DE130628C - - Google Patents
Info
- Publication number
- DE130628C DE130628C DENDAT130628D DE130628DA DE130628C DE 130628 C DE130628 C DE 130628C DE NDAT130628 D DENDAT130628 D DE NDAT130628D DE 130628D A DE130628D A DE 130628DA DE 130628 C DE130628 C DE 130628C
- Authority
- DE
- Germany
- Prior art keywords
- sulfur
- salts
- printed
- metals
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011780 sodium chloride Substances 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- 239000011133 lead Chemical class 0.000 claims description 4
- 239000000988 sulfur dye Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Chemical class 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical class [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Chemical class 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229910052759 nickel Chemical class 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- 230000000694 effects Effects 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- -1 sulfur sodium Chemical compound 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- XMXNVYPJWBTAHN-UHFFFAOYSA-N Potassium chromate Chemical compound [K+].[K+].[O-][Cr]([O-])(=O)=O XMXNVYPJWBTAHN-UHFFFAOYSA-N 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N Sodium sulfide Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 229940091251 Zinc Supplements Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L Zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
M 130628 KLASSE Sk. M 130628 CLASS Sk.
Um weiße oder andersfarbige Druckeffecte beim Färben mit Schwefel farbstoffen herzustellen, bediente man sich bisher der sogenannten Chlorat-Aetzen. Tiefe Färbungen werden jedoch durch Chlorat - Aetze nur unvollkommen angegriffen, so daß dieses Verfahren den Anforderungen der Praxis nicht ganz genügt.To produce white or other colored printing effects when dyeing with sulfur dyes, So far the so-called chlorate etching has been used. Deep colors are only imperfectly caused by chlorate etching attacked, so that this process does not meet the requirements of practice quite enough.
Wir haben nun gefunden, daß die Herstellung von Druckeffecten bei Anwendung von Schwefelfarben viel einfacher und besser möglich ist, wenn das Baumwollgewebe mit Metallsalzen bedruckt wird, welche mit den Schwefelfarben unlösliche Lacke geben und so verhindern, daß an den bedruckten Stellen die Baumwolle angefärbt wird.We have now found that the production of printing effects when using of sulfur colors is much easier and better possible when using the cotton fabric Metal salts are printed, which give insoluble lacquers with the sulfur inks and in this way prevent the cotton from being stained in the printed areas.
Als solche schützende lackgebende Salze haben sich in erster Linie die Zink-, Kupfer-, Mangan-, Blei- und Nickelsalze erwiesen, und zwar können hierzu beliebige Salze dieser Metalle, z. B. Acetate, Sulfate, Nitrate, benutzt werden, oder auch Gemische verschiedener Metallsalze.As such protective paint-giving salts, the zinc, copper, Manganese, lead and nickel salts have been proven, and any salts of these can be used for this purpose Metals, e.g. B. acetates, sulfates, nitrates can be used, or mixtures of different Metal salts.
Die Ausführung erfolgt beispielsweise wie folgt:The execution takes place as follows, for example:
Man bedruckt das Baumwollgewebe mit einer Reserve, bereitet ausThe cotton fabric is printed with a reserve, prepared
2OO g Zinksulfat,2OO g zinc sulfate,
2OO g Wasser,2OO g water,
250 g Porzellanthon (Chinaclay),250 g china clay (Chinaclay),
350 g Gummilösung,350 g rubber solution,
welche zusammen gekocht und nach dem Erkalten verwendet wird.which is cooked together and used after cooling.
Nach dem Drucken wird die Waare getrocknet und in kalter oder lauwarmer Flotte ausgefärbt, welche beiläufig wie folgt zusammengesetzt ist.After printing, the goods are dried and placed in a cold or lukewarm liquor colored, which is casually composed as follows.
Für 50 kg Waare in 1000 1 Flotte:For 50 kg goods in 1000 1 liquor:
10 kg Immedialschwarz,10 kg immediate black,
6 kg Schwefelnatrium,
10 kg Dextrin, gelblich,
15 kg Kochsalz,6 kg sulfur sodium,
10 kg dextrin, yellowish,
15 kg table salt,
2 kg Türkischrothöl.2 kg of Turkish red oil.
