DE1660297A1 - Method and device for the manufacture of fiber products by asymmetrical spinning of filaments - Google Patents

Method and device for the manufacture of fiber products by asymmetrical spinning of filaments

Info

Publication number
DE1660297A1
DE1660297A1 DE19651660297 DE1660297A DE1660297A1 DE 1660297 A1 DE1660297 A1 DE 1660297A1 DE 19651660297 DE19651660297 DE 19651660297 DE 1660297 A DE1660297 A DE 1660297A DE 1660297 A1 DE1660297 A1 DE 1660297A1
Authority
DE
Germany
Prior art keywords
spinning
air
filaments
manufacture
asymmetrical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19651660297
Other languages
German (de)
Inventor
Ludwig Dipl-Chem Dr Hartmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lutravil Spinnvlies GmbH and Co
Original Assignee
Lutravil Spinnvlies GmbH and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE19641435466 priority Critical patent/DE1435466A1/en
Priority to NL6513277A priority patent/NL6513277A/xx
Priority to FR35356A priority patent/FR1450274A/en
Priority to ES0318618A priority patent/ES318618A2/en
Priority to GB44844/65A priority patent/GB1132575A/en
Application filed by Lutravil Spinnvlies GmbH and Co filed Critical Lutravil Spinnvlies GmbH and Co
Priority to DE19651660297 priority patent/DE1660297A1/en
Priority to US592545A priority patent/US3528129A/en
Publication of DE1660297A1 publication Critical patent/DE1660297A1/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/04Dry spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/098Melt spinning methods with simultaneous stretching
    • D01D5/0985Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/22Formation of filaments, threads, or the like with a crimped or curled structure; with a special structure to simulate wool
    • D01D5/23Formation of filaments, threads, or the like with a crimped or curled structure; with a special structure to simulate wool by asymmetrical cooling of filaments, threads, or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Nonwoven Fabrics (AREA)

Description

CARl FREUDENBERG · ' "8Ϊ1ΪΛ965CARl FREUDENBERG · '"8Ϊ1ΪΛ965

Weinheim/Bergstr. Dr.Z/Rh OF 391Weinheim / Bergstrasse Dr.Z / Rh OF 391

Verfahren und Vorrichtung zur Herstellung τοη Faserprodukten durch asTam· trie ehe s AusspinnenMethod and device for producing τοη Fiber products by asTam · trie before s spinning

von Filamentreihenof rows of filaments

Bei der Herstellung von Faserprodukten durch Schmelzspinnen bei der die aus Spinnlöchern austretenden geschmolzenen Filamente mit Hilfe von Luftströmen verstreckt werden, ist das aus Spinngeschwindigkeit und Luftgeschwindigkeit erhaltene. Verzugsverhältnis für die erzielbare Festigkeit des Fadens von Bedeutung. Durch den Verzug tritt bekanntlioh eine Längs orient ie· rung der Molekülketten ein, die durch genau gezielte Abkühlung eingefroren werden kann. Für die erzielbaren Orientierungseffekte ist der Wärmetransport vom Faserinnern zur. Oberfläche und dann zur Umgebungsluft von Wichtigkeit, um die beim Verzug erhaltene Orientierung zu erhalten. Das Mantel-Kern-Verhältnis des Fadens gewinnt dadurch an Wichtigkeit, dass der Wärmeabtransport von der Fadenoberfläche wesentlich schneller geht als vonIn the manufacture of fiber products by melt spinning that the molten filaments emerging from the spinning holes are stretched with the help of air currents, that's over Spinning speed and air speed obtained. Warpage ratio for the achievable strength of the thread of Meaning. As a result of the warpage, a longitudinal orientation occurs, as is known. tion of the molecular chains, which can be frozen by precisely targeted cooling. For the achievable orientation effects, the heat transport from the fiber interior to the. surface and then to the ambient air of importance in order to obtain the orientation obtained during the warping. The sheath-to-core ratio of the thread gains in importance because the heat dissipation goes much faster from the thread surface than from

der Fadenmitte zur Oberfläche hin. Im deutschen Patent .·*.*the middle of the thread towards the surface. In the German patent. *. *

