DE1234937B - Lost casting model made of foamed plastic, especially styrene polymer - Google Patents

Lost casting model made of foamed plastic, especially styrene polymer

Info

Publication number
DE1234937B
DE1234937B DEG42589A DEG0042589A DE1234937B DE 1234937 B DE1234937 B DE 1234937B DE G42589 A DEG42589 A DE G42589A DE G0042589 A DEG0042589 A DE G0042589A DE 1234937 B DE1234937 B DE 1234937B
Authority
DE
Germany
Prior art keywords
casting
foamed plastic
styrene polymer
model made
model
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEG42589A
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Isover G+H AG
Original Assignee
Gruenzweig und Hartmann AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gruenzweig und Hartmann AG filed Critical Gruenzweig und Hartmann AG
Priority to DEG42589A priority Critical patent/DE1234937B/en
Priority to CH1630665A priority patent/CH439597A/en
Priority to JP263466A priority patent/JPS519686B1/ja
Publication of DE1234937B publication Critical patent/DE1234937B/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C7/00Patterns; Manufacture thereof so far as not provided for in other classes
    • B22C7/02Lost patterns
    • B22C7/023Patterns made from expanded plastic materials

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Description

Verlorenes Gießmodell aus geschäumtem Kunststoff, insbesondere Styrolpolymerisat Die Erfindung betrifft ein verlorenes Gießmodell aus geschäumtem Kunststoff, insbesondere Styrolpolymerisat, das durch in die Gießform einfließendes Gießmaterial ohne wesentliche Rückstände vergast und verdrängt wird. Modelle dieser Art sowie das sogenannte Vollformgießverfahren sind aus der deutschen Patentschrift 1108 861 bekanntgeworden. Als Modellwerkstoff werden hauptsächlich in an sich bekannterWeise, etwa nach der deutschen Patentschrift 941389, aufgeschäumte Styrolpolymerisate verwendet.Lost casting model made of foamed plastic, especially styrene polymer The invention relates to a lost casting model made of foamed plastic, in particular Styrene polymer, which by flowing into the casting mold casting material without substantial Residues are gasified and displaced. Models of this type as well as the so-called full mold casting process are known from the German patent specification 1108 861. As a model material are mainly in a manner known per se, for example according to the German patent specification 941389, foamed styrene polymers are used.

Es hat sich gezeigt, daß bei der Vergasung solcher Schaumstoffmodelle mitunter Rückstände hinterbleiben, die in ungünstigem Fall die Oberflächengüte der Gußstücke beeinträchtigen. Man hat daher schon vorgeschlagen, dem Schaumstoff dieser Modelle Stoffe zuzusetzen, die seine Vergasung in der Gießform beschleunigen, so z. B. ionisch wirksame Depolymerisationskatalysatoren wie Bortrifluorid-Verbindungen u. dgl., die jedoch teilweise gesundheitsschädliche Gase entwickeln.It has been shown that when gasifying such foam models sometimes residues are left behind which, in the worst case, can affect the surface quality of the Affect castings. It has therefore already been proposed to use this foam Adding substances to models that accelerate its gasification in the casting mold, like that z. B. ionically active depolymerization catalysts such as boron trifluoride compounds and the like, but some of them develop harmful gases.

Ein anderer Vorschlag sieht vor, dem Schaumstoff des Modells als Flammschutzmittel wirksame Halogenverbindungen und gleichzeitig die Wirkung auslösende oder steigernde Synergisten, d. h. radikalbildende Verbindungen wie z. B. organische Peroxyde u. dgl., gegebenenfalls zusammen mit infrarotabsorbierenden Substanzen, zuzusetzen.Another suggestion is to use the foam of the model as a flame retardant effective halogen compounds and at the same time triggering or increasing the effect Synergists, d. H. radical-forming compounds such. B. organic peroxides u. Like., optionally together with infrared-absorbing substances, to be added.

