DE1171560B - Process for the preparation of a sealing paste for dental purposes by mixing a metal oxide with eugenol - Google Patents
Process for the preparation of a sealing paste for dental purposes by mixing a metal oxide with eugenolInfo
- Publication number
- DE1171560B DE1171560B DEA41198A DEA0041198A DE1171560B DE 1171560 B DE1171560 B DE 1171560B DE A41198 A DEA41198 A DE A41198A DE A0041198 A DEA0041198 A DE A0041198A DE 1171560 B DE1171560 B DE 1171560B
- Authority
- DE
- Germany
- Prior art keywords
- eugenol
- mixing
- metal oxide
- preparation
- dental purposes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 title claims description 12
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 title claims description 6
- 239000005770 Eugenol Substances 0.000 title claims description 6
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 title claims description 6
- 229960002217 eugenol Drugs 0.000 title claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 title claims description 4
- 150000004706 metal oxides Chemical class 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims 3
- 238000007789 sealing Methods 0.000 title description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 244000283070 Abies balsamea Species 0.000 claims description 3
- 235000007173 Abies balsamea Nutrition 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004858 Canada balsam Substances 0.000 claims description 3
- 244000302151 Myroxylon pereirae Species 0.000 claims description 3
- 235000014150 Myroxylon pereirae Nutrition 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000001157 myroxylon pereirae klotzsch resin Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229920003002 synthetic resin Polymers 0.000 claims description 3
- 239000000057 synthetic resin Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000004568 cement Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- -1 zinc oxide Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C5/00—Filling or capping teeth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/889—Polycarboxylate cements; Glass ionomer cements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Description
BUNDESREPUBLIK DEUTSCHLANDFEDERAL REPUBLIC OF GERMANY
DEUTSCHESGERMAN
PATENTAMTPATENT OFFICE
AUSLEGESCHRIFTEDITORIAL
Internat. Kl.: A 61kBoarding school Class: A 61k
Deutsche Kl.: 30 h -12/02German class: 30 h -12/02
Nummer: 1171 560Number: 1171 560
Aktenzeichen: A 41198 IV a / 30 hFile number: A 41198 IV a / 30 h
Anmeldetag: 20. September 1962 Filing date: September 20, 1962
Auslegetag: 4. Juni 1964Opening day: June 4, 1964
Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung einer Verschlußpaste für zahnärztliche Zwecke durch Mischen eines Metalloxyds, wie Zinkoxyd, mit Eugenol.The present invention relates to a method for producing a sealing paste for dental use Purposes by mixing a metal oxide, such as zinc oxide, with eugenol.
Solche Verschlußpasten sind in der Form des sogenannten Zementtyps bekannt. Sie werden dadurch hergestellt, daß ein geeignetes Oxyd mit einem salzbildenden Stoff in flüssiger Form gemischt wird. Die beiden Ingredienzen werden in geeigneten Proportionen gemischt und als eine mehr oder weniger weiche Masse an der gewünschten Stelle appliziert. Die Masse kann dazu gebracht werden, entweder eine Zahnfleischwunde oder Zahnkavitation zu decken. Die Masse erstarrt danach zu einem Zement und bildet einen widerstandsfähigen Deckverband. Es hat sich herausgestellt, daß solche Zemente bisher mit gewissen Nachteilen behaftet sind, unter anderem ist nämlich die Adhäsion des Verbandes nicht zufriedenstellend, und die Festigkeit ist nicht so hoch, wie es wünschenswert wäre. Die gegenwärtig im Handel befindlichen Zemente bestehen hauptsächlich nur aus Zinkoxyd und Eugenol.Such sealing pastes are known in the form of the so-called cement type. You will through it produced that a suitable oxide is mixed with a salt-forming substance in liquid form. the Both ingredients are mixed in suitable proportions and as one more or less soft mass applied to the desired location. The crowd can be made to either to cover a gum wound or dental cavitation. The mass then solidifies to form a cement and forms a resistant cover bandage. It has been found that such cements so far are afflicted with certain disadvantages, among other things the adhesion of the association is not satisfactory and the strength is not as high as would be desirable. The present Cements on the market consist mainly of zinc oxide and eugenol.
