DE102008000685A1 - Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections - Google Patents
Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections Download PDFInfo
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- DE102008000685A1 DE102008000685A1 DE200810000685 DE102008000685A DE102008000685A1 DE 102008000685 A1 DE102008000685 A1 DE 102008000685A1 DE 200810000685 DE200810000685 DE 200810000685 DE 102008000685 A DE102008000685 A DE 102008000685A DE 102008000685 A1 DE102008000685 A1 DE 102008000685A1
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- interlayer film
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- polyvinyl acetal
- perylene pigments
- colorless
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10651—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments
- B32B17/1066—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments imparting a tint in certain regions only, i.e. shade band
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10678—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising UV absorbers or stabilizers, e.g. antioxidants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10697—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer being cross-linked
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J3/00—Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
- B60J3/007—Sunglare reduction by coatings, interposed foils in laminar windows, or permanent screens
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3437—Six-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
Abstract
Description
Technisches GebietTechnical area
Die vorliegende Erfindung betrifft ganz oder teilweise gefärbte Folien für Verbundverglasungen, insbesondere Windschutzscheiben, die eine hohe Transparenz für IR-Strahlung aufweisen.The The present invention relates wholly or partially colored Films for laminated glazing, in particular windscreens, which have a high transparency for IR radiation.
Stand der TechnikState of the art
PVB-Folien als Zwischenschicht für Verbundverglasungen werden entweder transparent oder ganz oder teilweise eingefärbt angeboten. Insbesondere Zwischenschichtfolien für Kfz-Windschutzscheiben werden häufig teilgefärbt, d. h. mit einem so genannten Farbband oder Farbkeil im oberen Bereich der Scheibe ausgerüstet, um die Blendwirkung durch Sonnenstrahlung zu minimierenPVB films as an intermediate layer for composite glazing be either transparent or wholly or partially dyed offered. In particular, interlayer films for automotive windscreens are often partially colored, d. H. with one like that equipped ribbon or color wedge in the upper region of the disc, to minimize the glare from solar radiation
Bei
gleichmäßig eingefärbten PVB-Folien wird
das farbgebende Mittel (Pigment oder Farbstoff) vor der Extrusion
der PVB-Masse zugesetzt. Bei der Herstellung von Folien mit Farbband
wird üblicherweise ein transparenter Hauptstrom und ein
eingefärbter Seitenstrom über zwei entsprechend
dimensionierte Extruder im Extrusionswerkzeug zusammen geführt
und koextrudiert. Verfahren dieser Art sind bekannt und z. B. in
Die üblicherweise verwendeten Farbstoffe oder Pigmente müssen eine ausreichende Löslichkeit oder Dispergierbarkeit im weichmacherhaltigen PVB-Harz besitzen und gleichzeitig eine ausreichende UV-Stabilität aufweisen. Als ausgezeichnet Lichtstabiles Pigment wird insbesondere Farbruß zur Pigmentierung des Farbbandes von PVB-Folie eingesetzt. In blau oder grau eingefärbten Farbbändern überwiegt die Menge an Ruß in der Gesamtpigmentmischung, da zur Einstellung der geforderten Dunkelheit, genauer eines niedrigen L-Wertes im L,a,b-System, die eigentlich farbbestimmenden Pigmente bzw. Farbstoffe mit einer großen Menge Farbruß kombiniert werden müssen.The usual used dyes or pigments must have sufficient Solubility or dispersibility in the plasticizer-containing PVB resin and at the same time have sufficient UV stability. As excellent light-stable pigment is in particular color soot Pigmentation of the ribbon of PVB film used. In blue or gray colored ribbons outweighs the amount of carbon black in the total pigment mixture because of the adjustment the required darkness, more precisely a low L value in the L, a, b system, the actually color-determining pigments or dyes be combined with a large amount of color black have to.
Nachteilig ist, dass Ruß auch bis weit in den NIR- bzw. IR-Bereich hinein absorbiert.adversely is that soot also far into the NIR or IR range absorbed into it.
