DE14950C - Diazotir process and its continuation for color formation - Google Patents
Diazotir process and its continuation for color formationInfo
- Publication number
- DE14950C DE14950C DENDAT14950D DE14950DA DE14950C DE 14950 C DE14950 C DE 14950C DE NDAT14950 D DENDAT14950 D DE NDAT14950D DE 14950D A DE14950D A DE 14950DA DE 14950 C DE14950 C DE 14950C
- Authority
- DE
- Germany
- Prior art keywords
- diazotir
- color formation
- continuation
- fiber
- colors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 4
- 230000015572 biosynthetic process Effects 0.000 title claims 3
- 238000005755 formation reaction Methods 0.000 title claims 3
- 239000000203 mixture Substances 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 150000002989 phenols Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 150000002826 nitrites Chemical class 0.000 claims 1
- 239000003086 colorant Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- SATZKZRGXNAHHL-UHFFFAOYSA-N 1-(diazomethyl)-2-methylbenzene Chemical compound CC1=CC=CC=C1C=[N+]=[N-] SATZKZRGXNAHHL-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- MBENGEYDAUUYCZ-UHFFFAOYSA-N 1-diazo-2H-naphthalene Chemical compound C1=CC=C2C(=[N+]=[N-])CC=CC2=C1 MBENGEYDAUUYCZ-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 150000008049 diazo compounds Chemical class 0.000 description 2
- CRGRWBQSZSQVIE-UHFFFAOYSA-N diazomethylbenzene Chemical compound [N-]=[N+]=CC1=CC=CC=C1 CRGRWBQSZSQVIE-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 1
- CAMXVZOXBADHNJ-UHFFFAOYSA-N Ammonium nitrite Chemical compound [NH4+].[O-]N=O CAMXVZOXBADHNJ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- FCPGLSSNBUVLLD-UHFFFAOYSA-N naphthalen-1-ol;sodium Chemical compound [Na].C1=CC=C2C(O)=CC=CC2=C1 FCPGLSSNBUVLLD-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/68—Preparing azo dyes on the material
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Paints Or Removers (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Dieses Verfahren unterscheidet sich von dem bisherigen und bekannten dadurch, dafs keine freie Säure zur Zersetzung des Nitrits, dagegen letzteres als Ammoniumsalz oder in Verbindung mit Ammoniumsalzen angewendet wird.This procedure differs from the previous and known one in that there is none free acid to decompose the nitrite, on the other hand the latter as ammonium salt or in combination is applied with ammonium salts.
In kaltem Zustande erfolgt hie.r anfänglich keine Zersetzung, wohl aber beim Erwärmen des in geeigneter Form auf die Faser gebrachten Gemisches. Dies gestattet, sämmtliche zur Bildung von Farbniederschlägen vermittelst Combinirung von Diazoverbindungen mit Naphtolen und Phenolen dienlichen Substanzen unzersetzt in einer Mischung auf die Faser zu bringen und die Farben dann auf dem in der Praxis für andere Farben üblichen Weg des Hängens und Dämpfens zu entwickeln und zu fixiren.In the cold state there is initially no decomposition, but it does so on warming of the mixture applied to the fiber in a suitable form. This allows all for education of color precipitates through the combination of diazo compounds with naphthols and phenols to apply undecomposed substances to the fiber in a mixture and then the colors in the usual way of hanging other colors in practice and to develop and fixate dampening.
Bei Anwendung dieses Verfahrens auf die Diazoverbindungen des Benzols und seiner Homologen, ferner des Naphtalins, erhält man mit den Naphtolen vorzugsweise rothe Farben, und zwar in Verbindung mit Diazobenzol oder Diazotoluol Gelbroth, Diazoxylol mittleres Roth, Diazonaphtalin violet Roth; mit den Phenolen erhält man gelbe Farben, und zwar in Combination mit Diazobenzol, Diazotoluol, Diazoxylol reingelb bis orange, und mit Diazonaphtalin orange Töne.When applying this method to the diazo compounds of benzene and its homologues, furthermore of naphthalene, one obtains preferably red colors with the naphtholes, and in combination with diazobenzene or diazotoluene gelbroth, diazoxylol medium roth, diazonaphthalene violet Roth; With the phenols, yellow colors are obtained, namely in combination with diazobenzene, diazotoluene, diazoxylol pure yellow to orange, and with diazonaphthalene orange Sounds.
