DE102007055595A1 - Producing organic composition, useful e.g. as washing agent, comprises mixing n-nonyl ester (obtained by reacting n-nonyl alcohol-component with further component e.g. carboxylic acid), functional component e.g. enzyme and further additive - Google Patents

Abstract

Producing an organic composition comprising a functional component comprising a thermoplastic polymer, enzyme, binder, paraffin, oil, colorant and a hair- or skin care substance, comprises: providing a n-nonyl ester as additive, which is obtained by reacting a n-nonyl alcohol-component with a further component (iaa), which may be reacted with the n-nonyl alcohol component under formation of a n-nonyl ester, the functional component and optionally at least a further additive; and mixing the n-nonyl ester, the functional component and optionally the further additive. Independent claims are included for: (1) producing a molded body, comprising (I) providing a thermoplastic composition, (II) heating the thermoplastic composition to the glass transition temperature of the thermoplastic polymer or to a temperature above the glass transition temperature of the thermoplastic polymer and (III) producing a molded body from the heated thermoplastic composition produced in the step (II); (2) producing packaged goods comprising providing goods and the molded body and at least partially covering the good with the molded body; and (3) a procedure for coating an edible substance, comprising providing an edible substance and the n-nonyl ester and at least partially covering the substance with the n-nonyl ester.

Description

The The present invention relates to a process for the preparation of a organic composition which is a functional component selected from the group consisting of a thermoplastic Polymer, an enzyme, a binder, a paraffin, an oil, a colorant and a hair or skin care substance, as well includes an n-nonyl ester, a process for producing a molded article, a method for producing a packaged good, the use at least an n-nonyl ester and the use of a molding.

Medium chain linear fatty alcohols are now being used successfully as raw materials for surfactants, foam flow, solvents, bodying agents, lubricant additives and as etherification or esterification components in plastics processing. Available are either linear C ₈ - or C ₁₀ -alcohols or branched C ₉ -alcohols (i-nonanol). The linear alcohols are mostly of native origin and always even. C ₈ / C ₁₀ cuts with 40 to 48% by weight of C ₈ -alcohols and 51 to 59% by weight of C ₉ -alcohols are preferably used here.

Although pure C ₁₀ alcohol and its derivatives, such as, for example, ethers or esters, have a high boiling point and are thus comparatively less volatile, they have high solidification points. Pure C ₈ -alcohol and its derivatives are in turn characterized by low solidification points, but have low boiling points and are thus very volatile.

The branched i-nonanols are substance mixtures and become petrochemical produced. The branching of the alcohols leads to a poorer biodegradability. Disadvantageous in connection with the use in i-nonanols is still too high melting point or too low boiling range of the derivatives such as esters, ethoxylates, Sulfates, even if alcohol mixtures are used. Due to the non-ideal viscosity behavior in particular at lower temperatures, this product group are therefore limits set.

Of the Present invention was based on the object resulting from the At least partially overcome the disadvantages of the prior art.

Especially the present invention was based on the object, a method to provide by means of which organic compositions containing Esters of linear fatty alcohols short with medium chain length can be provided as an additive, these being organic compositions compared to those of the prior art known in the art, comparable, organic compositions have less volatile components and the even at low temperatures have a satisfactory viscosity behavior.

About that In addition, the present invention was the object of a Specify method, with the help of which organic compositions containing esters of linear fatty alcohols short of medium chain length can be provided as an additive, where possible many components of these organic compounds on renewable Raw materials or from educts, which are made from renewable raw materials can be won.

About that In addition, the available by this method, organic compositions compared to those of the prior art improved by the art, organic compositions, have application properties.

a Contribute to the solution of at least one of the above Tasks perform the objects of the category-forming Claims, the dependent claims further embodiments of the invention represent.

• i) das Bereitstellen ia) eines n-Nonylesters als Additiv, welcher erhältlich ist durch Reaktion einer n-Nonylalkohol-Komponente mit einer weiteren Komponente, welche mit der n-Nonylalkohol-Komponente unter Bildung eines n-Nonylesters zu reagieren vermag, ib) der funktionellen Komponente, sowie gegebenenfalls ic) mindestens eines weiteren Zusatzstoffes;
• ii) das Mischen des n-Nonylesters, der funktionellen Komponente und gegebenenfalls des mindestens einen weiteren Zusatzstoffes.

