DE1669156A1 - Binder colors - Google Patents

Binder colors

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Publication number
DE1669156A1
DE1669156A1 DE19671669156 DE1669156A DE1669156A1 DE 1669156 A1 DE1669156 A1 DE 1669156A1 DE 19671669156 DE19671669156 DE 19671669156 DE 1669156 A DE1669156 A DE 1669156A DE 1669156 A1 DE1669156 A1 DE 1669156A1
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DE
Germany
Prior art keywords
binder
paint
diameter
hollow beads
hollow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19671669156
Other languages
German (de)
Inventor
Herbert Dr Bartl
Frank Dr Wingler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
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Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of DE1669156A1 publication Critical patent/DE1669156A1/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres
    • C08L2205/20—Hollow spheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)

Description

Binderfarben Gegenstand der Erfindung ist die Verwendung von Hohlperlen mit einem Durchmesser von 15 b38 1000 aus Copoiymoriten von Vinylchlorid Und Äthylen ogebemmonfalls in P®ehumit l'ropylen oder Is®butylen aio Allstoffe für Binderfarben. l.ßtoff'kltio BindeNfarben sind bereits behato ` solchen rarbea z¢ B. thizotropQ @io@l@@ederite oder Kohl- perlen ano Phenol odere@..®ß@en als rüliot®ffä ZugeOetzt. Dbei ergab sich aberg daß Anot2iche aus diesen 1-aaon booanders in dickere, Schachten beim Trocknen rissig cezdGno Dio Eßbildung beruht im wesentlichen daraufg daß bei dQƒ Bintformou eee Lösungs- mittels sich dis Volumen der AnstrichmsEoono@ind und die Füllstoffe nicht elastisch und dehnbar genug eigad fl um diese Schrumpfung ohne Rißbi`1 dung auszugleichen. - wurde nun gefunden, daß man Binderfarben von 10 ° 90 tg', bezogen auf die fertige Nischung von Hohlperlen, wit-. einem Durchmesser von 15 bis 10ü0 ju aus Copolymerisaten von 8® 92 Gewichtsteilen Vinylc%lorid und 1 6 ® 8 Gewichtsteilen Äthylen, da® teilweise durch Propylen oder I®obutylen ersetzt sein kann, zumischen kann. Die so erhaltene Binderfarbe trocknet auch in dicken Schichten ohne Rißbildung. Hohlperlen mit einem Durchmesser von 15 bis 1000 p aua dem ge ten Niechpolymerisat können gemäß einem eigenen älteren Vorschlag erhalten werden, wenn man Vinylohlorid und Äthylen, gegobenünäalls in Nechung mit Proylen oder ädobutglen,in SuspGnsion unter Druck polymerisiert und nach Beendigung der Polyea2sation eatopat. Dabei bilden: sich kleiie Poly®erisat- bläochon. Ik ist uch möglichg von einem fertigen-Vinylchlorl- cop®l@riQt auszugahon, in diceee l,terial eia Treibmittel o. inonz2b- aiten und denn das E°Lteri vl - .Fz",g 'ra2Fcäumen. Bevorzugt ®@@.,'u@'.Qt a zu In #;äMßrigo2 Suspension unter starkem Ruhren bGilc@c@,itier Anv-jooaahGit düo Treiburi Stele .@ Wann man die ®C@''@'QI efies 3 vIlötLjmdiäurchf`t g können-auch- die g, C'3 st@tt`'CGiu'`@-'','Ig al@ Treibmittel -vjzkenß Sonst -kann ;n Klo Treibau tol niedrig siedende Lösungsmittel wie Methyl® chlor i d:c@ h` Q@.hlorid, Tetrachlorkchlenstoäf, Benzole Methyl- ae Gtßt g Acotom ®dQz Gase abpaltonde Verbindungen Z . B ® $ Azudiearbom-, Dintrosopentafethy® er BQ inz®-l° 1: 3.cadiaulk.®hy drasi verwenden. e Größe der e.#l tenen Hohlperlen kann. durch die Rührge- schwindigkeit bei der Suepeneionapolymerieti on. und durch die Art und Menge dzo s variiert :erden. Eine weitere- Möglß ehteit besteht eazin, diPolerition frühzeitig abzu- brechen, wobei die Restmengen der Monomeren als Treibmittel wirken. Die Menge des vorhandenen Treibmittele richtet sich dann nach dem Folymerieationsumsatz. Erfindungsgemäß kann dieses Hohlperlenmaterial jeder beliebigen Anstrichmasse zugesetzt werden. De-Anstrichmasse darf lediglich kein Lösungsmittel enthalten, das die Vinylchloridcopolymeren löst oder quillt. Das gilt z. B. für Anstrichmassen, die @@Ev aromatische Kohlenwasserstoffee Betone oder Ester als Lösungsmittel enthalten. Bevorzugt verwendet man Hohlperlen als Füll-Stoffe für Anstrichmassen, die als Binder eine wäßrige Polymerisatemulsion enthalten. Es kommen aber auch Anstrichmittel in Frage,7die aliphatische Kohlenwasserstoffe oder Alkohole als lösungemittel oder trocknende Öle als Suspendiermittel enthalten. Als Bindermittel eignen sich Polymerieate, bzw. Copolymerieate von Vinylchlorid, Vinylidenchlbrid, Propylen, Iaobutylen, 1.3-Diolefinen, Styrol, Acrylnitril, VinylesterAcrylsäure- bzw. Methacrylsäureester, Miachpolymerisate aus den aufgeführten Monomeren, gegebenenfalls mit weiteren Comonomeren wie Maleinsäure-Derivate oder Äthylen. Die Binder können auch selbstvernetzende -Gruppen enthalten. Es kommen auch polymerisate mit funktionellen Gruppen infrage, die mit einem iernetzer reagieren können wie z. B. Carboxyl-, Ester-, Anhydrid-, geto-, Isocyanat-, Hydraxyl-, Amino- oder Epoxidgruppen enthaltende Copolymere der oben aufgeführten Monomere. Gleichgut geeignet sind Anatrichmittel auf Basis unverseifter oder vollständig verseifter Vinylester-Homo- oder Copolymerisate. Die Anstrichmittel können die üblichen Füll-Stoffe wie Kalk, Kreide, Schwerspat, Kieselsäure-Derivate, Titantioxid, Bariumsulfat, Zinksulfid, Zithopone und Farbstoffe in Form von Pigmenten oder löslicher Farben enthalten. Die erfindungsgemäß verwendeten Hohlperlen mit einem Durchmesser von 15 bis 1000A können der fertigen Anatrichmasse in Mengen von 10 - 90 Volumen %, bezogen auf die fertige Mischung, zugesetzt werden. Bei Mengen bis zu 50 Volumen % bleibt die Anstrichmasse streichfähig. Sie kann in dicken Schichten aufgetragen werden, Die Masse stellt dann ein nichttropfendes Anstrchmittel dar, Beim Zusatz von Mengen zwischen 50 - 90 Volumen % erhält man dickflüssige Massen, die als Spachtel- oder Verputzmassen geeignet sind. Die Anstrichmitte.1 können in Dicken bis 5 mm an senkrechten Wänden aufgetragen werden, ohne daB ein Ablaufen zu befürchten ist. Da die Hülle der Hohlperlenpolymerisate plastisch ist, passen sich die Perlen dem Schrumpfvorgang-beim Trocknen an, ohne zu reißen. Schichtdicken bis 5 mm trocknen ohne weiteres ohne Rißbildung durch. Da die Hohlperlen schwer entflammbar sind, wirken die Hohlperlen gleichzeitig als Flammschutzmittel. Darüberhinaus besitzen diese Anstrichmittel eine gute Isolier-und Schalldämmwirkung, so daß mit diesen Mischungen dämmende Anstriche ausgeführt werden können. Hierzu eignen sich besonders die Hohlperlen von einem Durchmesser von 100/i bis 1000w.Binder colors The invention relates to the use of hollow beads with a diameter of 15 b38 1000 from Copoiymorites of vinyl chloride and ethylene ogebemmonfalls in P®ehumit l'ropylen or Is®butylen aio all substances for binder colors. l.stoff'kltio binding colors are already behato ' such rarbea e.g. thizotropQ @ io @ l @@ ederite or cabbage pearls ano phenol or @ .. ®ß @ en as rüliot®ffäzugOetzt. But it turned out that anot2iche from these 1-aaon booanders in thicker, shafts cracked when drying cezdGno Dio edible formation based essentially daraufg that eee at dQƒ Bintformou solution by means of the volume of the paints Eoono @ ind and The fillers are not elastic and stretchable enough to fit them Compensate for shrinkage without cracking. - it has now been found that binder colors of 10 ° 90 tg ', based on the finished niche of hollow pearls, wit-. one Diameter from 15 to 10μ0 from copolymers of 8® 92 Parts by weight of vinyl chloride and 1 6 ® 8 parts by weight of ethylene, since® can be partially replaced by propylene or I®obutylene . The binder paint thus obtained dries even in thick layers without cracking. Hollow beads with a diameter of 15 to 1000 p on the ge th Niechpolymerisat can according to its own older Proposal can be obtained if you use vin y chloride and