DE19531828A1 - Recovering highly viscous prods., e.g. oils, from storage areas - Google Patents

Recovering highly viscous prods., e.g. oils, from storage areas

Info

Publication number
DE19531828A1
DE19531828A1 DE1995131828 DE19531828A DE19531828A1 DE 19531828 A1 DE19531828 A1 DE 19531828A1 DE 1995131828 DE1995131828 DE 1995131828 DE 19531828 A DE19531828 A DE 19531828A DE 19531828 A1 DE19531828 A1 DE 19531828A1
Authority
DE
Germany
Prior art keywords
highly viscous
oils
storage areas
prods
recovering highly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE1995131828
Other languages
German (de)
Other versions
DE19531828C2 (en
Inventor
Peter Dr Traut
Helmut Dr Gorke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OMROS GES fur UMWELTTECHNIK G
Original Assignee
OMROS GES fur UMWELTTECHNIK G
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE19944438269 priority Critical patent/DE4438269C2/en
Application filed by OMROS GES fur UMWELTTECHNIK G filed Critical OMROS GES fur UMWELTTECHNIK G
Priority to DE1995131828 priority patent/DE19531828C2/en
Publication of DE19531828A1 publication Critical patent/DE19531828A1/en
Application granted granted Critical
Publication of DE19531828C2 publication Critical patent/DE19531828C2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B1/00Dumping solid waste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/02Extraction using liquids, e.g. washing, leaching, flotation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C1/00Working-up tar
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C3/00Working-up pitch, asphalt, bitumen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Soil Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

The process for recovering highly viscous products from dumps or other storage areas (P4438269.3-24) comprises using an alkaline soln. as an additive. Reactive lime is pref. used as an additive, in an amt. of 0.1-22 wt.%

Description

Die Erfindung betrifft ein verbessertes Verfahren zur Bergung hochviskoser Produkte gemäß Patentanmeldung P 44 269.3-24
In der Patentanmeldung P 44 38 269.3-24 wird ein Verfahren zur Bergung hochviskoser Produkte, die insbesondere bei der Verarbeitung von Mineralölen, Hydroraffinaten, Altölen, Teeren und anderen Kohlenwasserstoffen entstehen und als Abfallprodukte in Becken, Gruben, Behältern u. a. deponiert oder gelagert werden, beschrieben, bei dem durch Einbringung von Zusatzmittel eine pumpfähige Konsistenz dieser Produkte erreicht wird. Als Zusatzmittel werden dazu flüssige Kohlenwasserstoffgemische mit einer Viskosität von mindestens 4 mm²/s bei 20°C oder Wasser vorgeschlagen, die bis zu 10 Ma.-Teile Tenside oder andere geeignete oberflächenaktive Stoffe enthalten können.
The invention relates to an improved method for recovering highly viscous products according to patent application P 44 269.3-24
Patent application P 44 38 269.3-24 describes a process for recovering highly viscous products, which are produced in particular when processing mineral oils, hydroraffinates, waste oils, tars and other hydrocarbons and are deposited or stored as waste products in basins, pits, containers and others , in which a pumpable consistency of these products is achieved by adding additives. Liquid hydrocarbon mixtures with a viscosity of at least 4 mm² / s at 20 ° C. or water are proposed as additives, which may contain up to 10 parts by weight of surfactants or other suitable surface-active substances.

Bei der Durchführung des Verfahrens gemäß Patentanmeldung P 4438269.3-24 hat es sich nun erfindungsgemäß als vorteilhaft erwiesen, zur Verbesserung der Pumpfähigkeit insbeson­ dere hochviskoser säurehaltiger Produkte mit Säuregehalten zwischen 10 und 40 Ma.-% als Zusatzmittel eine wäßrige alkalische Lösung bzw. Suspension zu verwenden. Besonders vor­ teilhaft hat sich dabei die Verwendung einer calciumhydroxidhaltigen wäßrigen Suspension mit Calciumhydroxidgehalten von 0,1 bis zu 22 Ma.-% erwiesen.When carrying out the method according to patent application P 4438269.3-24, it was now proven to be advantageous according to the invention, in particular to improve pumpability their highly viscous acidic products with acid contents between 10 and 40% by mass as Additive to use an aqueous alkaline solution or suspension. Especially before The use of an aqueous suspension containing calcium hydroxide has also been of some benefit Calcium hydroxide contents from 0.1 to 22% by mass have been proven.

