische mit einer Viskosität von mindestens 4 mm²/s
bei 20°C oder Wasser vorgeschlagen, die bis zu 10 Ma.-Teile Tenside oder andere geeignete
oberflächenaktive Stoffe enthalten können.The invention relates to an improved method for recovering highly viscous products according to patent application P 44 269.3-24
Patent application P 44 38 269.3-24 describes a process for recovering highly viscous products, which are produced in particular when processing mineral oils, hydroraffinates, waste oils, tars and other hydrocarbons and are deposited or stored as waste products in basins, pits, containers and others , in which a pumpable consistency of these products is achieved by adding additives. Liquid hydrocarbon mixtures with a viscosity of at least 4 mm² / s at 20 ° C. or water are proposed as additives, which may contain up to 10 parts by weight of surfactants or other suitable surface-active substances.
Bei der Durchführung des Verfahrens gemäß Patentanmeldung P 4438269.3-24 hat es sich nun erfindungsgemäß als vorteilhaft erwiesen, zur Verbesserung der Pumpfähigkeit insbeson dere hochviskoser säurehaltiger Produkte mit Säuregehalten zwischen 10 und 40 Ma.-% als Zusatzmittel eine wäßrige alkalische Lösung bzw. Suspension zu verwenden. Besonders vor teilhaft hat sich dabei die Verwendung einer calciumhydroxidhaltigen wäßrigen Suspension mit Calciumhydroxidgehalten von 0,1 bis zu 22 Ma.-% erwiesen.When carrying out the method according to patent application P 4438269.3-24, it was now proven to be advantageous according to the invention, in particular to improve pumpability their highly viscous acidic products with acid contents between 10 and 40% by mass as Additive to use an aqueous alkaline solution or suspension. Especially before The use of an aqueous suspension containing calcium hydroxide has also been of some benefit Calcium hydroxide contents from 0.1 to 22% by mass have been proven.
Dabei hat sich gezeigt, daß bei der Anwendung des erfindungsgemäßen Verfahrens deponierte hochviskose säurehaltige Produkte im Rahmen der angegebenen Säurekonzentrationen überraschend gut in eine pumpfähige Konsistenz unter Vermeidung von Klumpenbildung überführt werden können. Darüber hinaus hat es sich als vorteilhaft erwiesen, daß bei der Anwendung der Erfindung ein Zusatz von Tensiden gegenüber der im Hauptpatent vorge schlagenen Verfahrensvarianten nicht mehr erforderlich ist.It has been shown that when using the method according to the invention deposited highly viscous acidic products within the specified acid concentrations surprisingly good in a pumpable consistency while avoiding clumping can be transferred. In addition, it has proven to be advantageous in that Application of the invention an addition of surfactants compared to that in the main patent proposed process variants is no longer required.
Die Erfindung soll nachstehend an einem Ausführungsbeispiel näher erläutert werden:The invention will be explained in more detail below using an exemplary embodiment:
1000 kg Säureharz mit einem Schwefelsäuregehalt von 29,5 Ma.-% und einer Viskosität von 10300 mm²/s werden gemäß Patentanmeldung P 44 38 269.3-24 geborgen, wobei als Löse- Trägerflüssigkeit eine alkalische Flüssigkeit bestehend aus 3000 kg Wasser und 230 kg techn. Kalkhydrat verwendet wird. Es entsteht eine dünnflüssige, wäßrige Suspension, die eine gut pumpbare Konsistenz aufweist.1000 kg of acid resin with a sulfuric acid content of 29.5 mass% and a viscosity of 10300 mm² / s are recovered in accordance with patent application P 44 38 269.3-24. Carrier liquid an alkaline liquid consisting of 3000 kg water and 230 kg techn. Hydrated lime is used. The result is a thin, aqueous suspension that is good has pumpable consistency.
Claims (2)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19944438269 DE4438269C2 (en) | 1994-10-26 | 1994-10-26 | Process for the recovery of highly viscous products |
DE1995131828 DE19531828C2 (en) | 1994-10-26 | 1995-08-15 | Process for the recovery of highly viscous products |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19944438269 DE4438269C2 (en) | 1994-10-26 | 1994-10-26 | Process for the recovery of highly viscous products |
DE1995131828 DE19531828C2 (en) | 1994-10-26 | 1995-08-15 | Process for the recovery of highly viscous products |
Publications (2)
Publication Number | Publication Date |
---|---|
DE19531828A1 true DE19531828A1 (en) | 1997-02-20 |
DE19531828C2 DE19531828C2 (en) | 2003-02-20 |
Family
ID=25941403
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19944438269 Expired - Fee Related DE4438269C2 (en) | 1994-10-26 | 1994-10-26 | Process for the recovery of highly viscous products |
DE1995131828 Expired - Lifetime DE19531828C2 (en) | 1994-10-26 | 1995-08-15 | Process for the recovery of highly viscous products |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19944438269 Expired - Fee Related DE4438269C2 (en) | 1994-10-26 | 1994-10-26 | Process for the recovery of highly viscous products |
Country Status (1)
Country | Link |
---|---|
DE (2) | DE4438269C2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4438269C2 (en) * | 1994-10-26 | 1998-07-23 | Omros Ges Fuer Umwelttechnik G | Process for the recovery of highly viscous products |
DE19833192C2 (en) * | 1998-07-23 | 2001-06-28 | Omros Ges Fuer Umwelttechnik M | Process for the recovery of highly viscous products containing hydrocarbons |
DE19847197C1 (en) * | 1998-10-13 | 2000-03-16 | Omros Ges Fuer Umwelttechnik G | Recovering highly viscous products from waste sites, mines and other deposits comprises adding alkaline products to viscosity-reducing additives during the process |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1918332A1 (en) * | 1969-04-10 | 1970-10-15 | Konink Mij Tot Het Uitvoeren V | Thickening sludge using polyelectrolytes or cellulose |
US4028240A (en) * | 1973-10-15 | 1977-06-07 | Manchak Frank | Method and apparatus for treating sumps |
DE2556283C3 (en) * | 1975-12-13 | 1980-08-14 | Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt | Device for admixing additives reducing flow resistance in the boundary layer of a medium flowing through a pipe-shaped pipe |
HU180394B (en) * | 1980-11-21 | 1983-02-28 | Magyar Szenhidrogenipari | Process and equipment for the neutralization of acid tar and for getting it from conserving tanks |
DE4438269C2 (en) * | 1994-10-26 | 1998-07-23 | Omros Ges Fuer Umwelttechnik G | Process for the recovery of highly viscous products |
-
1994
- 1994-10-26 DE DE19944438269 patent/DE4438269C2/en not_active Expired - Fee Related
-
1995
- 1995-08-15 DE DE1995131828 patent/DE19531828C2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE4438269A1 (en) | 1996-05-02 |
DE19531828C2 (en) | 2003-02-20 |
DE4438269C2 (en) | 1998-07-23 |
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