DE1817704A1 - Clear hard candy and process for its production excretion from 1806816 - Google Patents

Clear hard candy and process for its production excretion from 1806816

Info

Publication number
DE1817704A1
DE1817704A1 DE19681817704 DE1817704A DE1817704A1 DE 1817704 A1 DE1817704 A1 DE 1817704A1 DE 19681817704 DE19681817704 DE 19681817704 DE 1817704 A DE1817704 A DE 1817704A DE 1817704 A1 DE1817704 A1 DE 1817704A1
Authority
DE
Germany
Prior art keywords
syrup
glucose syrup
parts
permeable membrane
glucose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19681817704
Other languages
German (de)
Other versions
DE1817704B2 (en
DE1817704C3 (en
Original Assignee
Corn Products Company Englewood Cliffs, NJ (V St A )
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corn Products Company Englewood Cliffs, NJ (V St A ) filed Critical Corn Products Company Englewood Cliffs, NJ (V St A )
Publication of DE1817704A1 publication Critical patent/DE1817704A1/en
Publication of DE1817704B2 publication Critical patent/DE1817704B2/en
Application granted granted Critical
Publication of DE1817704C3 publication Critical patent/DE1817704C3/de
Granted legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/40Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/56Cocoa products, e.g. chocolate; Substitutes therefor making liquid products, e.g. for making chocolate milk drinks and the products for their preparation, pastes for spreading, milk crumb
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/346Finished or semi-finished products in the form of powders, paste or liquids
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/42Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44Ion-selective electrodialysis
    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13BPRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00Purification of sugar juices
    • C13B20/18Purification of sugar juices by electrical means
    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13KSACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00Glucose; Glucose-containing syrups
    • C13K1/06Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
    • C13K1/08Purifying
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2200/00COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
    • A23G2200/06COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2317/00Membrane module arrangements within a plant or an apparatus
    • B01D2317/04Elements in parallel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Urology & Nephrology (AREA)
  • General Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Confectionery (AREA)
  • Jellies, Jams, And Syrups (AREA)

Description

009885/OU1009885 / OU1

Claims (2)

