DE102013223228A1 - Immobilisierte katalytisch aktive Zusammensetzung mit tridentaten Phosphorliganden in einer ionischen Flüssigkeit zur Hydroformylierung von olefinhaltigen Gemischen - Google Patents

Immobilisierte katalytisch aktive Zusammensetzung mit tridentaten Phosphorliganden in einer ionischen Flüssigkeit zur Hydroformylierung von olefinhaltigen Gemischen Download PDF

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Publication number
DE102013223228A1
DE102013223228A1 DE102013223228.4A DE102013223228A DE102013223228A1 DE 102013223228 A1 DE102013223228 A1 DE 102013223228A1 DE 102013223228 A DE102013223228 A DE 102013223228A DE 102013223228 A1 DE102013223228 A1 DE 102013223228A1
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composition according
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aromatic
substituted
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DE102013223228.4A
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German (de)
English (en)
Inventor
Katrin Marie Dyballa
Hanna Hahn
Robert Franke
Dirk Fridag
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Evonik Operations GmbH
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Evonik Industries AG
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Priority to DE102013223228.4A priority Critical patent/DE102013223228A1/de
Priority to PCT/EP2014/074281 priority patent/WO2015071266A1/fr
Priority to EP14796126.2A priority patent/EP3068533A1/fr
Priority to TW103139383A priority patent/TW201545814A/zh
Publication of DE102013223228A1 publication Critical patent/DE102013223228A1/de
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/007—Promoter-type Additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE102013223228.4A 2013-11-14 2013-11-14 Immobilisierte katalytisch aktive Zusammensetzung mit tridentaten Phosphorliganden in einer ionischen Flüssigkeit zur Hydroformylierung von olefinhaltigen Gemischen Withdrawn DE102013223228A1 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE102013223228.4A DE102013223228A1 (de) 2013-11-14 2013-11-14 Immobilisierte katalytisch aktive Zusammensetzung mit tridentaten Phosphorliganden in einer ionischen Flüssigkeit zur Hydroformylierung von olefinhaltigen Gemischen
PCT/EP2014/074281 WO2015071266A1 (fr) 2013-11-14 2014-11-11 Composition catalytiquement active immobilisée avec des ligands phosphorés tridentés dans un liquide ionique pour l'hydroformylation de mélanges contenant des oléfines
EP14796126.2A EP3068533A1 (fr) 2013-11-14 2014-11-11 Composition catalytiquement active immobilisée avec des ligands phosphorés tridentés dans un liquide ionique pour l'hydroformylation de mélanges contenant des oléfines
TW103139383A TW201545814A (zh) 2013-11-14 2014-11-13 用於含烯烴混合物的氫甲醯化之於離子性液體中之具有三牙團磷配子之固定化催化活性組成物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102013223228.4A DE102013223228A1 (de) 2013-11-14 2013-11-14 Immobilisierte katalytisch aktive Zusammensetzung mit tridentaten Phosphorliganden in einer ionischen Flüssigkeit zur Hydroformylierung von olefinhaltigen Gemischen

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DE102013223228A1 true DE102013223228A1 (de) 2015-05-21

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EP (1) EP3068533A1 (fr)
DE (1) DE102013223228A1 (fr)
TW (1) TW201545814A (fr)
WO (1) WO2015071266A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013217174A1 (de) 2013-08-28 2015-03-05 Evonik Industries Ag Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen
DE102013225883A1 (de) 2013-12-13 2015-06-18 Evonik Industries Ag Zweistufige Hydroformylierung mit Kreisgas- und SILP-Technologie
CN113385234B (zh) * 2021-01-12 2022-05-24 杭州师范大学 一种催化剂体系及其制备己二胺的方法
CN113694969B (zh) * 2021-04-26 2022-12-16 河南平煤神马尼龙工程技术有限公司 一种催化剂体系及其催化合成1，6-己二胺的方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4789753A (en) 1984-02-17 1988-12-06 Union Carbide Corporation Phosphite ligands
EP1008581B1 (fr) 1998-12-10 2004-04-21 Mitsubishi Chemical Corporation Procédé pour la préparation d' aldéhydes
DE102006058682A1 (de) 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
DE102010041821A1 (de) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Einsatz von Supported Ionic Liquid Phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in 2-Stellung unverzweigten Aldehyden
DE102011085883A1 (de) 2011-11-08 2013-05-08 Evonik Oxeno Gmbh Neue Organophosphorverbindungen auf Basis von Anthracentriol

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4789753A (en) 1984-02-17 1988-12-06 Union Carbide Corporation Phosphite ligands
EP1008581B1 (fr) 1998-12-10 2004-04-21 Mitsubishi Chemical Corporation Procédé pour la préparation d' aldéhydes
DE102006058682A1 (de) 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
DE102010041821A1 (de) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Einsatz von Supported Ionic Liquid Phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in 2-Stellung unverzweigten Aldehyden
DE102011085883A1 (de) 2011-11-08 2013-05-08 Evonik Oxeno Gmbh Neue Organophosphorverbindungen auf Basis von Anthracentriol

Non-Patent Citations (18)

* Cited by examiner, † Cited by third party
Title
A. Riisager, P. Wasserscheid, R. van Hal, R. Fehrmann, J. Catal. 2003, 219, 252
Angew. Chem. Int. Ed. 2000, 39, 3772-3789
B. CORNILS, W. A. HERRMANN, "Applied Homogeneous Catalysis with Organometallic Compounds", Vol. 1 & 2, VCH, Weinheim, New York, 1996
DIN 66131
DIN 66133
DIN 66135
F. Ramirez, S. B. Bhatia, C. P. Smith, Tetrahedron 1967, 23, 2067-2080
M. Beller, B. Cornils, C. D. Frohning, C. W. Kohlpaintner, J. Mol. Catal. 1995, 104, 17
M. Haumann, K. Dentler, J. Joni, A. Riisager, P. Wasserscheid, Adv. Synth. Catal. 2007, 349, 425
M. Jakuttis, A. Schoenweiz, S. Werner, R. Franke, K.-D. Wiese, M. Haumann, P. Wasserscheid, Angew. Chem. Int. Ed. 2011, 50, 4492
P. W. N. M. van Leeuwen, in Rhodium Catalyzed Hydroformylation, P. W. N. M. van Leeuwen, C. Claver (Hrsg.), Kluwer, Dordrecht, 2000
Purification of Laboratory Chemicals, W. L. F. Armarego (Autor), Christina Chai (Autor), Butterworth Heinemann (Elsevier), 6. Auflage, Oxford 2009
R. Franke, D. Selent, A. Börner, "Applied Hydroformylation", Chem. Rev., 2012, DOI:10.1021/cr3001803
Rhodium-catalyzed Hydroformylation, ed. by P.W.N.M. van Leeuwen et C. Claver, Kluwer Academic Publishers 2006, AA Dordrecht, NL, Seite 45-46
Riisager et al. J. Catal. 2003, 219, 452
Riisager et al., Catal. Lett. 2003, 90, 149
S. Shylesh, D. Hanna, S. Werner, A. T. Bell, ACS Catal. 2012, 2, 487
V. A. Likholobov, B. L. Moroz, Hydroformylation on Solid Catalysts in: Handbook of Heterogeneous Catalysis, 2nd ed.; G. Ertl, H. Knoezinger, F. Schüth, J. Weitkamp (Eds.), Wiley-VCH, Weinheim, Germany, 2008, 3663

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Publication number Publication date
EP3068533A1 (fr) 2016-09-21
TW201545814A (zh) 2015-12-16
WO2015071266A1 (fr) 2015-05-21

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