DE1594594A1 - Lubricating grease mixture - Google Patents

Lubricating grease mixture

Info

Publication number
DE1594594A1
DE1594594A1 DE19651594594 DE1594594A DE1594594A1 DE 1594594 A1 DE1594594 A1 DE 1594594A1 DE 19651594594 DE19651594594 DE 19651594594 DE 1594594 A DE1594594 A DE 1594594A DE 1594594 A1 DE1594594 A1 DE 1594594A1
Authority
DE
Germany
Prior art keywords
net
lubricating grease
mixture according
marked
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19651594594
Other languages
German (de)
Inventor
Caruso Gerard Paul
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US395024A external-priority patent/US3370007A/en
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of DE1594594A1 publication Critical patent/DE1594594A1/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/06—Mixtures of thickeners and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/044—Acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/061—Metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/08—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-nitrogen bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/02—Macromolecular compounds from phosphorus-containg monomers, obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/02—Esters of silicic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

!l.Ilm8IdC#... j "#,91 f,).211:. daß es c"*i.>x ez;em !RI Vvaall e"' s d er= Gr u p FI c% .f.(@ - (. TTB V!3 @@.. J. i . Il:l.c. k V PIJngG3.n) ode @ @,r,.jfni.3t# Ei#ral.-# (#.e .? j - s -#ifs:3rl#rr."# -dt'.a.r ji..LeuteZ%e und/oder ein 0:Z.ec)1).,LlilLeii l1lexi und e.:ne rre!e:s.' c3.e# r r, .;Lff-mener@ w- eine normale C, ur.l31,,,:=:ca@nä-- mexl -,rr.nigeteriß Der-hier verwendete Ausdruck "oleophiler Ton" bezieht sich auf Minen. Tone dem durch die Behandlung mit einer Ammoniumbase oleophil eensc'_nai'tcn :=erl.i.ehen worden sind,. ri.n oleophiler Ton kann zoBo ein 1'On.um-Ton" sein und aus dem Reaktionsprodukt einer Anmoni.tunbase (oder ihres Salzes und eines nicht-oleophit? en Tones bestehen, Wenn das @chm@erm@j 4-i:elgem-Esi@h ein Metallsulfid enthält, so können ein oder mehreres @c i@ala.sul.fdde vorliegen;> ihre vIengex beträgt zweckmäßig bis zu 3 G4wo" zoB. 091 -- 1:n25 Gewo%o Bei. Verwendung .einer größeren Mange dient das Sulfid gege.- benen f a17 s als Verdickungsmätte1. Werden jedoch die verstehend angegebenen spezifischen :teengen verwendet, so wird eine aus- reichende Menge oleoghiler Ton zugegeben, um das Eindicken zu erreichen,und das Sulfid dient nicht diesem Zweck. Als Metallsulfid können .Yo?ybdändisulf:id, ein amorphes Antimon- sulfid oder deren Gemische verwendet werden. Amorphes .A.ntimon-v sulfid wird gegenüber kristallnem Antimonsulfd bevorzugt,, da: letzteres einen Abrieb Vor! I4xetallteilchen verursachen kann" vielleicht aufgrund der Härte `der Kristalle oder von Verunrei- nigungen in dem Sulfid. Bei.9piele :für amorphe Sulfide sind Antimontrisulfid a @@@e>>rasul_fid oder --pentasulfid y von denen wenigstens eines verwendet wird. Sie können grau bis gelb ge- färbt sein, gewöhnlich weinen sie jedoch je nach ihrer Her- stellung und Teilchengröße eine rote Farbe auf" .r Z tr .. J:3!@@ j e ;@.a.E . @L. m^1.:1'? d a r n@. e11.rc:l1 .E.us3..i ?.utzZ aus cine27 Wäc@sri.-- ixr@g dv.:t@ch c? z1 Sulfi.d s ?:,B. Natrium -@.;:...:.!.@ asserigtoffp hergestellt <<iexdenö r@; k-.,,ilsa n@° r,@:@'t.Ql@_s tzlfid durch ein Ietall.napbthe- 13.:? c-rgältzr e- oder ers%'"ti werden. Tjrcn (-Teiili.r"cli =von Naphthensöuren mit y Cät @::r:rl. '1.:".'z'1''.@:Zls.!. von wen '.gotßn9 250 tt?'''ä üG?.ro Dz-, o Gem: L Sch 'Cann von einem f,la,_ s. : f @i 3C: #1!?iä !i=:`Cö..l. 2: <" _ 2.j>. C:d.nea' Erdöl 2 stammen. t.'C@.ß-'C@Gsn ta.:. .., ß"7) C@e1'@o>s .035 "' Q'6 Tewojvp eines T,! e _ ?'.v p.t-lhE':#_.s `a t# Die TäengL des Bleinaplith£nates so 15 ä bo ci gen auf cl., Schnli:erfett!, nicht überstei-- >>#7( 0 gen, da goße:e T°.!e7:agela ti:t.e Konsistenz des Schmierfettes schäd- "@ be`iaifaus sexi ctoc=1, a ucA zerstöxwxi können. Das B? cinaphthe- f nat :Lax'zx# 25 -.. "5 G#t* #:" Blei enthalten ki-,-izn C.u:cch Umre''-,zunb einer Bleiverbindung _-i; ei:acr ri".nhtlieiigäuze;. z,B@ dem ,rovstehend gensrlnten Gemisch von Naphthensäureiz- hergestellt werden. Zur Bildung des Blei.- ., .# ila? W? J.:!' t@o#'°üL1n'`J'ile7 se ein B#e#C. ### tr d ein yd, `G'oBa Bleiglätte p 3Rzu den Sauregemi ach Zt.gegebenn welahea dann erhitzt wird o Auch 3i_ei c;axborat kann vüzwende'ü wexden, j)Cr Zusatz vor Blei_napli+henat und,/oder. Tyletallsulfid ermöglicht die Herabsetzung der T:e <,?_:! c @.z@bon.atmer;e a insbesondere, wenn .gung i n "Jllel?1 Q!.eß)hlen Ton oder 91.s (Z,-in '@facE,cjext als ir@:l.'@xz@@e:r:ri Bcotzllaltewl c@@-1 ctte4@ va9.9handCfz isst- In Gegenwart von Vlasser niiEmt# c@c#.n,1e:JLaa.a.su_t'id;# jedoch #,,. I@@is nicht nur :für eine Beibehaltung der Höchs-- druc.keigenschaf-ten desvii,.cr trockenen Bed:?ngtua- £,rt?11g. sondern auch iUx r:.%1.6: iäteK.-"erong d2.eser Eigens-chafte11 un- '@ex, _nassen redingungozi.. .'i gemäß des' jrl`'.`L??.rll,@t;,i@as sar ? 0 äGl@#8##2nl##.e:Z' .'i@#E3'tr.t1`iC'tiit,.''? .#. de mjA nicht :! n .'Cäx'Eli eine; .7.'@.;??@lf; in doiu o*i.eoph:.'.lez? To'i# menge n. '`JC??_°hcant#G'n st y so Ii#1 z#7.e@!cl` zur VGrbe"soerm# fei.' # L@a .. aus ei::@hnrd se:i.?.z, Die kann .B, 0r : -@ 1 Cevr07p des Seh1Ei;erfet»- teq betragen Dasv in @.rgencze:tnc;@@ su^:Pührungsform der Erfindung @°cx'lrc:nd.ctto Metallearäonat hat eine Härte nach Igohs von 1 - 5F vorzugs- weise ?. 5, und ze 2ssel:z@: sich nicht wesentlich, wenn es .n .Tl.s_ft bis zu einer T'emT?:.'c^-..@il@Z" J'(1 3iY(:11#.t#liens7(:() @' el.^h:L#e`? wird,- Es können natürliche g minerall-eahe oder sy nihetisc:he Uarbonate verwendet werden z:B., DolomitGOMg(C3)2 ts.nleri'c E'23Co 3oMgCO, _ «-Pe co79 caicit v-nd Arago.ni.t ((ca.co i ,a. G ,UC-git Asurit ei _@ @?c@icfo.@ Cu(ol1)@Tl r Malachit . cIlco._ (Jcts'_oZV@ 7; am 'Lh,@a . @@ (7@_üc>. ) St?ar_@u:i.r::xa@:-trc (.pZ:iC.e#.z p .Zara -it !#i_c(,': 0 9:>rj. o.TL'r# : ^'T#r# 0 -..rl rrlagnes@.' i M@t\';#= 9 Rhod ochrosn:t (Ynco,.Sder;i.t a (@a@o.F `, c,,y--uss:,Lt (Na2(110ocaCC)V 5110)p Thermonatrt =Sü:2Cs1,?.,112 Ut und I@Tatril2rnearbcnaL (lüa2003). Z@rüa! 1ca_lne-'cai.? und lc:!_@:c:z@hola.ai@e 4@re?'ci@rx<e @c@.@zu;@; p !1. -n Ist vorzugsweise re- -@A ..CS:...@.a.JC .. MG..n ... il.@..-tl frei. vor. .ii ib D: -#,.eJ Ver4Lbireinigungen,,. z" B. wird en ausgefälltes Garbonat, wie bE-.,;io,zug*'4 :Falls ds Ewdalkalimetall die ein- YM..voc e:ä.ä.e:r# l°eta l. a'ogo:Li ts:°,eVerb3:ndung in dem Schmier- an dJ.e@:baemenge 3 ... 795 Gew4 des Schmier- _<?G@";i ti`Jenn: @@Tre@3 er ea_n @.ZC @aa l.l'i.d oder ein Metallnaphthenat . @# .# r #"c c# =or 1 i. c. g7 e@? 9 h:ann die Garbonatmenge 0905 .- - 1,5 Gew 4 , #i d .x .. ä? Gw @@;,lE:@s@ k @:Y@rz:i.e^:ettes betragen. Kann ei.! :Las de]? norm_lerweise in Schmiexmittelge- Jl,.... J selin o Es kann ein filineralöl oder f;Jun synthetiseho; öl. oder gewüri schten:ialls ein Gemisch r( Beign.o:ze für en Mineralschmü:aröl sind raf- :@_n.@ ni.r<h ü halbraffinierte a paraffinieehe s Be",i smi.t@eraltile , die Viskosi- Von L:0 4#000 >@@y@c@'?; Univeroäl Sekunden (SiS)' bei 37980C haben für ein oynthetieches Schmieröl sind .@1.:.$ r@@:!@@@:x.e(h@: :J@.ar.Ic>n,ir.uxeestex° (zaD, ßs-(2-äthylhexy:l)--aeba- :-4s.'i' lara@Z 1.f.I)ha lJ:.:c'@o fl":l""r;3.te oder Phosphate. Der r,;n kann @.zz cä.ze:-r f ü3- die Bildung eines Schmierfet- `n;i -aufä dr..iii Menge vorhanden sein. falls ra (;r T ori von #. 1.neri. <120a1 w:.t eInex hohen Basenaustauschkapazität - gewöhnlich 2,5 -- 10 Gewt,t7,'9 bezogen auf sfIa @e w:ir%ri1; cles anorgtaniEjehcn Teile da;, YrodukteB" Wie ge-'@de den isüzi@A :@-:@.a2N@@rt 'Tan -i_iii:i'Z ei.E3a ti< #, z i#g.. r: @a. se 25-10G 2# ,# 11,'1e: li'o#'N@#Fjrt@tyie# e pro 100 g DJe prägt u BEi2p ie- le :'Ur eirem no:f ehsi Tom @:7xic' #-?oi2°@r?rzr:'11i.o.@i te e z.,B. 1rGtriurn- oder insbesondere solch(-,' von der Art des ( ,V .,. 1.T ; Yll,@' V'_ :rs # C?i r 7 ... ty .