1 2 ■■"■■■■1 2 ■■ "■■■■ ger als 15 Teile Aminosäuren pro Million Teilenless than 15 parts amino acids per million parts Patentanspruch: Glukosesirup enthält und eine um wenigstens etwaClaim: Contains glucose syrup and one by at least about 40*/» gegenüber dem Ausgangsglukosesirup verbes-40 * / »compared to the starting glucose syrup Verwendung einer gekochten Mischung von 30 serte Farbe, gemessen bei Raumtemperatur, ebenso bis 60 °/u Saccharose (Trockensubstanz) und dem 5 wie eine um wenigstens etwa 40 % gegenüber dem Rest, bestehend im wesentlichen aus einem einer Ausgangsglukosesirup verbesserte Farbbeständigkeit, Behandlung durch Elektrodialyse auf dem gemessen bei 100° C anfänglich und nach 2 Stunden, Durchgang unter einer angelegten Gleichstrom- aufweist, zur Herstellung klarer harter Bonbons,
spannung durch mindestens eine Kammer unter- Durch die Erfindung wird nicht nur die eines mit
Use of a cooked mixture of 30% color, measured at room temperature, also up to 60 ° / u sucrose (dry matter) and the 5 as one by at least about 40% compared to the rest, consisting essentially of a color fastness improved from a starting glucose syrup, treatment by electrodialysis on which measured at 100 ° C initially and after 2 hours, passage under an applied direct current has, for the production of clear hard candies,
voltage through at least one chamber
worfenem Glukosesirup, wobei die Kammer auf io SO2 vorbehandelten Glukosesirups vermieden, sonder einen Seite von einer kationendurchlässigen dem die mit seiner Hilfe hergestellten Bonbons besit-Membran und auf der gegenüberliegenden Seite zen mindestens die gleiche Härte und Klarheit und von einer anionendurchlässigen Membran be- ebenso mindestens die gleiche Farbbeständigkeit und grenzt ist, während die Membranen von außen Farbverbesserung, wie sie bisher nur die Bonbons mit einem wäßrigen Medium gewaschen werden, 15 aufwiesen, welche aus mit SO2 vorbehandeltem GIu- und der Glukosesirup ein Dextroseäquivalent im kosesirup hergestellt waren. Sie sind jedoch völlig frei Bereich von etwa 30 bis etwa 70, einen Aschege·· von Restspuren von SO2, dessen Anwesenheit als halt unterhalb etwa 0,2 Vo, eine Leitfähigkeit bei Fremdstoff in den Bonbons auf jeden Fall uner-25° C von etwa 350 Mikrosiemens oder weniger wünscht und vielleicht auch gesundheitswidrig ist.
hat, weniger als 15 Teile Aminosäuren pro Mil- 20 Die belgische Patentschrift 645 544 und USA.-Palion Teilen Glukosesirup enthält und eine um we- tentschrift 3 276 908 beschreibt eine andere Elektronigstens etwa 40 Vo gegenüber dem Ausgangsglu- dialyse von Glukosesirup, worin ein an Asche angekosesirup verbesserte Farbe, gemessen bei Raum- reichertet Zweigstrom auf einer Seite einer Membran temperatur, ebenso wie eine um wenigstens etwa fließt, während ein aschearmer Zweigstrom sich auf 40 1Vo gegenüber dem Ausgangsglukosesirup ver- 25 der anderen Seite der Membran befindet. Hierdurch besserte Farbbeständigkeit, gemessen bei 100° C soll eine Verringerung im Aschegehalt erzielt weranfänglich und nach 2 Stunden, aufweist, zur den.
thrown glucose syrup, whereby the chamber avoided glucose syrup pretreated on io SO 2 , special one side of a cation-permeable membrane that the sweets produced with its help possesses and on the opposite side zen at least the same hardness and clarity and of an anion-permeable membrane as well at least the same color fastness and is limited, while the membranes from the outside improved color, as previously only the sweets were washed with an aqueous medium, 15, which were made from GIu pretreated with SO 2 and the glucose syrup a dextrose equivalent in the cose syrup. However, they are completely free in the range from about 30 to about 70, an ash layer of residual traces of SO 2 , the presence of which is below about 0.2 Vo, a conductivity in the case of foreign matter in the candy in any case below -25 ° C about 350 microsiemens or less and may also be unhealthy.
has less than 15 parts of amino acids per mil- 20 Belgian patent specification 645 544 and USA.-Palion contains parts of glucose syrup and another at least about 40% electronically describes the starting glucose syrup, in which a ash syrup improved color, measured at room-enriched branch flow on one side of a membrane temperature, just as one flows by at least about, while a low-ash branch flow is 40 1 Vo compared to the starting glucose syrup on the other side of the membrane. This improves color stability, measured at 100 ° C, a reduction in the ash content should be achieved initially and after 2 hours, to the.
Herstellung klarer harter Bonbons. Demgegenüber wird bei der vorliegenden ErfinMaking clear hard candies. In contrast, in the present inventor dung, wie bereits erwähnt, der Sirup durch minde-30 stens eine Elektrodialysekammer geleitet, welche aufAs already mentioned, the syrup is passed through at least one electrodialysis chamber, which opens einer Seite durch eine kationendurchlässige Membran und auf der anderen Seite durch eine anionendurchlässige Membran begrenzt ist, und auf beidenone side through a cation-permeable membrane and on the other side through an anion-permeable membrane Diaphragm is limited, and on both Zur Herstellung von klären harten Bonbons ist die Seiten wird ein wäßriges Medium für das Auswa-Verwendung eines mit Schwefeldioxyd behandelten 35 sehen der Verunreinigungen in dem Sirup verwendet, Glukosesirups bekannt. In vielen Ländern besteht wenn diese Verunreinigungen durch die Wände der nun ein immer stärker werdendes Bestreben, den Ge- Membranen hindurchgewandert sind (s. deutsche Ofhalt von Fremdstoffen in Lebensmitteln so gering wie fenlegungsschrift 1 806 816).For the production of clear hard candies the sides becomes an aqueous medium for the selection use one treated with sulfur dioxide 35 see of the impurities in the syrup used, Glucose syrups known. In many countries if this exists contamination through the walls of the now an ever increasing endeavor, which Ge membranes have wandered through (see German Ofhalt of foreign substances in food as low as decree 1 806 816). möglich zu halten oder einen solchen Gehalt über- Somit handelt es sich um zwei verschiedene Elek-possible to keep or exceed such a content. Thus, there are two different elec- haupt nicht zuzulassen. Zweifelsohne ist ein Restge- 40 trodialyseverfahren, auf Grund derer auch Produkte halt an SO2 in Bonbons als Fremdstoff aufzufassen, mit verschiedenen Eigenschaften erhalten werden,
