DE1792622A1 - cleaning supplies - Google Patents

Description

cleaning supplies

The invention relates to new cleaning agents which are mainly used for removing black eye marks and from Serving picks.

It is known that the rubber soled shoes on plastic coverings of floors, tiles and linoleum remaining black traces are difficult to remove permit. Usually they are removed by means of powders which contain substances with an abrasive effect, e.g. the Scouring powder or by means of strongly alkaline preparations, e.g. detergents. However, all of these products own the main disadvantage that they are only after relatively

longer

209833/1080

Tangier and for the user always cumbersome application provide relatively good results. on the other hand often destroy these products as a result of wear and tear or the chemical reactions they cause Uniformity and the color tones of floor coverings, so that the latter quickly become cloudy and their freshness Lose appearance. Ultimately, the removal of black marks causes the wax skin to peel off, which

W - ■ '

usually covers the flooring. To restore the wax skin removed in this way, a new amount of wax must be applied after using detergent powder or detergents; this additional work process represents a loss of time that cannot be overlooked.

An object of the invention is to eliminate the above-mentioned drawbacks by providing the housewife with the maintenance of the P black shoe prints on floor coverings made of plastic or other materials are easy, effective and easy made possible quickly without changing the appearance and condition of these coverings in any way would.

Another object of the invention is the easy removal of marks, flakes and stains of all kinds, which are otherwise difficult to remove, such as the removal of! Eeerflecken and car grease, as well as the

209833/1090

cleaning furniture and seats.

Another purpose of the invention is the formation of Cosmetically usable compositions also with regard to the production of substances for cleaning hands dirty during technical work.

The cleaning agent according to the invention is characterized by ™ in that there is at least one solvent made from ethers of conoethylene glycol and monopropylene glycol-1,3 existing group.

This group corresponds to the "series of glycol ethers, which have the essential property of being volatile solvents due to their low boiling point. Compared with cyclic solvents or with polyglycol ether η with a similar molecular weight has the experience | shown that said glycol ethers are advantageous show a significantly lower activity towards plastics in the same application quantities.

The solvents used according to the invention are hereinafter referred to as "special type" solvent.

According to

209833/1090 BAD ORIGINS.

According to a preferred embodiment of the invention, the solvents of a particular type consist of monomethyl ethers of monoethylene glycol and monopropylene glycol- "1,3 and are used separately or in a mixture. These Monoethers have the lowest molecular weights and are consequently the most volatile; they are opposite Plastics are inert, regardless of their proportion in the cleaning agent according to the invention, they are non-toxic and do not irritate the skin.

The weight proportion of the volatile solvent special kind is preferably between 8 and 91 percent by. -I "the cleaning agent.

In practice, the cleaning agent according to the invention can have very different forms, in particular can it in liquid, paste or powder form or it can also be supplied in a push-button dispenser like an aerosol spray bottle. In this latter embodiment, which is often preferred, the pressurized is generally Liquefied propellant mixed with the cleaning agent if the distributor consists of a single container. However, the invention also advantageously comprises the use of two containers

Aerosol dispensers '209833/109 0

Aerosol dispensers (e.g. one in the other), one of which is the abrasive and the other the Contains detergent.

When the detergent is contained in aerosol dispensers is, it generally becomes at the moment of its application atomized into fine droplets, but it can also be composed in such a way that a foam or f receives a jet at the moment of atomization. According to a first embodiment of the invention contains the detergent composition which can be used in an aerosol dispenser, which forms the active concentrate and mainly used to remove black marks from At least one additional solvent is determined together with the special type of solvents, a surfactant and at least one wax.

It is known that black sole rubber consists of quite different compounds depending on the qualities, but in usually next to one that forms the basic component Elastomers (made from styrene-butadiene, nitrile rubber, polybutadiene, styrene-butadiene / polybutadiene, butyl rubber, Ifeoprene, etc.) contains:

Resins to increase rigidity and durability (especially phenolic resins)

209833/1090 stearic acid

Stearic acid
Zinc oxide

sulfur introduced by vulcanization

Plasticizers (naphthenic plasticizers, adipic acid esters, etc.)

and fillers, the most important of which, because coloring, consists of carbon black in an average Share of $ 30-40, based on the total mass.