#.y:)n wird ein .,i`1 , G@:S:R^w uinb°ntonit g. ein woge ma22l ::e'° aln T:..`'-.; itC:y'tidtend.''G , Zur ole)phil_en -l'oneü wird ei.? nichii oloophilex n (uoBa e.a.n Ton mit mit', einer oder vul heinem Gemionh davon. ,adelte B.; ,#e iwsi?lele für Solche v ui # :tt=_. #1 sind S in den @i@# S 3_a: --Paren'c- s@ihriften 2 833. 809 lunnd ? 875 15112 @ ngegt:beno D ie Menge des kanonischen (-)bprflähei?aI:til"en Mittels kann 275 .*. 5 Ggiv o1.4 bBLüö,Bn auf "las Grewicht Schmierfettes, be'ürag:n. Rs kann ein Imidazoli n und/oder ein aus bestimmten _Tzi'e't'tsäurc:'1 und PolyUthylenpoly,irn.inen rn(:1@ verwendet werden. Uewünschtenfal 7.s It:znn das iD.f:()ptii:L Ina @:9.r@nscio oberflächenak- tive Mittel oder. eir Gemisch solcher rii:-t t,(#7. alse@'tar;d'ce:L des @#e,htitäexi'e'h-i:es vor`- lege.- o(irxderi oleophilen Ton ein-trer. leibt wer- den. In solch einem Z'13.1. harn ein Ihlidazolin und/oder 81Y1 ai;19 his:: ctr @.3.:r~:; `?ist c'. i.@.`?c:ir .elpo`y@?Ft@i?# ,eb11-- ##£? tote es 32aChsGehend im eillzel- @'l t-ta r r r. #.#5" 1 ri, ;hf, .; .r..y und U' # 1. - ..£ .# ..., ._,.z .on c:L@2 ..._:e b t, /ode ## h hei#@as dte l des Schmier-- f e :;r;<<@r a c3.e_o@n@2@.J ne 01 e e Tzr ric7.a z f oIir: bcs oht # aus v, - enige tens " vorzuns#weise einem! C10-20- 11 ._1r) ".i.!n@fi,o:.:Lr? so:l i.nBesonders Y '[,,°@yt c.n ,0#f.@.# #7 dqY h r r -in C! es _Lr?s.duzo:! inke rns be f in- @e sind 2-Hepta-- (@ (znrrK. r 1'j tl.de .ivr7.Z@#.l#@!@:I .i.l:. 2'et.#' @#11ep- -. und `t-Hexddecyl-2r .L s oaecr.r, i__.-res imi.dero:l in wenigstens ein Hydroxyp #:._ kann als . Ltla:r.eniassersi;cfi-:ic:h?Re:t:a:j#ers#c;f'--%m-lEaolin; vorzugsweise ein I:yiir. ohy-C#.1-y.#-?11>-#rl -.riidazciz}i u:2d/oder (Hydroxy-C1.--2p°al-- '-Yz -nalhcnylimidaz:oliiz verwendet werden. Beispiele für solche Terb_lndungen sind: 2-be ,#a-F-yd j'oxyä'@hyl- 4-uzldecylimidazol-n; !@ be ra.-H,r# .decylimidazo@.inF 1-ue-!;a-Hydroxybuty1-2-heptadecyl:.mü,<zelin; 2--alpha--F>tydro xyhexyl-- @j..@ciodecet@y@.?_mi:d@z@nl? n f . 1:-.T@ca-1;a-T@yc@rc@äv @.chyl@.2-ut@daoylimdazolin9 :. lnd J G' w:@ s Qleophilo.kann auoh als en Aminol;oh- .Sa!lftäti,n7@':Z''u'@Si:@^@Lo,..ZZ@i,1.1@rl@i@'@@ -miG a.@,16 @, r.t #L v.i ine'# bnr,w,.#c! e1 n s tf # x# Stickstoffatom Und Vorzugsweise Stichstoffat emfn Vor#" Megen. Das basische ` ü:.! C.'ltLLt?":@':@'3?I? kann. e3-2? p`?.211'.:°e$ p SC@dtli..filti:°t@ oder tertiäres sein und j'_in :Pelle vc3 :'?C@.@.1jC' als offnem bcaüistt`hen Atom können- G1~? e s? Beispiele fü3' sCt! chp Verbinq# @1@.@:.CYt':f find 2, br 4 @ lt dem Toll einverleibte und der als ue'standteil des @rorl iegende t.mi noain d be - "-c:h-b aas t;@e : @ä:-a@@s ei-neni Aminoamid@ d- sch vorzugsweise von £3.tol' @.' # jC:und einem n."einem #=':#F@#.thZF-. t c:b.Le.Ge'i:. Dao ;`1.LZ'f:-#Sittr.ß11'Gsve?;'ä!'rna.s des .1!T11°- noawici ä oder dp f'. "_aypide kann ;,51)`7C' #y 4-0/60-e ?.B-. 30r70 3'5/63 be ü.C'agen . 1Ja£ililL@. kann durlib Erbi.-lf zen Voll -3'0- 75 der '6I Wl s( r rm Y m^ lt # ru -i S äurC7 e nxyt 7 0 0..2 5 C c; Rl7 des, #, %t)t<.., u g stL,e.#: 7W @.@'@LLYICf (@jj auf 200 - 222to0 ;. lierges'Lu#:,'1:l"h werden. Das. A-ninoamid leitet siel-! vorzugsweise voll einem C hvon denen Y@G1@7_- stens 50 Cet'#aG;teni.s'Eie:a:@ eine D,)prcl:b:?iidtine enthalten. oder von einem C10-i3'*T'ei#tw tz.;=gemisch ab r @@@@3@.)P:(. diese eine J'od.^ah_l. von höetis,@;ens 50 auf:"Gä:-#?ün °c? ;ha ei-r- !^:!@!i_2@t@am:i.dgE@miscll leitet si*h ab e die zu -a.t)`i ira:j .F? '. iIr 1.1!a0 trl,l .#` `:`3irÜS.#ßls'@.-.. t...... P, 2,-n (#o@1s:.Z..L.-.#.-#...L.iita -@#i.t..'L'yl%!.T#7Zr111?d.. @t 45(": ?)<. : Rt 'nvJ.@Gn und v)enieer als 50 _ @@'t e n D e. c..- Produkte können als 73oden- @@ b 1_ -# vt@ j=-@?j E P@'1Fll:a anfallet' ,l#r,-f ,e#; , "t z I _- c.2 ..n der Rlzyzo. E, die vors-Gefaencl:,.?fr.;u haben, kann in einer. ,Frs. _,V t:9 d,..# ":#. f.) es, ", .roraegen e Die Grup- t cl Ac Gruppe Rene 2 @i _@- Bai sy.1,: .::ir°@,-;wird ri:Ls er bvoxvu@to rf@@F:@@neten Mitteln her. e- @e@ioc;h "Direk-tverfahxen" o # Fe --i der in. au 1.-jt. gelNo%igen wässrigen von der die @aiz@;-rr; durch oec:menta- '-.r;n oeifir 7er<tr jAxeen a br(e17r': v", ig=(#d (A n 1MYin9 so daß eine r F f 33 ,@# (l f i t4 .L `' , e_ 7t :ie<.an E. i: r, : y :; -1. e. f '# i).:i !.y (, x e #e:j..;=.._r, i via I.() Gfvi u % c$J-'il. .i. t hä It o 1)j:e irlä:@rjrJ.fC:'f: ail:[.,'.ijaF@ f @f,'1.;.YS dann ^ u e mit dem l%-:# ' mit des Shmierbls u?3,.ec?'z31@1.,t'd.C,E?@.£' :`..zt1",@ Durch ausreichende.--, Bewecer @:'J:3.1's'@ und dridurc;Il die i@3s@rp'tzof :1r oherfläghEnakt3 Dien Mittels' a'!t:@_' den Tonoberflächen er:ech@:. j):37 oleo;iLile Ton °erbndet s1 e.ki n:U der (J3. und scheide- sieh von der Hauptmenge Wasser ab. ?Jas restliche Ü2_ IMd der noch o:?eophi1:e Ton" können ürh:i"Gz@ werdßnv 1.3L11 dai gesamte i'- 2cr zu -;3erdc`ampfen. .1%1e B°etaandte?.Le -."jorden eher hohen entweder 11"ährend de: ,@as se@zr@relam@ftang oder ansch1:i.aaß. end uxi-,",er.iorfen; @.@r^@@lid dieses Zeitraums wird gegebenenfalls noch weiteres Schm."!rö-#. zugegeben. - Das Flleta? :Lcarhonaf tandA der ßle f;hena @; wand der Ester können währe?ld irgendeiner geeigneten Stufe des "iier_# ahr°eris zugegeben .!erden,, vorzug s,:jiise werden sie aber 1aaz=h der Entfernunr-1 des Wassers einver*,@,¢i.bt o. Ein Teil oder dass ge- samte. erforderliche Carbonat wird jedoch gegebenenfalls d*i-]sch das nach der. Entfernung der Gangart zurückbleibende bona't geliefert. Diese Bestandteile können entweder getrennt oder zusammen in 'froclener norm zugegeben werden. Vorzugsweise werden sie als öliger Sahlamm oder Konzentrat zu dem sone'@ fer- tigen Schmier:Cett zugegeben. ,*riIitend es. möglich ist;, duroh bI.os- =ia liUnverlebung und IIomogeiii:@J.'srang ausreichende Ergebnisse Zia erxialteng wird das so modifz:ier*üovorzugsweise einüx hohen Soheruigsgeschwindigkeit unterworfen, weil siele ach@cschenlich auf Grund ihz,3r sorgfältigeren Disper- sion, ei-o-i'i erhöhte. '@@@@1 @c;t:@ I=nn cyer@`:e:@,e?°e@c-t noch andere Bestandteile zuge- @:@:,@@@; @@:rz@@?en; 2q;,zuz° irerh@s^es@ng der Oxydationsstabilität Und ;etazrt S@.!l.z@L@@@.2L:tr@@S e, Zur kann ein 'i@@,r@; @eF 3 Amin. `Z ö B e _@1@n@r-I und lfi" nxi c llylamine ; wie Di phenyla.- @@,.;;t@@i.@-C@ä@-:.?chth;;@?:.-i.n verwende-:, ein Alk2?:metallnitrit od°1 wA_n ?'eaktiensprorinkt von JJ e:@!.. : `I E''JeI1 -m. z L oJ.n em 1'hft^r,lio:.'ha1r)r'e.-t :?:i üep. oinem Phoophor- @:: werden. Der kann in einer zlcnge "tL@li M. 1e0 GS@'#'@` iiS '7'@i1@??0'i'@` :GS en.h2.Ite11 Seine ütu@ E31' d:!-e fol gGendeT_Besi@iele näher erläutert. Beis p_i e? Q?i"'-F@e@'c) e7 Mi n er.-ilöle Verwendet. _ @@.1p i @P l@?" za vierden @ol@imie.fe t t, hergestellt di e einen mit 60 -Gew o@ be- L,Fi@ .irr ääse@@cl@t des Tones. Eines .f@si.noamids überzogenen R .eo tö^i:-c torl ent?ia? -%eri o Das Ami rioamd @: z @d aus Tall.ö? fe ttsö.uxen :?nd dem va:.estehend beschriebenen als Botenprodukt bei der Äthy- ,f_y ^,-t.hy@.enpol@arai:ngemisoh lendi_a.mnhers tellung anfallenden hergestellt.- .gE) .h(@'lri .. ä@-@d.@f..n_k,,... - --- n.@.- S t t !@'w7 , 2 .4:-b- @: @r r . 1 .6 u a ° z a j: £ R @@ea tJ,?@@n T j 2(' ` jh(oE,S° ' h x:@e@ _, .@. 2a. ».. j; U t7 5 2j-.-b C 03 0 n 'fr? - r@ 2.:t ä ä@7:G s !, r; - @ @ ß G :@ tw@ f - ? -r 6L.' .^- .-. r r a 2 ., 5 55@ @.. o T _.ml@ua@--@richstdr.?2t,k -T es @-Y r1ST,3 _j:J@A , .(e- :in 22_8, äob2t° 958 ?C-1° n@,,- # n . -# t;j4:L°Z :L°Z4Z zur :6esch:cei.bvarag derI@@cI@;# csl: °;@"r#. r .tl vtt @yschaften !ier @hmae#°fe#t»@c: verwendet. _.L - - Tabelle :!: zeig-L. d`ß die Iss vc:-i° gelb! -i: i.m# den mit Ton einged.:Lck- t en S c?1mier41 et en l-cR.nr'!7a 1,11v.e'.t Be zug auf die .Hö c:hg t .. Fr re'r-,J:i;@:,ezao Tt^ch15.eh'Pi.gr .._ MJA dem Schmierfett I3, daß nu_die. '..P-EigenschS.1. Ueü I3,orb:%ncltixig mit dem Blei- des Basissehmierfet'@es je".. -4. J. 'Tatsächlich vierden gerade die EIP-Eigen- S !; des cnrnierfettes. #,:if mehr r,1. (IC, h#.r#gerraiuserxg äal Gor @a4 Wei arbonat enthält? ganz in t n a v ck##.# yi#enn c#asle.i#carboz#a-#. v1Ird. :t_'()"F@?