DE102008002352A1 - Additive Fabrication - 3 D pressure - Google Patents
Additive Fabrication - 3 D pressure Download PDFInfo
- Publication number
- DE102008002352A1 DE102008002352A1 DE102008002352A DE102008002352A DE102008002352A1 DE 102008002352 A1 DE102008002352 A1 DE 102008002352A1 DE 102008002352 A DE102008002352 A DE 102008002352A DE 102008002352 A DE102008002352 A DE 102008002352A DE 102008002352 A1 DE102008002352 A1 DE 102008002352A1
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- meth
- acrylate
- powder matrix
- group
- powder
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000000654 additive Substances 0.000 title claims abstract description 6
- 230000000996 additive effect Effects 0.000 title claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000011159 matrix material Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 18
- 239000011230 binding agent Substances 0.000 claims description 24
- 239000003999 initiator Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 150000001253 acrylic acids Chemical class 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000011147 inorganic material Substances 0.000 claims description 2
- 239000011368 organic material Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 150000004992 toluidines Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 5
- 239000004566 building material Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- -1 dimethylaminoethyl Chemical group 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- ZAFFWOKULJCCSA-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate;trimethylazanium;chloride Chemical compound [Cl-].C[NH+](C)C.CCOC(=O)C(C)=C ZAFFWOKULJCCSA-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- VZTGWJFIMGVKSN-UHFFFAOYSA-O trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium Chemical compound CC(=C)C(=O)NCCC[N+](C)(C)C VZTGWJFIMGVKSN-UHFFFAOYSA-O 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/165—Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/002—Coloured
- B29K2995/0021—Multi-coloured
Abstract
Die Erfindung betrifft ein Additive Fabrication-Verfahren, mit dem farbige dreidimensionale Objekte aus einer Pulvermatrix hergestellt werden können, ohne zusätzliche Verfahrensschritte zur Verfestigung des Materials.The invention relates to an additive fabrication method with which colored three-dimensional objects can be produced from a powder matrix without additional process steps for solidifying the material.
Description
Die Erfindung betrifft ein Additive Fabrication-Verfahren, mit dem farbige dreidimensionale Objekte aus einer Pulvermatrix hergestellt werden können, ohne zusätzliche Verfahrensschritte zur Verfestigung des Materials.The The invention relates to an additive fabrication process with which colored Three-dimensional objects are made from a powder matrix can, without additional procedural steps to Solidification of the material.
Rapid-Prototyping bzw. Rapid-Manufacturing-Verfahren, generell Additive Fabrication-Verfahren sind Fertigungsverfahren, die das Ziel haben, vorhandene 3 D CAD-Daten möglichst ohne manuelle Umwege oder Formen direkt und schnell in Werkstücke umzusetzen.Rapid prototyping or rapid manufacturing process, generally additive fabrication process are manufacturing processes that have the goal of existing 3 D CAD data as possible without manual detours or forms directly and quickly to convert into workpieces.
Unter den Rapid-Prototyping-Verfahren gibt es zwei Gruppen von Verfahren. Bei einer Vorgehensweise wird auf die gesamte Oberfläche aufgetragenes Material selektiv gebunden (Selektivverkleben). Stereolithographie und Selektiv-Laser-Verfahren (SLS) sind bekannte Verfahren, die nach diesem Prinzip arbeiten. Bei der anderen Verfahrenstechnik wird das Material selektiv abgelagert und gebunden (Selektivauftragen).Under The rapid prototyping process has two groups of procedures. An approach will affect the entire surface applied material selectively bonded (selective bonding). stereolithography and Selective Laser Techniques (SLS) are known methods that work on this principle. In the other process technology is the material selectively deposited and bound (selective application).
Die
Aus
der
Wachs oder ähnliche Supporting-Materialien wie Harze können durch einen Drop-on-Demand-Druckkopf jedoch wegen der materialspezifischen Oberflächenspannung nur in sehr kleinen Tropfen aufgetragen werden. Die Ablagerung der Wachstropfen zum Verfüllen eines großen Volumens der Supporting-Struktur pro Schicht ist sehr aufwendig und kann daher für große Objekte zu Herstellungszeiträumen von mehreren Tagen führen.wax or similar supporting materials such as resins through a drop-on-demand print head, however, because of the material specific Surface tension applied only in very small drops become. The deposition of wax drops to fill a large volume of the supporting structure per shift very elaborate and can therefore be used for large objects lead to production periods of several days.