Moderne Fahrzeuge sind häufig mit Sensoren ausgerüstet, die z. B. Regentropfen auf der Windschutzscheibe durch die Absorption von Wasser im NIR-Bereich detektieren und somit eine automatische Regelung der Scheibenwischfunktion erlauben. Ebenfalls existieren bereits Nachtsichtsysteme, deren wesentlicher Bestandteil im Infraroten arbeitende Videokameras sind. Diese Systeme haben gemeinsam, dass dabei die Windschutzscheibe und damit auch die darin eingebettete PVB-Folie im IR- oder NIR-Bereich transparent sein müssen.modern Vehicles are often equipped with sensors the z. B. Raindrops on the windshield by the absorption of water in the NIR range and thus an automatic Allow regulation of the windscreen wiper function. Also exist already night vision systems, their essential component in the infrared working video cameras are. These systems have in common that while the windshield and thus the embedded therein PVB film in the IR or NIR range must be transparent.
Die Abschwächung von NIR- und IR-Strahlung durch Absorption von in der PVB-Folie befindlichem Farbruß beeinträchtigt die Funktion solcher Sensoren erheblich. Somit kann die Verbundglasscheibe weder vollständig eingefärbt noch das sicherheitsrelevante Ausstattungsmerkmal „Farbband" als Blendschutz mit den o. g. Ausstattungsmerkmalen die einen NIR-Sensor benötigen, kombiniert werden.The Attenuation of NIR and IR radiation by absorption affected by color black present in the PVB film the function of such sensors considerably. Thus, the laminated glass pane can neither fully colored nor the security relevant Feature "ribbon" as anti-glare with the o. g. Equipment features that require an NIR sensor, be combined.
Ein technischer Ausweg wäre, einen Ausschnitt im Farbband herzustellen, der dann wieder mit klarer PVB-Folie ausgefüllt wird. Alternativ müssten die Pigmente nachträglich lokal gebleicht werden. Beide Varianten sind sehr aufwendig.One technical solution would be to make a cutout in the ribbon, which is then filled again with clear PVB film. alternative would have the pigments subsequently bleached locally become. Both variants are very expensive.
Aufgabetask
Aufgabe der vorliegenden Erfindung war es daher, ganz oder teilweise gefärbte Zwischenschichtfolien für Verbundverglasungen bereit zu stellen, die einerseits eine ausreichende Absorption von Licht im UV/VIS-Bereich und andererseits eine hohe IR-/NIR-Transparenz aufweisen.task The present invention was therefore wholly or partially colored Interlayer films for composite glazing ready On the one hand, there is sufficient absorption of light in the UV / VIS range and on the other hand have high IR / NIR transparency.
Darstellung der ErfindungPresentation of the invention
Farbstoffe
mit einer guten Absorption im sichtbaren Bereich des Sonnenlichts
und einer gleichzeitig geringen Absorption im IR-/NIR-Bereich sind
bekannt. So offenbart
Gegenstand der vorliegenden Erfindung sind daher ganz oder teilweise gefärbte Zwischenschichtfolien für Verbundverglasungen, enthaltend weichmacherhaltiges Polyvinylacetal, Perylenpigmente und UV-Absorber bzw. die aus mindestens zwei Glasscheiben mit mindestens einer solchen Zwischenschichtfolie hergestellten Verbundverglasungen oder Windschutzscheiben für Kraftfahrzeuge oder Flugzeuge.The present invention therefore wholly or partially colored Zwischenschichtfoli for composite glazings containing plasticizer-containing polyvinyl acetal, perylene pigments and UV absorbers or the composite glazings or windshields for motor vehicles or aircraft produced from at least two glass panes with at least one such interlayer film.
Erfindungsgemäße Zwischenschichtfolien, Verbundglaslaminate oder Windschutzscheiben weisen bevorzugt eine Differenztransparenz ΔD der Transparenz für NIR-Strahlung bei 880 nm abzüglich der Transparenz für Sonnenlichtstahlung TL bei 380–780 nm von mindestens 20%, bevorzugt von mindestens 30%, insbesondere von mindestens 50% auf, wobei die Obergrenze der Differenztransparenz ΔD 100% beträgt. Die Messungen der jeweiligen Transparenzen wird gemäß EN KCO durchgeführt.invention Interlayer films, laminated glass laminates or windshields preferably have a differential transparency ΔD of transparency for NIR radiation at 880 nm minus the transparency for sunlight directing TL at 380-780 nm from at least 20%, preferably at least 30%, in particular at least 50%, with the upper limit of the difference transparency ΔD 100%. The measurements of the respective transparencies is carried out according to EN KCO.