Die vorliegende Erfindung bezweckt die Schaffung eines Verbandes dieser Art, der ein wesentlich verbessertes Adhäsionsvermögen und verbesserte Haltbarkeit besitzt.The present invention seeks to provide a dressing of this type which is a substantially improved one Has adhesiveness and improved durability.
Das wird erfindungsgemäß dadurch erreicht, daß man der Paste ein Harz und Fasern zusetzt, die Wasser nicht absorbieren. Für die Harzbeimischung können Natur- oder Kunstharze verwendet werden. Insebsondere eignen sich Kolophonium, Kanadabalsam und Perubalsam. Für die Faserbeimischung haben sich besonders die Kunstharzfasern bewährt, die unter dem Warenzeichen »Terylen« im Handel erhältlich sind. Diese bestehen aus Polyterephthalaten. Sie sind insbesondere aus Terephthalsäure und Äthylenoxyd hergestellt. Ein aus der zuletzt genannten Mischung erhaltener Verband besitzt ein Adhäsionsvermögen und Festigkeitseigenschaften, welche die entsprechenden Eigenschaften früher bekannter Verbandsmaterialien bei weitem überschreiten. This is achieved according to the invention by adding a resin and fibers to the paste, which Do not absorb water. Natural or synthetic resins can be used for adding resin. Rosin, Canada balsam and Peru balsam are particularly suitable. For adding fibers The synthetic resin fibers, which are sold under the trade mark "Terylen", have proven themselves in particular are available. These consist of polyterephthalates. In particular, they are made from terephthalic acid and Ethylene oxide produced. A dressing obtained from the latter mixture has a Adhesiveness and strength properties, which are the corresponding properties previously known Far exceed bandages.
Zum Vergleich wurden zylindrische Probestücke sowohl aus dem bisher besten Verbandszement und
aus dem Verbandsmaterial nach der vorliegenden Erfindung hergestellt. Die zylindrischen Probestücke
hatten eine Höhe von etwa 1 cm und einen Durchmesser von 1,1 cm und wurden der Reihe nach
zwischen planparallele Platten in einer hydraulischen Druckprüfmaschine vom Typ Alpha eingeführt. Dabei
stellte sich heraus, daß der Zylinder nach der vorliegenden Erfindung mit 193 kp/cm2 und der aus
Verfahren zur Herstellung einer Verschlußpaste
für zahnärztliche Zwecke durch Mischen eines
Metalloxyds mit EugenolFor comparison, cylindrical coupons were made from both the best cast cement to date and the dressing material of the present invention. The cylindrical specimens had a height of about 1 cm and a diameter of 1.1 cm and were inserted in sequence between plane-parallel plates in an Alpha-type hydraulic compression testing machine. It was found that the cylinder according to the present invention with 193 kgf / cm 2 and the method for producing a sealing paste
for dental use by mixing one
Metal oxides with eugenol
Anmelder:Applicant:
Aktiebolaget Bofors, Bofors (Schweden)Aktiebolaget Bofors, Bofors (Sweden)
Vertreter:Representative:
Dipl.-Chem. Dr. W. Koch,Dipl.-Chem. Dr. W. Koch,
Hamburg 4, Simon-von-Utrecht-Str. 4,Hamburg 4, Simon-von-Utrecht-Str. 4,
und Dr.-Ing. R. Glawe, München 22,and Dr.-Ing. R. Glawe, Munich 22,
PatentanwältePatent attorneys
Als Erfinder benannt:Named as inventor:
Ingjald Reichborn-Kjennerud, OsloIngjald Reichborn-Kjennerud, Oslo
Beanspruchte Priorität:Claimed priority:
Schweden vom 4. Oktober 1961 (9835)Sweden October 4, 1961 (9835)
dem handelsüblichen Material hergestellte Zylinder mit 114 kp/cm2 belastet werden konnten.Cylinders made of the commercially available material could be loaded with 114 kp / cm 2.