@Lit't(@ `_@.'W?1) eIf des 1339issehm_ E ?2_@tc?. ilie:' ge a'is@Jt@@eX1 ?-J!'@:@TL-'39:S-haf"4en die- : L - a..@.@.c!:coona 3L :miie.i# ' p EB.,: ;rindr# Versagt 3 H S e @5. c.' @ #T @ @r@ _i.iGS 20 25 s@ 0'@ `T 4 0 35 4-0 i -5 -20 2@, 5 Ca C;0 ; =r 45 1 2 2-0 25 2 0, g ?t? % :3 40 4Z: Der z!ere«e? ch dos;:'?@ q mit dem EaSSsabm2.Srfe"i'i: :ei jb- v daß dnr Ester :7 ??tue, ac u°egganwart eiP#-" Mee'allca:rbt"-= at P die L!#--j@#e#t@#C@`?:'z '3"t:.:S.@. ?I Wh'# fln4' e,En iluß#El o ci v#.. Joah der Ester dai:1 ha. einem .='.äach den Verfahren der V-@erden Sohn:Eerfetre denen amorphes Axi- ':Lil1C)xlr`'"3@1@.'1.f@ zu,E'.:3Q"'#i?1@ s@la.:i:.:@" i' a l' _ ' @:s'3? _1 Troƒkgkne x' @-@.:arse@ TAmken # 2r # L` rz 1'r# #^#j 1 ,STI c # .e 1 a,# : .sa # s y s. j#p..s C.1",.# i it w r ,3 rt. 0 i 1 r%L% tue;, I fe p>: 25 0 2 @, > >y. @ , l a ? 01 7% .5l ,@ 55 - 0. - y ) f ,@ ; b f ` E t' 7 :@@, ... 5G E .. ä Fn@i e 7 # und dem .t.sc f 1 °#c'P" c--r_ =.__l«.-7 #17.3._üd u.# . .,.e ::.! 1 r:- (:# 7(..f aT.("#fj..# #!t 'IA kf ^#l.Il..#.Üi'@iretori S()'D(Ihi'1#. < l. _J . S' J-@.4#.s. 1d." fi.L:;geringe NIilng al?f 0s .Ines da entha31.tenden Sehmier- ;.@-@ 1Ver`leich von L m.'@t 0 bev?z-kt e:: ° :.le der. EP-Exgenschaff.Ql! nassem Bedingungen. V f@_1 ll,s'Fr. es i s-t dieesief@e eine T,stermenge üben -wa 0p75;, keine 'ila:rkung au' das Seh:i erßett hatp das kein An- enthält. Das ist e`.:ti22 we? l;erE! für die %@y P daß die ei zes chmiexfetteg in Ab- wesenheit J.Z# J J:1.J#4%@: 7N 7 - f wesenheit eines 'iue'i;ällcar_bonates M.er i,ic:#Lall:sillfds durch die e:£-f :T @zc@@@? n£sgcazä.ße@@ Car bon sä:areer.@e r_ nicht verraess e L -s3 werden. Beispiel IV 1l!ech, dem Verfahren gemäß Beispiel !_ :@w"C.G'i'2 Sehmierfette hergP#- s tellt g die an Sbell e des retel icarbonats amorphes An timansul - :CM #enthalten. Zu einzelnen proben der erhaltenen Sohtnicxfotl-e vierdeAS Est Ue:. Nug@egnben, u m. festzustellen. ob Sie d J.a EP-aW ixkung des ' Tabelle I V r. .:11 5,ane ?j ': rr ra@ c Ke@.i1'3@' _ () j°r: 5'0 - 5 Tde-f:hyls tea:ca t'; 016 C.jC 60@ # - Me thy? s@earat 0175 . 0y6 60 - - -- S . Butylateazat 0175 0#17ä 60.t -@ 50 'i Hexylsteara*t 0@5 0,%5 60 ` ,- - u Butylaeetat 0175 0175 60+ '- - Bu'J1.yloleat 015 0,15 40 ¢5a @. - Dioctylsebara t- 0.1`i5 01'5 - 20 -@ Dideoylphenalat 01)5 o f5 35 A0 - I-Z,,r@,ß @@'> >;,@'<<;i.(@ iäe.te, ret'4i$äuren .,;;:E@.:``sF: s=;eg xr!7 v bhrend die Ester r# ri-n# a,r# ? B".i::: c'@.:i:'iü:r!'.3@#i,13:z$ i2iX1e :1 #.'J.... . #l 11 0,#m2 :3Fä.j@1':.F..'@ i.,a -3ä.:e für die ausgezeä ehae te ET-Eigen- _:a:.'@j:@:<< " ;@r:@;. @?W @_ '3aL'c@:e c@n t;ax@'ciz@siz!rees ternq Me-',all- . ti@?zrn.'@e>> rün an::Ivelsen, sind die Basisschm1.er- - '' Zusatzstoffe en'th 3it en i Bl e'i-- _ "# ......#..#_.i..,,..@........t..#...r#. na y tu yf e .l.ai o io thena - Gew ..; C,at,` 0, , i..; G 7przT .:@'@.°fP@! @s`.reaxa 0 ttr i , f,a@ 2'%2 n-Oet<y,ls teara.1; . i}" f@..a. CIL -(310 vi,' -#palmi,üa,b 3 0 15 1 I j 1 n. 01 0 2i0 n-Pen-'1-,ylmyrista't 2 0 @earat 2.J # o75 n--:t'Ly1:3-hGarat 0N25 0: <:. !ry@; 0 25 _ i L -° nrr :.# r #).E 2 e :#TIc) 2 f1 Csui7. . e; a ( o11) 2 ;:? (i a z-:ui;;r:La:i; cssanG:i: 2 0 r;@.@`)@; @1,@G# Y.f.@'ra .b.,25' @;);. 0#c3zz#Al@txii###Jl.paarn.i:a' :@:,0 5 - :i C) .'r.fi0:7b; 0 (111a(010 ,5 1 10.1.. °_'1`; C;::@;(#3@ T, t) xa--13@x1:y7.denrzYLoat@i 1,@0 Die Fähigkeit der L1'1! EP-Eigenschaften Fron . Me",allsulfide--n und Metallarbnnaten als -Ppwluse,tzstoffe zu verbessern, ersmhein`, unso überrawehe%ider 9 ä`! s die Ester kei- nerlei Verzweigungen oder Subs'titutidn mit funktionellen Grup- pen enthalten; denn ge*ir-;ß dem Bucht von Coi. Bauer "Yianufacture and Application 3f lubricat2ng G-easei3" (neinhold publishing Corp- p New York9 1950:c ß@ 11-115)t enthalten die Mei steh Zu- sntzstoffe einige Bestandteile (zo,. Sohjefel, Chlor, Phosphor, Seien, Tellur- üder Blei v$rbindun gen), die wahr- scheinlich mit den ge c@amie3,-ter r:eLa@..@@be:@nfl.oh::n reagieren und einen Überzug der entweder die Belastung aushält oder wenigstens eine Schweßung der ges2riinex':on Oberflächen verh>>.n.- der t. ! l.Ilm8IdC # ... j "#, 91 f,). 211 :. that it c "* i.> x ez; em ! RI Vvaall e "'s d er = Gr u p FI c% .f. (@ - (. TTB V! 3 @@ .. J. i. Il: lc k V PIJngG3.n) ode @ @, r, .jfni.3t # Ei #ral .- # (# .e.? j - s - # ifs: 3rl # rr. "# - d t'.a. rj i..L eute Z% e and or a 0: Z.ec) 1)., LlilLeii l1lexi and e.:n e rre! e: s. ' c3. e # r r,.; Lff-mener @ w- a normal C, ur.l3 1, ,,: =: ca @ nah-- mexl -, rr.nigeteriß As used herein, "oleophilic clay" refers to on mines. Tone that by treating with one Ammonium base oleophilic eensc'_nai'tcn: = allowed to marry. ri.n oleophilic tone can be zoBo a 1'On.um tone "and off the reaction product of an ammonia base (or its salt and one non-oleophite? in tones, If the @ chm @ erm @ j 4-i: elgem-Esi @ h contains a metal sulfide, so there may be one or more @ ci @ ala.sul.fdde;> your vIengex is suitably up to 3 G4wo "ZOB 091-1. n25 Gewo% o At. When used to a greater extent, the sulphide serves against benen f a17 s as thickening mat 1. However, they will be understanding specified specific: teen gen is used, an ex- Sufficient amount of oleoghilic clay added to thicken to achieve, and the sulfide does not serve that purpose. As a metal sulfide, .Yo? Ybdändisulf: id, an amorphous antimony sulfide or mixtures thereof can be used. Amorphous .A.ntimon-v sulfide is preferred over crystalline antimony sulfide, there: the latter an abrasion before! I4x metal particles can cause " perhaps due to the hardness of the crystals or impurities tendencies in the sulphide. Examples: are for amorphous sulfides Antimony trisulfide a @@@ e >> rasul_fid or --pentasulfide y of those at least one is used. They can be gray to yellow be colored, but usually weep depending on their nature position and particle size a red color " .r Z tr .. J: 3! @@ j e ; @. aE. @L. m ^ 1.: 1 '? darn @. e11.rc: l1 .E.us3..i ? .utzZ from cine27 Wäc@sri.-- ixr @ g dv.:t@ch c? z1 Sulfi.ds?:, B. Sodium - @.;: ...:.!. @ Asserigtoffp produced << iexdenö r @; k -. ,, ilsa n @ ° r, @: @ 't.Ql@_s tzlfid by a Ietall.napbthe- 13.:? c-rgältzr e- or ers% '"ti. Tjrcn (-Teiili.r "cli = of naphthenic acids with y Cät @ :: r: rl. '1.: ".'Z'1''. @: Zls.!. From whom '.gotßn9 250 tt? '''ä üG? .ro D z-, o Gem: L Sch' Cann from a f, la, _ s.: f @i 3C: # 1!? iä! i =: `Cö..l. 2: <"_ 2.j> . C: d.nea 'petroleum 2 originate. t.'C @ .ß-'C @ Gsn ta.:. .., ß "7) C @ e1 '@ o> s .035"'Q'6 Tewojvp one T ,! e _? '. v p .t-lhE': #_. s `at # Die TäengL des leadaplith £ nates so 15 ä bo ci gen on cl., Schnli: erfett !, do not exceed-- >># 7 ( 0 gen, da pour: e T °.! e7: agela ti: te consistency of the lubricating grease "@ be`iaifaus sexi ctoc = 1, a ucA destroywxi can. The B? cinaphthe- f nat: Lax'zx # 25 - .. " 5 G # t * #:" Contains lead ki -, - izn Cu: cch Umre '' -, zub a lead compound _-i; ei: acr ri ".nhtlieiigäuze ;. z, B @ the above mentioned mixture manufactured by Naphthensäureiz-. For the formation of the lead. .,. # ila? W? J.:! ' t @ o # '° üL1n'`J'ile7 se a B # e # C. ### tr d a yd, `G'oBa black lead p 3R to the Sauregemi at the time given which is then heated o Also 3i_ei c; axborat can vüzwende'ü wexden, j) Cr addition before Blei_napli + henat and, / or. Tyletallsulfid made possible the reduction of the T: e <,? _ :! c @ .z @ bon.atmer; ea especially if .gung in "Jllel? 1 Q! .eß) hlen tone or 91.s (Z, -in '@ facE, cjext as ir @: l.' @ xz @@ e: r: ri Bcotzllaltewl c @@ - 1 ctte4 @ va9.9handCfz eats- In the present by Vlasser niiEmt # c @ c # .n, 1e: JLaa.a.su_t'id;# however # ,,. I @@ is not only: for maintaining the highest-- pressure characteristics desvii, .cr dry conditions:? ngtua- £, rt? 11g. but also iUx r:.% 1.6: iäteK .- "erong d2.eser properties11 un- '@ex, _nassen redetzungozi .. .'i according to the 'jrl''.`L ??. rll, @ t;, i @ as sar? 0 äGl @ # 8 ## 2nl ##. E: Z '.'i @ # E3'tr.t1`iC'tiit ,.''