DE1635623B2 - ADHESIVE TEXTILE WALLPAPER - Google Patents

ADHESIVE TEXTILE WALLPAPER

Info

Publication number
DE1635623B2
DE1635623B2 DE19671635623 DE1635623A DE1635623B2 DE 1635623 B2 DE1635623 B2 DE 1635623B2 DE 19671635623 DE19671635623 DE 19671635623 DE 1635623 A DE1635623 A DE 1635623A DE 1635623 B2 DE1635623 B2 DE 1635623B2
Authority
DE
Germany
Prior art keywords
adhesive
textile
textile web
layer
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19671635623
Other languages
German (de)
Other versions
DE1635623C3 (en
DE1635623A1 (en
Inventor
Jean Anicet Croix Nord Gäbet (Frankreich)
Original Assignee
Ets. Randon & Immain, Hem, Nord (Frankreich)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ets. Randon & Immain, Hem, Nord (Frankreich) filed Critical Ets. Randon & Immain, Hem, Nord (Frankreich)
Publication of DE1635623A1 publication Critical patent/DE1635623A1/en
Publication of DE1635623B2 publication Critical patent/DE1635623B2/en
Application granted granted Critical
Publication of DE1635623C3 publication Critical patent/DE1635623C3/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21—Paper; Textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0002—Wallpaper or wall covering on textile basis
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C09J2400/263—Presence of textile or fabric in the substrate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0218—Vinyl resin fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0245—Acrylic resin fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0263—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/04—Vegetal fibres
    • D06N2201/042—Cellulose fibres, e.g. cotton
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/02—Natural macromolecular compounds or derivatives thereof
    • D06N2203/022—Natural rubber
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/045—Vinyl (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/142—Hydrophobic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1628—Dimensional stability
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/14—Furniture, upholstery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2865—Adhesive compositions including monomer or polymer of carbohydrate [e.g., starch, dextrin, etc.] Or protein [e.g., casein, animal protein, etc.] Or derivative thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2896—Adhesive compositions including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2738—Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/2885—Coated or impregnated acrylic fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/2893—Coated or impregnated polyamide fiber fabric

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Description

Die Erfindung betrifft eine klebbare Textiltapete, einem einzigen Durchgang, insbesondere durch Aufbestehend aus einer textilen Bahn, einer auf deren walzen oder Aufsprühen, auf die Ruckseite der tex-Rückseite haftenden Kunststoffschicht und einer an as tilen Bahn eine Kunstharzdispersion aufbringt, so der Rückseite der Kunststoffschicht vorgesehenen daß ein weicher wasserundurchlässiger Film mit Klebstoffschicht. einer zusammenhängenden Oberfläche gebildet wird,The invention relates to an adhesive textile wallpaper, a single pass, in particular by standing from a textile web, one on its roll or spray on, on the back of the tex back adhesive plastic layer and an as tilen web applies a synthetic resin dispersion, so the back of the plastic layer provided that a soft waterproof film with Adhesive layer. a cohesive surface is formed,

Derartige Textiltapeten, bei denen die Rückseite der an der textilen Bahn haftet. Schließlich wird auf der textilen Bahn eine Abdeckschicht aus Kunststoff die Oberfläche dieses Films eine Klebstoffschicht, aufweist, welche mit einem Selbstkleber bestrichen 3° insbesondere durch Aufsprühen oder durch Aufwalist, sind aus den Unterlagen des DT-Gbm 19 04 026 zen aufgebracht, die mit dem Material des Films verbekannt. Die Kunststoffschicht soll auf der Gewebe- träglich ist und die daran sowie an der Unterlage bahn sitzen und elastisch sein, weshalb vorzugsweise oder Wand gut haftet, wobei die Klebstoffmenge so eine Schaumstoffschicht verwendet wird, die gewisse bemessen ist, daß die Tapete sowohl an rauhen als Unregelmäßigkeiten in der Oberfläche der Unterlage 35 auch an polierten Flächen haftet. Vorzugsweise wird ausgleichen soll. die Tapete zwischen jeder Behandlungsstufe ge-Such textile wallpapers in which the back of the sticks to the textile web. Eventually it will the textile web a covering layer made of plastic the surface of this film an adhesive layer, which has been coated with a self-adhesive 3 °, in particular by spraying on or by whale-coating, are from the documents of the DT-Gbm 19 04 026 zen applied, which is known with the material of the film. The plastic layer should be wear-resistant on the fabric and on it and on the base Bahn sit and be elastic, which is why preferably or wall adheres well, with the amount of glue so a foam layer is used, which is certain that the wallpaper is both rough and rough Irregularities in the surface of the pad 35 also adheres to polished surfaces. Preferably will should compensate. the wallpaper between each treatment stage