In
der
Aufgabe war es ein 3 D Druck-Verfahren zur Verfügung zu stellen, das ohne die Verwendung von Supporting-Fluiden arbeitet.task was it to provide a 3 D printing process that works without the use of supporting fluids.
Es war Aufgabe, die Objekte in ausreichender Festigkeit herstellen zu können. Eine Nachbearbeitung durch das Auftragen von festigkeitserhöhenden Beschichtungen oder die Verfestigung über einen nachgeschalteten Einbrennprozess soll vermieden werden.It was task that produce objects in sufficient strength to be able to. A post-processing by the application of strength-increasing coatings or solidification over a subsequent burn-in process should be avoided.
Der Einsatz von Feststoffen sollte jedoch auch nicht in die Problematik der Feinstäube, mit ihrem Gefährdungspotential für die Gesundheit, gelangen.Of the However, use of solids should not be a problem either the fine dusts, with their hazard potential for health, get.
Eine weitere Aufgabe war es, farbige Objekte darstellen zu können, wobei die Farbe nicht erst durch einen zusätzlichen Verarbeitungsschritt eingebracht werden soll.A another task was to be able to represent colored objects, the color does not come first through an additional processing step should be introduced.
Gelöst wurde diese Aufgabe durch ein Verfahren zur Herstellung dreidimensionaler Strukturen durch mehrfache aufeinanderfolgende Auftragung dünner Schichten eines Pulvermaterials, dadurch gekennzeichnet, dass ein reaktives Methyl(meth)acrylat/Polymethyl(meth)acrylat-Bindemittel mit Beschleuniger auf eine Pulvermatrix aufgetragen wird, und die Matrix ein Initiatorsystem enthält.Solved This task was accomplished by a method of producing three-dimensional Structures thinner by multiple successive application Layers of a powder material, characterized in that a reactive methyl (meth) acrylate / polymethyl (meth) acrylate binder with accelerator is applied to a powder matrix, and the Matrix contains an initiator system.
Überraschend wurde gefunden, dass bei der Auftragung der dünnen Schichten mit dem erfindungsgemäßen reaktiven Methyl(meth)acrylat/Polymethyl(meth)acrylat Bindemittel, das einen Beschleuniger enthält, sofort eine Reaktion bei Kontakt mit dem in der Pulvermatrix befindlichen Initiator ausgelöst wird. Dies führt zur sofortigen Bildung einer festen Struktur.Surprised was found that when applying the thin layers with the reactive methyl (meth) acrylate / polymethyl (meth) acrylate according to the invention Binder containing an accelerator, immediately one Reaction on contact with the initiator in the powder matrix is triggered. This leads to immediate education a solid structure.
Die Schreibweise (Meth)acrylat bedeutet hier sowohl Methacrylat, wie z. B. Methylmethacrylat, Ethylmethacrylat usw., als auch Acrylate, wie z. B. Ethylhexylacrylat, Ethylacrylat usw., sowie Mischungen aus beiden.The notation (meth) acrylate here means both methacrylate, such as. Methyl methacrylate, Ethyl methacrylate, etc., as well as acrylates, such as. As ethylhexyl acrylate, ethyl acrylate, etc., as well as mixtures of the two.
Vorteilhafterweise können dem Bindemittel Farbstoffe zugegeben werden.advantageously, Dyes can be added to the binder.
Dem Bindemittel können beliebige Farbstoffe zugegeben werden, bevorzugt die drei Primärfarben und Schwarz. In einer besonderen Ausführungsform sind die Bindemittel farblos.the Binders can be added to any desired dyes, prefers the three primary colors and black. In a special Embodiment, the binders are colorless.
Die Bindemittel enthalten reaktives Methyl(meth)acrylat/Polymethyl(meth)acrylat aus der Gruppe der (Meth)acrylate, (Meth)acrylsäuren, (Meth)acrylaminen oder kationischen (Meth)acrylaten und/oder deren Mischungen.The Binders contain reactive methyl (meth) acrylate / polymethyl (meth) acrylate from the group of (meth) acrylates, (meth) acrylic acids, (meth) acrylamines or cationic (meth) acrylates and / or mixtures thereof.