? . #. de mjA not:! n .'Cäx'Eli a; .7. '@.; ?? @ lf; in doiu o * i.eoph:. '. lez? To'i # quantity n. '`JC ?? _ ° hcant # G'n st y so Ii # 1 z # 7.e @! cl` to the VGrbe " soerm # fei. ' # L @ a .. from ei :: @ hnrd se: i.?. z, The can .B, 0r: - @ 1 Cevr07p des Seh1Ei; erfet »- teq Dasv in @ .rgencze: tnc; @@ su ^: embodiment of the invention @ ° cx'lrc: nd.ctto Metal araeonate has a hardness according to Igohs of 1 - 5F, preferably way ?. 5, and ze 2ssel: z @: is not essential if it .n .Tl.s_ft up to a T'emT?:. 'C ^ - .. @ il @ Z "J' (1 3iY (: 11 # .t # liens7 (: () @ 'el. ^ H: L # e`? will, - It can be natural g minerall-eahe or sy nihetisc: he Ucarbonates are used e.g., dolomiteGOMg (C3) 2 ts.nleri'c E'23Co 3 oMgCO, _ «-Pe co 7 9 caicit v-nd Arago.ni.t ((about co i , a. G, UC-git Asurit ei _ @ @? c @ icfo. @ Cu (ol1) @Tl r Malachite. cIlco._ (Jcts'_oZV @ 7; am 'Lh, @ a . @@ (7 @ _üc>.) St? Ar_ @ u: ir :: xa @: - trc (.pZ: iC.e # .zp .Zara -it! #i_c (, ': 0 9:> rj. o.TL ' r #: ^ 'T # r # 0 - .. rl r rlagnes @.' i M @ t \ ';# = 9 Rhod ochrosn: t (Ynco, .Sder; it a (@ a @ oF `, c ,, y - uss:, Lt (Na2 ( 110ocaCC) V 5110) p Thermonatrt = Sü: 2Cs1,?., 11 2 Ut and I @ Tatril2rnearbcnaL (lüa2003). Z @ rüa! 1ca_lne-'cai.? and lc:! _ @: c: z @ hola.ai @ e 4 @ re? 'ci @ rx <e @c @. @ to; @; p !1. -n is preferably re- - @ A ..CS: ... @. A.JC .. MG..n ... il. @ ..- tl free. before. .ii ib D: - #,. eJ Ver4Lbireinigungen ,,. e.g. "B. becomes en precipitated carbonate, such as . bE -; io, train * '4: If the incoming ds Ewdalkalimetall YM .. vo c e: ä.ä.e: r # l ° eta l. a'ogo: Li ts: °, eVerb3: ndung in the lubricant an dJ.e @: baemenge 3 ... 795 Gew4 des lubrication _ <? G @ "; i ti`Jenn: @@ Tre @ 3 er ea_n @ .ZC @aa l.l'i.d or a metal naphthenate . @ #. # r # "cc # = or 1 ic g7 e @? 9 h: ann the amount of carbonate 0905 .- - 1.5 wt. 4, #id .x .. ä? G w @@ ;, lE: @ s @ k @: Y @ rz: ie ^: ettes be. Can e i .! : Las de]? normally in lubricant Jl, .... J selin o It can be a filineral oil or f; Ju n synthetiseho; oil. or flavored: iall a mixture r ( Beign.o: ze for en mineral jewelery oil are raf- : @_ n. @ ni.r <h ü semi-refined a paraffinieehe s Be ", i smi.t@eraltile, the viscose From L: 0 4 # 000> @@ y @ c @ '?; Universal seconds (SiS) 'at 37980C have for a synthetic lubricating oil . @ 1.:. $ R @@:! @@@: xe (h @:: J @ .ar.Ic> n, ir.uxeestex ° (zaD, ßs- (2-äthylhexy: l) - aeba - : -4s.'i 'lara @ Z 1.fI) ha lJ:.: C' @ o fl ": l""r; 3.te or phosphates. The r,; n can @ .zz cä.ze: -rf ü3- the formation of a lubricating grease- `n; i -aufä dr..iii amount to be available. if ra (; r T ori of #. 1.neri. <120a1 w: .t eInex high base exchange capacity - usually 2.5 - 10 wt, t7, '9 based on sfIa @ew: ir% ri1; cles anorganiEjehcn parts there ;, YproductsB " How ge - '@ d e den isüzi @ A : @ -: @. a2N @@ rt 'Tan -i_iii: i'Z ei.E3a ti <#, zi # g .. r: @a. se 25-10G 2 #, # 11, '1e: li' o # 'N @ # Fjrt @ ty i e # e per 100 g DJe stamps u AT 2 p i e- le: 'Ur eirem no: f ehsi Tom @: 7xic'# -? oi2 ° @ r? rzr: '11i.o. @ i te e z., B. 1rGtriurn- or in particular such (-, ' of the kind of ( , V .,. 1.T ; Yll, @ ' V'_ : rs # C? i r 7 ... ty . #. Y:) n becomes a., I`1, G @: S: R ^ w uinb ° ntonit g. a wave ma22l :: e '° aln T: .. `' - .; itC: y'tidtend. '' G, To ole) phil_en -l'oneü becomes ei.? nichii oloophilex n (uoBa ean tone with with ', one or vul h a Gemionh of it. , ennobled B .; , # e iwsi? lele for such v ui #: tt = _. # 1 are S in the @ i @ # S 3_a: --Paren'c- s @ ihriften 2 833. 809 lunnd? 875 15112 @ ngegt: beno ? (-) T he amount of canonical bprflähei aI: til 's agent can 275 . *. 5 Ggiv o1.4 bBLüö, Bn on "read Grewicht lubricating grease, be'ürag: n. Rs can be an imidazoli n and / or one of certain _Tzi'e't'tsäurc: '1 and PolyUthylenpoly, inn.inen rn (: 1 @ can be used. If 7.s It: znn das iD.f :() ptii: L Ina @: 9.r@nscio oberflächenak- tive means or. eir mixture of such rii: -tt, (# 7. alse @ 'tar;d'ce: L des @ # e, htitäexi'e'h-i: es vor` - lege.- o (irxderi oleophilic sound ein-trer. leibt be the. In such a Z'13.1. urine an ilidazoline and / or 81Y1 ai; 19 his :: ctr @ .3.: r ~ :; '? is c'. i. @. `? c: ir .elpo`y @? Ft @ i? #, eb11-- ## £? tote es 32aCh s walking in eillzel- @ 'l t-ta r r r. #. # 5 " 1 ri ,; hf, .; .R..y and U '# 1. - .. £. # ..., ._ ,. z .on c: L @ 2 ..._: ebt, / ode ## h he # @ as dte l of the lubricant-- f e:; r; << @ ra c3.e_o @ n @ 2 @ .J n e 01 ee Tzr ric7.azf oIir: bcs oht # from v, - at least ten " in front of you! C10-20- 11 ._1r) ".i.! N @ fi, o:.: Lr? So: l i.nSpecial Y '[,, ° @ yt cn , 0 # f. @. # # 7 d qY hr r -in C! it _Lr? s.duzo :! inke rns be f in- @e are 2-hepta-- (@ (znr rK. r 1 ' j tl. d e .ivr7.Z @ #. l # @! @: I .il :. 2 ' e t. #' @ # 11ep- -. and `t-Hexddecyl-2r .L s oaecr.r, i __.- res imi.dero: l in at least one hydroxyp #: ._ can be used as. Ltla: r.eniassersi; cfi-: ic: h? Re: t: a: j # ers # c; f '-% m-lEaolin; preferably one I: yiir. ohy-C # .1-y. # -? 11> - # rl -.riidazciz} iu: 2d / or (Hydroxy-C1 .-- 2p ° al-- '-Yz -nalhcnylimidaz: oliiz can be used. Examples of such Terminations are: 2-be, # aF-yd j'oxyä '@ hyl- 4-uzldecylimidazole-n; ! @ be ra.-H, r # .decylimidazo @ .inF 1-ue - !; a-Hydroxybuty1-2-heptadecyl: .mü, <zelin; 2 - alpha - F> tydro xyhexyl-- @j .. @ ciodecet @ y @.? _ mi: d @ z @ nl? nf. 1: -. T @ ca-1; aT @ yc @ rc @ äv @ .chyl @ .2-ut @ daoylimdazolin9 :. ln d JG 'w: @ s Q l eophilo. can auoh as en aminol; oh- .Sa! Lftäti, n7 @ ': Z``u' @ Si: @ ^ @ Lo, .. ZZ @ i, 1.1 @ rl @ i @ '@@ -miG a. @, 16 @, rt #L vi ine '# bnr, w,. # C ! e1 n s tf # x # nitrogen atom And preferably Stichstoffat emfn before # " Blessings. The basic `ü:.! C.'ltLLt? ": @ ': @' 3? I? Can. E3-2? P`? .211 '.: ° e $ p SC @ dtli..filti: ° t @ or being tertiary and j'_in : Pelle vc3: '? C @. @. 1jC' as open bcaüistt`hen Atom can- G1 ~? it? Examples of 'sCt! chp verbinq # @ 1 @. @ :. CYt ': f find 2 , b r 4 @ according to incorporated into the Toll and as part of the @rorl iegende t.mi noain d be - "-c: hb aas t; @e: @ ä: -a @@ s ei-neni Aminoamid @ d - sch preferably from £ 3.tol '@.'# jC: and an n. "a # = ': # F@#.thZF - . t c: b.Le.Ge'i :. Dao ; `1.LZ'f: - # Sittr.ß11'Gsve?;'Ä!' Rna.s des .1! T11 ° - noawici ä or dp f '. "_aypide can;, 51)` 7C '#y 4-0 / 60-e? .B-. 30r70 3'5 / 63 be ü.C'agen. 1Yes £ ililL @. can durlib hereditary lf zen full -3'0- 75 der '6I Wl s (r rm Y m ^ lt # ru -i Acid C7 e nxyt 7 0 0 .. 2 5 C c; Rl7 des, #, % t) t <.. , inf tL , e . #: 7 W @. @ '@ LLYICf (@jj to 200 - 222to0;. Lierges'Lu # :,' 1: l "h be. The. A-ninoamid directs fell-! preferably full of one C h of which Y @ G1 @ 7_- at least 50 Cet '# aG; teni.s'Eie: a: @ a D,) prcl: b:? iidtine included. or from a C10-i3 '* T'ei # tw tz.; = mixture from r @@@@ 3 @.) P :(. this one J'od. ^ ah_l. from Höetis, @; ens 50 on: "Gä: - #? ün ° c?; ha ei-r-! ^:! @! i_2 @ t @ am: i.dgE@miscll leads si * h from e to -at) `i ira: j .F? '. i Ir 1.1! a0 trl, l . # ``: `3irÜS. # ßls' @ .- .. t ...... P, 2, -n (# o @ 1s: .Z..L .-. #. - # ... L.iita -@#it.'L'y l % !. T # 7Z r 111? D .. @t 45 (":?) < .: Rt 'nvJ. @ Gn and v ) less than 50 _ @@ 'ten D e. c ..- products can be used as 73oden- @@ b 1_ - # v t @ j = - @? j EP @ '1Fll: a incurred' , l # r, -f, e #; , "t z I. _ - c.2 ..n the Rlz y zo. E, the vors-Gefaencl:,.? Fr.; U can have in a. , Frs. _, V t: 9 d, .. # ": #. F. ) Es,", .roraegen e The group t cl Ac group Rene 2 @i _ @ - Bai sy.1 ,:. :: ir ° @, -; becomes ri: Ls er bvoxvu @ to rf @@ F: @@ neten means. e- @ e @ ioc; h "Direk-tverfahxen" o # F e --i der in. Au 1.-jt. gelNo% aqueous from which the @aiz @; - rr; by oec: menta- '-.r; n oeifi r 7er <tr jAxeen a br (e17r': v ", ig = (# d (A n 1MYin9 so that a r F F 33 @ # (lfi t4 .L '', e_ 7t: ie <.an E. i: r: y:; -1 e f.. '# i) .: i .y (,! x e #e: j ..; = .._ r, i via I. () Gfvi u% c $ J-'il. .i. t hä I t o 1) j: e irlä: @ rjrJ.fC: 'f: ail: [.,'. ijaF @ f @ f, '1.;. YS then ^ ue with the l% -: # ' with des Shmierbls u? 3, .ec? 'z31 @ 1., t'd.C, E? @. £': `..zt1", @ by sufficient .