DE1545473A1 - Method and device for the production of combustible gases by catalytic cracking of liquid or gaseous hydrocarbons - Google Patents

Method and device for the production of combustible gases by catalytic cracking of liquid or gaseous hydrocarbons

Info

Publication number
DE1545473A1
DE1545473A1 DE19651545473 DE1545473A DE1545473A1 DE 1545473 A1 DE1545473 A1 DE 1545473A1 DE 19651545473 DE19651545473 DE 19651545473 DE 1545473 A DE1545473 A DE 1545473A DE 1545473 A1 DE1545473 A1 DE 1545473A1
Authority
DE
Germany
Prior art keywords
cracking
catalytic cracking
production
hydrocarbon
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19651545473
Other languages
German (de)
Inventor
Jacques Decaux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
G E G I STE DE CONSTRUCTION D
Original Assignee
G E G I STE DE CONSTRUCTION D
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by G E G I STE DE CONSTRUCTION D filed Critical G E G I STE DE CONSTRUCTION D
Publication of DE1545473A1 publication Critical patent/DE1545473A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Description

Unser Zeichen: S 2110Our reference: S 2110

Verfahren und Einrichtung zur Erzeugung brennbarer Gase durch katalytieche Krackung flüssiger oder gasförmigerMethod and device for the production of flammable gases by catalytic cracking of liquid or gaseous forms

KohlenwasserstoffeHydrocarbons

Die Erfindung betrifft eine Verbesserung der Herstellung brennbarer Gase durch katalytische Krackung flüssiger oder gasförmiger Kohlenwasserstoffe.The invention relates to an improvement in manufacturing flammable gases through catalytic cracking of liquid or gaseous hydrocarbons.

Bekanntlich erfolgt die katalytische Krackung von Kohlen-Wasserstoffen gemäss einer der folgenden Methoden:It is known that the catalytic cracking of hydrocarbons takes place according to one of the following methods:

Katalytische Dampfkrackung mit ausaerer Erhitzung:Catalytic steam cracking with external heating:

Die Einrichtung besteht aus in einem Ofen angeordneten, mit Katalysator gefüllten Rohren; der su behandelnde The device consists of tubes arranged in an oven and filled with catalyst; the su treated

Dr.Ea/MaDr Ea / Ma

909884/0805909884/0805

KohlenwasserstoffHydrocarbon

Kohlenwasserstoff durchquert nach Zusatz τοη Wasserdampf und/oder eines anderen fliesefähigen Mediums den Kataly-Hydrocarbon traverses water vapor after adding τοη and / or another flowable medium the catalyst

eator, wobei die endotherme Krackungereaktion Tor sich geht; die entsprechende Kalorieneufuhr wird durch äussere Erwärmung geliefert.eator, the endothermic cracking reaction being gate itself goes; the corresponding calorie intake is provided by external Warming delivered.

Endotherme katalytische Krackung mit Luft und/oder Sauerstoff:Endothermic catalytic cracking with air and / or oxygen:

Sie Einrichtung besteht aus einer den Katalysator enthaltenden Kammer; der mit Luft und/oder Sauerstoff und/oder einem anderen fliessfähigen Medium versetzte, zu behandelnde Kohlenwasserstoff durchsetzt den Katalysator, wobei sich die Krackungsreaktion abspielt, welche dank der richtigen Wahl der miteinander reagierenden Medien endotherm verläuft·The device consists of a chamber containing the catalyst; the one with air and / or oxygen and / or another flowable medium to be treated hydrocarbon passed through the catalyst, whereby the cracking reaction takes place, which is endothermic thanks to the right choice of media that react with one another

öemäss der Erfindung werden nun zwei oder mehrere der vorstehend genannten Einrichtungen so in Beihe geschaltet, dass die zweite und die folgenden Krackungen in Anwesenheit von bei der ersten Krackung austretenden fliessfähigen Medien erfolgen·öemäss of the invention, now two or more of the above-mentioned devices are so connected in B e ihe that the second and the following Krackungen in the presence of exiting at the first cracking flowing media carried ·

Der Grund für dieses Torgehen ist darin zu suchen, dass in der Regel bestimmte der fliessfähigen Medien im Überschuss verwendet werden müssen» insbesondere der Wasser-The reason for this goal is to be found in the fact that As a rule, certain of the flowable media must be used in excess »in particular the water

909884/0805909884/0805

dampf, und dass der bei der ersten Kraokung rorhandene Überschuss für die aaschliessenden Kraokungen ausgenutzt wird, so dass der Oesaatttberschuse an fliesefähigen Medien rerringert werden kann ι die Wäraeausbeute wird dabei erhöht, da Wäraererluste infolge einer Herabsetsung dieser überschüssigen fliesafähigen Medien rerringert werden·steam, and that the rorhandene at the first Kraokung The surplus used for the closing fractions so that the Oesaatttberschuse of flowable media can be rerredert ι the heat yield is thereby increased because of the loss of water due to a lowering this excess flowable media rerringert will·

Die Zeichnung zeigt «ine beispielsweise Ausführungeform der erfindungsgemäss zu rerwendenden Einrichtung. In den Tier Figuren der Zeichnung bezeichnen gleiche Bezugsseiohen gleiche TeileιThe drawing shows an example of an embodiment the device to be used according to the invention. In the Animal figures in the drawing refer to the same reference series and the same parts