Die
zur Herstellung von erfindungsgemäßen Folien eingesetzten
Perylenpigmente sind mit vielen Substitutionsmustern z. B. aus
Natürlich können solche NIR-transparenten Schwarzpigmente auch in Kombination mit als NIR- und IR-Filter wirkenden Nanopartikeln bzw. Pigmenten bzw. entsprechenden Gläsern kombiniert werden, so dass gegebenenfalls nur in einem engen Wellenlängenfenster, welches für die Funktion des Sensors maßgeblich ist, die Transparenz erhalten bleibt, im übrigen Wärmestrahlung im NIR- und IR-Bereich jedoch nicht durch das Verbundglas dringt. Dies ist insbesondere bei der Verwendung der erfindungsgemäßen Folien für Windschutzscheiben von Bedeutung, da so das Aufheizen des Fahrzeuginnenraums vermindert wird.Naturally Such NIR-transparent black pigments can also be used in Combination with nanoparticles acting as NIR and IR filters Pigments or corresponding glasses are combined, so that optionally only in a narrow wavelength window, which is decisive for the function of the sensor, the transparency is retained, otherwise heat radiation However, in the NIR and IR range does not penetrate through the laminated glass. This is especially true when using the invention Films for windshields of importance, since so the Heating the vehicle interior is reduced.
Zur Einstellung eines bestimmten Farbtones und der gewünschten Lichttransmission im sichtbaren Bereich können die NIR-transparenten Perylenpigmente mit weiteren Farbstoffen oder Pigmenten kombiniert werden.to Setting a specific color tone and the desired Visible light transmission can be the NIR transparent Perylene pigments are combined with other dyes or pigments.
Beispiele für diesen Zweck einsetzbare organische Farbstoffe sind z. B. Farbstoffe der Typenreihe Macrolex® der Firma Bayer, welche u. A. Anthrachinonabkömmlinge umfasst, oder Farbstoffe der Typenreihe Waxoline® der Firma Zeneca Colours, welche u. A. Chinolinabkömmlinge umfasst. Geeignete organische Pigmente sind z. B. Quinacridone oder Phthalocyanine verschiedener Hersteller. Als Beispiel für ein anorganisches Pigment sei neben den gängigen Metalloxidabkömmlingen Farbruß genannt, sofern dieser in solch kleiner Menge verwendet wird, dass eine ausreichend hohe Transmission im NIR-Bereich bzw. der bevorzugten Differenztransparenz ΔD erhalten bleibt. Weitere, geeignete Pigmente oder Farbstoffe sind eine oder mehrere Verbindungen der Gruppe Chinophthalone, Pyrazolone, Anthrachinone, Perinone, Monoazofarbstoffe, Phthalocyanine, Perylene, Azopigmente, Cromophtale, Thioindigopigmente, Dioxazine, Diketopyrrolopyrrole, Benzimidazolone, Isoindoline, Indanthrone, Metalloxide, -sulfide, -chromate und Kohlenstoff (Ruß).Examples of organic dyes which can be used for this purpose are, for example, B. dyes of the type series Macrolex ® the company Bayer, which u. A. Anthrachinonabkömmlinge includes, or dyes of the type series Waxoline ® Zeneca Colors, which u. A. Chinolinabkömmlinge includes. Suitable organic pigments are, for. As quinacridones or phthalocyanines from different manufacturers. As an example of an inorganic pigment, in addition to the common metal oxide derivatives, color black may be mentioned if it is used in such a small amount that a sufficiently high transmission in the NIR range or the preferred differential transparency ΔD is maintained. Other suitable pigments or dyes are one or more compounds of the group quinophthalones, pyrazolones, anthraquinones, perinones, monoazo dyes, phthalocyanines, perylenes, azo pigments, cromophtals, thioindigo pigments, dioxazines, diketopyrrolopyrroles, benzimidazolones, isoindolines, indanthrones, metal oxides, sulfides, chromates and carbon (soot).