--, Bewecer @: 'J: 3.1's '@ and dridurc; Il die i @ 3s @ rp'tzof: 1r oherfläghEnakt3 Dien means' a '! t: @_' the clay surfaces he: ech @ :. j): 37 oleo; iLile Ton ° erbndet s1 e.ki n: U der (J3. and separate from the main amount of water.? Yes remaining Ü 2 _ IM d the still o:? eophi1: e tone "can ürh: i" Gz @ will be 1.3L11 dai all i'- 2cr to -; 3erdc`ampfen. .1% 1e B ° etaandte? .Le -. "jorden rather high either 11" de:, @ as se @ zr @ relam @ ftang or Ansch1: i.aaß. end uxi -, ", er.iorfen; @. @ r ^ @@ lid of this period, if necessary, another Schm. "! rö- #. admitted. - The Flleta? : Lcarhonaf tandA der ßle f; hena @; Wall of the ester can be at any suitable level of the "iier_ # ahr ° eris admitted.! earth ,, prefer s,: jiise they will be 1aaz = h the distance of the water consigned *, @, ¢ i.bt o. A part or that velvet. however, the required carbonate is optionally d * i-] sch that after the. Removal of the gait lagging behind bona't delivered. These components can either be separated or can be added together in 'froclener norm. Preferably are they used as oily lamb or concentrate for the sone '@ fer- term smear: Cett added. , * riIing it. is possible ;, duroh bI.os- = ia liUnverlebung and IIomogeiii: @ J.'srang sufficient results Zia This is modified axially: ier * üo preferably Subjected to a very high speed, because they would oh @ cschenlich due to ihz, 3r more careful dispersion sion, ei-o-i'i increased . '@@@@ 1 @c; t: @ I = nn cyer @ `: e: @, e? ° e @ ct also added other components @: @:, @@@; @@: rz @@? en; 2q;, zuz ° irerh @ s ^ es @ ng the oxidation stability And; etazrt S @.! Lz @ L @@@. 2L: tr @@ S e, Zur can a 'i @@, r @; @eF 3 Amin. `Z ö B e _ @ 1 @ n @ rI and lfi" nxi c llylamine; like Di phenyla.- @@ ,. ;; t @@ i. @ - C @ ä @ -:.? chth ;; @?: .- in use- :, an alk2?: metal nitrite od ° 1 wA_n? 'share price of JJ e: @! ..: `I E''JeI1 -m. z L oJ.n em 1'hft ^ r, lio:. 'ha1r) r'e.-t:?: i üep. oinem Phoophor- @ :: will be. That can be a bit "tL @ li M. 1e0 GS @ '#' @` iiS '7' @ i1 @ ?? 0'i '@ `: GS en.h2.Ite11 Seine ütu @ E31 'd:! - e followingT_Besi @ iele explained in more detail. Beis p_i e? Q? I "'- F @ e @' c) e7 Mi n er.-iloils Used. _ @@. 1p i @P l @? " za vierden @ ol @ imie.fe tt, produced the one with 60 weight L, Fi @ .irr ääse @@ cl @ t of the tone. One of the .f @ si.noamids coated R .eo tö ^ i: -c torl ent? Ia? -% eri o The Ami rioamd @: z @d from Tall.ö? fe ttsö.uxen :? nd the one described above as a messenger product in the case of the , f_y ^, - t.hy @ .enpol @ arai: ngemisoh lendi_a.mherding incurred manufactured.- .g E) .h (@ 'lri .. ä @ - @ d. @ f..n_k ,, ... - --- n. @ .- S t t! @ 'w7 , 2 .4: -b- @: @r r . 1 .6 et al ° zaj: £ R @@ ea tJ,? @@ n T j 2 (' `jh (oE, S ° 'h x: @ e @ _,. @. 2 a. ».. j; U t7 5 2j -.- b C 03 0 n 'fr? - r @ 2.:t ä ä @ 7: G s!, r; - @ @ ß G : @ tw @ f -? -r 6L. ' . ^ - .-. r ra 2., 5 55 @ @ .. o T _.ml@ua @ - @ richstdr.?2t, k - T es @ -Y r1ST, 3 _j: J @ A,. (E-: in 22_8, äob2t ° 958 ? C -1 ° n @ ,, - # n. - # t; j4: L ° Z: L ° Z4Z zur: 6esch: cei.bvarag derI @@ cI @; # csl: °; @ "r #. r .tl vtt @yschaften! ier @ hmae # ° fe # t »@c: used. _.L - - Table :!: Show-L. d`ß the Iss vc: -i ° yellow! -i: in the # with sound input: Lck- t en S c? 1mier41 et en l-cR.nr '! 7 a 1,11v.e'.t reference to the .Hö c: hg t .. Fr re'r-, J: i; @ :, ezao Tt ^ ch15.eh'Pi.gr .._ MJA the grease I3 that n u _die. '.. P-PropertyS.1. Ueü I3, orb:% ncltixig with the lead des Basissehmierfet '@ es je ".. -4. J. 'Indeed four the EIP's own S !; of the kidney fat. # ,: if more r, 1. (IC, h # .r # gerraiuserxg äal Gor @ a4 contains white carbonate? quite in tnav ck ##. # yi # enn c # asle.i # carboz # a- #. v1Ird. : t _ '() "F @? @ Lit't (@` _ @.' W? 1 ) eI f des 1339issehm_ E? 2_ @ tc ?. ilie: 'ge a'is @ Jt @@ eX1 ? -J!' @: @ TL-'39: S-haf "4en die- : L - a .. @. @. c!: coona 3L: miie.i # ' p EB .,: ; rindr # Failed 3 H S e @ 5. c. ' @ #T @ @ r @ _i.iGS 20 25 s @ 0 '@ `T 4 0 35 4-0 i - 5 - 20 2 @, 5 Ca C; 0 ; = r 45 1 2 2-0 25 2 0 , g ? t ? %: 3 40 4Z: The other one? ch dos;: '? @ q with the E aSSsabm2.Srfe "i'i: : ei jb- v that dnr Ester: 7 ?? do, ac u ° egganwart eiP # - "Mee'allca: rbt" - = at P die L! # - j @ # e # t @ # C @ `?: 'z'3" t:.: S. @.? I Wh '# fln4' e, En iluß # El o ci v # .. Yeah the ester dai: 1 ha. one . = '. according to the method of the V- @ earth son: Eerfetre which amorphous axis ': Lil1C) xlr`'"3 @ 1 @. '1.f @ zu, E'.: 3Q"'# i? 1 @ s @ la.: I:.: @ " i 'a l ' _ '@: s'3? _1 Troƒkgkne x '@ - @ .: ass @ TAmken # 2r # L` rz 1'r # # ^ # j 1 , S TI c # .e 1 a, # : .sa # s y s. j # p..s C.1 ",. # i it w r, 3 rt. 0 i 1 r% L% tue ;, I fe p>: 25th 0 2 @, >> y. @, la? 01 7% . 5l , @ 55 - 0. - y ) f , @; b f ` E t ' 7 : @@, ... 5G E .. ä Fn @i e 7 # and the .t.sc f 1 ° # c 'P " c - r_ = .__ l «.- 7 # 17.3._üd u. #. .,. e ::.! 1 r: - (: # 7 (.. f aT. ("# Fj .. # #! T 'IA kf ^ # l.Il .. #. Üi '@ ireto r i S ()' D (Ihi'1 #. < l. _J . S ' J- @ .4 # .s. 1d. "Fi.L:; low N I ilng al? F 0s. One of the included Sehmier ;. @ - @ 1Comparison of L m. '@ T 0 bev? z-kt e :: °: .le der. EP-Exgenschaff.Ql! wet conditions. V f @ _1 ll, s'Fr. This is a set of keys to practice -about 0p75; contains. That is e`.: Ti22 we? l; erE! for the % @ y P that the egg zes chmiexfetteg in the absence entity JZ # JJ: 1.J # 4% @: 7N 7 - f essence of a 'iue'i; ällcar_bonates M.er i, ic: #Lall: sillfds through the e: £ -f: T @zc @@@? n £ sgcazä.ße @@ Car bon sä: areer. @ e r_ not verraess e L -s3 be. Example IV 1l! Ech, the procedure according to example! _: @W "C.G'i'2 Sehmierfette hergP # - sets the sbell e des retel icarbonate amorphous antimansul - : CM # included. To individual samples of the surviving Sohtnicxfotl-e vierdeAS Est Ue :. Nug @ egnben, u m. Determine. whether you d Yes EP notification of ' Table IV r. .: 11 5, ane? J ': r r ra @ c K e @ .i1'3 @ '_ () j ° r: 5'0 - 5 Tde-f: hyls tea: ca t '; 016 C.jC 60 @ # - Me thy? s @ earat 0175 . 0y6 60 - - - S. Butylate acetate 0175 0 # 17ä 60.t - @ 50 'i Hexylsteara * t 0 @ 5 0,% 5 60 `, - - u Butyl acetate 0175 0175 60+ '- - Bu'J1.yloleate 015 0.15 40 [5a @. - Dioctylsebara t- 0.1`i5 01'5 - 20 - @ Dideoylphenalat 01) 5 o f5 35 A0 - IZ ,, r @, ß @@ '>>;, @'<<; i. (@ Iäe.te, ret'4i $ auren ., ;;: E @ .: `` sF: s =; eg xr! 7 v while the esters r # ri-n # a, r # ? B ".i ::: c '@ .: i:' iü: r! '. 3 @ # i, 13: z $ i2iX1e : 1 #. 'J ..... #l 11 0, # m2 : 3Fä.j@1 ':. F ..' @ i., a -3ä. e f o r the ausgezeä ehae te ET-equity _: a:. '@ j: @: <<"; @r: @ ;. @? W @_'3aL'c @: ec @ nt; ax @ 'ciz @ siz! rees ternq Me -', all - . ti @? zrn. '@ e >> rün an :: Ivelsen, are the basic Schm1.er- - '' Additives en'th 3it en i Lead-- _ "# ...... # .. # _. i .. ,, .. @ ........ t .. # ... r #. na y do yf e. la io io thena - wt .; C, at, `0, i ..; G 7przT.: @ '@. ° fP @! @ s`.reaxa 0 ttr i, f, a @ 2 '% 2 n-Oet <y, ls teara.1; . i} " fa. CIL - (310 vi, ' - # palmi, üa, b 3 0 15 1 I j 1 n. 01 0 2i0 n-Pen-'1-, ylmyrista't 2 0 @earat 2.J # o75 n -: t'Ly1: 3-hGarat 0N25 0: <:. ! ry @; 0 25 _ i L - ° no r:. # r #). E 2 e: #TIc) 2 f1 Cs u i7. . e; a ( o11) 2 ;:? (ia z-: ui ;; r: La: i; cssanG: i: 2 0 r; @. @ `) @; @ 1, @ G # Yf @ 'r a .b., 25' @;) ;. 0 # c3zz # Al @ txii ### Jl.paarn.i: a ': @ :, 0 5 -: i C) .'r.fi0: 7b; 0 (111a (010, 5 1 10.1 .. ° _'1`;C; :: @; (# 3 @ T, t) xa - 13 @ x1: y7.denrzYLoat@i 1, @ 0 The ability of the L1'1! EP properties Fron. Me ", all sulfide - n and Metallarbnnaten as -Pwluse, corrosives too improve, ersmhein`, unso überrawehe% ider 9 ä`! s the esters no- any branches or subsistence with functional groups pen included; because ge * i r- ; ß the bay of Coi. Bauer "Yianufacture and Application 3f lubricat2ng G-easei3 "(no hold publishing Corp- p New York9 1950: c ß @ 11-115) t contain the mei some ingredients (zo, soy yeast, chlorine, Phosphorus, bees, tellurium and lead compounds), the true apparently with the ge c @ amie3, -ter r: eLa @ .. @@ be: @ nfl.oh :: n react and a cover who either withstands the load or at least one welding of the entire surface: on surfaces m >>. n.- the t .