und es ist daher zu erwarten, daß auch die Verwen- Zwar wird nach dem Stand der Technik ebenfalls
not to be allowed at all. There is no doubt that a residual trodialysis process, on the basis of which products containing SO 2 in candy can be regarded as foreign matter, is obtained with different properties,
and it is therefore to be expected that the use will also be made according to the prior art
dung eines mit SO2 behandelten Glukosesirups sogar ein Glukosesirup durch ein von dem hier verwendemöglicherweise in naher Zukunft eingeschränkt oder ten verschiedenes Elektrodialyseverfahren gereinigt, gar nicht mehr gestattet wird, wobei es dahingestellt 45 jedoch wird in der Literatur die Eignung eines so gebleiben kann, ob eine solche Forderung aus gesund- reinigten Glukosesirups für die Herstellung harter heitlicben Gründen berechtigt ist oder nicht. klarer Bonbons nicht angedeutet. Daher wird dortWhen a glucose syrup is treated with SO 2 , even a glucose syrup is no longer allowed to be cleaned by an electrodialysis process that may be restricted or different from the one used here in the near future, although it is left open in the literature whether a such a demand for healthy-purified glucose syrups for the production of hard uniform reasons is justified or not. clear sweets not indicated. Hence there will be Die Erfindung schafft nun bereits die Möglichkeit die erfindungsgemäße Verwendung des neuen Glukoeiner solchen möglichen Forderung zu entsprechen, sesirups nicht nahegelegt. Erst recht konnten aus ihr indem sie an Stelle eines mit SO2 behandelten Gluko- 50 die mit der Erfindung erzielbaren Vorteile nicht entsesirups einen in anderer Weise vorbehandelten Sirup nommen werden,
benutzt.
The invention already creates the possibility of using the novel gluco according to the invention to meet such a possible requirement that sesyrups are not suggested. A syrup pretreated in a different way could all the more be taken from it by using a syrup pretreated in a different way instead of a gluco-50 treated with SO 2, the advantages achievable with the invention
used.
Demgemäß besteht die Erfindung in der Verwen- AusführungsbeispielAccordingly, the invention consists in the use embodiment dung einer gekochten Mischung von 30 bis 50 %preparation of a cooked mixture from 30 to 50% Saccharose (Trockensubstanz) und dem Rest, beste- 55 40 Gewichtsteile Saccharose und 30 Gewichsteile hend im wesentlichen aus einem einer Behandlung eines gemäß dem im Vorstehenden angegebenen durch Elektrodialyse auf dem Durchgang unter einer Elektrodialyseverfahrens gereinigten Maissirups, welangelegten Gleichstromspanmmg durch mindestens eher ein Dextroseäquivalent von etwa 39 besitzt, eine Kammer unterworfenem Glukosesirup, wobei die werden mit 12 Teilen Wasser gemischt. Die Mi-Kammer auf der einen Seite von einer kationen- 60 schung wird auf etwa 132° C erwärmt und auf dieser durchlässigen Membran und auf der gegenüberlie- Temperatur gehalten, bis der Wassergehalt des sich genden Seite von einer anionendurchlässigen Mem- ergebenden Produktes unter etwa 3 Gewichtsprozent bran begrenzt ist, während die Membranen von beträgt. Dann wird das Produkt sich auf etwa 93 bis außen mit einem wäßrigen Medium gewaschen wer- 104° C abkühlen gelassen, wodurch sich eine plastiden, und der Glukosesirup ein Dextroseäquivalent im 65 sehe Masse bildet. Diese Masse wird dann in eine ge-Bereich von etwa 30 bis etwa 70, einen Aschegehalt wünschte Gestalt gebracht und bei Raumtemperatur unterhalb etwa 0,2 Vo, eine Leitfähigkeit bei 25° C unter Bildung eines klaren harten Bonbons erhärten von etwa 350 Mikrosiemens oder weniger hat, weni- gelassen.Sucrose (dry matter) and the rest, best 55 40 parts by weight of sucrose and 30 parts by weight essentially consisting of a treatment of one according to that given above Corn syrup purified by electrodialysis on the passage under an electrodialysis process, well-laid DC voltage by at least rather a dextrose equivalent of about 39, a chamber subjected to glucose syrup, which is mixed with 12 parts of water. The Mi Chamber on one side of a cation mixture is heated to about 132 ° C and on this permeable membrane and kept at the opposite temperature until the water content of the water low side of an anion-permeable membrane-giving product below about 3 percent by weight bran is limited, while the membranes of is. Then the product will get down to about 93 up Washed outside with an aqueous medium, allowed to cool 104 ° C, whereby a plastid, and the glucose syrup forms a dextrose equivalent in the 65 see mass. This mass is then put into a ge area from about 30 to about 70, an ash content of the desired shape and made at room temperature below about 0.2 Vo, harden a conductivity at 25 ° C to form a clear hard candy of about 350 microsiemens or less has left little.
DE19681817704 1967-11-02 1968-11-04 Glucose syrup for making clear hard candies. Eliminated from: 1806816 Granted DE1817704B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US68022967A 1967-11-02 1967-11-02