Derartige Tapeten mit Selbstkleber haben jedoch trocknet.Such wallpapers with self-adhesive, however, have dried out.

gewisse Nachteile. Einmal muß der Klebstoff durch Die Erfindung ist nachstehend an Hand der Zeichein im allgemeinen silikonisiertes Papier geschützt nung, die einen schematischen Schnitt durch ein Gewerden, wodurch höhere Herstellungskosten ent- 40 webe zeigt, erläutert.certain disadvantages. The invention is illustrated below with reference to the drawings generally siliconized paper protected tion, which is a schematic section through a become, as a result of which higher manufacturing costs developed.

stehen. Bei der Verwendung muß das silikonisierte Auf der Rückseite der hydrophoben Gewebeunter-Papier abgezogen werden, wodurch sich die Dirnen- lage 1 befindet sich eine Kunststoffschicht 2, die das sionen der Tapete ändern können. Dimensionsände- Gewebe wasserundurchlässig macht und es in seinen rungen können bei derartigen Tapeten auch durch Dimensionen stabilisiert. Auf der Kunststoffschicht andere mechanische Belastungen oder dadurch, daß 45 befindet sich eine Klebstoffschicht 3 aus einem durch die textile Bahn in Berührung mit Wasser oder Luft- Wasser reaktivierbaren Klebstoff. Dieser muß gegen feuchtigkeit schrumpft oder sich ausdehnt, auftreten. atmosphärische Feuchtigkeit unempfindlich sein, so Diese Dimensionsänderungen führen zu einer Ver- daß die Tapete ohne ein Schutzpapier gelagert werschiebung der Muster auf zwei benachbarten Bahnen den kann.stand. In use, the siliconized must be on the back of the hydrophobic fabric sub-paper be peeled off, whereby the prostitute 1 is a plastic layer 2, which the sions of the wallpaper can change. Dimensional changes- fabric makes water impermeable and it in its In wallpapers of this type, stanchions can also be stabilized by dimensions. On the plastic layer other mechanical loads or the fact that 45 is an adhesive layer 3 from a through the textile web in contact with water or air-water reactivatable adhesive. This must against moisture shrinks or expands, occur. atmospheric moisture to be insensitive, so These dimensional changes lead to a shift in the wallpaper that is stored without a protective paper the pattern on two adjacent tracks can.

bzw. zu Zwischenräumen zwischen zwei Bahnen, 50 Man macht die textile Bahn hydrophob, indemor to gaps between two webs, 50 The textile web is made hydrophobic by adding

wenn eine Schrumpfung eingetreten ist. Tapeten mit man sie in ein Bad eintaucht, das Zirkonsalze ent-when shrinkage has occurred. Wallpapers by immersing them in a bath containing zirconium salts.