Obviously, the removal of such prints from heavily pigmented rubber soles with additives, which give these prints a strong bond strength, exceptionally difficult.

It has now surprisingly been found that the application of the cleaning agent according to the invention on the questionable impressions for two to three seconds and a subsequent light rubbing with a dry one All you have to do is wipe it and these marks disappear allow.

Without being bound by it, the following explanation can be given for this process: The cleaning agent very quickly decomposes the rubber membrane forming the shoe sole impression, and this decomposition is likely to be a

209833/1090 quasi

this skin is quasi-deplasticizing. This so destroyed skin can then be removed by removing its organic and inorganic residues are brought back into emulsion when wiping with the cloth.

This re-emulsification is further promoted by the use of a surface-active agent.

At the same time, the wax contained in the active concentrate allows the wiping to be balanced out Loss of dry wax that has occurred to the rag, since fresh wax is supplied, which again has a forms protective and smooth skin and is applied to the floor covering with the aerosol composition.

Preferably, the active concentrate contains for the removal of black rubber footprints other than those above called constituents a colloidal silica.

This colloidal silica enables that at the same time re-emulsification and the settling of such re-emulsified Shares on the mopping cloth.

In practice, the essential components of the

according to the invention 209 833/1090

cleaning agent according to the invention according to the first Embodiment the following:

Solvent of a special kind '89 -91 * for additional solvent 5 - 10 $ surface-active agent about 0.5 7 »wax 0.5 - 5 Io

W colloidal silica up to. $ 5

The peculiarities of the components mentioned, in addition to the solvents of a special kind, are described below described in detail.

The additional solvent is preferably a ftaphthalene derivative, namely 1,2,3,4-tetrahydronaphthalene, which is inert to plastics, but enables accelerated decomposition of the rubber skin in combination with solvents of a special kind. However, 1, 2,3,4-tetrahydronaphthalene can also be used in a mixture with decahydronaphthalene in a ratio of 65λ> of the former and 35 ° of the second or in a mixture with white spirit 130-160 with at least 5 ° aromatics, namely with Use monochlorobenzene, methylcyclohexane, cyclohexanone, etc. .

ORIGINAL BATHROOM • 209833/1090

The surface-active agent is expediently a glycol ester of fatty acids with a long or medium chain length, for example the monopalmitate of polyethylene glycol 1000 or the monolaurate of polyethylene glycol 300. The wax is generally a hard, natural or synthetic wax, which is also a Esterwachs, an acidic wax type derMontansäure, a polyethylene wax, an ozokerite or Λ a petroleum wax, z-.B. Paraffin, oxidized microcrystalline wax, or petroleum jelly can be.

The colloidal silica is preferably substantially The solvent phase of the cleaning agent is completely dispersible.

The proportions in the aerosol dispenser are such a composition and the propellant gas on average 70 and 30 wt .- ^. The propellant is a saturated hydrocarbon such as butane or a chlorofluorinated hydrocarbon.

Just like the one described above in solution phase In the present detergent composition, the invention also provides the use of a detergent in the mixed phase consisting of solvent / water, if not with regard to the

■ Use

209833/1090

ORIGlMAL BATHROOM

Use in aerosol dispensers. In this case, it is particularly possible to advantageously produce compositions which can be dispensed in the form of a foam. This latter can either be directed towards the marks or stains to be removed, this removal then being carried out by wiping with a cloth, or the foam can be applied to the cloth, whereupon it is spread over the impression or the stain and then through Rubbing away. The detergent composition present in mixed solvent / water phase differs qualitatively from the previous one in that the additional solvent is water, which is present in the form of an aqueous wax emulsion, on the one hand the surface-active agent acting as an emulsifier during the preparation of the emulsion and on the other hand which often contains water-soluble solvents of a special kind. The surface-active agent, which is also different, is a reaction product of ethylene oxide with fatty alcohols and preferably a condensate of 20 moles of ethylene oxide and 1 mole of copro fatty alcohol with a hydrophilic-lipophilic equilibrium value of about 15-16.