More particularly, the present invention relates to a process for producing an organic composition which comprises a functional component selected from the group consisting of a thermoplastic polymer, an enzyme, a binder, a paraffin, an oil, a colorant and a hair or skin care substance , containing as process steps:

• i) providing ia) an n-nonyl ester additive which is obtainable by reacting an n-nonyl alcohol component with another component capable of reacting with the n-nonyl alcohol component to form an n-nonyl ester; functional component, and optionally ic) at least one further additive;
• ii) mixing the n-nonyl ester, the functional component and optionally the at least one further additive.

For the purposes of the present invention, a "functional component" is preferably understood to mean a component which imparts its characteristic, functional property to the composition to which this functional component is added. [So So] For the purposes of the present invention, the functional component of a thermoplastic composition is the thermoplastic component Polymer, the functional component of a Adhesive the binder, the functional component of a lubricant formulation, the oil, the functional component of a detergent the enzyme, the functional component of a defoamer, the paraffin, the functional component of a paint or a color, the colorant and the functional component of a cosmetic preparation, the hair or skin care substance ,

For the purposes of the present invention, an "organic composition" is preferably understood as meaning a composition which consists of more than 50% by weight, based on the total weight of the organic composition, of organic components, wherein as an organic component it is preferable to use a carbon-containing compound Exception is to be understood of CO ₂ , CO, carbides, CSO and pure carbon compounds such as graphite, carbon black or diamond The organic component is preferably a hydrocarbon compound which may contain oxygen, nitrogen, phosphorus, sulfur or at least two of these atoms as heteroatoms ,

in the Step ia) of the method according to the invention is initially provided an n-nonyl ester as an additive, which is obtainable by reaction of an n-nonyl alcohol component with another component, which with the n-nonyl alcohol component reacts to form an n-nonyl ester.

• ia1) das Bereitstellen einer n-Nonylalkohol-Komponente;
• ia2) das Bereitstellen einer weiteren Komponente, welche mit der n-Nonylalkohol-Komponente unter Bildung eines n-Nonylesters zu reagieren vermag;
• ia3) die Umsetzung der n-Nonylalkohol-Komponente mit der mindestens einen Komponente unter Bildung eines n-Nonylesters.

This provision of an n-nonyl ester preferably comprises the following process steps:

• ia1) providing an n-nonyl alcohol component;
• ia2) providing a further component capable of reacting with the n-nonyl alcohol component to form an n-nonyl ester;
• ia3) the reaction of the n-nonyl alcohol component with the at least one component to form an n-nonyl ester.

In method step 1a1) of the method for providing an n-nonyl ester, an n-nonyl alcohol component is initially provided. According to a preferred embodiment of the method according to the invention for producing an organic composition, it is preferred that the n-nonyl alcohol component is at least 80% by weight, more preferably at least 90% by weight and most preferably at least 99% by weight. %, in each case based on the provided n-nonyl alcohol component, is obtained from pelargonic acid. In this context, it is further preferred that the provision of the n-nonyl alcohol component, the catalytic hydrogenation of pelargonic acid (octanecarboxylic acid, nonanoic acid), for example according to the in the WO-A-2006/021328 described method, or the catalytic hydrogenation of incurred in the ozonolysis of oleic acid Ölsäureozonids or both. Also conceivable is the catalytic hydrogenation of esters of pelargonic acid, for example the catalytic hydrogenation of the methyl, ethyl, propyl or butyl ester of pelargonic acid. If the n-nonyl alcohol component is obtained by the catalytic hydrogenation of pelargonic acid, the pelargonic acid itself can be obtained, for example, by ozonolysis of oleic acid and subsequent oxidative work-up of the oleic ozone or else by ozonolysis of erucic acid and subsequent oxidative work-up of the erucic acid ozone. Such a process is carried out on an industrial scale, for example by Unilever Emery and Henkel and is inter alia in "Ozonation of Alkenes in Alcohols as Solvents", dissertation by Eberhard Rischbieter, University of Carolo-Wilhelmina zu Braunschweig, 2000 or in US 2,813,113 described. The oxidation of the oxidative workup of ozonides accumulating aldehydes and formation of the corresponding acid derivatives is for example in the DE-C-100 70 770 described. The production of the oleic acid can in turn be obtained from tallow or tall oils, as for example in US 6,498,261 is described. In addition to the ozonolysis of oleic acid or erucic acid, the pelargonic acid can also be obtained by isomerization of petrochemical raw materials. Also conceivable is the petrochemical production of pelargonic acid, such as by Harold A., Wittcoff, Bryan G., Reuben, Jeffrey S. Plotkin in "Fats and Oils", Industrial Organic Chemicals (Second Edition) (2004), John Wiley & Sons, Inc., pp. 411-433 or the preparation of pelargonic acid from oleic acid according to the in the GB-A-813842 described method.