Claims (1)

i; e n r ä n s D x ü c h e
:; S ch?ii@er@e+-Leemaochq dadurch gekonnzaichnetp daß es ein Metall- oax bonat eine" Mejralles der Gruppe If'i g 1e ITA, IVB9 VITA oder y --1- des ='cei odicehei2 System der Elemer ce und/oder ein Metall- ein Schm,*-e*@ölp eirein oleophilsn Ton"und einen Es,@er der allgemeinen Pornäe1
R.CO 0R2 er.-t;hä2It t in dir -c1 s_@_Y@o normale 0-1.-2, --?!lzzylgruppe ist' R2 eine .normale C-; -ö-A lkyl#r uppe bedeu-ue ü und. und R zusa@r?en o.@ens 5 Kohlenstoffatome aufweisen. ?. Gcl?uaierftett,gemi sch nach Anspruch 1, dadurch gekennzeichnet, da!' e:: ein l#e-etallsulfid enthält: Schna.a;Qre-t-i;g@ni.sch nach Anspruch 2 s dadurch gekennzeichnet, daß es bis zu 3 Gevl a % des Sulf i ds enthält. @@. Schmlexfettgensch nach Anspruch 2 und 3, dadurch gekennzeich- net, daß es Molybdänsul fi.d enthält. Schmierfettgemisch nach Ansptuch 2 lind 3, dadurch gekennzeieh- Met r daß es ein amorphes Antimonsulfid enthält: 6.. Schmierfettgemisch nach Anspruch 1 - 5, dadurch gekennzeeh- net g daß es ein Ne tallnaphthenat enthält. -
7. nach Anspruch 6, dL,diira1x gehennzeichriet daß sich daF 1?#iDh'@henwt von einem Gemisch von Naphthensätren ,al äLti,cho .i , . t3he n c :, -.gem icht v On wenigstens 250 a. blei'[,et.. . Scbmi erfe t tgeauisch nach Anspruch 7, dadurch ge hcnnzeichne-t 3 daß das hlaph-"-.heraz cit:c durchschnittliches 1`xcVlelculargevaicht von 250 - 3_00O @3. Sc?@?rii_cr.@°ei@t@fct??@.sch na sbruch sC 3. dadurch geksannzeich-- . net d daß es Bleina.:-,li@;3.@c :@.G S ohmi.er:re-L tgemzscla nach. ns prvc@2 9, d41dl?rch gekennzeichnet., o rin 7naplat;Iir.,a #j. 0 c, hR1(;:" e"' c' 0r75 c=0 i# w da_R >- die Menge c@e>a # #w# :zr#_ # ,.: @ @ezz.@ des chnlerettns 'beträgt. 11. Schmiedet tgemi sch nach Anspruch und 109 dadurch gekennzeinh- net, daß das Bleinaphtheziat 25 35 Gera.;-" Blei enthält. 12. Schmi erfettgemlsch nach Anspruch 3. .- 11, dadurch gekeisn "etcl.s- net, daß es .Wasser zLv-,- Verüesserunf- der,. Schmierfc-L ükonsisten z enthält. 13# Schmierfettgeraisch nach -Anspruch 12, dadurch gekeiinze_i.chne,t, daß die TZenge des Wassers O. r- -- l Gew.! des Schmierfettes be- träg b . 14. Schmierfettgemisch nach Anspruch 1 -- 139 dadurch gekennzeich- net, daß das Carbonat eine Härte nach r,Ztihs von 1 a 5 aufweist und sich nicht wesentlich zersetzt, wenn es in Luft bis zu einer Temperatur von wenigstens 250 0C erhitzt wird.
12 :-r. ` t ^ .,." j t ... Caf.u h g enthält AYi.:i-D"s'uc h 1 4 1t7.128 15, dadurch gekL'Jttnzeieh- S-@ 5 : :.-y:3 vs? E f JT>y'r@ f :yin f'y @.'( k s C.!6`l J w Anspruch 16; dadurch daB '@ t - Uh vlütd 15 g. d#U.L6rG.C.Lek11171e#.Vh@°' j e @, @r 4 @ ena enthält. 18, dadurch gekeIFleich hIletg 20 Pac ri ,-sDruch 14 und 15? dadurch geken?IZech#- 2 rc:h:?:@ @--,. .,@era:@@o& u^^h Anopruch i -- 20, dadurch gekennzeichnet, c«,.c(sphil c 9'.an v=on finera Ton mit einer hohen Basen- 2>. ^.zz_:z@s:x2 21, dadurch gekennzeichnet, daß dte igüne des oieopnx:)-en 2v5 -- 10 Gew.cpf des Tonanteils den ni:ch Axispruch ?_1 und 22q dadurch gekennzeich#- '@r-`t daß Uer TOn 7r012 eix.e?n Tun mit einer Basen-- 25 @@l.» Ir@1T lchk^ FJ@`i:',.L'ft.:'@t '@rC@YI 'J'i@a,@aß'@LYt: mA.quvalent 'e'n pro 100 g',,
24. nach 21Stt@n 25.Q drediz?"aeeZ@YZeeY1.'1@:'a daß sich der ol-nphi-l n Ton von einem Ton mit einer Basona us- von 25 ./. 100 mc-#qtiiiraler-beea- pro 100 g ablei- J e f- 25. ächmierfet°tgemisch nach jLnspruch 247 dadurch gekennzeichnet, daß sich der oleophas Ton von einem Heotorit ableitet. 26. Schmierfeftgerrz_isch ?Zach Anspruch 21 .- 25; dadurch gekennzeich.- net s dcaß eich der oleophile Ton iron ` einem nicht oleophilen Ton und einer organischen Ammmoni u#üabase als dleophiles kati oni °y° sches oberflächenaktd.veü !",litte! ableitet. 27. Schmi erfettgemisch nach Anspruch 26, dadurch gekennzeichnet 2 daß zur Herstellung des ßloophi wen Tonei 2 ;@ 5 - 5 Gem u 'J des kationisehen oberfläohenaktivei? Mittels verwendet werden.. 28. Schmierfettgemisch :rasch Anspruch 26 und 27, dadurch geken n- seichne°t e daß es als selbständiger' Bestandteil eine orgarxis^he Ammoniumbaee als cl eophilles lati oxii sches oberflächenaktives Mittel enthält. 29. Schmierfettgemisch. nach Anspruch 2f> - 28, dadurch gekeniazexc,J:1- netp daß der oleophile Ton mit einem oleophilen Imidauolin überzogen ist und/oder daß das Imidazolin als ein Bestandteil des Schmierfettes vorliegt. 30. "ohmierfettgemisch nach Anspruch 29, dadurch gekennzeichnet, daß das oleophile Imidarolin ei.n =Kohl enwasserstoff--Imida?olin ist
31. '.`,.'iilliwZP@'4tfüa'ßrl.@ weh na ch Ansr eich 71,0? dadurch gekennzeichnet, . @d;iß daa I!idazol-i"i ein Cut p_2Ü""Al_@rl;mida@ o@lin ist. 32c@.ierfetf_ger>z? sc.# nach Anspruch 30, dadurch gekennzeichnet, zl;ß das ..mi da:zel in ein CZQ-20~Alkenylianidazolin ist. )woä^::niexe'ct^misci.@ nach Anspruch 29.4 dadurch gekennzeichnet, d.a r das o? ec@ps@:le Zr:-a riazol in ein Hjrdro7.ykohlenwasseratoff- @_FV Aet J na^h Artspruch 33, dadurch gekennzeichnet, r < , o @r < <. s ri e2:r ( @' @.t z.°y._@:@ »20_a1T 7 )-alhylim@.dazo@.:i.i h. bohni_Frfattgeniach =zanh Ans2Lich 33, dadurch gekennzeichnet, daß das :nida Polin e.n . (h a'":'%@@.@Clp°'@x@ayl)-alkenyl.mi@iazv.- d !.@: S -t. 26. Sr:hmi erfe ttüer@.sr nach Anspzuc;_h 29, dadurch gekennzeichnet, där3 das ct@.eonh-.l@e lmidazolin ein Aminohohlenwasäers toffimi- t @@f@z o_=.in ist, 37. "chm? erfettg--n? sch nach Anspruch 26 - 36, dadurch gekennzeich- net, daß der oleophil e Tor. mit einem aleophilen Aminoamid icherzogen ist und/oder dieses Araincamxd als Bestandteil dee @clunierfettes vorliegt. 38: Srhmierfettgemi sch nach Anspruch 37, dadurch gekennzeichnet, daß sich das Arninoamid von einer Clp-2p-Fettsäure und einem Polyäthylenpolyamin ableitete
59. Schmierfetzgernzsch nach Anspruch 38s dadurch gekennzeichnet, .daß es mehr als ein Aminoamid enthält. 1.0'' Sehmierfettgemisch nach Anspruch 38* und 39, dadurch gekenn- zeichnet, daß das Gewichtsverhältnie von Amin zu Säure für das oder die Aminoamide.30/70 - 40160 beträgt. U..Schmierfettgemisch nach Anspruch 39 und 40, dadurch gekenn- ze-t chnet, daß sich. die Amizoamide von C16-20-Pettsäuren ab- leiten, von denen wenigstens 50 Gew.ö eine Doppelbindung ent- halten. 12. Schmierfettgemisch nach Anspruch 39 und 40, dadurch gekenn- zeichnet, daß sich die Aminoamide von C10-18'Pettsäuren ablei- ten, die eine Jodzahl von höchstens 50 aufweisen. 1.3. Sehmierfettgemiseh nach Anspruch 41 und 42, dadurch gekenn- zeichnet, daß sich die Aminoamide von Bolyäthylenpolyaminen . ableiten, die zu 20 - 80 Gew.% aus biäthylentriamin und zum Rest aus.Polyäthylenpolyaminen mit einem durchschnittlichen Molekulargewicht von 220 - 450 bestehen. @.4. ,Schmierfettgemiech nach Anspruch 43, dadurch gekennzeichnet, daß sich die Aminoamide von Polyäthylenpolyaminen ableiten, die weniger als 50 Gew.% Diäthylentriamin enthalten. U) Schnieriettgemisch nach-Anspruch 1 - 44, dadurch gekennzeieh-- . net, daß es 0,25 -- 5 Gew.% des. Esters enthält:
46. Schmieriettgemisch nach Anspruch 1 - 459 dadurch gekennzeic'. net, daß der Substituent R1 des Esters eine 016-18"Alkylg:cu- pe ist. 47. Schmierfettgemisch nach Anspruch 1 - 46, dadurch gekennzeicit net, daß der Substituent R2 des Esters eine 01-6-Alkyigrupp, ist. 48. Schmierßettgemisch nach Anspruch 1 - 47, dadurch gekennzeic. net, däB es Butylstearat als Ester enthält.
i; enr ä ns d x ü che
:; S c h? Ii @ er @ e + -Leemaochq in that it is a metal oax bonat a "Mejralles of the group If'i g 1e ITA, IVB9 VITA or y --1- des = 'cei odicehei2 system of elements and / or a metal a Schm, * - e * @ Ölp eirein oleophilsn Ton "and an Es, @ er of general pornography 1