The proportions of the constituents of this composition are quantitative in mixed phase, which differs significantly from those of the constituents of the solvent

209833/1090 ^J.

phase present composition distinguish the following: '

Special type of solvent approx. 20 % additional solvent (water) 30 - 50 ^c / o surface-active agent 4 - 7 ^c ß>

Wax . 7-10 ^c / o

Silica 0 - 15 ° / ° '

The proportions of the mixed composition and propellant gas inside the aerosol dispenser are also different and are on average 92 or 5 wt .- ^. That Propellant gas is preferably butane here.

Independent of. the type of cleaning agent, namely whether> in solvent phase or in mixed solvent / Water phase, offers such a composition which removes black marks from shoes with chewing soles should and is released in the form of aerosol the advantage very easy to use. The application takes place light, effective, economical and practical and it is enough to gently rub the surface two or more three seconds after spraying. The later application of a layer of wax, which was the case with previous methods was necessary, is also omitted. This results in a

209833/109 0 considerable

ORIGINAL

considerable time savings.

The cleaning agent according to the invention also has the advantage of not changing synthetic floor coverings, not even from Kautsehubboden. The inventive & improper Composition, which has no solvency for rubber, limits its effect to Destruction of the rubber membrane forming the black marks. On the other hand, the composition is not aggressive towards other plastics. The floor coverings thus retain their original appearance and their freshness of color.

The use of the cleaning agent as an aerosol is in the Pail of plastic floor coverings made of polyvinyl or rubber sheets, made of polyvinyl chloride or coumarone resins containing asbestos sheets and linoleum sheets are particularly effective. The application extends However, it can also be used on floors made of materials other than plastic, e.g. terrazzo flooring in the form of tiles or one-piece floors.

According to a second embodiment of the invention, the cleaning agent contains which is in liquid form and mainly to remove black marks

^209833/1090 BADOR ₁ G ₁ CAL.

pressing of rubber soles is intended, along with that Solvents "of a special kind, at least one additional solvent and at least one surface-active agent.

The proportions of these essential components are as follows:.

Special kind of solvents 20 - 40? Ί λ

additional solvent 5 - 10 % surfactant 25 -50 ^σ β>

Preferably the additional solvent consists of a ternary solvent mixture consisting of:

1 part decahydronaphthalene

2 parts of 1,2,3,4-tetrahydronaphthalene 2 parts monochlorobenzene

This mixture has the advantage of being significantly increased Effect.

The surface-active. Means also consists of several components, preferably a mixture of condensation products of ethylene oxide with a substituted phenol or with castor oil and a ■ EthiolaTflid of copra fatty acids. But you can too Use ternary mixtures that can be obtained by adding a

surface active 209 8 33/1090 - -

surfactants such as the sodium salt of Lauryl polyethylene glycol sulfate is obtained for the above mixture.

The removal of black marks from rubber soles is easy and quick with a cloth which one gives the liquid detergent; afterwards, in the same way as with the aerosols in Form of foam released means the traces by rubbing with the rag on the surface to be cleaned eliminated.

The liquid cleaning agents according to the invention have the same effectiveness as the detergents dispensed from aerosol bottles.

According to a third embodiment of the invention that is present in paste form and mainly contains Cleaning agents and solvents used to remove black marks from rubber soles a particular type of at least one adsorbent filler, one surface-active agent and at least one wax in aqueous emulsion.

Here the adsorbing fillers are used to achieve this the paste form.