Publications (3)

Publication Number Publication Date
DE1817704A1 true DE1817704A1 (en) 1971-01-28
DE1817704B2 DE1817704B2 (en) 1974-03-07
DE1817704C3 DE1817704C3 (en) 1974-10-17

Family

ID=24730266

Family Applications (3)

Application Number Title Priority Date Filing Date
DENDAT1594704 Pending DE1594704A1 (en) 1967-11-02
DE19681806816 Pending DE1806816A1 (en) 1967-11-02 1968-11-04 Color-fast glucose syrup and its production by electrodialysis
DE19681817704 Granted DE1817704B2 (en) 1967-11-02 1968-11-04 Glucose syrup for making clear hard candies. Eliminated from: 1806816

Family Applications Before (2)

Application Number Title Priority Date Filing Date
DENDAT1594704 Pending DE1594704A1 (en) 1967-11-02
DE19681806816 Pending DE1806816A1 (en) 1967-11-02 1968-11-04 Color-fast glucose syrup and its production by electrodialysis

Country Status (6)

Country Link
BE (1) BE723183A (en)
DE (3) DE1806816A1 (en)
FR (1) FR1594716A (en)
GB (1) GB1245275A (en)
IT (1) IT1028001B (en)
NL (1) NL6815593A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3333676C1 (en) * 1983-09-17 1991-11-21 Krüger GmbH & Co KG, 5060 Bergisch Gladbach Beverage powder containing cocoa

Also Published As

Publication number Publication date
DE1817704B2 (en) 1974-03-07
GB1245275A (en) 1971-09-08
FR1594716A (en) 1970-06-08
DE1594704A1 (en)
IT1028001B (en) 1979-01-30
BE723183A (en) 1969-04-30
NL6815593A (en) 1969-05-06
DE1806816A1 (en) 1969-06-26
DE1817704C3 (en) 1974-10-17

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977
8339 Ceased/non-payment of the annual fee