ethylene, given in contact with propylene or ädobutglen, in Suspension polymerized under pressure and after the end of the Polyea2sation eatopat. In the process: small poly®erisat- bläochon. Ik is also possible from a finished vinyl chloride cop®l @ riQt extract, in diceee l, material eia propellant o. inonz2b- aiten and then the E ° L t e r i vl - .Fz ", g 'ra2Fcäum. Preferred ® @@., 'U@'.Qt a to I n #; äMßrigo2 suspension with vigorous stirring bGilc @ c @, itier Anv-jooaahGit düo Treiburi stele. @ When to use the ®C @ '' @ 'QI e fi es 3 vIlötLjmdiäurchf`tg can-also- those g, C'3 st @ tt`'CGiu'` @ - '', 'Ig al @ Propellant -vjzkenß Otherwise -can ; n Klo Treibau tol low-boiling solvents such as Methyl® chlorine id: c @ h` Q @ .hloride, carbon tetrachloride, benzenes methyl ae Gtst g Acotom ®dQz gas-separating compounds Z. B ® $ Azudiear b om-, Dintrosopentafethy® er BQ inz®-l ° 1 : 3 .cadiaulk.®hy dra s i use. e size of the e . # l tenen hollow beads can . through the agitator speed of Suepeneionapolymerieti on. and through the Type and amount dzo s varies: earth. Another- It is possible for eazin to reduce diPolerition at an early stage. break, with the residual amounts of the monomers acting as a blowing agent. The amount of propellant present then depends on the turnover of the polymerisation. According to the invention, this hollow bead material can be added to any paint composition. De-paint must only contain no solvent that dissolves or swells the vinyl chloride copolymers. This applies e.g. B. for paints that contain @@ Ev aromatic hydrocarbons, concretes or esters as solvents. Hollow beads are preferably used as fillers for paint compositions which contain an aqueous polymer emulsion as a binder. However, paints which contain aliphatic hydrocarbons or alcohols as solvents or drying oils as suspending agents are also suitable. Suitable binders are polymers or copolymers of vinyl chloride, vinylidene chloride, propylene, Iaobutylene, 1,3-diolefins, styrene, acrylonitrile, vinyl ester, acrylic or methacrylic acid esters, copolymers of the listed monomers, optionally with other comonomers such as maleic acid derivatives or ethylene. The binders can also contain self-crosslinking groups. There are also polymers with functional groups that can react with a crosslinker such. B. carboxyl, ester, anhydride, geto, isocyanate, hydroxyl, amino or epoxy group-containing copolymers of the monomers listed above. Also suitable are cosmetic agents based on unsaponified or completely saponified vinyl ester homo- or copolymers. The paints can contain the usual fillers such as lime, chalk, barite, silicic acid derivatives, titanium dioxide, barium sulfate, zinc sulfide, zithopone and dyes in the form of pigments or soluble colors. The hollow beads used according to the invention with a diameter of 15 to 1000 Å can be added to the finished anatrichmass in amounts of 10-90% by volume, based on the finished mixture. In quantities of up to 50% by volume, the paint remains spreadable. It can be applied in thick layers. The mass then represents a non-dripping paint. When adding amounts between 50 - 90% by volume, thick masses are obtained, which are suitable as leveling or plastering masses. The coating center 1 can be applied to vertical walls in thicknesses of up to 5 mm without fear of running off. Since the shell of the hollow bead polymer is plastic, the beads adapt to the shrinking process during drying without tearing. Layer thicknesses of up to 5 mm dry easily without cracking. Since the hollow beads are hardly inflammable, the hollow beads also act as a flame retardant. In addition, these paints have a good insulating and soundproofing effect, so that insulating paints can be carried out with these mixtures. The hollow beads with a diameter of 100 / i to 1000w are particularly suitable for this purpose.