According to a particular embodiment of the process according to the invention for the preparation of an organic composition, the n-nonyl alcohol component used for the preparation of the n-nonyl alcohol contains, in addition to the n-nonyl alcohol, further alcohols, for example C ₈ and / or C ₁₀ alcohols, but in In this case, it is particularly preferred that the n-nonyl alcohol component is less than 10 wt .-%, more preferably less than 7.5 wt .-% and most preferably less 5 wt .-%, each based on the n-nonyl alcohol Component, C ₈ and C ₁₀ alcohols. The proportion of n-nonyl alcohol in the n-nonyl alcohol component in the case of use of a mixture of n-nonyl alcohol and at least one further alcohol before preferably at least 90 wt .-%, more preferably at least 92.5 wt .-% and am most preferably at least 95 wt .-%, each based on the total weight of the n-nonyl alcohol component.

A according to the invention particularly preferred n-nonyl alcohol component is in particular that n-nonyl alcohol component prepared by catalytic hydrogenation under the under brand name EMERY ^® 1202 EMERY ^® 1203 and Emery ^® 1210 sold pelargonic acid or more than 10 wt .-%, preferably more than 25 wt .-%, each based on the Pelargonsäuremischung-containing, pelargonic Pelargonsäuremischungen., wherein EMERY ^® 1202 to less than 1 wt .-% of C ₆ monocarboxylic acids, to about 1 wt .-% of C ₇ monocarboxylic acids consists wt .-% of other by-products, in particular monocarboxylic acids having more than 9 carbon atoms to about 4 wt .-% of C ₈ monocarboxylic acids, to about 93 wt .-% of pelargonic acid and about 2, EMERY ^® 1203 about 0, 1 wt .-% of C ₆ -C ₈ monocarboxylic acids, to about 99 wt .-% of pelargonic acid and from about 0.9 wt .-% of other by-products, in particular monocarboxylic acids having more than 9 carbon atoms, while EMERY ^® 1210 to about 3 wt .-% of C ₅ monocarboxylic acids, about 27 wt .-% of C ₆ monocarboxylic acids, about 31 wt .-% of C ₇ monocarboxylic acids, about 12 wt .-% of C ₈ Monocarboxylic acids and about 27 wt .-% of pelargonic acid, but the use of EMERY ^® 1203 is particularly preferred because here the proportion of pelargonic acid is particularly high.

in the Process step ia2) of the process for providing an n-nonyl ester is at least one further component, which with the n-nonyl alcohol component provided to form an n-nonyl ester, wherein this further component is preferably a inorganic acid, especially an inorganic acid selected from the group consisting of sulfuric acid, sulphurous acid, phosphoric acid or phosphorous Acid, or an organic acid, in particular to an organic acid selected from the group consisting of monocarboxylic acids, dicarboxylic acids, Tricarboxylic acids, tetracarboxylic acids or derivatives the above-mentioned carboxylic acids.

Of the Term "carboxylic acid" as used herein comprising the carboxylic acid in its protonated form, the carboxylic acid in its deprotonated form (ie in particular Salts of the carboxylic acid) as well as mixtures of the carboxylic acid in their protonated form and their deprotonated form. Farther The term "carboxylic acid" basically includes all Compounds having at least one carboxylic acid group. It therefore also includes, in particular, compounds which, in addition to the at least a carboxylic acid group also other functional groups, such as hydroxyl groups, keto groups or ether groups.

Of the The term "derivative of a carboxylic acid" includes all Derivatives of a carboxylic acid which react with an alcohol to a corresponding ester of the carboxylic acid to lead. In particular, the term "derivative a carboxylic acid "are the acid chlorides of Carboxylic acid and the acid anhydrides of the carboxylic acid. These derivatives preferably have one compared to the carboxylic acid increased reactivity of the carboxylic acid group so that when reacted with an alcohol ester formation is favored.

Particularly according to the invention the use of mono-, di-, tri-, tetra- or polycarboxylic acids is preferred with more than four carboxyl groups, a derivative of such Carboxylic acid or a mixture of such a carboxylic acid and a derivative of such a carboxylic acid as further Component. As the carboxylic acid come in particular saturated or unsaturated carboxylic acids with a number at carbon atoms in a range of 6 to 26, particularly preferred in a range of 8 to 24, more preferably in a range of 10 to 22, moreover, in a range of 12 to 20 and most preferably in a range of 14 to 18 into consideration. Particularly preferred according to the invention Carboxylic acids are therefore fatty acids.