Besonders bevorzugt sind (Meth)acrylate, die sich von gesättigten Alkoholen mit 1 bis 40 C-Atomen, vorzugsweise 1 bis 24 C-Atome ableiten, wobei der Alkoholrest linear oder verzweigt sein kann.Especially preferred are (meth) acrylates which are derived from saturated Derive alcohols having 1 to 40 carbon atoms, preferably 1 to 24 carbon atoms, wherein the alcohol residue may be linear or branched.
Besonders bevorzugt sind Dimethylaminoethyl(meth)acrylat, Trimethylammoniumethylmethacrylat-chlorid, Dimethylaminopropylmethacrylamid und Trimethylammoniumpropylmethacrylamid-chlorid.Especially preferred are dimethylaminoethyl (meth) acrylate, trimethylammoniumethyl methacrylate chloride, Dimethylaminopropylmethacrylamide and trimethylammoniumpropylmethacrylamide chloride.
Es wurde gefunden, dass die Pulvermatrix aus organischem oder anorganischem kugelförmigem Material bestehen kann. Dabei ist es vorteilhaft, wenn die Pulvermatrix aus Material mit unterschiedlicher Korngrößenverteilung besteht.It It was found that the powder matrix of organic or inorganic may consist of spherical material. It is advantageous if the powder matrix of material with different particle size distribution consists.
Geeignet ist kugelförmiges Material mit Kugeldurchmessern zwischen 2 und 500 μm, bevorzugt zwischen 2 und 50 μm, besonders bevorzugt zwischen 5 und 30 μm.Suitable is spherical material with ball diameters between 2 and 500 μm, preferably between 2 and 50 μm, more preferably between 5 and 30 microns.
Es können organische Materialien, bevorzugt aus Polymethy(meth)acrylat oder Polyamid und deren Mischungen eingesetzt werden.It may be organic materials, preferably polymethyl (meth) acrylate or polyamide and mixtures thereof.
Es können aber auch anorganische Materialien, bevorzugt aus SiO2 oder Al(OH)3 und deren Mischungen verwendet werden.However, it is also possible to use inorganic materials, preferably of SiO 2 or Al (OH) 3, and mixtures thereof.
Es sind verschiedene Systeme aus Bindemitteln mit Beschleuniger und Initiator in der Pulvermatrix geeignet.It are different systems of binders with accelerator and Initiator in the powder matrix suitable.
Beispielsweise werden die Beschleuniger im Bindemittel ausgewählt aus der Gruppe der Toluidine. Hierzu werden dann als Initiatorsysteme ausgewählt aus der Gruppe der Peroxide, bevorzugt Benzoylperoxid oder Laurylperoxid in der Pulvermatrix eingesetzt.For example the accelerators in the binder are selected from the group of toluidines. These are then called initiator systems selected from the group of peroxides, preferably benzoyl peroxide or lauryl peroxide used in the powder matrix.
Ein anderes geeignetes System enthält als Beschleuniger im Bindemittel organosulfonische Verbindungen. Diese werden dann bevorzugt mit Initiatoren ausgewählt aus der Gruppe der Permaleinate kombiniert.One other suitable system contains as accelerator in Binder organosulfonic compounds. These are then preferred combined with initiators selected from the group of permalates.
Bei dem Zusammentreffen dieser oder anderer geeigneter Bindemittel mit Beschleuniger und dem entsprechenden Initiator erfolgt eine chemische Reaktion am Auftragungspunkt. Diese führt zum Aushärten der Matrix.at the meeting of these or other suitable binder with Accelerator and the corresponding initiator is a chemical reaction at the point of application. This leads to curing the matrix.