Selbstkleber haben feiner den Nachteil, daß sie nach hält, z. B. in eine Wachsemulsion mit ZirkonsalzenSelf-adhesives have the disadvantage that they last, z. B. in a wax emulsion with zirconium salts

dem Anbringen nicht mehr verschoben werden kön- oder in ein Bad, das neben den Zirkonsalzen auchafter attaching it can no longer be moved - or in a bath that, in addition to the zirconium salts, also

nen, um kleinere Ungenauigkeiten auszugleichen. Titanalkoholat enthält. Die textile Bahn kann aberto compensate for minor inaccuracies. Contains titanium alcoholate. But the textile web can

Ferner sind aus der DT-AS 11 52 987 Papiertape- 55 auch mit fluorierten Kunststoffen oder Pyridinderi-Furthermore, from the DT-AS 11 52 987 paper tape 55 also with fluorinated plastics or pyridine

ten bekannt, die auf ihrer Rückseite eine oder zwei vaten hydrophobiert werden.th known that one or two vaten are hydrophobized on their back.

Schichten aus einem trocknen, mit Wasser aktivier- Man kann als Stabilisatoren auch verträglicheLayers of a dry, water-activated one can also be used as stabilizers

baren Klebstoff tragen. Bei den häufig weitmaschigen Harze auf der Grundlage von Melamin-Harnstoff,wearable adhesive. In the case of the often wide-meshed resins based on melamine urea,

Textiltapeten ist jedoch die Aufbringung der Kleb- Harnstoff-Formaldehyd. Melamin-Formaldehyd oderTextile wallpaper, however, is the application of the adhesive urea formaldehyde. Melamine formaldehyde or

Stoffschicht ohne besondere Vorsichtsmaßnahmen 60 andere polymerisierbar oder nicntpolymerisierbareLayer of fabric without special precautions 60 other polymerizable or non-polymerizable

nicht möglich, da der Klebstoff leicht durchschlagen Substanzen zusetzen. Entsprechend den verwendetennot possible as the adhesive penetrates easily, adding substances. According to the used

kann. Ferner finden sich keine Hinweise über eine Imprägnierungsmitteln erhält man ein hydrophobescan. Furthermore, there is no information about an impregnating agent, a hydrophobic one is obtained

Dimensionsstabilisierung der Tapetenbahn. Gewebe, das entweder waschbar oder abwischbar ist.Dimensional stabilization of the wallpaper strip. Fabric that is either washable or wipeable.

Der Erfindung liegt die Aufgabe zugrunde, eine Die Emulsion, die die wasserundurchlässige Kunstklebbare Textiltapete vorzuschlagen, bei der Dirnen- 65 Stoffschicht liefern soil, kann eine wäßrige Emulsion sionsänderungen beim Aufbringen sowohl durch die oder eine Emulsion in einem Lösungsmittel sein.
Einwirkung von Wasser bzw. Wasserdampf als auch In wäßriger Emulsion kann man verschiedene durch mechanische Einflüsse vermieden werden. Kunststoffe verwenden, z. B. Polyvinyl- oder Poly-The invention is based on the object of providing an emulsion that the water-impermeable art-adhesive textile wallpaper is intended to provide, an aqueous emulsion, or an emulsion in a solvent.
The effects of water or steam as well as in aqueous emulsion can be avoided by various mechanical influences. Use plastics, e.g. B. polyvinyl or poly

vinylidcnchloride, Acrylate usw., die noch polymerisierbar und selbstvernetzend oder aber bereits in Emulsion polymerisiert sein können. Der Kunststoff muß gegen Wasser unempfindlich sein. Das Emulgieren kann mechanisch oder mit Hilfe eines Emulgators erfolgen. Man kann ein geeignetes Verdikkungsmittel zusetzen, das nach dem Trocknen wasserunempfindlich ist. Die Feststoffmenge muß so groß rein, daß der Kunststoffilm bei einem einzigen Durchgang auf der Walze gebildet wird. Die Viskositat der Emulsion hängt von dem verwendeten Material ab und sollte so eingestellt sein, daß der Film auf der Oberfläche gebildet wird und beim Durchgang durch die Walze nicht durch das Gewebe hindurchgedrückt wird. Metallsalze, die anschließend bei der Reaktivierung des Klebstoffes stören könnten, sollen nicht vorhanden sein.vinylidcnchloride, acrylates, etc., which are still polymerizable and self-crosslinking or already in Emulsion can be polymerized. The plastic must be insensitive to water. The emulsification can be done mechanically or with the help of an emulsifier. One can use a suitable thickener add, which is insensitive to water after drying. The amount of solids must be like this great pure that the plastic film in a single Passage is formed on the roller. The viscosity of the emulsion depends on the material used and should be adjusted so that the film is formed on the surface and upon passage is not pushed through the fabric by the roller. Metal salts, which subsequently that could interfere with the reactivation of the adhesive should not be present.