Examples suitable carboxylic acids include in particular caproic acid, enanthic acid, Caprylic acid, pelargonic acid, capric acid, Lauric acid, myristic acid, fish oil, Palmitic acid, palmitic acid, pelagic acid, Margarine acid, stearic acid, elaeostearic acid, Isostearic acid, isotridecanoic acid, arachidic acid, Behenic acid, lignoceric acid, cerotic acid, Undecylenic acid, oleic acid, elaidic acid, vaccenic acid, Icosenoic acid, rapeseed oil, cetoleic acid, erucic acid, Nervonic acid, linoleic acid, linolenic acid, arachidonic acid, Timnodonic acid, clupanodonic acid, petroselinic acid, Gadoleic acid or cervonic acid.

Next The fatty acids mentioned above also contain di-, tri- or tetracarboxylic acids or their anhydrides from the group consisting of phthalic anhydride, isophthalic acid, phthalic acid, Terephthalic acid, tetrahydrophthalic anhydride, Hexahydrophthalic anhydride, naphthalenedicarboxylic acid, 4,4'-biphenyldicarboxylic acid, diphenylmethane-4,4'-dicarboxylic acid, Succinic acid, fumaric acid, adipic acid, Sebacic acid, azelaic acid, trimellitic acid, Pyromelic acid, mellitic acid and maleic anhydride into consideration, whereby of these acids adipic acid, Trimellitic acid, terephthalic acid and azelaic acid are particularly preferred.

Also included as suitable carboxylic acids are hydroxycarboxylic acids, of these hydroxyfatty acids, such as, for example, ricinoleic acid, 12-hydroxystearic acid, hydrogenated castor oils fatty acids (fatty acids containing small amounts of stearic acid and palmitic acid, as well as 12-hydroxystearic acid), sabinic acid, 2-hydroxytetradecanoic acid, ipurolic acid (3,11-dihydroxytetradecanoic acid, 2-hydroxyhexadecanoic acid, jalapinolic acid, juniperic acid, ambrettolic acid, aleuritic acid, 2-hydroxyoctadecanoic acid , 18-hydroxyoctadecanoic acid, 9,10-dihydroxyoctadecanoic acid, camiolic acid, ferroic acid, cerebronic acid, 9-hydroxystearic acid and 10-hydroxystearic acid are particularly preferred, and 12-hydroxystearic acid and ricinoleic acid are most preferred. Hydroxypropionic acid, 2-hydroxybenzoic acid, 3-hydroxybenzoic acid or 4-hydroxybenzoic acid.

The The above mentioned fatty acids can be natural occurring grease and oils, for example, over lipolysis at elevated temperature and elevated levels Pressure and subsequent separation of the resulting fatty acid mixtures, if appropriate, hydrogenation of the double bonds present become. Preferably here are technical fatty acids used, which are usually mixtures of different fatty acids a certain chain length range with a fatty acid as a main component. Preference is given to fatty acids provided with 12 to 18 C atoms alone or in mixture.

in the Process step ia3) of the process for providing an n-nonyl ester becomes the n-nonyl alcohol component with the at least one component reacted to form an n-nonyl ester.

The Preparation of the n-nonyl esters can be accomplished by any of those skilled in the art Process for preparing such an ester take place.

Preferably For the preparation of the esters, the n-nonyl alcohol component and the carboxylic acid or the derivative of the carboxylic acid and then in the presence of a suitable Catalyzed esterification catalyst. As esterification catalysts may be acids such as sulfuric acid or p-toluenesulfonic acid, or metals and their compounds be used. For example, tin, titanium, zirconium, which are suitable as finely divided metals or useful in the form of their Salts, oxides or soluble organic compounds used become. The metal catalysts are in contrast to protic acids High-temperature catalysts, their full activity in usually reach only at temperatures above 180 ° C. However, they are preferred according to the invention because they have fewer byproducts compared to proton catalysis, such as for example, olefins. Particularly according to the invention preferred esterification catalysts are one or more divalent tin compounds or tin compounds or elemental tin, which react with the educts to convert divalent tin compounds. For example can be used as a catalyst tin, tin (II) chloride, stannous sulfate, stannous (II) alcoholates or tin (II) salts of organic acids, in particular of mono- and dicarboxylic acids. Particularly preferred tin catalysts are tin (II) oxalate and tin (II) benzoate.