Üblicherweise wird die Bindemittelflüssigkeit über eine bewegliche Kartusche aufgebracht, die über dem Pulvermaterialreservoir angeordnet ist. Zur Bearbeitung farbiger Objekte können wie aus dem Stand der Technik für 2-D-Tintenstrahl-Farbdrucker bekannt, mehrere Farbkartuschen verwendet werden, die das Bindemittel, den Beschleuniger und Farbstoffe sowie weitere Hilfs- und Zusatzstoffe enthalten. Die Kartusche umfasst mindestens eine Bindemitteldüse, wobei jede Düse mit einem Bindemittelvorrat gekoppelt ist, um Bindemittel auf die Schichten des Aufbaumaterials selektiv aufzubringen.Usually the binder liquid is a mobile Cartridge applied over the powder material reservoir is arranged. For editing colored objects As known from the prior art for 2-D ink-jet color printer, several color cartridges are used, which are the binder, the Accelerators and dyes and other auxiliaries and additives contain. The cartridge comprises at least one binder nozzle, wherein each nozzle is coupled to a binder supply, to selectively apply binder to the layers of the building material.
Verschiedene Mengen von Bindemittel können in den Schichten der Pulvermatrix aufgebracht werden. Durch die unterschiedlichen Bindemittelmengen kann die Teilfestigkeit gesteuert werden. Insbesondere an den Außenseiten bzw. an stärker beanspruchten Stellen wird somit eine höhere Festigkeit erzielt.Various Amounts of binder may be present in the layers of the powder matrix be applied. Due to the different binder amounts the partial strength can be controlled. Especially on the outside or at higher stress points thus becomes a higher Strength achieved.
Erfindungsgemäß wird ein Vorrat an gefärbten und farblosen Bindemitteln eingesetzt. Tropfen von Bindemittel und Farbstoff werden selektiv auf die Pulvermatrix aufgebracht, um mehrfarbige Objekte zu erzeugen.According to the invention a supply of colored and colorless binders used. Drops of binder and dye are selectively applied to the powder matrix applied to create multicolored objects.
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - EP 0171069 [0004] EP 0171069 [0004]
- - WO 88/02677 [0005] WO 88/02677 [0005]
- - WO 95/05943 [0006] WO 95/05943 [0006]
- - EP 1227926 [0008] EP 1227926 [0008]
Claims (13)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008002352A DE102008002352A1 (en) | 2008-06-11 | 2008-06-11 | Additive Fabrication - 3 D pressure |
| PCT/EP2009/054876 WO2009149984A2 (en) | 2008-06-11 | 2009-04-23 | Additive fabrication – 3d printing |
| EP09761547A EP2282885A2 (en) | 2008-06-11 | 2009-04-23 | Additive fabrication 3d printing |
| TW098119060A TW201012635A (en) | 2008-06-11 | 2009-06-08 | Additive fabrication-3-D print |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008002352A DE102008002352A1 (en) | 2008-06-11 | 2008-06-11 | Additive Fabrication - 3 D pressure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102008002352A1 true DE102008002352A1 (en) | 2009-12-17 |
Family
ID=41278251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102008002352A Withdrawn DE102008002352A1 (en) | 2008-06-11 | 2008-06-11 | Additive Fabrication - 3 D pressure |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2282885A2 (en) |
| DE (1) | DE102008002352A1 (en) |
| TW (1) | TW201012635A (en) |
| WO (1) | WO2009149984A2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6414714B2 (en) * | 2014-03-25 | 2018-10-31 | ディーダブリューエス エス．アール．エル． | An improved computer-implemented method for defining the development point of a support element of an object made by a stereolithography process |
| TWI508026B (en) * | 2014-05-29 | 2015-11-11 | Wistron Corp | Method, apparatus and computer program product for producing prototype diagram of three dimentional object |
| WO2018015554A1 (en) | 2016-07-22 | 2018-01-25 | Dsm Ip Assets B.V. | Methods and compositions for forming three-dimensional objects by additive fabrication |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0171069A2 (en) | 1984-08-08 | 1986-02-12 | 3D SYSTEMS, INC. (a California corporation) | Method and apparatus for production of three-dimensional objects by stereolithography |