Demgegenüber sieht die Erfindung bei einem verlorenen Gießmodell der eingangs geschilderten Art vor, daß der Schaumstoff des Modells wenigstens einen, insbesondere organischen Farbstoff, der die Wärmestrahlung der Schmelze bei der Gießtemperatur gut absorbiert und praktisch restlos vergasbar ist, vorzugsweise fein verteilt, enthält.In contrast, the invention provides for a lost casting model type described above that the foam of the model at least one, in particular organic dye, which reduces the heat radiation of the melt in the Casting temperature is well absorbed and practically completely gasifiable, preferably finely divided, contains.

Es hat sich nämlich überraschenderweise gezeigt, daß der Zusatz eines Farbstoffs allein in vielen Fällen bereits genügt, um die Vergasungsgeschwindigkeit des Schaumstoffmodells bedeutend zu erhöhen. Da die Absorptionseigenschaften der zahlreichen handelsüblichen Farbstoffe bekannt und tabellarisiert sind, hat es der Fachmann in der Hand, einen oder mehrere davon auszuwählen, der bzw. die bei den Wellenlängen, die bei den jeweils angewendeten Gießtemperaturen vorherrschen, gut absorbiert bzw. absorbieren.It has been shown, surprisingly, that the addition of a In many cases, the dye alone is sufficient to increase the rate of gasification of the foam model to increase significantly. Since the absorption properties of the numerous commercial dyes are known and tabulated, it has the A person skilled in the art can select one or more of them to be found in the Wavelengths that prevail at the casting temperatures used in each case are good absorbs or absorb.

Bei Modellen aus reinen Schaumstoffen beträgt der Abstand zwischen der z. B. etwa 1500° C heißen Schmelze und dem nahezu unverändert erhaltenen Schaumstoff meist nur wenige Millimeter. Das zeigt an, daß der Schaumstoff weitgehend »durchstrahlt« wird, ohne sich nennenswert zu erwärmen. Die Vergasung erfolgt vielmehr nur in unmittelbarer Nachbarschaft zur Schmelze. Nachdem sich zwischen beiden ein Polster der Pyrolysegase ausbildet, wird die Vergasungsgeschwindigkeit des Schaumstoffs stark von der Durchlässigkeit des Formstoffs für die Pyrolysegase abhängen. Da der Abstand zwischen Schmelze und Schaumstoff, wie gesagt, sehr gering ist und der Strömungswiderstand des Formstoffs aus gießtechnischen Gründen relativ hoch liegt, ist die Vergasungs- und damit auch die Gießgeschwindigkeit insgesamt relativ niedrig. Der Vorschlag der Erfindung bringt hier insofern Abhilfe, als selbst mit weniger als 1 Gewichtsprozent Farbstoffanteil im Modell die Gießgeschwindigkeit erheblich gesteigert werden kann, da der Abstand Schmelze -SchaumstofE sich auf Grund höherer Wärmezufuhr zu letzterem erhöht und dem Gaspolster eine größere Fläche des Formstoffs zum Entweichen zur Verfügung steht.For models made of pure foam, the distance is between the z. B. about 1500 ° C hot melt and the almost unchanged foam usually only a few millimeters. This indicates that the foam largely "shines through" without heating up significantly. Rather, the gassing takes place only in the immediate vicinity Neighborhood to the melt. After there is a cushion of pyrolysis gases between the two is formed, the gasification rate of the foam is largely dependent on the permeability depend on the molding material for the pyrolysis gases. Since the distance between melt and Foam, as I said, is very low and the flow resistance of the molding material for reasons of casting technology is relatively high, the gasification and thus also the overall casting speed is relatively low. The proposal of the invention brings a remedy here, as even with less than 1 percent by weight of dye In the model, the casting speed can be increased considerably, since the distance Melt foams increase due to higher heat input to the latter and the gas cushion has a larger area of the molding material available to escape.

