DE135843C - - Google Patents
Info
- Publication number
- DE135843C DE135843C DENDAT135843D DE135843DA DE135843C DE 135843 C DE135843 C DE 135843C DE NDAT135843 D DENDAT135843 D DE NDAT135843D DE 135843D A DE135843D A DE 135843DA DE 135843 C DE135843 C DE 135843C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- water
- acid
- amido
- paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002253 acid Substances 0.000 claims description 5
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 229910052751 metal Chemical class 0.000 claims description 2
- 239000002184 metal Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 229910000000 metal hydroxide Inorganic materials 0.000 claims 1
- 150000004692 metal hydroxides Chemical class 0.000 claims 1
- AKBIVIMPMQGECH-UHFFFAOYSA-N naphthalen-1-ylmethanesulfonic acid Chemical compound C1=CC=C2C(CS(=O)(=O)O)=CC=CC2=C1 AKBIVIMPMQGECH-UHFFFAOYSA-N 0.000 claims 1
- 239000012266 salt solution Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002966 varnish Substances 0.000 description 9
- AFVFQIVMOAPDHO-UHFFFAOYSA-N methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 5
- 229940098779 methanesulfonic acid Drugs 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ZUYFLSARRQBQPE-UHFFFAOYSA-M [Cl-].[Ba+] Chemical compound [Cl-].[Ba+] ZUYFLSARRQBQPE-UHFFFAOYSA-M 0.000 description 2
- YVKMMZAFUFUAAX-UHFFFAOYSA-N aluminum;tetrahydrate Chemical compound O.O.O.O.[Al] YVKMMZAFUFUAAX-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- -1 chlorine barium Chemical compound 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-Naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N Barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 241000219495 Betulaceae Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Ethylene tetrachloride Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 101710027641 PPARGC1B Proteins 0.000 description 1
- 235000015450 Tilia cordata Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B63/00—Lakes
- C09B63/005—Metal lakes of dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
KLASSE 22/.CLASS 22 /.
Zur Darstellung der Farblacke wird ein Monoazofarbstoff aus diazotirter ßj-Amido-ctjnaphtylmethansulfosäure und ß-Naphtol benutzt, welcher sowohl als freie Farbsäure als in Form der Alkalisalze durch seine Schwerlöslichkeit in Wasser charakterisirt ist.A monoazo dye made from diazotized β-amido-ctynaphthyl methanesulfonic acid is used to produce the color lakes and ß-naphtol used, which both as a free color acid and in the form of alkali salts due to its poor solubility in Water is characterized.
Man erhält nun gänzlich wasser-, alkohol- und ölunlösliche Farblacke, wenn man eine Suspension der Alkalisalze oder des Ammoniaksalzes des Farbstoffs öder eine solche der freien Farbsäure mit wasserlöslichen Metallsalzen, Metalloxyden, -oxyhydraten oder -carbonaten zur Umsetzung bringt. Zweckmäfsig geschieht die Bildung des Farblackes, wie auch sonst üblich, bei Gegenwart von Substraten oder unter gleichzeitiger Herstellung derselben.You get completely water-, alcohol- and oil-insoluble colored varnishes if you have one Suspension of the alkali salts or the ammonia salt of the dye or one of the free color acid with water-soluble metal salts, metal oxides, oxyhydrates or carbonates brings to implementation. The formation of a colored varnish occurs expediently, as well otherwise usual in the presence of substrates or with simultaneous production of the same.
Die auf diese Weise erhaltenen Producte sind, abgesehen von den erwähnten werthvollen Eigenschaften der Schwer- bezw. Unlöslichkeit in den für Lacke in Frage kommenden Flüssigkeiten durch ihre leuchtende, schöne, carmoisinrothe Nuance ausgezeichnet. Man konnte bisher Lacke von derartig blaurother Nuance nur entweder mittelst der Eosine darstellen, deren Verwendung indessen ihres hohen Preises wegen für viele Zwecke von vornherein ausgeschlossen war, oder mittelst der blaustichigen Marken der Ponceauklasse, welche indessen nur die Herstellung von Lacken erlaubten, die hinsichtlich der Schwer- bezw. Unlöslichkeit nur wenig befriedigten.The products thus obtained, apart from those mentioned, are valuable Properties of the heavy or Insolubility in the liquids in question for paints distinguished by its bright, beautiful, carmoisine-red shade. So far you could Varnishes of such a bluish-red shade can only be represented either by means of the eosins, their However, due to their high price, use is excluded from the outset for many purposes was, or by means of the blue-tinged marks of the Ponceau class, which meanwhile only allowed the production of varnishes, which in terms of heavy or. insolubility only a little satisfied.
Der somit durch Benutzung der neuen Amidonaphtylmethansulfosäure erreichte technische Effect war nicht vorauszusehen, da sowohl die als Ausgangsmaterial benutzte Amidonaphtylmethansulfosäure als auch Azocombinationen aus dieser Säure überhaupt bisher nicht bekannt waren.The technical level thus achieved by using the new amidonaphthyl methanesulfonic acid Effect could not be foreseen, as both the amidonaphthyl methanesulfonic acid used as starting material as well as azo combinations of this acid were not known at all.