1 bezeichnet die in ier rorstehend beschriebenen ersten Methode erwähnten Kraokungsrohre, 2 bezeichnet die in der beschriebenen zweiten Methode erwähnte Kraokungskauter, der Katalysator ist mit 3 bezeichnet, der Heizbrenner alt 4, der Kamin zur Abführung der Heizgase mit 5, die Zufuhr für den Kohlenwasserstoff Bit 6, die Daapfzuleitung alt 7, die Luft- und/oder Sauerstoff einleitung mit 8, die Zuführung für ein etwa τerwendetes anderes fllessfähiges Medium Bit 9, die Terbindungsleitmngen zwischen den beiden Kraolningseinrichtungen mit 10 und die Abführung für das als Endprodukt erhaltene brennbare das alt 11. Der Kraokungsofen Bit äusserer Xrhitzung ist1 denotes the first described in ier ror Method mentioned Kraokungsrohre, 2 denotes the Kraokungskauter mentioned in the second method described, the catalyst is denoted with 3, the heating burner old 4, the chimney for the discharge of the heating gases with 5, the supply for the hydrocarbon bit 6, the Daapf supply line old 7, the air and / or oxygen supply with 8, the feed for something else that is used approximately Fluid capable medium bit 9, the connection lines between the two Kraolningseinrichtungen with 10 and the Discharge for the combustible das obtained as the end product alt 11. The coking oven is bit of external heating

909 884/0805909 884/0805

der Einfachheit halber nur durch ein einsigee Bohr und einen einzigen Brenner dargestellt, kann jedoch natürlich mehrere Rohxe und mehrere Brenner enthalten.for the sake of simplicity only represented by a single drill and a single burner, but can of course contain several tubes and several burners.

909884/060S909884 / 060S

Claims (4)

Patent an sprü ehePatent to spray / 1) i Verfahren zur Herstellung brennbarer Grase durch katalytisehe Krackung von Kohlenwasserstoffen, wobei die zu krackenden Kohlenwasserstoffe im Gemisch mit einem anderen fliessfähigen Medium, z.B. Wasserdampf, Luft oder Sauerstoff, durch einen Katalysator geführt werden, an welchem sich die Krackungereaktion abspielt, dadurch gekennzeichnet, dass man die gemischten fliessfähigen Medien nacheinander durch zwei oder mehrere, in Reihe geschaltete Krackungeeinrichtungen führt./ 1) i process for the production of combustible grass by catalytic cracking of hydrocarbons, the hydrocarbons to be cracked in the Mixture with another fluid medium, e.g. water vapor, air or oxygen a catalyst are performed on which the cracking reaction takes place, characterized in that the mixed flowable Media leads one after the other through two or more cracking devices connected in series. 2) Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der zu krackende Kohlenwasserstoff mit Wasserdampf gemischt wird.2) Method according to claim 1, characterized in that the hydrocarbon to be cracked is mixed with water vapor. 3) Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der zu krackende Kohlenwasserstoff mit luft oder Sauerstoff gemischt wird.3) Method according to claim 1, characterized in that the hydrocarbon to be cracked with air or oxygen is mixed. 4) Einrichtung zur Durchführung des Verfahrens nach den Ansprüchen 1 bis 3, enthaltend ein oder mehrere mit Katalysator gefüllte, von aussen erhitzt· Rohre oder Kammern, durch welche das Gemisch aus dem su krackenden Kohlenwasserstoff und dem oder den anderen4) Device for performing the method according to claims 1 to 3, containing one or more tubes or chambers filled with catalyst, heated from the outside, through which the mixture from the see below cracking hydrocarbon and one or the other 909884/0805909884/0805 fliessfähigen Medien hindurcligefülirt wird, dadurch gekennzeichnet, da·· zwei oder mehrere dieser Einrichtungen in Reihe geschaltet sind·flowable media is hindurcligefülirt, characterized in that ·· two or more of these devices are connected in series · 909884/0805909884/0805
DE19651545473 1964-06-30 1965-06-05 Method and device for the production of combustible gases by catalytic cracking of liquid or gaseous hydrocarbons Pending DE1545473A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR980104A FR1408764A (en) 1964-06-30 1964-06-30 Further training in fuel gas production equipment

Publications (1)

Publication Number Publication Date
DE1545473A1 true DE1545473A1 (en) 1970-01-22

Family

ID=8833517

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19651545473 Pending DE1545473A1 (en) 1964-06-30 1965-06-05 Method and device for the production of combustible gases by catalytic cracking of liquid or gaseous hydrocarbons

Country Status (7)

Country Link
BE (1) BE660649A (en)
CH (1) CH506610A (en)
DE (1) DE1545473A1 (en)
ES (1) ES311569A1 (en)
FR (1) FR1408764A (en)
GB (1) GB1109474A (en)
NL (1) NL6508378A (en)

Also Published As

Publication number Publication date
NL6508378A (en) 1965-12-31
ES311569A1 (en) 1965-07-01
BE660649A (en) 1965-09-06
FR1408764A (en) 1965-08-20
CH506610A (en) 1971-04-30
GB1109474A (en) 1968-04-10

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