209 83 3/1090 the

The proportions, the essential components of the pasty Detergents are the following:

solvent "special kind about $ 10 adsorbent filler 50-75 $ surfactant 6-10 $ $ 15 aqueous wax emulsion

of a hard ester wax 10 fo Λ

The adsorbent filler preferably consists of a combination of finely powdered pumice stone and talc, the latter softening the smeary effect of the pumice stone; both components are present in approximately equal proportions. However, other fillers can also be used, 2.3. a mixture of very fine hydrated aluminum oxide and bentonite, in which the bentonite makes up a preferred proportion of 7-10 ^c / o .

■ .. ■■: ■ - i

The surfactant gown is a condensation product of ethylene oxide and a substituted phenol and preferably a condensate of 10 Hol ethylene oxide and 1 hol of nonylphenol. Han can also use mixtures of the above Use the said ion-condensation products with ethanolamides of zopra fatty acids.

To remove the black marks from rubber soles If you spread the pasty detergent by means of

209833/1090

BAD QRIGfNAL

1732622

- Apply a cloth to the cleansing breastfeed and rub wit b§i dtn previous Mafuarungiforsren Place with a flap until the removal of the

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s? vi © rte & Auifütoimtsf © 2? ». iit the detergent piilvtiefosmig and. ¹ determines the suhw & aiSin abdrueke

j es b ^ st ^ ht in Kotablnatloji with the L ^ Büngstaittöla special Äi? t from at least a eintta lUeungsffiittel and © is.eE strong

Si © Äntiiii der Wiseiätliciiiii Bistanttiilt fö3emig «n Heinigangsaittels and die

Art

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trabydrönaphtlaalla. · Man karni aa§b. Bi

A strongly adsorbent quenching consists of types iron ^

* 2 0 S 8 3 3 / 101Q _iAD original

The powdery one! Leave detergents like that apply in paste form and have the same advantages.

According to a fifth embodiment of the invention relating to a more general application of the cleaning agent, the cleaning agent contains at least one μ in combination with the solvents of a particular type

■ additional solvent.

These additional solvents are preferably: Methyleyclohexan, Cyclohexanon., Diohloraethan-1,2, Tetrahydrofurfuryl alcohol, ethanol, isopropanol. The detergents correspond! the fifth embodiment have very different applications. Those that do the same for the first four embodiments are similar to those given are:

The elimination of marks left on the frames by the black "rubber hinges of the car doors of automobiles,

the removal of tar stains,

cleaning plastic-covered office desks, by yourself if they are soiled with ballpoint pen ink,

the cleaning of plastic-covered armchairs.

as 209833/1090 Ol ^,

Other uses include: cleaning enamelled metal furniture, polishing other than ferrous metals, defrosting windows,
fc dissolving nail polish,

cosmetic applications.

All of these cleaning agents can be in the forms they are intended for the first application, . i.e. in the form of a liquid, a paste, a powder, an aerosol in solvent phase and a Aerosol in mixed solvent / water phase.

\ The following non-limiting examples are for loading · voted embodiments of the five preferred modes of the inventive detergent described,

Example I.

Detergent in the form of an aerosol to remove "the." black imprints of rubber soles.

^:: - · .209833 / 1090 'V ,. ·; .; v ^ y ^ sos

a) l

0 * 5 J * 3 / ^

Waö & s S (as

70 ¹ ^ de § concentrate a) 30 fo Möhlöfäifluörarthaft

S)

l ia JLt-röäölfe ^ a fü ^ din gieiöhöii 4a.

k wi © la Btiepitl ■ X «

a) Koaeentaiat!

aiin

5 5j 1,2,3V
0.5 ^ Measpalmitate of polyethylene glycol 1000

1 fa yellow American ozokerite 84--86 ⁰ G 1.5 ^ Äfrosil U (colloidal silica)

2 fs isoamylaoetat (as a scent)

■ fe) aerosol:
70 0 des ICönsentrats a) 5 fi 3) iehl-oa? Diiluormei; han (Preoa 12)

Example IIT

BATH ORIGINAL

Example III

Cleaning preparations in aerosol form for removing tar stains, in particular on car bodies, floors, shoes.