The Conducting the esterification reaction between the n-nonyl alcohol component and the carboxylic acid or the derivative of the carboxylic acid be carried out by methods known in the art. It can in particular be advantageous that formed in the reaction of water from the Remove reaction mixture, this removal of the water preferably by distillation, optionally by distillation with excess alcohol used. Also can unreacted after carrying out the esterification reaction Alcohol can be removed from the reaction mixture, with these too Removal of the alcohol is preferably carried out by distillation. Furthermore, after completion of the esterification reaction, in particular after the separation of unreacted alcohol in the reaction mixture residual catalyst, optionally after treatment with a base, by filtration or by centrifuging be separated.

Farther it is preferred that the esterification reaction between the n-nonyl alcohol component and the carboxylic acid or the derivative of the carboxylic acid at a temperature in a range of 50 to 300 ° C, more preferably in a range of 100 to 275 ° C and most preferably in a range of 200 to 250 ° C perform. The optimal temperatures depend of the feed alcohol (s), the progress of the reaction, the type of catalyst and the catalyst concentration. You can for Each individual case can be easily determined by experiment. higher Temperatures increase the reaction rates and favor side reactions, such as dehydration from alcohols or formation of colored by-products. The desired Temperature or the desired temperature range can through the pressure in the reaction vessel (slight overpressure, Normal pressure or optionally negative pressure) can be set.

According to a particular embodiment of the process for providing an n-nonyl ester, this may, as a further process step, comprise the step of Ia4) alkoxylation, preferably ethoxylation or propoxylation, of the n-nonyl ester with formation of an alkoxylated, preferably an ethoxylated or propoxylated n-nonyl ester 2 to 50, especially before preferably comprising 4 to 25 ether repeating units, these ether repeating units preferably being a - [O-CH ₂ -CH ₂ ] unit, a - [O-CH ₂ -CH ₂ -CH ₂ ] unit or a mixture out of these units.

Such alkoxylated n-nonyl esters can be obtained, for example, by reacting the n-nonyl ester with ethylene oxide, propylene oxide or a mixture of ethylene oxide and propylene oxide in the presence of suitable catalysts in relative amounts such that 2 to 50 ether repeat units, particularly preferably 4 to 25 ether repeat units be inserted into the ester bond. A method by which esters can be alkoxylated is described, for example, in US Pat DE-A-40 10 606 The disclosure of which is incorporated herein by reference for the alkoxylation of ester and forms part of the disclosure of the present invention.

• 1. Gemäß einer ersten Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionellen Komponente um ein thermoplastisches Polymer und bei der organischen Zusammensetzung mithin um eine thermoplastische, organische Zusammensetzung.

In process step ib) of the process according to the invention for producing an organic composition, a functional component is provided.

• 1. According to a first variant of the method according to the invention, the functional component is a thermoplastic polymer and the organic composition is therefore a thermoplastic, organic composition.

Under the term "thermoplastic polymer" as used herein is used, plastics are understood that are in one deform certain temperature range simply (thermo-plastic) to let. This process is reversible and may be due to cooling and reheating to the molten one Condition can be repeated as often as long as not by overheating the thermal decomposition of the material begins.

When thermoplastic polymers which are used as functional component according to the first variant of the method according to the invention can be used, generally polycondensates or Chain polymers or a mixture of these two, in particular thermoplastic Polyurethanes, thermoplastic polyesters, thermoplastic polyamides, thermoplastic polyolefins, thermoplastic polyvinyl esters, thermoplastic Polyethers, thermoplastic polystyrenes, thermoplastic polyimides, thermoplastic sulfur polymers, thermoplastic polyacetals, thermoplastic fluoroplastics, thermoplastic styrene-olefin copolymers, thermoplastic Polyacrylates, thermoplastic ethylene-vinyl acetate copolymers or Mixtures of two or more of the above, thermoplastic Polymers in question.

It However, according to the invention is preferred that the thermoplastic polymer to more than 90 wt .-%, more preferably at more than 95% by weight, moreover more preferable at least 99% by weight, and most preferably 100% by weight, each based on the total weight of the thermoplastic polymer, based on thermoplastic polyester. Under designation "polyester", As used herein, in particular, polymers that fall through Polycondensation reaction between a polycarboxylic acid and a polyol (so-called "AA // BB polyester") or by polycondensation reaction a hydroxycarboxylic acid or by ring-opening polymerization a cyclic ester (so-called "AB-polyester") were. In an embodiment according to the invention can, polycarbonates, by reaction of phosgene with Diols are available, from the invention used Term "polyester" be excluded.