R. CO 0R2 er.-t; holds in you -c1 s _ @ _ Y @ o normal 0-1.-2, - ?! lzzyl group is' R2 one .normal C-; - ö-A lkyl # r uppe mean-ue ü and. and R together o. @ ens have 5 carbon atoms. ?. Gcl? Uaierftett, mixed according to claim 1, characterized in that there!' e :: a l # e-metal sulfide contains: Schna.a; Qre-ti; g@ni.sch according to claim 2 s characterized that it contains up to 3 Gevl a% of the sulfidic acid. @@. Schmlexfettgensch according to claim 2 and 3, characterized in that net that it contains molybdenum sulphate. Lubricating grease mixture according to claim 2 and 3, thus marked With the fact that it contains an amorphous antimony sulphide: 6 .. lubricating grease mixture according to claim 1 - 5, characterized marked net g that it contains a metal naphthenate. -
7. according to claim 6, dL, diira1x gehtnzeichriet that daF 1? # iDh '@ henwt is from a mixture of naphthenic seeds , al ÄLti, cho .i,. t3he nc:, - according to at least on 250 a. b l ei '[, et .. . Scbmi erfe t tgeauisch according to claim 7, characterized ge hcnnzeichne-t 3 that the hlaph - "-. Heraz cit: c average 1`xcVlelculargevaicht from 250 - 3_00O @ 3. Sc? @? Rii_cr. @ ° ei @ t @ fct ?? @. Sch na sbruch sC 3. net d that it is Bleina.:-,li@;3.@c : @. GS ohmi.er:re-L tgemzscla after. ns prvc @ 2 9, d41dl? rch marked., o rin 7naplat; Iir., a #j. 0 c, hR1 (;: "e"'c' 0r75 c = 0 i # w da_R> - the set c @ e> a # # w #: zr # _ #,.: @ @ ezz. @ des chnlerettns' is. 11. Schmiedet tgemi sch according to claim and 109 thereby marked net that the lead naphthociate 25 35 Gera.; - "contains lead. 12. Schmi erfettgemlsch according to claim 3. .- 11, thereby gekeisn "etcl.s- net that there is .Water zLv -, - Verüesserunf-,. Lubricant lubricants z contains. 13 # lubricant device according to claim 12, thereby gekeiinze_i.chne, t, that the amount of water o.r- - 1 weight! of the grease sluggish b. 14. Lubricating grease mixture according to claim 1 - 139 characterized thereby net that the carbonate has a hardness according to r, Ztihs of 1 a 5 and does not decompose significantly when it is in air up to a temperature of at least 250 0C is heated.
12 : -r. ` t ^ .,." j t ... Caf.uhg contains AYi.:iD"s'uc h 1 4 1t7.128 15, thereby clipped S- @ 5:: .- y: 3 vs? E f JT>y'r @ f: yin f'y @. '(K s C.! 6`l J w Claim 16 ; through this that '@ t - Uh vlütd 15 g. d # U.L6rG.CL e k11171 e #.Vh@° ' contains @, @r 4 @ ena. 18, thus noticeably hIletg 20 Pac ri, -sDruch 14 and 15? thereby geken? IZech # - 2 rc: h:?: @ @ - ,. ., @ era: @@ o & u ^^ h Anopruch i - 20, characterized c «,. c (sphil c 9'.an v = on finera tone with a high base 2>. ^ .zz_: z @ s: x2 21, characterized in that dte igüne des oieopnx:) - en 2v5 - 10 cpf by weight of the clay component ni: ch Axis saying? _1 and 22q marked by # - '@ r-`t that Uer TOn 7r012 eix.e? n do with a base-- 25 @@ l. » Ir @ 1T lchk ^ FJ @ `i: ',. L'ft.:' @ T '@ rC @ YI'J'i @ a, @ aß '@ LYt: mA.quvalent'e'n per 100 g ' ,,
24. after 21Stt @ n 25.Q drediz? "AeeZ@YZeeY1.'1 @: 'a that the ol-nphi-ln tone differs from a tone with a basona us- from 25 ./. 100 mc - # qtiiirale r- beea- per 100 g lea- J e f- 25. ächmierfet ° t mixture according to jLnspruch 247 characterized in that that the oleophous clay is derived from a heotorite. 26. Lubricant Gerrz_isch? Zach claim 2 1 .- 25; characterized by this - net s dcaß the oleophilic clay iron `a non-oleophilic Clay and an organic ammmoni u # üabase as dleophiles kati oni ° y ° sches ober f lächenaktd.veü ! ", litte! derives. 27. Lubricating grease mixture according to claim 26, characterized in 2 that for the production of the ßloophi wen Tonei 2 ; @ 5 - 5 Gem u 'J des cationic surface active? Can be used by means of .. 28. Lubricating grease mixture: quickly claim 26 and 27, thereby geken n- see that it is an independent component of an organizational structure Ammoniumbaee as cl eophilles lati oxii cal surface-active Contains funds. 29. Mixed grease. according to claim 2f> - 28, thereby gekeniazexc, J: 1- netp that the oleophilic clay with an oleophilic imidauolin is coated and / or that the imidazoline is an ingredient of the grease is present. 30. "ohmic fat mixture according to claim 29, characterized in that that the oleophilic imidaroline ei.n = hydrocarbon - imida? olin is
31. '.`,.' IilliwZP @ '4tfüa'ßrl. @ Weh nach Ansr eich 71.0? characterized, . @d; eat daa I! idazol-i "i a cut p_2Ü""Al_ @ rl; mida @ o @ lin is. 32c @ .ierfetf_ger> z? sc. # according to claim 30, characterized in that zl; ß the ..mi da: zel is in a CZQ-20 ~ alkenylianidazoline. ) where ä ^ :: niexe'ct ^ misci. @ according to claim 29.4 characterized in that because r the o? ec @ ps @: le Zr: -a riazol in a Hjrdro7.ykohlenwasseratoff- @_FV Aet J na ^ h Artspruch 3 3, characterized in that r <, o @r <<. s ri e2: r (@ '@ .t z. ° y ._ @: @ »20_a1T 7) -alhylim @ .dazo @ .: ii H. bohni_Frfattgeniach = zanh Ans2Lich 33, characterized that the: nida Polin en. (h a '":'% @@. @ Clp ° '@ x @ ayl) -alkenyl.mi@iazv.- d!. @: S -t. 26. Sr: hmi erfe ttüer @ .sr after Anspzuc; _h 29, characterized där 3 the ct @ .eonh-.l @ e lmidazolin an Aminohohlenwasäers toffimi- t @@ f @ z o _ =. in is, 37. "chm? Erfettg - n? Sch according to claim 26 - 36, characterized thereby- net that the oleophilic gate. with an aleophilic amino amide I educated and / or this Araincamxd as part of dee @clunierfettes is available. 38: Creamy fat mixture according to claim 37, characterized in that that the amino amide of a Clp-2p fatty acid and a Polyethylene polyamine derived
59. Schmierfetzgernzsch according to claim in characterized 38s, .that it contains more than one amino amide. 1.0 '' Sehmier fat mixture according to claim 38 * and 39, characterized by draws that the weight ratio of amine to acid for the amino amide (s) .30 / 70-40160. U .. lubricating grease mixture according to claim 39 and 40, characterized ze-t chnet that. the amizoamides of C16-20 fatty acids conduct, of which at least 50% by weight form a double bond keep. 12. Lubricating grease mixture according to claim 39 and 40, characterized shows that the amino amides are derived from C10-18 'fatty acids that have an iodine number of 50 or less. 1.3. Sehmierfettgemiseh according to claim 41 and 42, characterized draws that the aminoamides of Bolyäthylenpolyaminen . derive from 20-80% by weight of biäthylenetriamine and for Rest aus.Polyäthylenpolyaminen with an average Molecular weight of 220-450 exist. @ .4. , Lubricating grease composition according to claim 43, characterized in, that the amino amides are derived from polyethylene polyamines, which contain less than 50% by weight of diethylenetriamine. U) Schnieriettverbindungen according to claim 1 - 44, thereby marked-- . net that it contains 0.25-5% by weight of the ester:
46. Lubricant mixture according to claim 1 - 459 thereby marked '. net that the substituent R1 of the ester is a 016-18 "alkylg: cu- pe is. 47. Lubricating grease mixture according to claim 1 - 46, characterized gekennzeicit net that the substituent R2 of the ester is a 01-6-Alkyigrupp, is. 48. lubricating grease mixture according to claim 1-47, characterized thereby. net, that it contains butyl stearate as an ester.
DE19651594594 1961-10-17 1965-09-06 Lubricating grease mixture Pending DE1594594A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14577161A 1961-10-17 1961-10-17
US383503A US3271309A (en) 1961-10-17 1964-07-17 Grease compositions
US395024A US3370007A (en) 1964-09-08 1964-09-08 Extreme-pressure grease compositions