Typische Einsatzkonzentrationen der Perylenpigmente bzw. aller eingesetzten farbgebenden Verbindungen bewegen sich in einem Bereich von 0,001 Gew.% bis 10 Gew.%, bevorzugt 0,001 Gew.% bis 5 Gew.% besonders bevorzugt 0,001 Gew.% bis 1,5 Gew.%, jeweils bezogen auf die gesamte Folienformulierung bzw. die gesamte Mischung.typical Use concentrations of perylene pigments or all used coloring compounds are in the range of 0.001 % By weight to 10% by weight, preferably 0.001% by weight to 5% by weight, especially preferably 0.001% by weight to 1.5% by weight, in each case based on the total Foil formulation or the entire mixture.
Zur Stabilisierung der im Farbband befindlichen Farbstoffe und Pigmente werden UV-Absorber wie Amine (insbesondere sterisch gehinderte Amine (HALS-Stabilisatoren), Benzophenonderivate und/oder wie Benzotriazolderivate (z. B. Tinuvin P, Tinuvin 326, 327, 328) oder Organophosphite eingesetzt.to Stabilization of the dyes and pigments in the ink ribbon UV absorbers such as amines (in particular sterically hindered amines (HALS stabilizers), benzophenone derivatives and / or as benzotriazole derivatives (eg Tinuvin P, Tinuvin 326, 327, 328) or organophosphites.
Die erfindungsgemäßen Folien enthalten bevorzugt unvernetztes Polyvinylacetal, insbesondere unvernetztes Polyvinylbutyral (PVB), das durch Acetalisierung von Polyvinylalkohol mit Butyraldehyd gewonnen wird.The Films according to the invention preferably contain uncrosslinked Polyvinyl acetal, in particular uncrosslinked polyvinyl butyral (PVB), which is obtained by acetalization of polyvinyl alcohol with butyraldehyde.
Der
Einsatz von vernetzten Polyvinylacetalen, insbesondere vernetztem
Polyvinylbutyral (PVB) ist ebenso möglich. Geeignete vernetzte
Polyvinylacetale sind z. B. in
Es ist auch möglich, die Acetalisierung mit anderen oder weiteren Aldehyden mit 5–10 Kohlenstoffatomen wie z. B. Valeraldehyd durchzuführen.It it is also possible to acetalize with others or others Aldehydes having 5-10 carbon atoms, such as. B. valeraldehyde perform.
Als zu acetalisierender Polyvinylalkohol können im Rahmen der vorliegenden Erfindung auch Terpolymere aus hydrolysierten Vinylacetat/Ethylen-Copolymeren eingesetzt werden. Diese Verbindungen sind in der Regel zu mehr als 98% hydrolysiert und enthalten 1 bis 10 Gew. auf Ethylen basierende Einheiten (z. B. Typ „Exceval" der Kuraray Europe GmbH).When To be acetalized polyvinyl alcohol can in the context of present invention also terpolymers of hydrolyzed vinyl acetate / ethylene copolymers be used. These compounds are usually more as 98% hydrolyzed and contain 1 to 10 wt. based on ethylene Units (eg type "Exceval" of Kuraray Europe GmbH).
Polyvinylacetale enthalten neben den Acetaleinheiten noch aus Vinylacetat und Vinylalkohol resultierende Einheiten. Die erfindungsgemäß verwendeten Polyvinylacetale weisen bevorzugt einen Polyvinylalkoholanteil von mindestens 14 Gew.%, bevorzugt mindestens 18 Gew.%, insbesondere 19,5 Gew.% auf. Ein Polyvinylalkoholanteil von 25 Gew.% sollte nicht überschritten werden.polyvinyl contain in addition to the acetal units still from vinyl acetate and vinyl alcohol resulting units. The inventively used Polyvinyl acetals preferably have a polyvinyl alcohol content of at least 14% by weight, preferably at least 18% by weight, in particular 19.5% by weight on. A polyvinyl alcohol content of 25% by weight should not be exceeded become.