Es sind zwar auch anorganische Pigmente und Farbstoffe bekannt, die sich unter den Gießbedingungen, d. h. bei Temperaturen zwischen etwa 600 und 1500° C, ohne merkliche Rückstände verflüchtigen lassen. Man wird für Zwecke der Erfindung aber insbesondere organische Farbstoffe heranziehen, da sie sich im Schaumstoff leichter verteilen lassen und ihre Vergasung auch bei niedrigen Gießtemperaturen glatter vonstatten geht.Inorganic pigments and dyes are also known which under the casting conditions, d. H. at temperatures between about 600 and 1500 ° C, allow to evaporate without leaving any noticeable residue. One is used for invention purposes but especially use organic dyes, as they are in the foam easier to distribute and their gasification even at low casting temperatures goes smoothly.

Es ist auch denkbar, nur bestimmte Teile des Modells mit dem Farbstoffzusatz zu versetzen, um sie besonders rasch zum Verschwinden zu bringen, etwa die Außenzonen des Modells. Im Regelfall ist es vorzuziehen, das Modell durchweg gleichmäßig einzufärben und die Farbstoffe zur besseren Ausnutzung möglichst fein zu verteilen.It is also conceivable to only use certain parts of the model with the dye addition to make them disappear particularly quickly, such as the outer zones of the model. As a rule, it is preferable to color the model uniformly throughout and to distribute the dyes as finely as possible for better utilization.

Claims (1)

Patentanspruch: Verlorenes Gießmodell aus geschäumtem Kunststoff, insbesondere Styrolpolymerisat, das durch in die Gießform einfließendes Gießmaterial ohne wesentliche Rückstände vergast und verdrängt wird, dadurch gekennzeichnet, daß der Schaumstoff des Modells wenigstens einen, insbesondere organischen Farbstoff, der die Wärmestrahlung der Schmelze bei der Gießtemperatur gut absorbiert und praktisch restlos vergasbar ist, vorzugsweise fein verteilt, enthält. In Betracht gezogene Druckschriften: Deutsche Auslegeschrift Nr. 1218 662.Claim: lost casting model made of foamed plastic, in particular styrene polymer, which is formed by the casting material flowing into the casting mold without essential residues are gasified and displaced, thereby characterized in that the foam of the model has at least one, in particular organic Dye that absorbs heat radiation from the melt well at the casting temperature and is practically completely gasifiable, preferably finely divided, contains. Into consideration Extracted publications: German Auslegeschrift No. 1218 662.
DEG42589A 1965-01-19 1965-01-19 Lost casting model made of foamed plastic, especially styrene polymer Pending DE1234937B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DEG42589A DE1234937B (en) 1965-01-19 1965-01-19 Lost casting model made of foamed plastic, especially styrene polymer
CH1630665A CH439597A (en) 1965-01-19 1965-11-26 Lost cast model made of foamed plastic, especially styrene polymer
JP263466A JPS519686B1 (en) 1965-01-19 1966-01-19

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEG42589A DE1234937B (en) 1965-01-19 1965-01-19 Lost casting model made of foamed plastic, especially styrene polymer

Publications (1)

Publication Number Publication Date
DE1234937B true DE1234937B (en) 1967-02-23

Family

ID=7126960

Family Applications (1)

Application Number Title Priority Date Filing Date
DEG42589A Pending DE1234937B (en) 1965-01-19 1965-01-19 Lost casting model made of foamed plastic, especially styrene polymer

Country Status (3)

Country Link
JP (1) JPS519686B1 (en)
CH (1) CH439597A (en)
DE (1) DE1234937B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0326095A2 (en) * 1988-01-29 1989-08-02 Fmi Full Mold International Gmbh Process for producing metallic castings by the full mold process

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1218662B (en) * 1964-02-29 1966-06-08 Gruenzweig & Hartmann Cast model made of foamed plastic

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1218662B (en) * 1964-02-29 1966-06-08 Gruenzweig & Hartmann Cast model made of foamed plastic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0326095A2 (en) * 1988-01-29 1989-08-02 Fmi Full Mold International Gmbh Process for producing metallic castings by the full mold process
EP0326095A3 (en) * 1988-01-29 1990-05-09 Fmi Full Mold International Gmbh Process for producing metallic castings by the full mold process

Also Published As

Publication number Publication date
JPS519686B1 (en) 1976-03-29
CH439597A (en) 1967-07-15

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