(Anmeldung F 44 310 VIIa/29a vom 24.10.1964) wurd® deshalb bereits vorgeschlagen, statt runder Spinalöcher profiliert« zu verwenden. Die Spinnlticher werden dabei in(Registration F 44 310 VIIa / 29a dated October 24, 1964) was therefore already suggested, profiled instead of round spinal holes «to use. The spinning lids are in

GiNAL 10S815/19H /# G iNAL 10S815 / 19H / #

so dass Scharen yon Filamenten gebildet werden. Jede aus einer Spinndüse kommende Schar wird dann von einem vorzugsweise jedoch mehreren Luftstrompaaren erfasst und von der Düse weggeführt. Die Luftstrompaare treten jeweils an beidseitig der Filament-Bchar angebrachten Schlitzen, die entweder an der Düse oder in sog. Führungskanälen angebracht sind, aus. Die Führung der Luftströme wird derart gehandhabt, dass die Filamente jeder Düse voneinander getrennt bleiben, so dass der Verzugsvorgang gleichmassig stattfinden kann. Die sohliesslich aus den Kanälen austretenden Filamentscharen werden sohliesslich auf einem Siebband, z.B. in Form eines Faservlieses, abgesaugt. Die gegenseitige Verfilzung kommt durch den engen Abstand der Spinnlöcher und durch das hohe Verhältnis von Spinngeschwindigkeit zu Siebbandgeschwindigkeit (z.B. 100:1) zustande, wodurch eine wechselseitige unregelmässige schlingenförmige Ablage erzielt wird.so that flocks of filaments are formed. Each from one The flock coming from the spinneret is then picked up by one, but preferably several, air stream pairs and guided away from the nozzle. The pairs of air flows enter slots on both sides of the filament Bchar, which are either on the nozzle or in So-called. Guide channels are attached. The guidance of the air streams is handled in such a way that the filaments of each nozzle remain separated from one another, so that the drafting process can take place evenly. The filament bundles that ultimately emerge from the channels are finally placed on a sieve belt, e.g. in the form of a fiber fleece, vacuumed. The mutual matting comes from the close spacing of the spinning holes and due to the high ratio of spinning speed to screen belt speed (e.g. 100: 1), whereby a reciprocal, irregular, loop-shaped deposit is achieved.

Da durch die reihenförmige Anordnung der Spinnöffnungen und durch die jeweils paarweise Anordnung der Luftströme die Filamentreihen beidseitig mit den Luftströmen beaufschlagt werden, ist es möglioh, Spannungen innerhalb der Täden zu erzeugen, z.B. dadurch, dass die Luftströme links und rechts der Fllamentschar verschiedene Temperaturen aufweisen. Diese Spannungen können» neben anderen Effekten, z.B. zur Kräuselung der fäden führen. Dies ist sur larsielung möglichst textilartiger Produkte erwünscht. Diese AerpMtrle der fadenscharen ist jedoch auch zur Verfilzung wesentlich, da die Fäden im Auffangbereioh des Siebbandes eine Turbuiens aufweisen sollen, um eine Wirrfaserstruktur zu erzielen« Brfindungsgemäss zeigte sich nun eine weitere Verbesserung ditserBecause by the row-like arrangement of the spinning orifices and by the arrangement of the air streams in pairs, the rows of filaments are acted upon by the air streams on both sides It is possible to create tension within the threads, e.g. by the fact that the air currents to the left and right of the crowd have different temperatures. These tensions can be »besides other effects, e.g. crimping of the threads. This is desirable for the use of textile-like products as possible. These AerpMtrle of the thread sheets is also essential for felting, since the threads in the catchment area of the sieve belt should have a turbulence in order to achieve a tangled fiber structure « According to the invention, there was now a further improvement in this

Effekte dadurch, dass die Aüjnnrmetri· innerhalb der FadenreiheEffects from the fact that the Aüjnnrmetri · within the thread row