In principle, all currently known thermoplastic polyesters and copolyesters can be used. Examples of such polyesters include substantially linear polyesters prepared by a condensation reaction of at least one polycarboxylic acid, preferably a dicarboxylic acid (diacid) or an ester-forming derivative thereof, and at least one polyol, preferably a dihydric alcohol (diol). The preferred dibasic acid and preferably divalent diol may both be either aliphatic or aromatic, but aromatic and partially aromatic polyesters are particularly preferred as thermoplastic molding materials in view of their high softening points and hydrolytic stability. For aromatic polyesters, substantially all ester linkages are attached to the aromatic rings. They can be semi-crystalline and even exhibit liquid crystalline behavior or be amorphous. Partially aromatic polyesters obtained from at least one aromatic dicarboxylic acid or an ester-forming derivative thereof and at least one aliphatic diol are particularly preferred thermoplastic polyesters according to the invention. Examples of suitable aromatic dicarboxylic acids include terephthalic acid, 1,4-naphthalenedicarboxylic acid or 4,4'-biphenyldicarboxylic acid. Examples of suitable aliphatic diols include alkylene diols, especially those containing 2 to 6 carbon atoms, preferably 2 to 4 carbon atoms, in particular ethylene glycol, propylene diols and butylene diols. Preferably, ethylene glycol, 1,3-propylene diol or 1,4-butylene diol are used as the polyol or diol component for the production of the thermoplastic polyester contained in the composition according to the invention as component a). Particularly preferred thermoplastic polyesters according to the invention, which are characterized by Reaction of a dicarboxylic acid with a diol are especially include polyalkylene terephthalates, for example, polyethylene terephthalate (PET), polypropylene terephthalate (PPT) or polybutylene terephthalate (PBT), polyalkylene naphthalates, for example, polyethylene naphthalate (PEN) or polybutylene naphthalate (PBN), polylactic acid (PLA), polyalkylene dibenzoates, for example Polyethylenbibenzoat and mixtures of at least two of these thermoplastic polyesters.

These described above, partially aromatic polyester optionally contain a small amount of units consisting of other dicarboxylic acids, for example isophthalic acid, or other diols such as cyclohexanedimethanol, which is generally reduced the melting point of the polyester. A special group partially aromatic polyesters are so-called segmented or block copolyesters which, in addition to the above polyester segments (also called "hard segments"), so-called "soft segments." These soft segments come from made of a flexible polymer; that essentially means one amorphous polymer with a low glass transition temperature (Tg) and low rigidity, with reactive end groups, preferably two hydroxyl groups. Preferably, the glass transition temperature is these "soft segments" below 0 ° C, especially preferably below -20 ° C and most preferred below - 40 ° C. In principle, several can different polymers are used as the soft segment. Suitable examples of "soft segments" are aliphatic polyethers, aliphatic polyesters or aliphatic Polycarbonates. The molecular weight of the soft segments can be within wide limits vary, but is preferably between 400 and 6,000 g / mol.

Next the above-mentioned, linear polyester, over a polycondensation reaction of at least one polycarboxylic acid or an ester-forming derivative thereof and at least one polyol can be obtained as the main component according to first variant of the method according to the invention also thermoplastic polyesters are used by polycondensation reaction short-chain hydroxycarboxylic acids or by ring opening reaction Cyclic esters are available.

Examples suitable, short-chain hydroxycarboxylic acid, which zur Production of thermoplastic polymers can be used include in particular L-lactic acid, D-lactic acid, DL-lactic acid, Glycolic acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 4-hydroxyvaleric acid, 5-hydroxyvaleric acid, 6-hydroxycaproic acid and mixtures of these hydroxycarboxylic acids. Examples of suitable cyclic esters include in particular glycolide (a dimer of glycolic acid) and ε-caprolactone (a cyclic ester of 6-hydroxy-caproic acid).

The preparation of the thermoplastic polyesters described above is also known in, inter alia "Encyclopedia of Polymer Science and Engineering", Vol. 12, pages 1 to 75 and pages 217 to 256; John Wiley & Sons (1988) and also in "Ullmann's Encyclopedia of Industrial Chemistry", Vol. A21, pages 227 to 251, VCH Publishers Inc. (1992) described. Thermoplastic polymers preferred according to the invention are polyethylene terephthalate (PET), polybutylene terephthalate (PBT) and polylactic acid (PLA). Furthermore, according to the first variant of the method according to the invention, it is preferred that this thermoplastic polymer is present as a functional component in an amount of at least 60% by weight, preferably at least 75% by weight and more preferably at least 90% by weight, in each case based on the total weight of the organic composition, while the n-nonyl ester as an additive, in particular as a mold release agent, as antifogging agent, as a plasticizer, as an antistatic agent or as a lubricant, most preferably in a function as a mold release agent, preferably in an amount in in the range of 0.001 to 40% by weight, more preferably in the range of 0.01 to 25% by weight, and most preferably in the range of 0.1 to 10% by weight, in each case based on the total weight of the thermoplastic composition is used.