Nach dem Färben wird das Gewebe zur Entfernung der Reserve gut gewaschen, schwach abgesäuert oder geseift.After dyeing, the fabric is washed well to remove the reserve, weakly acidified or soaped.
Wenn Bleisalze zur Anwendung kommen, kann das Gewebe nach dem Färben mit Schwefelfarbstoffen durch ein Bad mit doppelchromsaurem Kali passirt werden, wodurch man gelbe Effecte erzielt.If lead salts are used, the fabric can be colored with Sulfur dyes can be passed through a bath with double chromate of potash, whereby yellow effects are achieved.
Statt Immedialschwarz können in gleicher Weise sämmtliche anderen Schwefelfarbstoffe mit einigen Modificationen beim Färben Verwendung finden (z. B. Immedialblau, MeIanogenblau und Kryogenbraun); es ist nur darauf Bedacht zu nehmen, daß das Färben in kaltem oder lauwarmem Bade zu erfolgen hat.Instead of Immedial Black, all other sulfur dyes can be used in the same way can be used with some modifications in dyeing (e.g. Immedial blue, MeIanogen blue and cryogenic brown); Care should be taken to ensure that dyeing is done in a cold or lukewarm bath Has.
Eingehende Versuche haben zu dem Ergebniß geführt, daß die sämmtlichen zum Reservagedruck von uns verwendeten Metalle in gleicher Weise lackbildend wirken. Wäre dies nicht der Fall, so müßten durch Wechselwirkung der Metalle mit dem Schwefelalkali die verschiedenen Schwefelmetalle auf der Faser gebildet werden, und beispielsweise bei einer Reserve, welche Bleisalze enthält, dürften dann schließlich keine weißen, sondern braune oder schwarze Effecte entstehen. VerwendetThorough experiments have led to the result that all of the for Reserved printing metals used by us have the same effect as paint-forming. Were if this is not the case, it must be due to the interaction of the metals with the alkali sulfur the various sulfur metals are formed on the fiber, and for example at a reserve containing lead salts should not be white, but brown or black effects arise. Used
(2. Auflage, ausgegeben am π. December i(2nd edition, issued on December 1st
Irian nun die Schwefelmetalle, ζ. Β. Schwefelzink, zur Reservageverdickung statt der Salze dieses Metalls, so bleibt der gewünschte Effect aus, die bedruckten Stellen bleiben zwar heller, aber nicht" weiß. Benutzt man Schwefelkupfer statt Kupfersulfat, so werden die bedruckten Stellen braun. Aehnliche Erscheinungen beobachtet man, wenn man nach der Vorschrift Metallsalze aufdruckt, zuerst durch ein Schwefelkalibad passirt und dann in das Farbstoffbad eingeht. Der Vorgang ist so zu erklären, daß an der Oberfläche der bedruckten Stelle der Farbstoff mit dem Metallsalz eine undurchdringliche Lackschicht bildet, welche sowohl den Farbstoff als auch das Schwefelnatrium verhindert, zur Faser zu gelangen. Sobald dann durch Dämpfen die Verdickung fortgenommen wird, löst sich auch die Oberflächenschicht mit ab.Irian now the sulfur metals, ζ. Β. Zinc sulphide, to thicken the reserve instead of the salts of this metal, the desired one remains Effect off, the printed areas remain lighter, but not "white. You use it Copper sulphate instead of copper sulphate, the printed areas will be brown. Similar phenomena one observes when, according to the instructions, metal salts are printed on, first passed through a sulphurous potash bath, and then enters the dye bath. The process can be explained in such a way that on the surface the printed area of the dye with the metal salt creates an impenetrable layer of varnish which prevents both the dye and the sodium sulphide, to the fiber to get. As soon as the thickening is removed by steaming, it dissolves also remove the surface layer.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE130628C true DE130628C (en) |
Family
ID=399015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT130628D Active DE130628C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE130628C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4778267A (en) * | 1982-03-08 | 1988-10-18 | The Johns Hopkins University | Amblyopia screening |
-
0
- DE DENDAT130628D patent/DE130628C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4778267A (en) * | 1982-03-08 | 1988-10-18 | The Johns Hopkins University | Amblyopia screening |
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