Um die Adhäsion zu prüfen, wurde ein kreisrundes Loch mit einem Durchmesser von 11 mm in einer Kunststoffglasscheibe einer Dicke von 8,5 mm zuerst mit der Masse nach der vorliegenden Erfindung und dann mit der Masse nach dem bekannten Material gefüllt. Die Pfropfen, die aus den beiden Materialien gebildet wurden, wurden mit einem gut in das Loch passenden Stahlstab herausgestoßen. Dabei stellte sich heraus, daß eine Kraft von 111 kp/cm2 notwendig war, um die erfindungsgemäße Masse herauszustoßen, und eine solche von 57,8 kp/cm2, um die bekannte Masse herauszustoßen. Das zeigt deutlich das überlegene Adhäsionsvermögen des Zementes nach der Erfindung.In order to test the adhesion, a circular hole with a diameter of 11 mm in a plastic glass pane with a thickness of 8.5 mm was first filled with the mass according to the present invention and then with the mass according to the known material. The plugs formed from the two materials were pushed out with a steel rod that fitted well into the hole. It was found that a force of 111 kp / cm 2 was necessary to push out the mass according to the invention, and a force of 57.8 kp / cm 2 to push out the known mass. This clearly shows the superior adhesiveness of the cement according to the invention.
ι Der Pulverteil besteht aus 68 g Zinkoxyd, 28,5 g Kolophonium und 2,4 g haarfeinen Fasern einer Länge von 2 bis 4 mm aus Polyterephthalaten, die im Handel unter dem Zeichen »Terylen« erhältlich sind.ι The powder part consists of 68 g zinc oxide, 28.5 g rosin and 2.4 g hair-fine fibers 2 to 4 mm in length made from polyterephthalates, which are commercially available under the symbol "Terylen".
409 598/410409 598/410
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9835/61A SE306140B (en) | 1961-10-04 | 1961-10-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1171560B true DE1171560B (en) | 1964-06-04 |
Family
ID=20277614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA41198A Pending DE1171560B (en) | 1961-10-04 | 1962-09-20 | Process for the preparation of a sealing paste for dental purposes by mixing a metal oxide with eugenol |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE622384A (en) |
| CH (1) | CH453582A (en) |
| DE (1) | DE1171560B (en) |
| DK (1) | DK103631C (en) |
| FI (1) | FI41426C (en) |
| FR (1) | FR1335325A (en) |
| GB (1) | GB940717A (en) |
| NL (1) | NL283568A (en) |
| SE (1) | SE306140B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5266609A (en) * | 1989-01-27 | 1993-11-30 | Hall Neil R | Dental restorative adhesive having improved fracture toughness |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2684539A1 (en) * | 1991-12-04 | 1993-06-11 | Lenfant Eric | Reinforced composite dental splint |
| SE9604197L (en) * | 1996-11-18 | 1998-05-19 | N Lewinsky Ab | Bandage material for use in dental use |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE663717C (en) * | 1935-06-26 | 1938-08-12 | Lohmann Komm Ges | Bandages, zinc paste bandages, etc. Like. Which are softenable and hardened again after application |
| DK81148C (en) * | 1953-04-22 | 1956-06-18 | Wallco Ab | Object for surgical, dental or sanitary purposes. |
-
0
- BE BE622384D patent/BE622384A/xx unknown
- NL NL283568D patent/NL283568A/xx unknown
-
1961
- 1961-10-04 SE SE9835/61A patent/SE306140B/xx unknown
-
1962
- 1962-09-07 FI FI621634A patent/FI41426C/en active
- 1962-09-20 DE DEA41198A patent/DE1171560B/en active Pending
- 1962-09-21 GB GB36024/62A patent/GB940717A/en not_active Expired
- 1962-09-26 DK DK417562AA patent/DK103631C/en active
- 1962-09-26 FR FR910467A patent/FR1335325A/en not_active Expired
- 1962-10-03 CH CH1160762A patent/CH453582A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5266609A (en) * | 1989-01-27 | 1993-11-30 | Hall Neil R | Dental restorative adhesive having improved fracture toughness |
Also Published As
| Publication number | Publication date |
|---|---|
| CH453582A (en) | 1968-06-14 |
| FI41426B (en) | 1969-07-31 |
| FI41426C (en) | 1969-11-10 |
| FR1335325A (en) | 1963-08-16 |
| DK103631C (en) | 1966-01-31 |
| NL283568A (en) | 1900-01-01 |
| SE306140B (en) | 1968-11-18 |
| BE622384A (en) | 1900-01-01 |
| GB940717A (en) | 1963-10-30 |
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