DE102021123858A1 - Process for the environmentally friendly treatment of the waste water produced during olive pressing - Google Patents
Process for the environmentally friendly treatment of the waste water produced during olive pressing Download PDFInfo
- Publication number
- DE102021123858A1 DE102021123858A1 DE102021123858.7A DE102021123858A DE102021123858A1 DE 102021123858 A1 DE102021123858 A1 DE 102021123858A1 DE 102021123858 A DE102021123858 A DE 102021123858A DE 102021123858 A1 DE102021123858 A1 DE 102021123858A1
- Authority
- DE
- Germany
- Prior art keywords
- waste water
- water
- value
- environmentally friendly
- phenols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 23
- 240000007817 Olea europaea Species 0.000 title claims abstract description 9
- 238000003825 pressing Methods 0.000 title abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000002989 phenols Chemical class 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 4
- 239000001301 oxygen Substances 0.000 claims abstract description 4
- 239000002738 chelating agent Substances 0.000 claims abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 3
- 239000007800 oxidant agent Substances 0.000 claims abstract description 3
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000004006 olive oil Substances 0.000 claims description 6
- 235000008390 olive oil Nutrition 0.000 claims description 6
- 241000195493 Cryptophyta Species 0.000 claims description 4
- 239000000571 coke Substances 0.000 claims description 4
- 239000002910 solid waste Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 238000004939 coking Methods 0.000 claims description 3
- 238000005189 flocculation Methods 0.000 claims description 3
- 230000016615 flocculation Effects 0.000 claims description 3
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- 238000007669 thermal treatment Methods 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 abstract description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000007799 cork Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001728 nano-filtration Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
- C02F2103/322—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from vegetable oil production, e.g. olive oil production
Abstract
Die Erfindung betrifft ein Verfahren zur umweltschonenden Beseitigung des bei der Olivenpressung anfallenden Abwassers. Dieses Abwasser enthält eine Anzahl von Phenolderivaten, was bei der Weiterverwendung zu einer starken Geruchsbelästigung führt. Mit der Erfindung soll dieses Abwasser einer umweltfreundlichen Verwendung zugänglich gemacht werden.Die Aufgabe wird gelöst, indem in einem ersten Schritt durch Zusatz von Chelatbildnern in Form von Schwermetall-Ionen mit einem pH-Wert von 4,5 bis 5,5 die im Abwasser enthaltenen Phenole gebunden und ausgeflockt werden, die ausgefällten Flocken durch ein Filtersieb mit einer Maschenweite von 0.08 bis 0,12 mm abgeschieden werden, darauffolgend durch Zusatz von in Wasser gelöster Asche der pH-Wert auf einen Wert von 8 bis 9 erhöht wird und durch einen weiteren Zusatz von gemahlener Aktivkoks die restlichen Phenole gebunden werden, die mit den Reststoffen beladenen Aktivkohlepartikel werden danach durch ein Filtersieb mit einer Maschenweite von 0.008 bis 0,012 mm abgeschieden, als letzter Schritt werden durch Zusatz von aktivem Sauerstoff in Form bekannter Oxidationsmitteln noch verbliebene organische Verbindungen zu Kohlendioxid und Wasser umgesetzt.The invention relates to a method for the environmentally friendly disposal of waste water produced during olive pressing. This waste water contains a number of phenol derivatives, which leads to a strong odor nuisance when used further. With the invention, this waste water is to be made accessible to an environmentally friendly use. The object is achieved by, in a first step, by adding chelating agents in the form of heavy metal ions with a pH of 4.5 to 5.5 contained in the waste water phenols are bound and flocculated, the precipitated flakes are separated through a filter screen with a mesh size of 0.08 to 0.12 mm, the pH value is then increased to a value of 8 to 9 by adding ash dissolved in water and by another Addition of ground activated carbon binds the remaining phenols, the activated carbon particles loaded with the residues are then separated through a filter screen with a mesh size of 0.008 to 0.012 mm, as a last step, the remaining organic compounds are converted to carbon dioxide by adding active oxygen in the form of known oxidizing agents and water implemented.