a) concentrate:

80 ° / o monoethylene glycol monomethyl ether

7 'P oleic acid
13 # dichloroethane-1,2

b) aerosol:

■ 70 fo of the concentrate a)

30 f> dichlorodifluoromethane (Preon 12)

Example IV

Cleaning agent in aerosol form for the care of plastic-covered furniture, car seats or plastic fabrics.

a) concentrate:

S5 / o monoethylene glycol monomethyl ether or monopropylene glycol-1 , 3-rmonomethyl ether

7.5 fo oleic acid

5.5 i ° methoxy-3-propylamine

2 fo 3,5-dimethyl-1-hexyn-3-oi

b) aerosol:

• 20 9833/1090 bad original

b) aerosol:

70 -i <> of the concentrate a)

50 fo diehlordifluoromethane (Freon 12)

Example IT . '■ "

Cleaning agent in aerosol form for the care of enamelled metal furniture, e.g. refrigerators, washing machines, kitchen elements.

a) concentrate:

90 io monoethylene glycol monomethyl ether or monopro pylene glycol 1,3-monomethyl ether ■

8 ^c / o 90? Aige paste of ammonium oleate 2 ^G / o ammonia with 28 ° Baume

b) aerosol:

70 fo of the concentrate a)

30 ° / o dichlorodifluoromethane (Preon 12) or butane

Example VI ,

Cleaning agent in aerosol format for polishing calibration Ferrous metals e.g. copper, aluminum, chromium.

a) concentrate:

85 ίο monoethylene glycol monomethyl ether

JLi 209833/1090

* - 22 -

5 "fl cyclohexanone

4 ft 9O? £ ammonium oleate paste

6 fo diatomaceous earth

b) Aerosol:.

70 ^e / o of the concentrate a) 30 ^c / o dichlorodifluorraethane (Freon 12)

Example VII

Detergent in aerosol form for defrosting Washers with a cleaning effect.

a) concentrate:

70 ^c / o monoethylene glycol monomethyl ether

3 ^c / o 3,5-dimethyl-1-hexyn-3-ol (volatile surfactant)

27 ° denatured ethanol or isopropanol

b) aerosol:

70 ° / o of the concentrate a) 30 Jo dichlorodifluoromethane (Ereon 12)

Example VIII

Aerosol detergent for use as a general stain remover for:

Floors, tiles and tusks

rusted iron surfaces 209833/1090

and for the removal of all kinds of encrusted corners.

a) concentrate:

73 ° Monoath.ylene glycol monomethyl acetate or monopropylene glycol 1,3-iuonomethyl ether

5 i ° 90> iiges ammonium oleate

4 ° methylcyclohexane

1 ^c / o monoethanol amine

7 Φ fine silica ä

5% talc 00 / PA

2 ¹ P Pumice Stone OOOOÖ

3 ^c / o monolaurate of polyoxyethylene glycol 300

b) aerosol:

io of the concentrate a)

^a / o dichlorodifluoromethane (Preon 12)

Example IX

Detergent in aerosol form with dissolving effect for nail polishes.

a) concentrate:

52.5 1 * conoethylene glycol monomethyl ether 7.5 ϊ ° cyclohexanone
^c ß> tetrahydrofurfuryl alcohol

b) aerosol:

70 5 ^ of the concentrate a)
■ 30 io dichlorodifluoromethane

209833/1090 Example X

Example X

Cleaning agents in aerosol form for cosmetic purposes, namely:

for removing make-up (by spraying on a cellulose cloth or the like beforehand)

for the care of the hands
as a dry shampoo
against hair loss

a) concentrate:

$ 49.75 Monoethylene glycol monomethyl ether 40 fo tetrahydrofurfuryl alcohol

10 fo Honolaurate of Polyoxyethylene Glycol 300 (or 400) $ 0.25 Clove Perfume 12,001 DTG

b) aerosol:

