DE122886C - - Google Patents
Info
- Publication number
- DE122886C DE122886C DENDAT122886D DE122886DA DE122886C DE 122886 C DE122886 C DE 122886C DE NDAT122886 D DENDAT122886 D DE NDAT122886D DE 122886D A DE122886D A DE 122886DA DE 122886 C DE122886 C DE 122886C
- Authority
- DE
- Germany
- Prior art keywords
- resin
- paper
- finishing
- paraffin
- soap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011347 resin Substances 0.000 claims description 26
- 229920005989 resin Polymers 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000012188 paraffin wax Substances 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000001993 wax Substances 0.000 claims description 6
- 239000003925 fat Substances 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- -1 ceresin Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 238000004026 adhesive bonding Methods 0.000 claims description 2
- 230000001476 alcoholic Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims 9
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims 6
- 239000000944 linseed oil Substances 0.000 claims 5
- 235000021388 linseed oil Nutrition 0.000 claims 5
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Stearin Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 235000019198 oils Nutrition 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 239000005662 Paraffin oil Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive Effects 0.000 claims 1
- 230000001680 brushing Effects 0.000 claims 1
- 238000010790 dilution Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 238000007127 saponification reaction Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000003892 spreading Methods 0.000 claims 1
- 238000004078 waterproofing Methods 0.000 claims 1
- 239000004927 clay Substances 0.000 description 4
- 229910052570 clay Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- OIDPCXKPHYRNKH-UHFFFAOYSA-J Chrome alum Chemical compound [K]OS(=O)(=O)O[Cr]1OS(=O)(=O)O1 OIDPCXKPHYRNKH-UHFFFAOYSA-J 0.000 description 3
- NIKFYOSELWJIOF-UHFFFAOYSA-O Fuchsine Chemical compound Cl.C1=C(N)C(C)=CC(C(=C2C=CC(=[NH2+])C=C2)C=2C=CC(N)=CC=2)=C1 NIKFYOSELWJIOF-UHFFFAOYSA-O 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002889 oleic acids Chemical class 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
Landscapes
- Paper (AREA)
Description
bet 3icM4.&Z-(icf\C'l\' ι! bet 3icM4. & Z- (icf \ C'l \ ' ι!
j ,1 j , 1
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
Κι 122886
KLASSE 55/. Κι 122886
CLASS 55 /.
Gegenstand vorliegender Erfindung betrifft ein Verfahren, um Papier für gewisse Verwendungszwecke, wie Photographie, Drucksachen u. s. w., gegen die zur Verwendung gelangenden Lösungen, Farben u. s. w., wie z. B. Silberlösungen, wässerige, ätherische, alkoholische und sonstige organische Lösungsmittel, Druckfarben oder dergl., undurchlässig zu machen. '. . ■'The present invention relates to a method to paper for certain purposes, such as photography, printed matter, etc., against the solutions used, colors, etc., such as. B. silver solutions, aqueous, ethereal, alcoholic and other organic solvents, printing inks or the like. To make impermeable. '. . ■ '
Bei gewöhnlicher, auch · sattester Leimung wird, wenn der Harzleim ganz oder theilweise verseift und mit schwefelsaurer Thonerde gefällt wird, das Papier nicht vollkommen undurchlässig, so dafs selbst wässerige Lösungen noch durchschlagen. ...'.. .With the usual, even the fullest, glue, if the resin glue is wholly or partially saponified and precipitated with sulfuric alumina If the paper is not completely impermeable, so does even aqueous solutions still penetrate. ... '...
- Je mehr Harz in dem Papier auf diese Weise fkirt wurde, desto weniger durchlässig ist es. Aber ihclbst bei Papieren, die so viel Harz enthalten (5 bis 6 pCt.), als man ihnen nach den üblichen Leimmethoden einverleiben kann, schlagen wässerige und die anderen noch oben genannten Lösungen durch. Auch für pflanzliche und thierische Fette und OeIe, sowie Mischungen derselben mit Lösungsmitteln und Farbstoffen, für Fettfarben oder Mischungen derselben mit den vorstehend genannten Mitteln, z. B. die stearin- oder ölsauren Salze von basischen Anilinfarben (ölsaures Rosanilin, stearinsaures Tetraphenylrosanilin, das : sogen. Rosanilinblau),. ist das so hergestellte Papier nicht undurchlässig.- The more resin in the paper is made in this way, the less permeable it is. But even with papers that contain as much resin (5 to 6 pct.) As one would expect from them usual glue methods can incorporate, watery and the other still beat up mentioned solutions. Also for vegetable and animal fats and oils, as well Mixtures of the same with solvents and dyes, for fat colors or mixtures the same with the aforementioned means, e.g. B. the stearic or oleic acid salts of basic aniline dyes (oleic acid rosaniline, stearic acid tetraphenyl rosaniline, the so-called. Rosaniline blue) ,. the paper produced in this way is not impermeable.