Description
Die Erfindung betrifft ein Verfahren zur umweltschonenden Beseitigung des bei der Olivenpressung anfallenden Abwassers. Dieses Abwasser enthält eine Anzahl von Phenolderivaten, was bei der Weiterverwendung zu einer starken Geruchsbelästigung führt. Mit der Erfindung soll dieses Abwasser einer umweltfreundlichen Verwendung zugänglich gemacht werden.The invention relates to a method for the environmentally friendly disposal of waste water produced during olive pressing. This waste water contains a number of phenol derivatives, which leads to a strong odor nuisance when used further. With the invention, this waste water should be made accessible to an environmentally friendly use.
Stand der TechnikState of the art
Aus der
Die
Gemäß
Das durch die Verdunstung erhaltene Konzentrat hat einen Trockensubstanzgehalt von 30 bis 50 % und wird der Trocknung zugeführt, um die in dem Abwasser enthaltenen organischen Substanzen in Pulverform zu erhalten.The concentrate obtained through evaporation has a dry matter content of 30 to 50% and is sent for drying in order to obtain the organic substances contained in the waste water in powder form.
Da hierbei mit dem Wasser auch die darin enthaltenen Geruchsstoffe insbesondere die Phenolderivate verdunstet werden, bleibt auch hiermit das Problem der Geruchsbelästigung bestehen.Since the odorous substances contained therein, in particular the phenol derivatives, are also evaporated with the water, the problem of odor nuisance also remains.
Aufgabe der Erfindungobject of the invention
Somit ergibt sich als Aufgabe der Erfindung, ein Verfahren zur umweltschonenden Beseitigung des bei der Olivenpressung anfallenden Abwassers vorzuschlagen, das alle umweltschädlichen Inhaltsstoffe so eliminiert, dass das entstehende Wasser einer unschädlichen Verwendung zugeführt werden kann.The object of the invention is therefore to propose a method for the environmentally friendly disposal of the waste water occurring during olive pressing, which eliminates all environmentally harmful ingredients in such a way that the resulting water can be put to harmless use.
Beschreibung der ErfindungDescription of the invention
Erfindungsgemäß wird diese Aufgabe durch ein Verfahren mit den im Hauptanspruch beschriebenen Schritten gelöst.According to the invention, this object is achieved by a method with the steps described in the main claim.
In den Unteransprüchen werden weitere Schritte zur effektiveren Nutzung der Erfindung vorgeschlagen.Further steps to use the invention more effectively are proposed in the subclaims.
Erfindungsgemäß wird das Abwasser aus der Olivenölproduktion, das neben feststofflichen Abfällen im Zuge der Olivenverarbeitung anfällt, in einem ersten Schritt vorgereinigt indem durch Zusatz von Chelatbildnern in Form von Schwermetall-Ionen mit einem pH-Wert von 4,5 bis 5,5 die im Abwasser enthaltenen Phenole gebunden und ausgeflockt werden.According to the invention, the wastewater from olive oil production, which occurs in addition to solid waste in the course of olive processing, is pre-cleaned in a first step by adding chelating agents in the form of heavy metal ions with a pH of 4.5 to 5.5 in the wastewater contained phenols are bound and flocculated.
Die dadurch ausgefällten Flocken werden durch ein Filtersieb mit einer Maschenweite von 0,08 bis 0,12 mm abgeschieden.The flakes thus precipitated are separated through a filter screen with a mesh size of 0.08 to 0.12 mm.
Anschließend wird durch Zusatz von in Wasser gelöster Asche der pH-Wert auf einen Wert von 8 bis 9 erhöht. Durch den gleichzeitigen Zusatz von gemahlenem Aktivkoks werden die restlichen Phenole gebunden.The pH value is then increased to a value of 8 to 9 by adding ash dissolved in water. The remaining phenols are bound by the simultaneous addition of ground activated carbon.