Die Anstrichmittel.findän vielseitige Verwendung im Innen- und Außenanstrich. Mischungen mit Hohlperlen vom Durchmesser 15 bis 40 ja geben einen seidenähnlichen Glanze während durch Beimischung von Hohlperlen*vom Durchmeaaer 100 bis 1000ju muhe Effektoberflächen erhalten werden können. Beispiel 1 230 cm3 Hohlperlenpolymerisat mit einem Gehalt von 12 % Äthylen und 88 % Yinylohlorid und einem Durchmesser von 40 bis 150 werden mit 80 cm einer Polymerisatemuleion,. bestehen aus einem Copolymerieat aus Styrol und Acrylsäurebutyloster mit-einem Feststoffgehalt von 42 % gemischt. Mit der Mischung werden Prüfplatten aus Eternit in 1 mm und 5 mm Schichtdicke bestrichen und senkrecht aufgestellt. Die Parbe läuft nicht ab. IJach 2tägigem Trocknen bei Raumtempera tur-erhält man einen festen weian Anstrich ohne Rißbildung. Der Anstrich besitzt einen seidenmatten Oberflächenglanz. Beisp Aus 520 cm3 Hohlperlenpolymerisat und 80 cm der Binderfarbe wie in Beispiel 1 erhält man eine Masse, die mit einem Spach- tel in 6 ®m Schichtdicke aufgetragen, nach dem Abbinden und Trocknen bei Raumtemperatur keine Risse zeigt. Beispiel 3 Aus 100 cm5 Hohlperlen vom Durchmesser 100 bis 200 Und 50 em3 _einer Binderfarbe, die als Binder in wäßriger Emulsion 57 Ge- wichtsprozente eines Vinylchlorid-Äthylen-Copolymerisates enthält, wird eine dickflüssige: jedoch pocht streichfähige Anetrich®asser erhalte:.. Die Anatrichmasse läßt sich in Schicht- dicken von 0,2 his & mm auftragen, ohne nach dem Trocknungsprozeß zu reißen. Beispiel 4 6O@cm3 der Hohlperlen wie im Beispiel 3 werden mit 30 g einer Binderfarbe, bestehend aus 50 Gewichtsteilen eines Butadien-Styrol-Copolymerisates, das noch 5 y& Acrylsäure enthält, zu einen in ca. 0,2 mm bis 5 mm bequem auftragbaren Anstrichmasse gemischt. Nach dem Trocknen erhält man einen harten Anstrich ohne Rißbildung. Beispiel 5 Man verfährt wie in Beispiel 4 beschrieben, setzt jedoch 30 g einer Binderfarbe, bestehend aus 50 Gewichtsteilen eines Acrylsäurebutylester-Vinylacetat-Acrylsäure-Copolymerisates ein.The paints are used in a wide range of interior and exterior painting. Mixtures with hollow beads with a diameter of 15 to 40 give a silk-like sheen, while by adding hollow beads * with a diameter of 100 to 1000, smooth effect surfaces can be obtained. Example 1 230 cm 3 of hollow bead polymer with a content of 12% ethylene and 88 % yinylochloride and a diameter of 40 to 150 are mixed with 80 cm of a polymer mixture. consist of a copolymer of styrene and acrylic acid butyloster mixed with a solids content of 42%. Test plates made of Eternit in 1 mm and 5 mm layer thickness coated and set up vertically. the Parbe does not expire. After drying for 2 days at room temperature tur-you get a solid white paint without cracking. The paint has a silk matt surface gloss. Ex Made of 520 cm3 hollow bead polymer and 80 cm of the binder paint as in example 1, a mass is obtained which is tel applied in 6 ®m layer thickness, after setting and Drying at room temperature shows no cracks. Example 3 100 cm 5 hollow beads of diameter 100 to 200 U nd 50 em3 _a binder paint that acts as a binder in an aqueous emulsion 57 weight percent of a vinyl chloride-ethylene copolymer contains, becomes a viscous: however throbs spreadable Anetrich®asser get: .. The Anetrich mass can be divided into layers Apply thicknesses of 0.2 his & mm without cracking after the drying process. Example 4 6O @ cm3 of the hollow beads as in Example 3 are mixed with 30 g of a binder paint consisting of 50 parts by weight of a butadiene-styrene copolymer which still contains 5% acrylic acid to form a layer that can be easily applied in about 0.2 mm to 5 mm Mixed paint. After drying, a hard coating without cracking is obtained. EXAMPLE 5 The procedure described in Example 4 is followed, but 30 g of a binder paint consisting of 50 parts by weight of a butyl acrylate / vinyl acetate / acrylic acid copolymer are used.