Dabei hat sich gezeigt, daß bei der Anwendung des erfindungsgemäßen Verfahrens deponierte hochviskose säurehaltige Produkte im Rahmen der angegebenen Säurekonzentrationen überraschend gut in eine pumpfähige Konsistenz unter Vermeidung von Klumpenbildung überführt werden können. Darüber hinaus hat es sich als vorteilhaft erwiesen, daß bei der Anwendung der Erfindung ein Zusatz von Tensiden gegenüber der im Hauptpatent vorge­ schlagenen Verfahrensvarianten nicht mehr erforderlich ist.It has been shown that when using the method according to the invention deposited highly viscous acidic products within the specified acid concentrations surprisingly good in a pumpable consistency while avoiding clumping can be transferred. In addition, it has proven to be advantageous in that Application of the invention an addition of surfactants compared to that in the main patent proposed process variants is no longer required.

Die Erfindung soll nachstehend an einem Ausführungsbeispiel näher erläutert werden:The invention will be explained in more detail below using an exemplary embodiment:

1000 kg Säureharz mit einem Schwefelsäuregehalt von 29,5 Ma.-% und einer Viskosität von 10300 mm²/s werden gemäß Patentanmeldung P 44 38 269.3-24 geborgen, wobei als Löse- Trägerflüssigkeit eine alkalische Flüssigkeit bestehend aus 3000 kg Wasser und 230 kg techn. Kalkhydrat verwendet wird. Es entsteht eine dünnflüssige, wäßrige Suspension, die eine gut pumpbare Konsistenz aufweist.1000 kg of acid resin with a sulfuric acid content of 29.5 mass% and a viscosity of 10300 mm² / s are recovered in accordance with patent application P 44 38 269.3-24.  Carrier liquid an alkaline liquid consisting of 3000 kg water and 230 kg techn. Hydrated lime is used. The result is a thin, aqueous suspension that is good has pumpable consistency.

Claims (2)

1. Verfahren zur Bergung hochviskoser Produkte aus Deponien, Gruben oder anderen Lagerstätten nach Patentanmeldung P 4438 269.3-24, dadurch gekennzeichnet, daß als Zusatzmittel eine wäßrige alkalische Lösung verwendet wird.1. A process for the recovery of highly viscous products from landfills, pits or other deposits according to patent application P 4438 269.3-24, characterized in that an aqueous alkaline solution is used as an additive. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß als Zusatz reaktiver Kalk in Konzentrationen zwischen 0,1 und 22 Ma.-% verwendet wird.2. The method according to claim 1, characterized in that as an additive reactive lime is used in concentrations between 0.1 and 22% by mass.
DE1995131828 1994-10-26 1995-08-15 Process for the recovery of highly viscous products Expired - Lifetime DE19531828C2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19944438269 DE4438269C2 (en) 1994-10-26 1994-10-26 Process for the recovery of highly viscous products
DE1995131828 DE19531828C2 (en) 1994-10-26 1995-08-15 Process for the recovery of highly viscous products

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19944438269 DE4438269C2 (en) 1994-10-26 1994-10-26 Process for the recovery of highly viscous products
DE1995131828 DE19531828C2 (en) 1994-10-26 1995-08-15 Process for the recovery of highly viscous products

Publications (2)

Publication Number Publication Date
DE19531828A1 true DE19531828A1 (en) 1997-02-20
DE19531828C2 DE19531828C2 (en) 2003-02-20

Family

ID=25941403

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19944438269 Expired - Fee Related DE4438269C2 (en) 1994-10-26 1994-10-26 Process for the recovery of highly viscous products
DE1995131828 Expired - Lifetime DE19531828C2 (en) 1994-10-26 1995-08-15 Process for the recovery of highly viscous products

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19944438269 Expired - Fee Related DE4438269C2 (en) 1994-10-26 1994-10-26 Process for the recovery of highly viscous products

Country Status (1)