Die mit den Reststoffen beladenen Aktivkohlepartikel werden darauffolgend durch ein Filtersieb mit einer Maschenweite von 0,008 bis 0,012 mm abgeschieden.The activated carbon particles loaded with the residues are then separated through a filter screen with a mesh size of 0.008 to 0.012 mm.
Als letzter Schritt werden durch Zusatz von aktivem Sauerstoff in Form von Oxidationsmitteln noch verbliebene organische Verbindungen zu Kohlendioxid und Wasser umgesetzt. Das hierbei entstehende Kohlendioxid kann in Algenbecken gebunden werden.As a final step, the remaining organic compounds are converted into carbon dioxide and water by adding active oxygen in the form of oxidizing agents. The resulting carbon dioxide can be bound in algae tanks.
Durch Verkokung des getrockneten bei der Pressung anfallenden Ölkuchens wird ein Aktivkoks erzeugt, der gemahlen dem Prozess zur Bindung restlicher Phenole zugeführt wird.Activated coke is produced by coking the dried oil cake from the pressing process, which is then ground and fed into the process for binding the remaining phenols.
Alle in den Filtersieben ausgeschiedenen Substanzen werden getrocknet und durch thermische Behandlung für die Wiederverwendung im Prozess aufbereitet.All substances separated in the filter screens are dried and prepared for reuse in the process by thermal treatment.
Ein Teil des abgefilterten Aktivkokses wird zur Gewinnung der im Prozess benötigten Energie verbrannt. Die dabei anfallende Asche wird im Prozess eingesetzt.Part of the filtered activated carbon is burned to generate the energy needed in the process. The resulting ash is used in the process.
Aufführungsbeispielexample
Die Erfindung soll im Folgenden in Form eines Aufführungsbeispiels erläutert werden.The invention is to be explained below in the form of an exemplary embodiment.
Das Abwasser aus Betrieben zur Olivenölproduktion, das neben feststofflichen Abfällen im Zuge der Olivenverarbeitung anfällt, wird durch Zusatz chelatbildender Kupfer-Ionen mit einem pH-Wert 5 versetzt, wodurch die im Abwasser enthaltenen Phenole gebunden und ausgeflockt werden.The waste water from olive oil production plants, which is produced in addition to solid waste in the course of olive processing, is given a pH value of 5 by adding chelating copper ions, which binds and flocculates the phenols contained in the waste water.
Die dadurch ausgefällten Flocken werden durch ein Filtersieb mit einer Maschenweite von 0,08 mm abgeschieden und einer thermischen Verwertung zugeführt.The flakes thus precipitated are separated through a filter screen with a mesh size of 0.08 mm and fed to thermal recycling.
Anschließend wird durch Zusatz von in Wasser gelöster Asche der pH-Wert auf einen Wert von 8 erhöht. Durch den gleichzeitigen Zusatz von gemahlenem Aktivkoks werden die restlichen Phenole gebunden.The pH value is then increased to a value of 8 by adding ash dissolved in water. The remaining phenols are bound by the simultaneous addition of ground activated carbon.
Die mit den Reststoffen beladenen Aktivkohlepartikel werden darauffolgend durch ein Filtersieb mit einer Maschenweite von 0,01 mm abgeschieden.The activated carbon particles loaded with the residues are then separated through a filter screen with a mesh size of 0.01 mm.
Als letzter Schritt werden durch Zusatz von aktivem Sauerstoff in Form von Wasserstoffperoxid noch verbliebene organische Verbindungen zu Kohlendioxid und Wasser umgesetzt. Das hierbei entstehende Kohlendioxid wird nach Zusatz von Algenbrut in einem Algenbecken als Biomasse gebunden.As a final step, the remaining organic compounds are converted into carbon dioxide and water by adding active oxygen in the form of hydrogen peroxide. After the addition of algae spawn, the resulting carbon dioxide is bound as biomass in an algae tank.