70 ^c / o of the concentrate a)

30 io tetrafluoroethane (Preon 114), or dichlorodifluoromethane. (Preon 12), or butane or 50/50 Preon 114 or V 12 with butane

Example XI

Cleaning agent in aerosol form in aqueous phase for the same purpose as in Example I.

a.) concentrate

• 209833/1090 - ₀ -

a) concentrate:

20 ^a yes monoethylene glycol monomethyl ether

45 io aqueous emulsion of 15 ^σ / ° synthetic ester wax and 10 ⁰ Jo surface-active agent

15 ^c / ° Silicic acid Ur .. 6

10 io talc 00 / EA

10 ° / o pumice stone 00000 ■

b) aerosol:

92 io of the concentrate a)
8 io butane

Example XII

Foam detergent stored in an aerosol container for the same purpose as that of example

a) concentrate:

20 io monoethylene glycol monomethyl ether

Io 65 v / ässrige emulsion with 15 ^c / ° hard Esterwachs and 10 io oberflächenaktivennMittel

1.5 % talc 00 / PA
7> 5 i> aluminum silicate

b) aerosol:

92 '/ Ό of the concentrate a)
- 8 io butane

JBoLnpie.l XIII

209833/1090

Example XIII

Foam contained in an aerosol container for washing hands that have been soiled by technical products, in particular for cleaning tar and lubricants.

a) Concentrate: "

8 i « monoethyl glycol monomethyl ether

^{11.5 c} / o condensate of 10 moles of ethylene oxide and 1 mole of nonylphenol

7.5 $ condensate of 11 moles of ethylene oxide and 1 mole Octylphenol

11 ^c / o alkyl diethanolamide of copra fatty acids (100 $) 17 i ° isopropanol 4> 5 $ monochlorobenzene

8.5 $ white spirit with an aromatic content of at least 5 ° ß>

$ 0.7 decahydronaphthalene $ 30 distilled water

The viscosity of the medium can be increased and one can thereby obtaining a denser foam when using a carboxymethyl cellulose or something similar Derivative in a proportion of 0.2-0.5 $ dissolves in the water.

b) aerosol:

90 $ of the concentrate a) 10 ^c / o butane

the

209833/1090

Examples 11-13 above correspond to aerosol compositions in mixed solvent / water phase.

The following are examples of detergents which are not for aerosol dispensers ", but according to their nature in bottles, pots, tubes or other containers be kept.

These compositions all contain a solvent * of a special kind, and optionally one or more additional solvents. Yiasser can also be contained therein and then forms a solvent / water mixture; In addition, the Yfesser can play the role of a real additional solvent.

A) Cleaning agents in liquid form

Example XIV '

For removing black marks from rubber soles Cleaning agent intended for floors:

40 / j Honoethylene glycol-i-ioncc '^ aiyl ether

15 r> condensate from 10 hol ethylene oxide and 1 mol ionyl phenol

5 ', j condensate of 14 moles of ethylene oxide and 1 mole castor oil

5 / ί alkyl diethanolamide of copra fatty acids

20 <fo

ORIGINAL BATHROOM 20 9 833/1090

20 '/ ο isopropanol

10 ^c / o white spirit with at least $ 5 aromatics ^

1 ° / o decahydronaphthalene

2 " / o 1, 2,3,4-tetrahydronaphthaiin 2 ^c / o orthodichlorobenzene

In this way an amber-yellow, clear, mobile liquid is obtained which, in addition to the black footprints, also has Tar and smudges removed.

Example XV

Detergent for the same purpose as that of Example XI?, But in addition to washing the Hands can be used (for mechanics, tar workers, etc.)

^c / o monoethylene glycol monomethyl ether

5 io condensate from 10 moles of ethylene oxide and 1 mole of Konyiphenol

^c / o lauryl polyethylene glycol sulfate of sodium (28 $ i 5 io diethanolamide of copra fatty acids ^c / o isopropanol
io white spirit 130-160 with at least 5 $ aromatics 2 io decahydronaphthalene 4 ^ 1,2,3,4-tetrahydronaphthalene 4 ° r> monochlorobenzene

'209833/1090

B) Cleaning agents in paste form Example XVI

For removing black marks from rubber soles paste intended for floors.