Der Polyvinylacetatanteil liegt bevorzugt unter 5 Gew.%, bevorzugt unter 3 Gew.% und insbesondere unter 2 Gew.% Aus dem Polyvinylalkoholanteil und dem Restacetatgehalt kann der Acetalisierungsgrad rechnerisch ermittelt werden.Of the Polyvinyl acetate is preferably below 5 wt.%, Preferably below 3% by weight, and in particular less than 2% by weight, of the polyvinyl alcohol content and the residual acetate content, the degree of acetalization can be calculated be determined.
Bevorzugt weisen die erfindungsgemäßen Folien einen Weichmachergehalt von 15 bis 40 Gew.%, besonders bevorzugt 20 bis 40 Gew.% und insbesondere von 20 bis 30 Gew.% auf. Erfindungsgemäße Folien können einen oder mehrere Weichmacher enthalten.Prefers the films of the invention have a plasticizer content from 15 to 40% by weight, more preferably from 20 to 40% by weight, and especially from 20 to 30% by weight. Inventive films can contain one or more plasticizers.
Besonders geeignet als Weichmacher für die erfindungsgemäßen Folien ist mindestens eine Verbindung aus der Gruppe Di-2-ethylhexylsebacat, Di-2-ethylhexyladipat (DOA), Di-2-ethylhexylphthalat (DOP), Dihexyladipat (DHA), Dibutylsebacat (DBS), Di-2-butoxyethylsebacat (DBES), Triethylenglykol-bis-2-ethylhexanoat, Triethylenglykol-bis-n-heptanoat 3G7, Tetraethylenglykol-bis-n-heptanoat (4G7), Di-2-butoxyethyladipat (DBEA), Di-2-butoxyethoxyethyladipat (DBEEA).Especially suitable as a plasticizer for the inventive Foils is at least one compound from the group di-2-ethylhexyl sebacate, Di-2-ethylhexyl adipate (DOA), di-2-ethylhexyl phthalate (DOP), dihexyl adipate (DHA), dibutyl sebacate (DBS), di-2-butoxyethyl sebacate (DBES), triethylene glycol bis-2-ethylhexanoate, Triethylene glycol bis-n-heptanoate 3G7, tetraethylene glycol bis-n-heptanoate (4G7), di-2-butoxyethyl adipate (DBEA), di-2-butoxyethoxyethyl adipate (DBEEA).
Die genannten Weichmacher können alleine oder als Mischung eingesetzt werden.The Plasticizers mentioned can be used alone or as a mixture be used.
Das
Haftungsvermögen von Polyvinylacetalfolien an Glas wird üblicherweise
durch die Zugabe von Haftungsregulatoren wie z. B. die in
Die
prinzipielle Herstellung und Zusammensetzung von Folien auf Basis
von Polyvinylacetalen ist z. B. in
Erfindungsgemäße Zwischenschichtfolien können farbige und farblose Abschnitte aufweisen, wobei
- a) 1 bis 80% der Aufsichtfläche farbig ist und eine Mischung aus weichmacherhaltigem Polyvinylacetal, Perylenpigmenten und UV-Absorber enthält
- b) 99 bis 20% der Aufsichtfläche farblos ist und eine transparente Mischung auf von Basis weichmacherhaltigem Polyvinylacetal ohne Perylenpigmente enthält.
- a) 1 to 80% of the surface is colored and contains a mixture of plasticized polyvinyl acetal, perylene pigments and UV absorbers
- b) 99 to 20% of the top surface is colorless and contains a transparent mixture based on plasticized polyvinyl acetal without perylene pigments.
Als transparentes Material für die farblose Fläche b) wird bevorzugt die identische Mischung wie für die farbige Fläche gemäß a), allerdings ohne Perylenpigmente, eingesetzt.When transparent material for the colorless surface b) is preferably the same mixture as for the colored Surface according to a), but without perylene pigments, used.