Specielles Verfahren.Special procedure.
Um ein schönes Roth auf Baumwollstoff in solider Weise herzustellen, werden:To make a beautiful red on cotton fabric in a solid way:
2Va 1 Wasser, 2 Va 1 water,
200 g Stärke oder sonst ein geeignetes Verdickungsmittel, 200 g starch or any other suitable thickener,
144 g Betanaphtol,144 g betanaphtol,
121 g Xylidin, und .
69 g Natriumnitrit121 g xylidine, and.
69 g sodium nitrite
zu einem homogenen Kleister gekocht; in dem heifsen Kleister können sowohl Naphtol als Xylidin in so feine Vertheilung gebracht werden, dafs die Masse eine gute Druckfarbe abgiebt. Nach dem Erkalten werden zugegeben und verrührt: 60 bis 100 g Salmiak oder die entsprechende Menge eines anderen Ammoniumsalzes (Nitrat, Acetat, Sulfat etc.).cooked to a homogeneous paste; Both naphthol and Xylidine can be distributed so finely that the mass gives off a good printing ink. After cooling, add and stir: 60 to 100 g salmiak or the corresponding amount of another ammonium salt (nitrate, acetate, sulfate, etc.).
Das Nitrat, sowie der Salmiak können trocken oder in Lösung angewendet werden; letzterer kann bei Anwendung von Ammoniumnitrit ganz oder theilweise in Wegfall kommen; bei Anwendung von Naphtolnatrium (oder sonst einer alkalischen Naphtollösung) setzt man entsprechend mehr Salmiak hinzu.Nitrate and ammonia can be used dry or in solution; the latter can be wholly or partly omitted when ammonium nitrite is used; when applying of sodium naphthol (or some other alkaline naphthol solution) is used accordingly add more ammonia.
Der Stoff wird mit der Masse imprägnirt oder bedruckt, getrocknet und gedämpft, worauf sich sofort eine hübsch rothe Farbe entwickelt, welche sich beim Auswaschen als haltbar, und demnach in der Faser selbst fixirt, erweist.The material is impregnated or printed with the mass, dried and steamed, whereupon it becomes immediately develops a pretty red color, which when washed out as durable, and therefore fixed in the fiber itself, proves.
Die Verwendung der anderen genannten Körper geschieht nach äquivalenten Verhältnissen. The other bodies mentioned are used in equivalent proportions.
Bei den Phenolfarben ist es besser, nicht zu dämpfen, dagegen nach dem Hängen in warmem Raum durch eine schwach alkalische Flüssigkeit oder Ammoniakdämpfe zu passiren. Die Phenolfarben sind weniger haltbar.With phenolic paints, it is better not to steam, but after hanging in warm Room to pass through a weakly alkaline liquid or ammonia vapors. The phenolic paints are less durable.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE14950C true DE14950C (en) |
Family
ID=292006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT14950D Active DE14950C (en) | Diazotir process and its continuation for color formation |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE14950C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4212648A (en) * | 1977-09-09 | 1980-07-15 | Hoechst Aktiengesellschaft | Process for the printing of cellulose fiber fabrics |
| US4212646A (en) * | 1977-09-09 | 1980-07-15 | Hoechst Aktiengesellschaft | Process for the printing of mixed fabrics of polyester and cellulose fibers |
-
0
- DE DENDAT14950D patent/DE14950C/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4212648A (en) * | 1977-09-09 | 1980-07-15 | Hoechst Aktiengesellschaft | Process for the printing of cellulose fiber fabrics |
| US4212646A (en) * | 1977-09-09 | 1980-07-15 | Hoechst Aktiengesellschaft | Process for the printing of mixed fabrics of polyester and cellulose fibers |
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