Wird eine Harzemulsion in einem Lösungsmittel verwendet, so werden zweckmäßig ebenfalls Acrylharze oder Polyvinylchloride verwendet. Nach dem Auftragen der Emulsion kann das Lösungsmittel wiedergewonnen werden. Die Dicke des Films hängt vom Filmbildungsvermögen des Kunststoffes ab, und liegt zwischen einigen Mikron und einigen zehntel Millimetern.If a resin emulsion in a solvent is used, acrylic resins are also suitable or polyvinyl chlorides are used. After the emulsion has been applied, the solvent can be recovered will. The thickness of the film depends on the film-forming ability of the plastic, and lies between a few microns and a few tenths of a millimeter.

Der mit Wasser aktivierbare Klebstoff, der sich nicht von der Kunststoffschicht ablösen soll, kann eine Harzemulsion, z. B. eine Polyvinylacjtat-Emulsion, die gegen Wasser empfindlich sind, sein. Ferner können als Klebstoffe Proteine, Stärkemehl, Stärke, Dextrine. Caseine, Gummi, Polyvinylalkohol und -acetat, Isocyanate usw. verwendet werden.The adhesive that can be activated with water and that should not be detached from the plastic layer can a resin emulsion, e.g. B. a polyvinyl acetate emulsion, who are sensitive to water. Furthermore, proteins, cornstarch, starch, Dextrins. Caseins, gums, polyvinyl alcohol and acetate, isocyanates, etc. can be used.

Die Viskosität des Klebstoffes hängt von der Auftragsweise (z. B. Aufsprühen oder Aufwalzen) ab, wobei die erforderliche Dicke der Klebstoffschicht nach einmaligem Auftragen erhalten werden sollte. Zu diesem Zweck sollte der Feststoffgehalt des Klebstoffes in der Größenordnung von etwa 40% liegen. Das zum Reaktivieren des Klebstoffes verwendete Wasser darf nicht mit dem wasserundurchlässigen Kunststoffilm reagieren.The viscosity of the adhesive depends on the method of application (e.g. spraying on or rolling on), the required thickness of the adhesive layer should be obtained after a single application. For this purpose, the solids content of the adhesive should be on the order of about 40%. The water used to reactivate the adhesive must not mix with the waterproof one Plastic film react.

Nachstehend sind zwei Beispiele zur Herstellung der Tapete gemäß der Erfindung angegeben.Two examples of the manufacture of the wallpaper according to the invention are given below.

Beispiel 1example 1

1. Ein gebleichtes BaumwoUgewcbe mit mittelfester Textur, das bedruckt oder gefärbt sein kann, wird auf dem Foulard rr:;t einer handelsüblichen Emulsion von Wachs und Zirkonsalzen imprägniert. Die Badkonzentration wird durch einen Probeversuch bestimmt. Man setzt dem Bad Harnstoff-Formaldehydharz und einen entsprechenden Katalysator zu, um das Gewebe dimensionsbeständig und wasserabstoßend zu machen. Das Gewebe wird dann getrocknet und durch eine Polymerisationskammer geleitet und dann aufgewickelt.1. A bleached BaumwoUgewcbe medium strength texture that can be printed or dyed, will rr on the padder:; t impregnated with a commercially available emulsion of wax and zirconium salts. The bath concentration is determined by a trial. Urea-formaldehyde resin and an appropriate catalyst are added to the bath in order to make the fabric dimensionally stable and water-repellent. The fabric is then dried and passed through a polymerization chamber and then wound up.