Durch Verkokung von getrocknetem Ölkuchen wird Aktivkoks erzeugt, der dem Prozess zur Bindung der restlichen Phenole zugeführt wird.Activated coke is produced by coking dried oil cake and is fed into the process to bind the remaining phenols.
Ein Teil des abgefilterten Aktivkokses wird zur Gewinnung der im Prozess benötigten Energie verbrannt. Hierbei anfallende Asche wird im Prozess eingesetzt.Part of the filtered activated carbon is burned to generate the energy required in the process. The resulting ash is used in the process.
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDED IN DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list of documents cited by the applicant was generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.
Zitierte PatentliteraturPatent Literature Cited
- EP 1849756 B1 [0002]EP 1849756 B1 [0002]
- EP 1734013 A2 [0003]EP 1734013 A2 [0003]
- DE 3720408 A1 [0004]DE 3720408 A1 [0004]
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102021123858.7A DE102021123858B4 (en) | 2021-09-15 | 2021-09-15 | Process for the environmentally friendly treatment of the waste water produced during olive pressing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102021123858.7A DE102021123858B4 (en) | 2021-09-15 | 2021-09-15 | Process for the environmentally friendly treatment of the waste water produced during olive pressing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE102021123858A1 true DE102021123858A1 (en) | 2023-03-16 |
| DE102021123858B4 DE102021123858B4 (en) | 2023-07-06 |
Family
ID=85284769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102021123858.7A Active DE102021123858B4 (en) | 2021-09-15 | 2021-09-15 | Process for the environmentally friendly treatment of the waste water produced during olive pressing |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE102021123858B4 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3720408A1 (en) | 1987-06-19 | 1988-12-29 | Peter Dr Hussmann | METHOD AND DEVICE FOR THE ENVIRONMENTALLY FRIENDLY ELIMINATION OF WASTE WATER RESULTING FROM OLIVE PRESSING |
| EP1157972A1 (en) | 2000-05-26 | 2001-11-28 | Apostolos Vlissidis | A method of processing oil-plant wastes |
| EP1734013A2 (en) | 2005-06-10 | 2006-12-20 | Herwig Adler | Process to treat waste water from olive oil production |
| WO2009101455A1 (en) | 2008-02-11 | 2009-08-20 | Pantelis Xynogalas | Physicochemical method of processing liquid and semisolid wastes of olive mills using ozone (o3) |
| EP1849756B1 (en) | 2006-04-28 | 2018-05-30 | Universidade de Trás-os-Montes e Alto Douro | A process for the treatment and recovery of residues and effluents from olive oil production units through the utilisation and reprocessing of cork industry waste |
-
2021
- 2021-09-15 DE DE102021123858.7A patent/DE102021123858B4/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3720408A1 (en) | 1987-06-19 | 1988-12-29 | Peter Dr Hussmann | METHOD AND DEVICE FOR THE ENVIRONMENTALLY FRIENDLY ELIMINATION OF WASTE WATER RESULTING FROM OLIVE PRESSING |
| EP1157972A1 (en) | 2000-05-26 | 2001-11-28 | Apostolos Vlissidis | A method of processing oil-plant wastes |
| EP1734013A2 (en) | 2005-06-10 | 2006-12-20 | Herwig Adler | Process to treat waste water from olive oil production |
| EP1849756B1 (en) | 2006-04-28 | 2018-05-30 | Universidade de Trás-os-Montes e Alto Douro | A process for the treatment and recovery of residues and effluents from olive oil production units through the utilisation and reprocessing of cork industry waste |
| WO2009101455A1 (en) | 2008-02-11 | 2009-08-20 | Pantelis Xynogalas | Physicochemical method of processing liquid and semisolid wastes of olive mills using ozone (o3) |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102021123858B4 (en) | 2023-07-06 |
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