Die Mischung tropft ebenfalls nicht und trocknet selbst in ca. 5 mm Schichtdicke ohne Risse. Gleichgute Ergebnisse erhält man durch Abmischung von 30 g Hohlperlen mit 30 cm 2 einer ca.The mixture also does not drip and dries itself in about 5 mm Layer thickness without cracks. Equally good results are obtained by mixing 30 g hollow beads with 30 cm 2 of an approx.

53 Gewichtsprozent Festanteile enthaltenden Binderfarbe auf Basis einer Vinylchlorid-Ynylacetat-Polymerisatemulsion.Binder paint based on 53 percent by weight solids a vinyl chloride-ynyl acetate polymer emulsion.

Claims (1)

FatentansUruch: Verwendung von.Hohlperlen mit einem Durchmesser zwischen 15 bis 1000p aus einem Copolymerisat von 84 - 92 Gewichtsteilen Vinylchlorid und 16 - 8 Gewichtsteilen Äthylen, das teilweise durch Propylen oder'Isobutylen ersetzt sein kann, als Füllstoff fürAnstrichmassen.FatentansUruch: using von.Hohlperlen having a diameter between 15 to 1000p of a copolymer from 84 to 92 parts by weight of vinyl chloride and 16-8 parts by weight of ethylene, which may be partially replaced by propylene oder'Isobutylen, as a filler fürAnstrichmassen.
DE19671669156 1967-09-01 1967-09-01 Binder colors Pending DE1669156A1 (en)

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Application Number Priority Date Filing Date Title
DEF0053388 1967-09-01

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DE1669156A1 true DE1669156A1 (en) 1971-05-13

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0026388A1 (en) * 1979-09-27 1981-04-08 BASF Lacke + Farben AG Use of coating compositions containing finely divided hollow particles
DE3200730A1 (en) * 1981-03-16 1982-09-23 Hunter Douglas Industries B.V., 3008 Rotterdam "LACQUER, METHOD FOR LACQUERING WITH THE SAME AND ITEMS PAINTED WITH THE SAME"
EP0995781A1 (en) * 1998-04-23 2000-04-26 Idemitsu Petrochemical Co., Ltd. Coating material
WO2001090260A2 (en) * 2000-05-19 2001-11-29 Ppg Industries Ohio, Inc. Coating compositions comprised of a geometrically ordered array of unfused polymeric particles, composition exhibiting bragg diffraction, and a method for inhibiting sound transmission

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0026388A1 (en) * 1979-09-27 1981-04-08 BASF Lacke + Farben AG Use of coating compositions containing finely divided hollow particles
DE2939141A1 (en) * 1979-09-27 1981-04-16 Basf Farben + Fasern Ag, 2000 Hamburg COATING MEASURES
DE3200730A1 (en) * 1981-03-16 1982-09-23 Hunter Douglas Industries B.V., 3008 Rotterdam "LACQUER, METHOD FOR LACQUERING WITH THE SAME AND ITEMS PAINTED WITH THE SAME"
US4457965A (en) * 1981-03-16 1984-07-03 Hunter Douglas International N.V. Process for lacquering articles & articles lacquered therewith
US4617339A (en) * 1981-03-16 1986-10-14 Hunter Douglas International N.V. Lacquer, process for lacquering therewith, and articles lacquered therewith
DE3200730C3 (en) * 1981-03-16 1998-07-09 Hunter Douglas Ind Bv Process for producing a multi-layer pigmented coating from lacquer
EP0995781A1 (en) * 1998-04-23 2000-04-26 Idemitsu Petrochemical Co., Ltd. Coating material
EP0995781A4 (en) * 1998-04-23 2001-07-25 Idemitsu Petrochemical Co Coating material
US6545082B2 (en) 1998-04-23 2003-04-08 Idemitsu Petrochemical Co., Ltd. Coating material
WO2001090260A2 (en) * 2000-05-19 2001-11-29 Ppg Industries Ohio, Inc. Coating compositions comprised of a geometrically ordered array of unfused polymeric particles, composition exhibiting bragg diffraction, and a method for inhibiting sound transmission
WO2001090260A3 (en) * 2000-05-19 2002-06-13 Ppg Ind Ohio Inc Coating compositions comprised of a geometrically ordered array of unfused polymeric particles, composition exhibiting bragg diffraction, and a method for inhibiting sound transmission
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