| WO1988002677A2 (en) | 1986-10-17 | 1988-04-21 | Board Of Regents, The University Of Texas System | Method and apparatus for producing parts by selective sintering |
| WO1995005943A1 (en) | 1993-08-26 | 1995-03-02 | Sanders Prototypes, Inc. | 3-d model maker |
| DE69021248T2 (en) * | 1989-04-21 | 1996-02-15 | Du Pont | Method for producing three-dimensional bodies using light-curing compositions containing hollow spheres. |
| EP0995763A2 (en) * | 1998-10-23 | 2000-04-26 | Bayer Aktiengesellschaft | Copolymers for rapid prototyping |
| EP1227926A1 (en) | 1999-10-08 | 2002-08-07 | GENERIS GmbH | Rapid-prototyping method and apparatus |
| EP1226019B1 (en) * | 1999-11-05 | 2004-03-03 | Z Corporation | Methods of three-dimensional printing |
| EP1524049A2 (en) * | 2003-10-14 | 2005-04-20 | Hewlett-Packard Development Company, L.P. | System and method for fabricating a three-dimensional metal object using solid free-form fabrication |
| EP1666234A1 (en) * | 2003-08-28 | 2006-06-07 | Fuji Photo Film Co. Ltd. | Process for producing three-dimensional shaped article |
| DE102006038858A1 (en) * | 2006-08-20 | 2008-02-21 | Voxeljet Technology Gmbh | Self-hardening material and method for layering models |
| DE602004007359T2 (en) * | 2003-01-09 | 2008-03-13 | Hewlett-Packard Development Company, L.P., Houston | FREEFORM FABRICATION SYSTEMS WITH LOW-DENSITY MATERIALS |
| DE112006001961T5 (en) * | 2005-07-27 | 2008-05-15 | Shofu Inc. | Device for forming a layered object |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1475220A3 (en) * | 2003-05-09 | 2009-07-08 | FUJIFILM Corporation | Process for producing three-dimensional model, and three-dimensional model |
| US7381360B2 (en) * | 2003-11-03 | 2008-06-03 | Hewlett-Packard Development Company, L.P. | Solid free-form fabrication of three-dimensional objects |
-
2008
- 2008-06-11 DE DE102008002352A patent/DE102008002352A1/en not_active Withdrawn
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2009
- 2009-04-23 WO PCT/EP2009/054876 patent/WO2009149984A2/en active Application Filing
- 2009-04-23 EP EP09761547A patent/EP2282885A2/en not_active Ceased
- 2009-06-08 TW TW098119060A patent/TW201012635A/en unknown
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| EP0171069A2 (en) | 1984-08-08 | 1986-02-12 | 3D SYSTEMS, INC. (a California corporation) | Method and apparatus for production of three-dimensional objects by stereolithography |
| WO1988002677A2 (en) | 1986-10-17 | 1988-04-21 | Board Of Regents, The University Of Texas System | Method and apparatus for producing parts by selective sintering |
| DE69021248T2 (en) * | 1989-04-21 | 1996-02-15 | Du Pont | Method for producing three-dimensional bodies using light-curing compositions containing hollow spheres. |
| WO1995005943A1 (en) | 1993-08-26 | 1995-03-02 | Sanders Prototypes, Inc. | 3-d model maker |
| EP0995763A2 (en) * | 1998-10-23 | 2000-04-26 | Bayer Aktiengesellschaft | Copolymers for rapid prototyping |
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| EP1666234A1 (en) * | 2003-08-28 | 2006-06-07 | Fuji Photo Film Co. Ltd. | Process for producing three-dimensional shaped article |
| EP1524049A2 (en) * | 2003-10-14 | 2005-04-20 | Hewlett-Packard Development Company, L.P. | System and method for fabricating a three-dimensional metal object using solid free-form fabrication |
| US7220380B2 (en) * | 2003-10-14 | 2007-05-22 | Hewlett-Packard Development Company, L.P. | System and method for fabricating a three-dimensional metal object using solid free-form fabrication |
| DE112006001961T5 (en) * | 2005-07-27 | 2008-05-15 | Shofu Inc. | Device for forming a layered object |
| DE102006038858A1 (en) * | 2006-08-20 | 2008-02-21 | Voxeljet Technology Gmbh | Self-hardening material and method for layering models |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009149984A2 (en) | 2009-12-17 |
| EP2282885A2 (en) | 2011-02-16 |
| WO2009149984A3 (en) | 2010-02-18 |
| TW201012635A (en) | 2010-04-01 |
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