5 fo. Monoethylene glycol monomethyl ether

5 ° ß> monoethylene glycol monobutyl ether "

10 ⁰ Jo condensate of 10 moles of ethylene oxide and 1 mole of uronylphenol

10 fo aqueous emulsion with 15 i ° a hard Esterwachses

15 "aqueous solution containing 1 i jiOarboxymethylcellulose high viscosity

1 / ö monoethanolamine
29 ^c / o pumice stone 00000
25 ^c / o Talc 00/5 ¹ A ^ coloring perfume

The talc contributes to the flowability of the composition at and softens the abrasive effect of the pumice stone, which together with the viscosity of the paste of the composition takes any aggressiveness.

Example XVII . ■ ■

209833/1090

Example XVII

Paste for the same use v / ie in Example XIV that but can also be used to wash hands, e.g. for mechanics.

10 io monoethylene glycol monomethyl ether

2.5? £ condensate from 10 moles of ethylene oxide and 1 mole ÜTonyl phenol

1.5 £ o condensate of 11 moles of ethylene oxide and 1 mole Octylphenol

2> Diethanolamide of copra fatty acids 0.9 $ Monochlorobenzene 1, T / o white spirit 0.2f »Decahydronaphthalene 0.4 $ 1,2,3,4-Tetrahydronaphthalene 70 ⁽ fo fine hydrated aluminum oxide 4.8? Ü Bentonite

6 io demineralized Viasser

G Detergent in powder form Example XVIII

Cleaning agents for removing prints from Rubber shoe soles on floors.

40 _f 209833/1090

40 ^r / o monoethyleneglylcol-monomethyläthe.r β-fo 1, 2,3,4-tetrahydronaphthalene 4 'ρ dimethyl succinate
49j5 / »white, fan diatomaceous earth $ 0.5 perfume

Example XIX

■ ■

Cleaning powder for the same application a; e3lc as that of Example XTIII.

40 ■ /> Monopropylene glycol nonionomethyl ether 10 ^c , 'j dipentene

5 ^t p talc 00 / PA
44.5 '/ ^ iSLiie, strongly adsorbing diatomaceous earth 0.3 ^c p perfume.

This composition is very effective and attacks soil do not cover.

Example XX Cleaning powder which foams when added to water.

2 09 83 3/1090

10 ^ o Monoethylene glycol monomethyl ether

10 % white spirit 130-ΙβΟ with at least 5% aromatics

$ 0.8 decahydronaphthalene

1.2 % 1,2,3,4-tetrahydronaphthalene

30? » powdered sodium oleate

5 i »monochlorobenzene
P ^ 2.5 / O white diatomaceous earth

0.5 ^ perfume

This powder, which does not contain synthetic surfactants, can be useful for cleaning the Serving the hands of workers who have to handle very dirty objects or substances.

These pastes and powders can be granulated or compressed (e.g. into tablets) or they can be made into any other Form can be transferred in which their properties are not lost. These embodiments thus fall within the Scope of the invention.

Example XXI

Liquid, aerosol-packed cleaning agent for removal of footprints from shoe soles.

209833/1090

41.5 f ° methyl ester of ethylene glycol (component A)

41.5 ¹ P Essence E = aliphatic petroleum fraction Kp 110-140 (C ₈ -C ₁₀ ) (component B)

6.5 fb cetyl alcohol (component C)

1.0 fo 'silicone

(Component D) ^

9.5 fo perfume dissolved in turpentine oil. (Component G)

Jo concentrate

Finished product

% Concentrate

30 ■ $ butane propellant (isobutane / n-butane 80:20)

The invention is not limited to the specified compositions limited, these only serve to explain the many possibilities of the invention.