As additives which can be provided in accordance with this first variant of the process according to the invention in method step ic), especially scarf modifiers, filler materials, reinforcing agents, flame retardant compounds, heat and UV stabilizers, antioxidants, other processing aids, nucleating agents, dyes and anti-drip agents come into question. Examples of suitable impact modifiers, filler materials, reinforcing agents and flame retardant compounds include US 2005/0234171 A1 refer to. These other additives are preferably used in an amount in a range of 0.001 to 20% by weight, more preferably in an amount in a range of 0.01 to 10% by weight, and most preferably in an amount in a range of 0 , 1 to 5 wt .-%, each based on the total weight of the thermoplastic composition used.

The mixing of the n-nonyl ester, the functional component (thermoplastic polymer) and optionally the additive, which takes place in process step ii) in the case of the first variant of the process according to the invention, can be carried out using known techniques. That's how it works For example, blending may be a dry blending operation in which the various components are mixed below the melt processing temperature of the thermoplastic polymer, or a melt blending process wherein the components, optionally premixed and blended at the melt processing temperatures of the thermoplastic polymer. In particular, the melt-mixing method includes the invented melt-removing method which is, for example, continuous melt-kneading using a single-screw kneader, a twin-screw kneading-same-rotation-type kneading machine, gear-different-direction-rotation-type, non-serrating-same-directional Rotation type, non-serration different-direction rotation type, or other types, or by batch melt kneading using a roll kneading machine, a Banbury kneader or the like is feasible. Also conceivable is a combination of a dry mixing process and a melt mixing process.

Farther is the order and the way of adding the individual Components ia), ib) and optionally ic) in the mixing device in principle critical. For example, first the thermoplastic polymer and optionally the additives presented in the mixing device and only then be added to the n-nonyl ester. It is also conceivable, the n-nonyl ester or a portion of the n-nonyl ester first with one or more other components of the thermoplastic according to the invention Composition, for example with one or more additives, to mix and then mix this to either already in adding the mixing device, to be added thermoplastic polymer or but initially submit this mixture in the mixing device and only then add the thermoplastic polymer.

• M1) bei der Glasübergangstemperatur des thermoplastischen Polymers oder bei einer Temperatur oberhalb der Glasübergangstemperatur des thermoplastischen Polymers;
• M2) wobei der n-Nonylester flüssiger ist als das thermoplastische Polymer; oder
• M3) wobei mindestens ein Teil des n-Nonylesters dem Vorläufer des thermoplastischen Polymers zugesetzt wird.

In further embodiments of the method according to the invention for producing an organic composition according to the first variant of the method according to the invention, the mixing takes place according to at least one of the following measures:

• M1) at the glass transition temperature of the thermoplastic polymer or at a temperature above the glass transition temperature of the thermoplastic polymer;
• M2) wherein the n-nonyl ester is more fluid than the thermoplastic polymer; or
• M3) wherein at least a portion of the n-nonyl ester is added to the precursor of the thermoplastic polymer.

It also corresponds to embodiments according to the invention, if two or more of the above measures combined become. Thus, in detail as embodiments, the following using the combinations of numbers shown combinations of measures: M1M2, M1M3, M2M3 and M1M2M3.

According to one preferred embodiment M1 of the invention Procedure, the mixing takes place in the process steps ia), ib) and optionally ic) provided in the Process step ii) of the process according to the invention by a melt blending method. In this context, it is particular preferred that the mixing in process step ii) at the glass transition temperature of the thermoplastic polymer or at a temperature above the glass transition temperature of the thermoplastic polymer he follows. It is particularly preferred in this context that mixing at a temperature in a range of 5 degrees below the glass transition temperature (Tg) to 200 ° C above the glass transition temperature of the used, thermoplastic polymer, more preferably at a temperature in a range of 1 degree below the glass transition temperature (Tg) up to 180 ° C above the glass transition temperature of used, thermoplastic polymer and most preferred at a temperature in a range of 1 degree above the glass transition temperature (Tg) to 150 ° C above the glass transition temperature of the thermoplastic polymer used, but the upper Limit of the temperature range substantially from the decomposition temperature of the thermoplastic polymer used is limited. Further corresponds to embodiments of the invention, when mixing at temperatures in a range of 10 to 180 ° C and preferably 50 to 150 ° C above the glass transition temperature of the thermoplastic polymer used.