Abgesehen hiervon war aber auch die schöne, carmoisinrothe Nuance der Farblacke überraschend, da der Farbstoff sich auf Wolle und Seide nur relativ wenig von den ß-Naphtolcombinationen der gewöhnlichen ß-Naphtylaminsulfosäure (Scharlach für Seide, Echtsäureponceau etc.) unterscheidet.Apart from this, the beautiful, carmoisine-red nuance of the colored lacquers was also surprising, since the dye differs only relatively little from the ß-naphtol combinations on wool and silk the common ß-naphthylamine sulfonic acid (scarlet for silk, real acid ponceau etc.) differs.
Das Verfahren zur Darstellung der Farblacke wird durch nachstehende Beispiele erläutert:The procedure for the representation of the colored lakes is illustrated by the following examples:
Lithographielack.Lithographic lacquer.
10,5 Theile Paste (enthaltend 23,7 pCt. des Natronsalzes von ßj-Amido-aj-naphtylmethansulfosäure-azo-ß'-naphtol) werden mit 100 Theilen Wasser angeteigt und mit einer Lösung von 0,8 Theilen krystallisirtem Chlorbarium in 8 Theilen Wasser versetzt, aufgekocht und dann 100 Theile einer ca. 4proc. Thonerdepaste zugefügt. Man filtrirt ab, wäscht und trocknet.10.5 parts paste (containing 23.7 pCt. Of the sodium salt of β-amido-α-naphthyl methanesulfonic acid-azo-β'-naphtol) are made into a paste with 100 parts of water and with a solution of 0.8 part of crystallized chlorine barium was added to 8 parts of water, boiled and then 100 parts of an approx. 4 perc. Alder paste added. It is filtered off, washed and dries.
Buntpapierlack (Barytlack).Colored paper varnish (baryta varnish).
8 Theile Paste (enthaltend 23,7 pCt. des8 parts paste (containing 23.7 pCt. Des
Natronsalzes von ßj-Amido-aj-naphtylmethansulfosäure-azo-ß-naphtol) werden mit 75 TheilenSodium salt of ßj-amido-aj-naphtylmethanesulfonic acid-azo-ß-naphtol) become with 75 parts
Wasser angeschlemmt. Hierzu giebt man eineWashed up with water. For this one gives one
Lösung von 0,7 Theilen krystallisirtem Chlorbarium in 7 Theilen Wasser und bringt zum Kochen. Man fügt alsdann das fertig gebildete Thonerdehydrat, erhalten durch Vermischen einer Lösung von 10 Theilen schwefelsaurer Thonerde (i8pCt. Al2 O3) in 400 Theilen Wasser von 8o° und von 5 Theilen Soda in 50 Theilen Wasser von 8o° hinzu, fällt mit einer Lösung von 12,5 Theilen Chlorbarium in 125 Theilen Wasser das Blanc fixe, filtrirt und prefst.Dissolve 0.7 parts of crystallized chlorine barium in 7 parts of water, and bring to the boil. The completely formed alumina hydrate, obtained by mixing a solution of 10 parts of alumina sulfuric acid (18 pCt. Al 2 O 3 ) in 400 parts of 80 ° water and 5 parts of soda in 50 parts of 80 ° water, is then added Solution of 12.5 parts of chlorobarium in 125 parts of water fix, filter and prefix the blanc.
Beispiel III.Example III.
Buntpapierlack (Kalklack).
5 Theile gebrannter Kalk werden mit 50 Theilen Wasser gelöscht und zu einer Lösung
von 20 Theilen schwefelsaurer Thonerde (i8pCt. Al2 O8) in 200 Theilen Wasser gegeben.
Alsdann werden 16 Theile Paste (enthaltend 23,7 pCt. des Natronsalzes von ßj-Amido-cij-naphtylmethansulfosäure-azo-ß-naphtol)
in 150 Theilen Wasser angeschlemmt und mit dem entstandenen Gemisch aus Thonerdehydrat
und Gips vermischt. Man kocht einige Minuten, filtrirt und prefst ab.Colored paper varnish (lime varnish).
Five parts of quicklime are quenched with 50 parts of water and added to a solution of 20 parts of sulphate of alumina (18 parts of Al 2 O 8 ) in 200 parts of water. Then 16 parts of paste (containing 23.7 pCt. Of the sodium salt of βj-amido-cij-naphthylmethanesulfonic acid-azo-β-naphthol) are suspended in 150 parts of water and mixed with the resulting mixture of alumina hydrate and gypsum. It is boiled for a few minutes, filtered and prefilled.
Lack für A.nstrichfarben.
32 Theile Paste (enthaltend 23,7'pCt. des Natronsalzes von ßj-Amido-aj-naphtylmethansulfosäure-azo-ß-naphtol)
werden mit 3ooTheilen Wasser angeschlemmt. Hierzu giebt man eine Lösung von 2,8 Theilen krystallisirtem Chlorbarium
in 30 Theilen Wasser und lä'fst einige Minuten kochen. Alsdann giebt man 100 Theile
Schwerspath zu, vermischt gut, filtrirt und trocknet.Varnish for paints.
32 parts of paste (containing 23.7 parts of the sodium salt of β-amido-α-naphthyl methanesulfonic acid azo-β-naphthol) are suspended in 300 parts of water. A solution of 2.8 parts of crystallized chlorobarium in 30 parts of water is added and the mixture is boiled for a few minutes. Then add 100 parts of Schwerspath, mix well, filter and dry.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE135843C true DE135843C (en) |
Family
ID=403846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT135843D Active DE135843C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE135843C (en) |
-
0
- DE DENDAT135843D patent/DE135843C/de active Active
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