1090 1 5/19U1090 1 5 / 19U

iAD ORIGiNALiAD ORIGiNAL

erhöht wird. Eine Ausführungsform ist in Abb. 1 dargestellt. Hierbei ist eine Reihe a) von ypsilonartigen Spinnöffnungen dargestellt, die wechselseitig gegeneinander versetzt sind. Beidseitig der Reihe sind zwei Luftschlitze b1 und b« angebracht, aus denen Luftströme austreten, die die aus den Spinnöffnungen austretenden Filamente erfassen und nach vorn reissen. Die Spinnöffnungen erzeugen unter anderem infolge des einen längeren Schenkels einen im Querschnitt asymmetrischen Faden, der durch zwei sich gegenüberliegende Luftströme verzogen sowie abgekühlt wird. Der eine längere Schenkel erfährt auf dem Flugweg andere Abkühlungsbedingungen als die beiden Kurzschenkel, so dass im Faden Spannungen auftreten, die z.B. zur Kräuselung führen. Jeweils benachbarte Fäden haben infolge ihrer versetzten Anordnung die Spannungserzeugung jeweils spiegelbildlich. Beim Auffangen der Fäden in Form eines Wirrfaservlieses trägt diese Erscheinung zu einer erhöhten Verfilzung bei, da die Einkräuselung von einer Schrumpfung begleitet ist, die bei benachbarten Fäden jeweils ihre Richtung ändert. Die Asymmetrie kann noch dadurch verstärkt werden, dass die Temperaturen der Luftstrompaare verschieden gewählt werden, also z.B. b 1 y b 2. Weiterhin kann das Profil in seiner Asymmetrie noch weiter verstärkt werden, so dass auch entsprechend verschiedenartige Abkühlungsverhältnisse auftreten.is increased. One embodiment is shown in FIG. Here a row a) of ypsilon-like spinning openings is shown, which are mutually offset from one another. On both sides of the row there are two air slots b 1 and b ″, from which air streams emerge which grasp the filaments emerging from the spinning orifices and tear them forward. As a result of one of the longer legs, the spinning orifices produce a thread which is asymmetrical in cross section and which is drawn and cooled by two opposing air currents. One longer leg experiences different cooling conditions on the flight path than the two short legs, so that tensions occur in the thread, which lead to crimping, for example. Due to their staggered arrangement, adjacent threads generate the tension in a mirror image. When the threads are caught in the form of a tangled fiber fleece, this phenomenon contributes to increased felting, since the crimping is accompanied by shrinkage, which changes its direction in the case of adjacent threads. The asymmetry can be further increased by choosing different temperatures of the air flow pairs, for example b 1 y b 2. Furthermore, the asymmetry of the profile can be further increased so that correspondingly different cooling conditions also occur.

Als Spinndüsengrundstruktion kann z.B. die in der Abb. 2 gezeigte verwendet werden. Andere Konstruktionen können natürlich euch Verwendung finden, solange das Prinzip gewahrt bleibt, reihenförmig ausgesponnene Filamentscharen mit beidseitig an-For example, the one shown in Fig. 2 can be used as the basic structure of the spinneret. Other constructions can of course can be used, as long as the principle is maintained, rows of filament sheets spun out in rows with on both sides

10 ■"» q 1 /.10 ■ "» q 1 /.