Um nun das Papier für alle diese Mittel undurchlässig zu machen, hat man bisher das fertige Papier mit mineralischen Mitteln, z.B. Bariumsulfat,; das mit Wasser und Gelatine zu einem Teige angerührt war (sogen. Barytiren), oder mit Lösungen von Paraffin, Wachs oder, ahnlichen Appreturmitteln bestrichen. Das fertige Papier ist also erst für den gewünschten Zweck präparirt worden.In order to make the paper impermeable to all of these means, one has so far finished paper with mineral agents, e.g. barium sulfate; that with water and gelatin too was mixed with a dough (so-called Barytiren), or with solutions of paraffin, wax or, coated similar finishing agents. The finished paper is therefore only for the desired one Purpose prepared.
Man hat schon früher erkannt, dafs auf diese Weise ein undurchlässiges Papier sich nicht herstellen läfst, da es nicht möglich ist, das Appreturmittel in der erforderlichen Gleichmäfsigkeit und Tiefe über das Papier zu vertheilen, und hat diesen Uebelstand dadurch zu beseitigen versucht, dafs man Leimung und Appretirung gleichzeitig im Holländer vornahm und so ein Papier erhielt, welches einer weiteren Präparirung zwecks Undurchlässigmachenb nicht mehr bedurfte.It has already been recognized earlier that an impermeable paper is created in this way cannot be produced because it is not possible to use the finishing agent with the required uniformity and to distribute depth over the paper, and has tried to remedy this disadvantage by using glue and Finished at the same time in the Dutchman and thus received a paper, which another Preparation for the purpose of making it impermeable was no longer required.
Aber die zur Erreichung dieses Zweckes vorgeschlagenen Verfahren, wie der Zusatz von Tannin oder Thonerdesulfat oder von Thonerdesulfat und Chromalaun, haben die Lösung der Aufgabe nicht gebracht!But the methods proposed to achieve this end, such as the addition of Tannin or clay sulfate or of clay sulfate and chrome alum have the solution not brought to the task!
Schon bei der Ausführung des durch Patent 59485 geschützten Verfahrens hat sich ergeben, dafs Papier, zu deren Herstellung bei der Leimung gleichzeitig Tannin oder Thonerdesulfat verwendet wurden, nicht fest genug und nicht genügend widerstandsfähig gegen Wasser j war. Es ist deshalb nicht erklärlich, weshalb j Chromalaun zusammen mit dem bereits vor-ί geschlagenen Thonerdesulfat andere Wirkungen j auf die Leimung hervorrufen soll als letzteres allein. Vielmehr ist der Chromalaun aus dem Grunde nicht geeignet, da ja statt der weifsen Thonerdeverbindungen sich grüne bis graue Chro.noxydverbindungen auf dem Zeug niederschlagen werden, so dafs reinweifses Papier sich auf diese Weise nicht herstellen läfst-, daher" hat das Verfahren auch in die Industrie Eingang nicht gefunden, und man hat sich in der Praxis bisher ausschliefslich auf das Undurchlässigmachen des fertigen Papieres mittelst During the execution of the process protected by patent 59485, it became clear that dafs paper, for the manufacture of which at the Sizing at the same time tannin or clay sulfate were used, not firm enough and was not sufficiently resistant to water j. It is therefore inexplicable why j Chrome alum together with the ί proposed clay sulfate have other effects j is supposed to cause gluing than the latter alone. Rather, the chrome alum is from the Basically not suitable, since green to gray compounds are found instead of white alumina compounds Chromium oxide compounds are deposited on the stuff, so that pure white paper cannot be produced in this way, therefore "the process has also been introduced into industry No entry has been found, and in practice one has hitherto exclusively focused on making the finished paper impermeable
Claims (1)
Auch hat man versucht, Stearin oder Stearin-of the so-called Baryir method or by spreading the finishing agent.
Attempts have also been made to use stearin or stearin
Publications (1)
Publication Number | Publication Date |
---|---|
DE122886C true DE122886C (en) |
Family
ID=391778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT122886D Active DE122886C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE122886C (en) |
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0
- DE DENDAT122886D patent/DE122886C/de active Active
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