Bevorzugt befindet sich zwischen den farbigen und farblosen Abschnitten der Folien ein Übergangsbereich, der einen kontinuierlichen Gradienten der Inhaltsstoffe der genannten Flächen a und b aufweist. Der Übergangsbereich kann ebenfalls in weiten Grenzen eingestellt werden und umfasst bevorzugt 1 bis 15% der Gesamtaufsichtfläche der Folie. Als Übergangsbereich wird der Bereich mit einer 40–80%-igen Lichttransmission nach ECE 43, bezogen auf den Bereich mit der maximalen Lichttransmission (sog. Transparentteil) definiert.Prefers is located between the colored and colorless sections of the Foils a transitional area that is a continuous Gradients of the constituents of said areas a and b. The transition area can also be in wide Limits are set and preferably comprises 1 to 15% of the total supervisory area the foil. As a transition area, the area with a 40-80% light transmission according to ECE 43, based on the area with the maximum light transmission (so-called transparent part) Are defined.
Weiterer Gegenstand der Erfindung sind Verbundverglasungen aus mindestens zwei Glasscheiben mit mindestens einer zwischengelegten, wie oben beschriebenen Zwischenschichtfolie und/oder Windschutzscheiben für Kraftfahrzeuge oder Flugzeuge aus mindestens zwei Glasscheiben mit mindestens einer zwischengelegten, wie oben beschriebenen Folie.Another The invention relates to composite glazings of at least two glass panes with at least one interposed, as above described interlayer film and / or windscreens for Motor vehicles or aircraft made from at least two glass panes at least one interleaved, as described above.
BeispieleExamples
Es
wurden Testfolien einer Zusammensetzung gemäß Tab.
1 durch Kalandrieren eines Dryblends aus PVB-Polymer, Weichmacher
und Additiven samt Farbstoffen/Pigmenten und anschließendem
Pressen auf eine Stärke von 0.38 mm erhalten. 0.38 entspricht
ungefähr der Schichtdicke der im Farbbandbereich üblicher koextrudierter
Farbbandfolien (der Gesamtdicke 0.76 mm) eingebetteten gefärbten
Schicht. Tabelle 1:
Die erfindungsgemäßen Folien mit einem NIR-transparenten Pigment zeichnen sich gegenüber den üblichen Folien mit Farbruß dadurch aus, dass ihre Transmission bei einer Wellenlänge von 880 nm bezogen auf die Lichttransmission TL im sichtbaren Bereich des Wellenlängenspektrums, gemessen im Verbundglas aus 2 × 2 mm Klarglas + Folie, viel höher ist. Die Lichttransmission ist an einer Stelle im Farbbandbereich am Laminat gemäß EN 410 zu bestimmen. Als Farbbandbereich sind solche Bereiche der Folie definiert, deren Lichttransmission TL um mindestens absolut 10% geringer ist, als jene anderer entweder ungefärbter oder schwach gefärbter Bereiche der Folie.The Films according to the invention with an NIR-transparent Pigment are distinguished from the usual films with carbon black characterized by their transmission at a Wavelength of 880 nm based on the light transmission TL in the visible range of the wavelength spectrum, measured in laminated glass of 2 × 2 mm clear glass + foil, much higher is. The light transmission is at a point in the ribbon area to be determined on the laminate according to EN 410. As a ribbon area are defined areas of the film whose light transmission TL is at least absolutely 10% lower than those of others either uncoloured or weakly colored areas of the Foil.