209833/1090

Claims (22)

Claims 1. Cleaning agent, characterized in that there is at least one solvent of the monoethylene glycol ethers and monopropylene glycol 1,3-ethers existing group. 2. Cleaning agent according to claim 1, characterized in that that the ethers are monomethyl ether. 3. Cleaning agent according to claim 1, characterized in that that the amount of ether is between 8 and 91 wt .- ^ of the detergent. 4. Cleaning agent according to claim 1 for delivery from an aerosol container in Eorm of an active concentrate, preferably for removing black 'marks from rubber soles, characterized in that it is except the ethers at least one additional solvent, one surfactant and at least one Contains wax. 5. Cleaning agent according to claim 4> characterized in that that it is colloidal silica in a solvent phase contains. Documents (Art. 7 jl Abn. 2 No. I StaXz 3 dia Xruterunaaoes. *. 4. S 209833/1090 6. Cleaning agent according to claim 4, characterized in that the additional solvent. 1, 2,3,4-tetrahydronaphthalene is. 7. Cleaning agent according to claims 4,5,6, characterized characterized in that the surfactant is a polyglycol ester of fatty acids with long or medium chain length. 8. Cleaning agent according to claim 4, characterized in that that the wax is a hard, natural or synthetic v / ax. 9. Cleaning agent according to claims 4 and 6, characterized in that the amount of 1,2,3,4-tetrahydronaphthaiin between 5 and 10 wt .- ^ of the detergent. 10. Cleaning agent according to claim 4, characterized in that that the additional solvent is water. 11. Cleaning agent according to claims 4 and 10, characterized characterized in that the surfactant is a condensate of 20 moles of ethylene oxide and 1 mole of copro fatty alcohol with an HLB rating of about 15-16. 12th 20 9 8 33/1090 BADOBKSHNAi 12. Cleaning agent according to claims 4 and 10, characterized characterized in that the water added as an additional solvent is between 30 and 50% by weight of the cleaning agent amounts to. 13. Cleaning agent according to claim 1 in liquid form, mainly for removing the black marks from rubber soles, characterized in that it ^ · Together with the Ithers at least one additional Ψ Contains solvent and at least one surfactant. 14. Cleaning agent according to claim 13, characterized in that that the additional solvent is a ternary mixture of 1 part decahydronaphthalene, 2 parts 1, 2, .3,4-Tetrahydronäpthalin and 2 parts of monochlorobenzene. " 15. Cleaning agent according to claim 1 in paste form, mainly for removing the black marks from rubber soles, characterized in that it is composed with the ethers at least one adsorbent filling, one surface-active agent and at least one in Contains wax located in an aqueous emulsion. 16, 209833/1090 16. Cleaning agent according to claim 15, characterized in that that the adsorbent filling is a combination of finely powdered pumice stone and talc. 17. Cleaning agent according to claims 15 and 16, characterized characterized in that the adsorbent filling makes up between 50 and 75 G-ew .- ^ of the total detergent. - ■ i 18. Cleaning agent according to claim 1 in powder form, mainly for removing the black marks from rubber shoe soles, characterized in that, together with the ether solvents, there is at least one additional Contains solvent and a strongly adsorbent filling. 19. Cleaning agent according to claim 18, characterized in that that the adsorbent filling consists of different Types of diatomaceous earth. i 20. Cleaning agent according to claims 18 and 19, characterized characterized in that the adsorbent filling between 40 and 50% by weight of the detergent. 21. Cleaning agent according to claim 1 for general cleaning purposes, characterized in that it, together with the A'therlööungsmit bein, at least one additional Loηun ^ amit to L enth'i'H. BADOWGtNAt 20 9 8 3Ü7 H) Ui) ' 22. Cleaning agent according to claim 21, characterized in that that the additional solvent methylcyclohexane ,, Cyclohexanone, 1,2-dichloroethane, tetrahydrofurfuryl alcohol, Is ethanol and / or isopropanol.