greifenden Luftstrompaaren zu verstrecken und so zu führen, dass sie bahnförmig von der Spinndüse weggeführt werden. In Abb. 2 ist schematisch eine Spinndüse mit einer Reihe A assymetrisch angeordneter Ypsilon-Querschnitte dargestellt. Auf der einen Seite ist die Aufsatzplatte B angelegt, die mit dem die Spinnlochreihe tragenden Düsensteg C den Luftschlitz D bildet· Auf der anderen Seite ist die Aufaatzplatte B der besseren Übersicht wegen weggelassen, um das Prinzip der Lufteinspeisung zu zeigen. Die Luft wird von hinten durch zwei öffnungen der Nut Dp zugeführt, von wo sie durch die Stege F in die Nut E übertritt, um von dort der Ausgangsöffnung D zugeleitet zu werden. Durch entsprechend eingespeiste Luftmengen treten dann aus den beiden Spalten D beidseitig der Spinnlochreihe Luftströme, die die Filamentreinen nach vorn reissen und verstrecken. Nach dem Verlassen der Spinndüse, wird die Filamentreihe in einen Führungskanal eingebracht, in den weitere Luftstrompaare, z.B. zur schnelleren Abkühlung,eingebracht werden. Ausserdem werden mehrere Spinndüsen zu einem Aggregat zusammengefasst, wie dies in einer Ausführungsform im französischen Patent 1 364 916 beschrieben ist. Das erste Luftstrompaar kann in anderen Ausführungsformen auch erst innerhalb des Führungskanals aufgebracht werden, wird aber immer beidseitig der Filamentreihe angeordnet.to stretch the gripping airflow pairs and to guide them in such a way that they are led away from the spinneret in web form. In Fig. 2 a spinneret with a row A is schematically asymmetrical arranged Ypsilon cross-sections shown. On one side, the top plate B is created, with which the row of spinning holes The supporting nozzle web C forms the air slot D. On the other hand, the top plate B is the better one The overview is omitted to show the principle of the air supply. The air is from behind by two Openings of the groove Dp supplied, from where they through the webs F passes into the groove E in order to be fed to the outlet opening D from there. Due to the amount of air fed in then emerge from the two columns D on both sides of the spinning hole row air currents, which tear the filament pure forward and stretch. After leaving the spinneret, the filament row becomes introduced into a guide channel, into which further air flow pairs, e.g. for faster cooling. In addition, several spinnerets are combined into one unit, as described in one embodiment in French patent 1,364,916. The first pair of airflows can in other embodiments are also only applied within the guide channel, but is always on both sides of the Filament row arranged.

BeispieltExamples

Verwendet wurde eine Spinndüse, der in Abb. 2 skizzierten Art mit folgenden Abmessungen :A spinneret of the type shown in Fig. 2 with the following dimensions was used:

10 /:au *10 /: au *

3
0,3
340
378
3
0.3
340
378
nun
mm
mm
nun
well
mm
mm
well
0,5
0,35
0.5
0.35
nun
mm
well
mm
150150 300300 mmmm

Stegbreite 0: Luftschlitzbreite D: Luftschlitzbreite ϊ Düsenbreite:Bar width 0: air slot width D: air slot width ϊ nozzle width:

Spinnöffnung Ypsilon:Ypsilon spinning opening:

Lange Schenke Hänge: Kurze Schenkellängen:Long bar slopes: Short side lengths:

Zahl der Spinnlöcher: Länge der Spinnlochreihe ι Number of spinning holes: length of the row of spinning holes ι

Einlassbreite des Führungskanals: 380 mm Inlet width of the guide channel: 380 mm

Einlassweite des Führungs-Inlet width of the guide

kanals: 15 mmchannel: 15 mm

Länge des Führungskanals 600 mmLength of the guide channel 600 mm

Als Spinnsubstanz wurde Polycaprolactam verwendet, mit einer Viskositätszahl von \o red= 2, 25 (HgSO.) und einem Extraktgehalt von 0,3 $>· Das Polymere wurde im Extruder aufgeschmolzen und einer Düse von 2400O mit Hilfe einer Spinnpumpe zudosiert· Die Fördermenge betrug 0,3 ecm pro Minute. Den beiden Düsenschlitzen wurde Luft von 2380C in einer Menge vonlt7 War/mLn zugeführt» so dass eine Ausströmgeschwindigkeit der Luft von 190 m/sec in den Schlitzen erreicht wurde. Die beiden Luftströme rissen die Filamentreih· nach vorn und vorstreckten sie,Polycaprolactam was used as the spinning substance, with a viscosity number of \ o red = 2.25 (HgSO.) And an extract content of 0.3 $> The polymer was melted in the extruder and metered into a nozzle of 240 0 O with the aid of a spinning pump The delivery rate was 0.3 ecm per minute. Was the two nozzle slots, air was of 238 0 C in an amount of L t 7 War / mLn 'supplied so that an outflow of the air of 190 m / sec reached in the slots. The two air currents tore the filament rows forward and stretched them out,

so dass ein ausgewogener Titer von 1 den erhalten wurd·. Si· Filament· wurden durch Auffangen auf einem Drahtsieb nach den Verlassen des oben beschriebenen Führungskanal« in Form eines Wirrvlieaee aufgefangen. Das Vlies zeigte eine wesentlich erhöhte Bauschigkeit g«itnüt>er einem aus runden Löchern g·- •ponntnen.so that a balanced titer of 1 den was obtained. Si Filament · were collected on a wire screen after the Leaving the above-described guide channel "is collected in the form of a tangle. The fleece showed a significantly increased Puffiness is good for you from round holes - • fail.