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - EP 0111678 B1 [0003] - EP 0111678 B1 [0003]
- - US 4316868 [0003] US 4316868 [0003]
- - US 4476075 [0003] US 4476075 [0003]
- - DE 102004007382 A1 [0010, 0010, 0013] - DE 102004007382 A1 [0010, 0010, 0013]
- - EP 1527107 B1 [0020] - EP 1527107 B1 [0020]
- - WO 2004/063231 A1 [0020] WO 2004/063231 A1 [0020]
- - EP 1606325 A1 [0020] EP 1606325 A1 [0020]
- - WO 03/020776 A1 [0020] WO 03/020776 A1 [0020]
- - WO 03/033583 A1 [0028] WO 03/033583 A1 [0028]
- - EP 185863 B1 [0029] - EP 185863 B1 [0029]
- - EP 1118258 B1 [0029, 0029] - EP 1118258 B1 [0029, 0029]
- - WO 02/102591 A1 [0029] WO 02/102591 A1 [0029]
- - EP 387148 B1 [0029] - EP 387148 B1 [0029]
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200810000685 DE102008000685A1 (en) | 2008-03-14 | 2008-03-14 | Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200810000685 DE102008000685A1 (en) | 2008-03-14 | 2008-03-14 | Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections |
Publications (1)
Publication Number | Publication Date |
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DE102008000685A1 true DE102008000685A1 (en) | 2009-09-17 |
Family
ID=40952782
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---|---|---|---|
DE200810000685 Withdrawn DE102008000685A1 (en) | 2008-03-14 | 2008-03-14 | Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2548729A1 (en) * | 2011-07-22 | 2013-01-23 | Kuraray Europe GmbH | Film of polyvinyl(iso)acetal containing plasticizers |
WO2018115090A1 (en) * | 2016-12-21 | 2018-06-28 | Agc Glass Europe | Laminated glazing |
WO2018122768A1 (en) * | 2016-12-30 | 2018-07-05 | Agp America S.A. | Automotive laminated glazing with enhanced spectral properties using narrow band absorption dyes |
EP3604250A4 (en) * | 2017-03-31 | 2021-01-06 | Sekisui Chemical Co., Ltd. | Thermoplastic resin film and glass plate-containing laminate |
US11084254B2 (en) * | 2017-06-07 | 2021-08-10 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
EP3912807A1 (en) | 2020-05-19 | 2021-11-24 | Kuraray Europe GmbH | Printed interlayer films for laminated glazing with improved nir transparency |
US11376819B2 (en) | 2017-06-07 | 2022-07-05 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4316868A (en) | 1980-11-17 | 1982-02-23 | Monsanto Company | Extruding colored thermoplastic resin sheets |
US4476075A (en) | 1981-08-18 | 1984-10-09 | Dynamit Nobel Aktiengesellschaft | Process and apparatus for the production of sheeting having a color wedge |
EP0111678B1 (en) | 1982-10-27 | 1989-01-11 | Hüls Troisdorf Aktiengesellschaft | Method of and apparatus for manufacturing a plastic film having a coloured strip with a variable degree of colouring |
EP0185863B1 (en) | 1984-12-24 | 1989-05-03 | Hüls Troisdorf Aktiengesellschaft | Process for producing films, especially those based on polyvinyl butyral with a slight surface tackiness |
EP0387148B1 (en) | 1989-03-10 | 1993-08-25 | Saint Gobain Vitrage International | Window with sound insulation for vehicles |
WO2002102591A1 (en) | 2001-06-19 | 2002-12-27 | Ht Troplast Ag | Pvb film containing a plastifying agent |
EP1118258B1 (en) | 1998-09-29 | 2003-03-05 | Siemens Production and Logistics Systems AG | Method for checking components in pick-and-place robots |
WO2003020776A1 (en) | 2001-09-04 | 2003-03-13 | Kuraray Specialities Europe Gmbh | High-molecular, crosslinked polyvinyl butyrals, method for the production and use thereof |
WO2003033583A1 (en) | 2001-10-11 | 2003-04-24 | Ht Troplast Ag | Pvb film for composite safety glass and composite safety glass |
WO2004063231A1 (en) | 2003-01-09 | 2004-07-29 | Kuraray Specialities Europe Gmbh | Crosslinked polyvinyl acetals |
DE102004007382A1 (en) | 2004-02-11 | 2005-09-01 | Basf Ag | Black perylene pigments comprising fused-ring dipyridoperylenedione isomers useful for coloring high molecular weight organic material of natural and synthetic origin |