Country Link
DE (2) DE4438269C2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4438269C2 (en) * 1994-10-26 1998-07-23 Omros Ges Fuer Umwelttechnik G Process for the recovery of highly viscous products
DE19833192C2 (en) * 1998-07-23 2001-06-28 Omros Ges Fuer Umwelttechnik M Process for the recovery of highly viscous products containing hydrocarbons
DE19847197C1 (en) * 1998-10-13 2000-03-16 Omros Ges Fuer Umwelttechnik G Recovering highly viscous products from waste sites, mines and other deposits comprises adding alkaline products to viscosity-reducing additives during the process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1918332A1 (en) * 1969-04-10 1970-10-15 Konink Mij Tot Het Uitvoeren V Thickening sludge using polyelectrolytes or cellulose
US4028240A (en) * 1973-10-15 1977-06-07 Manchak Frank Method and apparatus for treating sumps
DE2556283C3 (en) * 1975-12-13 1980-08-14 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Device for admixing additives reducing flow resistance in the boundary layer of a medium flowing through a pipe-shaped pipe
HU180394B (en) * 1980-11-21 1983-02-28 Magyar Szenhidrogenipari Process and equipment for the neutralization of acid tar and for getting it from conserving tanks
DE4438269C2 (en) * 1994-10-26 1998-07-23 Omros Ges Fuer Umwelttechnik G Process for the recovery of highly viscous products

Also Published As

Publication number Publication date
DE4438269A1 (en) 1996-05-02
DE19531828C2 (en) 2003-02-20
DE4438269C2 (en) 1998-07-23

Similar Documents

Publication Publication Date Title
DE69631901T2 (en) PROCESS FOR REDUCING THE CORROSIVITY AND ACIDITY OF CRUDE OIL
DE1221226B (en) Process for the production of basic alkaline earth metal complex compounds of carbonic and / or oil-soluble organic sulfonic acids, which are soluble in hydrocarbon oils
DE3880523D1 (en) METHOD FOR PRODUCING A BASIC SALT, SALT OBTAINED THEREOF, AND OIL COMPOSITIONS CONTAINING SUCH A SALT.
DE1617226A1 (en) Phosphate-free cleaning agent
DE3532079A1 (en) METHOD FOR REMOVING SUSPENDED RED SLUDGE FROM AQUEOUS SOLIDS CONTAINING ALUMINUM
DE2910677C2 (en) Process for the treatment of radioactive concentrates containing boron from wastewater from pressurized water reactors
DE19622178A1 (en) Solidification of waste
DE19531828A1 (en) Recovering highly viscous prods., e.g. oils, from storage areas
DE2945841A1 (en) METHOD FOR PRODUCING HYDROGEN
DE3517170C2 (en)
DE19503142C2 (en) Binder and and its use
EP0355507B1 (en) Process for solidifying liquid waste concentrates
DE69835027T2 (en) LIQUID COMPOSITION WHICH MAY CREATE GLOSSARY CARBON AND GASKING METHOD AND METHOD FOR THE PRODUCTION THEREOF
EP0753568A3 (en) Granular builder for detergent compositions
DE19847197C1 (en) Recovering highly viscous products from waste sites, mines and other deposits comprises adding alkaline products to viscosity-reducing additives during the process
DE2916975C2 (en) Process for removing sulfur oxides from gases
DE1767490A1 (en) Process for making substances hydrophobic
DD142656A5 (en) METHOD FOR THE RECULTIVATION AND FASTENING OF DRILLING RESOURCES
DE1645726A1 (en) Desulfurization of petroleum fractions
US3258070A (en) Removal of iron compounds from water
DE10238789B4 (en) Process for the preparation of suspensions and their use
DE4244382C2 (en) Process for the preparation of tar and similar products, use of the resulting products and fuels obtainable by the process
DE2849426A1 (en) METHOD FOR PRODUCING OVERBASE MAGNESIUM SULPHONATE
DE3632360A1 (en) Process for the selective removal of contaminants from water
DE3828844A1 (en) Process for disposing of sodium sulphate having a high water of crystallisation content, in particular of wastes of flue gas desulphurisation in the combustion of high-sulphur fossil fuels, for example of low-grade coal

Legal Events

Date Code Title Description
AF Is addition to no.

Ref country code: DE

Ref document number: 4438269

Format of ref document f/p: P

AF Is addition to no.

Ref country code: DE

Ref document number: 4438269

Format of ref document f/p: P

8110 Request for examination paragraph 44
8304 Grant after examination procedure
AF Is addition to no.

Ref document number: 4438269

Country of ref document: DE

Kind code of ref document: P

8364 No opposition during term of opposition
8340 Patent of addition ceased/non-payment of fee of main patent
8370 Indication of lapse of patent is to be deleted