Publications (1)

Publication Number Publication Date
DE1594594A1 true DE1594594A1 (en) 1971-04-22

Family

ID=27386311

Family Applications (3)

Application Number Title Priority Date Filing Date
DES82042A Pending DE1284012B (en) 1961-10-17 1962-10-15 Lubricating grease mixtures
DE19651594590 Pending DE1594590A1 (en) 1961-10-17 1965-07-15 Lubricating grease mixture
DE19651594594 Pending DE1594594A1 (en) 1961-10-17 1965-09-06 Lubricating grease mixture

Family Applications Before (2)

Application Number Title Priority Date Filing Date
DES82042A Pending DE1284012B (en) 1961-10-17 1962-10-15 Lubricating grease mixtures
DE19651594590 Pending DE1594590A1 (en) 1961-10-17 1965-07-15 Lubricating grease mixture

Country Status (7)

Country Link
US (1) US3271309A (en)
BE (3) BE666946A (en)
CH (1) CH447443A (en)
DE (3) DE1284012B (en)
FR (1) FR88753E (en)
GB (3) GB960059A (en)
NL (3) NL6509144A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3344065A (en) * 1965-01-25 1967-09-26 Molykote Produktions G M B H Extreme pressure lubricants
NZ186808A (en) * 1977-04-06 1979-10-25 Rocol Ltd Lubricant composition containing group ii-a metal carbonate and halogenated organic lubricant
US4156655A (en) * 1978-01-30 1979-05-29 Exxon Research & Engineering Co. Grease composition resistant to salt water corrosion
US4435296A (en) 1981-05-22 1984-03-06 The British Petroleum Company Limited Lubricating grease
US20090325829A1 (en) * 2008-06-27 2009-12-31 Cowan Sandra S Reduced Molybdenum Grease Formulation

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1204605A (en) * 1916-02-26 1916-11-14 James M Stafford Device for locating and raising sunken vessels.
US2831809A (en) * 1952-11-25 1958-04-22 Shell Dev Onium clay grease containing surface active agent
US2704276A (en) * 1954-02-12 1955-03-15 Gulf Research Development Co Lubricating compositions
DE1065968B (en) * 1955-12-20 1959-09-24 N. V. De Bataafsche Petroleum Maatschappij, Den Haag Process for the production of lubricating greases
FR1282216A (en) * 1959-12-15 1962-01-19 Exxon Research Engineering Co Process for the manufacture of additives soluble in petroleum oils

Also Published As

Publication number Publication date
CH447443A (en) 1967-11-30
NL6511631A (en) 1966-03-09
BE623658A (en)
GB960059A (en) 1964-06-10
GB1041509A (en) 1966-09-07
DE1594590A1 (en) 1971-06-03
FR88753E (en) 1967-06-07
NL284414A (en)
BE669245A (en) 1966-03-07
BE666946A (en) 1966-01-17
GB1100189A (en) 1968-01-24
DE1284012B (en) 1968-11-28
US3271309A (en) 1966-09-06
NL6509144A (en) 1966-01-18

Similar Documents

Publication Publication Date Title
DE2727250A1 (en) SURFACE-COATED SINTER HARD METAL OBJECTS AND A PROCESS FOR THEIR PRODUCTION
EP0842944A3 (en) Heterocycles as inhibitors of leukocyte adhesion and as antagonists of VLA-4
DE3136449A1 (en) FERROMAGNETIC LIQUID COMPOSITION AND METHOD FOR THE PRODUCTION THEREOF
MX169456B (en) LIQUID, LUBRICATING AND FUNCTIONAL COMPOSITION CONTAINING PHOSPHOR AND SULFUR
DE1594594A1 (en) Lubricating grease mixture
DE2043952A1 (en) Process for aluminizing objects made of nickel, cobalt or their alloys
DE1278056B (en) Grease
DE1771228A1 (en) SHINE AGENT MIXTURE FOR GALVANIC COPPER PYROPHOSPHATE BAEDER
Nelson et al. Trace element analysis of obsidian artifacts from three shell midden sites in the littoral zone, Chiapas, Mexico
Fuchs Über neuere Polymetallate/Polyanions of Novel Structural Types
EP0915083A3 (en) Process for the preparation of substituted guanidine derivatives
Köhler Spätquartäre paläo-ozeanographische Entwicklung des Nordpolarmeeres und Europäischen Nordmeeres anhand von Sauerstoff-und Kohlenstoff-Isotopenverhältnissen der planktischen Foraminifere Neogloboquadrina pachyderma (sin.)
Long Magnetoelastic sensitivity and composition of Permalloy films
Näumann et al. Dinitrosylvanadiumkomplexe:[VL4 (NO) 2] Br (L= N, P, As, Sb, O und S-Donor/Akzeptor) und [VX (CNR) 3 (NO) 2](X= Cl, Br, I)/Dinitrosylvanadium Complexes:[VL4 (NO) 2] Br (L= N, P, As, Sb, O and S Donor/Acceptor) and [VX (CNR) 3 (NO) 2](X= Cl, Br, I)
DE3609309C2 (en)
DE1257332B (en) Grease containing a resin coated colloidal clay
Heilemann Hydrodynamische Änderungen des Mittelmeerausstromwassers und deren Abbildung in den Sedimenten des iberischen Kontinentalhangs
DE436439C (en) Refinement of hard alloys
DE2704691A1 (en) CYANIDE-FREE BATHROOM FOR THE GALVANIC DEPOSITION OF GLOSSY SILVER AND SILVER ALLOY COVERS AND WATER-SOLUBLE SILVER COMPLEX FOR THE PRODUCTION OF DESSELS
Andreae Fruchtfolgeformen in Deutschland
DE951225C (en) Additive to lubricating oils
DE1616478U (en) ELECTRIC PENDULUM
AT55461B (en) Process for the preparation of derivatives of tetrahydroberberine.
Bakerman OASI Statistics. A Program for Insurance Industry Employment Research. Part III
DE1214241B (en) Process for the preparation of nickel complexes