EP1606325A1 (en) | 2003-01-09 | 2005-12-21 | Kuraray Specialities Europe GmbH | Crosslinked polyvinly acetals |
EP1527107B1 (en) | 2002-07-04 | 2007-06-13 | Kuraray Europe GmbH | Crosslinked polyvinyl acetals |
-
2008
- 2008-03-14 DE DE200810000685 patent/DE102008000685A1/en not_active Withdrawn
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4316868A (en) | 1980-11-17 | 1982-02-23 | Monsanto Company | Extruding colored thermoplastic resin sheets |
US4476075A (en) | 1981-08-18 | 1984-10-09 | Dynamit Nobel Aktiengesellschaft | Process and apparatus for the production of sheeting having a color wedge |
EP0111678B1 (en) | 1982-10-27 | 1989-01-11 | Hüls Troisdorf Aktiengesellschaft | Method of and apparatus for manufacturing a plastic film having a coloured strip with a variable degree of colouring |
EP0185863B1 (en) | 1984-12-24 | 1989-05-03 | Hüls Troisdorf Aktiengesellschaft | Process for producing films, especially those based on polyvinyl butyral with a slight surface tackiness |
EP0387148B1 (en) | 1989-03-10 | 1993-08-25 | Saint Gobain Vitrage International | Window with sound insulation for vehicles |
EP1118258B1 (en) | 1998-09-29 | 2003-03-05 | Siemens Production and Logistics Systems AG | Method for checking components in pick-and-place robots |
WO2002102591A1 (en) | 2001-06-19 | 2002-12-27 | Ht Troplast Ag | Pvb film containing a plastifying agent |
WO2003020776A1 (en) | 2001-09-04 | 2003-03-13 | Kuraray Specialities Europe Gmbh | High-molecular, crosslinked polyvinyl butyrals, method for the production and use thereof |
WO2003033583A1 (en) | 2001-10-11 | 2003-04-24 | Ht Troplast Ag | Pvb film for composite safety glass and composite safety glass |
EP1527107B1 (en) | 2002-07-04 | 2007-06-13 | Kuraray Europe GmbH | Crosslinked polyvinyl acetals |
WO2004063231A1 (en) | 2003-01-09 | 2004-07-29 | Kuraray Specialities Europe Gmbh | Crosslinked polyvinyl acetals |
EP1606325A1 (en) | 2003-01-09 | 2005-12-21 | Kuraray Specialities Europe GmbH | Crosslinked polyvinly acetals |
DE102004007382A1 (en) | 2004-02-11 | 2005-09-01 | Basf Ag | Black perylene pigments comprising fused-ring dipyridoperylenedione isomers useful for coloring high molecular weight organic material of natural and synthetic origin |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2548732A1 (en) * | 2011-07-22 | 2013-01-23 | Kuraray Europe GmbH | Polyvinyl(iso)acetal film containing softeners |
EP2548729A1 (en) * | 2011-07-22 | 2013-01-23 | Kuraray Europe GmbH | Film of polyvinyl(iso)acetal containing plasticizers |
EA038461B1 (en) * | 2016-12-21 | 2021-08-31 | Агк Гласс Юроп | Laminated glazing |
WO2018115090A1 (en) * | 2016-12-21 | 2018-06-28 | Agc Glass Europe | Laminated glazing |
JP2020514216A (en) * | 2016-12-21 | 2020-05-21 | エージーシー グラス ユーロップAgc Glass Europe | Laminated glass |
US11097515B2 (en) | 2016-12-21 | 2021-08-24 | Agc Glass Europe | Laminated glazing |
WO2018122768A1 (en) * | 2016-12-30 | 2018-07-05 | Agp America S.A. | Automotive laminated glazing with enhanced spectral properties using narrow band absorption dyes |
EP3604250A4 (en) * | 2017-03-31 | 2021-01-06 | Sekisui Chemical Co., Ltd. | Thermoplastic resin film and glass plate-containing laminate |
US11084254B2 (en) * | 2017-06-07 | 2021-08-10 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
US11376819B2 (en) | 2017-06-07 | 2022-07-05 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
US11590735B2 (en) | 2017-06-07 | 2023-02-28 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
US11590736B2 (en) | 2017-06-07 | 2023-02-28 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
EP3912807A1 (en) | 2020-05-19 | 2021-11-24 | Kuraray Europe GmbH | Printed interlayer films for laminated glazing with improved nir transparency |
WO2021233807A1 (en) | 2020-05-19 | 2021-11-25 | Kuraray Europe Gmbh | Printed interlayer films for laminated glazing with improved nir transparency |
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