10 8 \! 1 -ΐ / 1 9 1 410 8 \! 1 -ΐ / 1 9 1 4

Claims (1)

AnspruchtClaims Verfahren zur Herstellung von Faserprodukten aus Hochpolymeren durch Schmelzspinnen von Filamentscharen aus geradlinig nebeneinander liegenden Spinnöffnungen und Verstrecken mittels beidseitig der Filamentscharen angreifenden Luftströmen, dadurch gekennzeichnet, dass die Spinnöffnungen einen aeyametrischen Querschnitt aufweisen und abwechselnd zueinander spiegelbildlich richtungsversetzt in der Reihe angeordnet werden.Process for the manufacture of fiber products from high polymers by melt spinning filament sheets in a straight line next to each other lying spinning orifices and drawing by means of air currents attacking the filament sheets on both sides, thereby characterized in that the spinning orifices have an aeyametric Have cross-section and are alternately arranged in mirror-inverted direction in the row. INSPECTED 109815/1914 INSPECTED 109815/1914
DE19651660297 1964-10-24 1965-11-11 Method and device for the manufacture of fiber products by asymmetrical spinning of filaments Pending DE1660297A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE19641435466 DE1435466A1 (en) 1964-10-24 1964-10-24 Process for the production of textile fiber products
NL6513277A NL6513277A (en) 1964-10-24 1965-10-13
FR35356A FR1450274A (en) 1964-10-24 1965-10-16 Manufacturing process for fiber-based textile products
ES0318618A ES318618A2 (en) 1964-10-24 1965-10-18 Apparatus for producing nonwoven fleeces
GB44844/65A GB1132575A (en) 1964-10-24 1965-10-22 Improvements relating to the production of non-woven fabrics
DE19651660297 DE1660297A1 (en) 1964-10-24 1965-11-11 Method and device for the manufacture of fiber products by asymmetrical spinning of filaments
US592545A US3528129A (en) 1964-10-24 1966-11-07 Apparatus for producing nonwoven fleeces

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19641435466 DE1435466A1 (en) 1964-10-24 1964-10-24 Process for the production of textile fiber products
DEF0044310 1964-10-24
DEF0047644 1965-11-11
DE19651660297 DE1660297A1 (en) 1964-10-24 1965-11-11 Method and device for the manufacture of fiber products by asymmetrical spinning of filaments

Publications (1)

Publication Number Publication Date
DE1660297A1 true DE1660297A1 (en) 1971-04-08

Family

ID=27430528

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19641435466 Pending DE1435466A1 (en) 1964-10-24 1964-10-24 Process for the production of textile fiber products
DE19651660297 Pending DE1660297A1 (en) 1964-10-24 1965-11-11 Method and device for the manufacture of fiber products by asymmetrical spinning of filaments

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19641435466 Pending DE1435466A1 (en) 1964-10-24 1964-10-24 Process for the production of textile fiber products

Country Status (6)

Country Link
US (1) US3528129A (en)
DE (2) DE1435466A1 (en)
ES (1) ES318618A2 (en)
FR (1) FR1450274A (en)
GB (1) GB1132575A (en)
NL (1) NL6513277A (en)

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US3696184A (en) * 1970-06-08 1972-10-03 Concorde Fibers Melt spinning
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DE3541034C2 (en) * 1984-11-21 1992-08-13 Mitsubishi Rayon Co., Ltd., Tokio/Tokyo, Jp

Also Published As

Publication number Publication date
FR1450274A (en) 1966-05-06
US3528129A (en) 1970-09-15
GB1132575A (en) 1968-11-06
DE1435466A1 (en) 1969-03-20
ES318618A2 (en) 1966-05-01
NL6513277A (en) 1966-04-25

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