2. Auf die Rückseite des hydrophobierten Gewebes wird in einer Menge von 100 bis 150 g/m2 eine mechanisch hergestellte kationische Acrylharzemulsion aufgebracht, die nach dem Trocknen einen gegen Wasser, Benzol oder Petroläther unempfindlichen, gegen chlorierte Lösungsmittel wenig empfindlichen und gegen Aceton empfindlichen Film ergibt. Das Aufbringen der Emulsion erfolgt mit einer Walze, wodurch eine gleichmäßige und fehlerfreie Harzschicht erhalten wird. Das beschichtete Gewebe wird getrocknet und aufgewickelt.2. A mechanically produced cationic acrylic resin emulsion is applied to the back of the hydrophobized fabric in an amount of 100 to 150 g / m 2 , which after drying forms a film that is insensitive to water, benzene or petroleum ether, less sensitive to chlorinated solvents and sensitive to acetone results. The emulsion is applied with a roller, whereby a uniform and defect-free resin layer is obtained. The coated fabric is dried and wound up.

3. Für eine Reaktivierung mit Wasser verwendet man einen Klebstoff auf Grundlage einer Emulsion von Polyvinylacetat, die mit einer Lösung von Dextrin mit einem Zusatz von Carboxymethylcellulose verdickt ist, um die notwendige Konsistenz für das Auftragen mit einer Walze zu erhalten. Diese neutrale Lösung wird durch ein Mittel gegen Schimmel, z. B. durch Laurylpentachlorphenol, geschützt.3. An emulsion-based adhesive is used for reactivation with water of polyvinyl acetate made with a solution of dextrin with an addition of carboxymethyl cellulose is thickened to obtain the necessary consistency for application with a roller. This neutral solution is through an anti-mold agent, e.g. B. by lauryl pentachlorophenol protected.

Der Klebstoff wird auf einmal auf das mit Kunststoff beschichtete getrocknete Gewebe aufgebracht, worauf das so behandelte Gewebe durch einen Trockentunnel geleitet wird.The adhesive is applied all at once to the plastic-coated dried fabric applied, whereupon the fabric treated in this way is passed through a drying tunnel.

Beispiel 2Example 2

Die erste Stufe, nämlich die Hydrophobierung und Stabilisierung des Gewebes erfolgt wie nach Beispie! 1 auf dem Foulard mit einem Produkt auf der Grundlage von Pyridinverbindungen, wobei die Konzentration des Bades auf dem Foulard 130 g/l Produkt 275 und 20 g/l Beschleuniger beträgt. Das Gewebe braucht nicht durch eine Polymerisationsvorrichtung geleitet zu werden. Das erhaltene Gewebe kann abgewischt werden, da es gegen Wasser unempfindlich isi.The first stage, namely the hydrophobization and stabilization of the fabric, takes place as in the example! 1 on the padder with a product based on pyridine compounds, with the concentration of the bath on the padder is 130 g / l of product 275 and 20 g / l of accelerator. The mesh does not need to be passed through a polymerizer. The tissue obtained can be wiped off as it is insensitive to water.

Das so behandelte Gewebe wird wie nach Beispiel 1 weiterbehandelt.The fabric treated in this way is treated further as in Example 1.

Hierzu 1 Blatt Zeichnungen1 sheet of drawings

Claims (2)

Diese Aufgabe wird erfindungsgemäß dadurch ge- Patentansnrüche· löst, daß die textile Bahn hydrophob ist und die Patentansprüche. Kunststoffschicht aus einem Vinyl- oder Acrylharz-This object is achieved according to the invention in that the textile web is hydrophobic and the claims. Plastic layer made of a vinyl or acrylic resin 1. Klebbare Textiltapete, bestehend aus einer Copolymerisat mit einer Stärke vonι einigen Mikron textilen Bahn, einer auf deren Rückseite haften- 5 bis e.n.gen zehntel Millimeter besteht und daß d,e den Kunststoffschicht und einer an der Rückseue Klebstof schicht einen durch Wasser reakuvierbarcn der Kunststoffschicht vorgesehenen Klebstoff- Klebstoff enthalt .. ..
schicht, dadurch g e k e η η ζ e i c h η e t, daß Die Kunststoffschicht ist so dünn ausgebildet, daß die textile Bahn hydrophob ist und die Kunst- die textile Bahn noch weich und schmiegsam„ t
Stoffschicht aus einem Vinyl- oder Acrylharz- χο Der mit Wasser reaktivierbare Klebstoff ,st vor-Copolymerisat mit einer Stärke von einigen Mi- zugsweise alterungs- und witterungsbeständig1. Adhesive textile wallpaper, consisting of a copolymer with a thickness of a few microns of textile web, one adhering to the back of 5 to narrow tenths of a millimeter and that the plastic layer and one on the Rückseue adhesive layer a water-reacuvable of the plastic layer intended adhesive- adhesive contains .. ..
layer, characterized geke η η ζ η et verifiable that the plastic layer is formed so thin that the textile web is hydrophobic and the art, the textile web is still soft and supple "t
A layer of material made from a vinyl or acrylic resin χο The water-reactivatable adhesive is a pre-copolymer with a thickness of a few millimeters, preferably aging and weather-resistant krön bis einigen zehntel Millimeter besteht und Die textile Bahn kann aus einem naturl.chen odercrown up to a few tenths of a millimeter and the textile web can consist of a natural or daß die Klebeschicht einen durch Wasser re- synthetischen Material bestehen; sie kann ein geweb-that the adhesive layer consist of a material which is resynthetic by water; it can be a tissue aktivierbaren Klebstoff enthält. tes oder gew.rktes Material oder ein Faservlies dar-Contains activatable adhesive. made or knitted material or a fiber fleece 2. Klebbare Textiltapete nach Anspruch 1, da- 15 stellen. Das Material kann gebleicht, bedruckt oder durch gekennzeichnet, daß die textile Bahn ein gefärbt sein. ^1-.,
Faservlies darstellt Die klebbare Textiltapete gemäß der Erfindung2. Adhesive textile wallpaper according to claim 1, represent 15. The material can be bleached, printed or characterized in that the textile web is colored. ^ 1 -.,
Nonwoven fabric represents the adhesive textile wallpaper according to the invention wird im allgemeinen dadurch hergestellt, daß man die textile Bahn hydrophobiert, z. B. mit Zirkonsaf-is generally produced by making the textile web hydrophobic, e.g. B. with zirconia 2o zen, fluorierten Harzen oder Pyridinderivaten, gegebenenfalls unter Zusatz eines die Dimensionen stabilisierenden Mittels und daß man anschließend in2o zen, fluorinated resins or pyridine derivatives, optionally with the addition of an agent that stabilizes the dimensions and then in
DE19671635623 1966-12-07 1967-12-06 Adhesive textile wallpaper Expired DE1635623C3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR86559 1966-12-07
FR86559A FR1504921A (en) 1966-12-07 1966-12-07 Sticky fabric and process for its manufacture
DER0047521 1967-12-06

Publications (3)

Publication Number Publication Date
DE1635623A1 DE1635623A1 (en) 1971-10-28
DE1635623B2 true DE1635623B2 (en) 1976-04-08
DE1635623C3 DE1635623C3 (en) 1976-11-25

Family

ID=

Also Published As

Publication number Publication date
NL6716337A (en) 1968-06-10
IE31840B1 (en) 1973-01-10
IE31840L (en) 1968-06-07
US3616146A (en) 1971-10-26
FR1504921A (en) 1967-12-08
DE1635623A1 (en) 1971-10-28
CH558855A (en) 1975-02-14
GB1203239A (en) 1970-08-26
BE707495A (en) 1968-04-01
LU54930A1 (en) 1968-02-16
DK142881B (en) 1981-02-16
CH558855B (en)
DK142881C (en) 1981-08-31

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E77 Valid patent as to the heymanns-index 1977
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