In the embodiment M2 according to the invention, in which the n-nonyl ester is more liquid than the thermoplastic polymer, it is preferred that the n-nonyl ester is used at a temperature at which it is liquid and the thermoplastic polymer is not yet liquid. Preferably, the temperature of the thermoplastic polymer is below the glass transition temperature of this polymer. Thus, it is preferred if the melting temperature of the n-nonyl ester and the glass transition temperature of the thermoplastic polymer differ by at least 5 ° C, preferably at least 10 ° C and more preferably at least 30 ° C. Furthermore, it is in this embodiment and also generally preferred to use the thermoplastic polymer as granules. In general, all known in the art granular forms with spherical or cylinder-like spatial form also present in Consideration. The granule size determined by sieve analysis is in a range of 0.01 to 5 cm and preferably in a range of 0.1 to 4 cm for at least 70% by weight of the granule particles. By the procedure according to this embodiment, the surfaces of the granule particles can be at least partially coated with the n-nonyl ester, so that an at least partially coated thermoplastic polymer granules are obtained. This allows the most homogeneous possible distribution of the n-nonyl ester according to the invention in the thermoplastic composition, especially if this is formulated as a formulation for the subsequent extrusion.

• 2. Gemäß einer zweiten Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionelle Komponente um ein Enzym und bei der organischen Zusammensetzung um ein Waschmittel.

In the inventive embodiment M3, in which the n-nonyl ester is added to the precursor of the thermoplastic polymer, n-nonyl esters in liquid and also in solid form are suitable. In principle, all precursors known to the person skilled in the art prior to obtaining the thermoplastic polymer are considered as precursors of the thermoplastic polymer. These include in particular precursors which have a lower molecular weight than the final thermoplastic polymer. It is preferred here that the molecular weight of the precursor differs from that of the finished thermoplastic polymer by at least 1.1, preferably at least 1.5, and more preferably at least 2-fold. In addition to the monomers and oligomers used for the preparation of the thermoplastic polymer, which preferably consist of 2 to 100 monomers, belongs, especially in the case of polycondensates, a prepolymer which is polymerized, usually by heat treatment, to form the finished thermoplastic polymer. Preferably, the prepolymer is based on more than 100 monomers as repeat units, wherein the number of monomers as repeat units and thus the final molecular weight of the finished thermoplastic polymer is not achieved. Thus, it is particularly preferred to add the n-nonyl ester to each of the monomers, oligomers or prepolymer, or at least two of them. As a result, in addition to a homogeneous distribution of the n-nonyl ester, also incorporation of the n-nonyl ester by chemical bonds with the thermoplastic polymer is achieved, usually by the conditions prevailing in the polymerization or polymerization.

• 2. According to a second variant of the method according to the invention, the functional component is an enzyme and the organic composition is a detergent.

suitable Enzymes are in particular amylases, proteases, lipases, cellulases, Peroxidases or mixtures of at least two of these enzymes.

Amylases are added to remove starch and glycogen. Useful according to the invention are alpha, beta and gamma amylases as well as glucoamylases and maltogenic amylases. Suitable amylases are commercially available for example under the names Duramyl ^®, Termamyl ^®, Fungamyl ^® and BAN ^® (Novo Nordisk), and Maxamyl ^®, Purafect ^® OxAm or. The amylases can be derived from any source, such as bacteria, fungi, pancreas glands of animal origin, germinated grains or yeasts. Genetically modified amylases may also be used, if desired, even as a functional component in the organic compositions according to the invention. The amylase enzymes may be present in the compositions of this invention in an amount of from 0.0001% to 5% by weight, more preferably from 0.0001% to 1% by weight, and most preferably from 0, 0005 to 0.5 wt .-%, each based on the total weight of the organic composition, are present.

In addition to amylases, it is also possible for proteases to cleave proteins and peptide residues to be added to the organic compositions according to the invention in accordance with the second variant of the method according to the invention. Proteases are particularly suitable for the hydrolytic cleavage and removal of protein residues, in particular dried-on protein residues. Proteases which are suitable according to the invention are proteinases (endopeptidases) and peptidases (exopeptidases). Useful proteases may be of plant, animal, bacterial and / or fungal origin. Suitable proteases are, in particular, serine, cysteine, aspartate and metalloproteases. Genetically modified proteases may also be used in the compositions according to the invention, if appropriate even preferred. Suitable proteases are commercially available under the names Alcalase ^®, BLAP ^®, Durazym ^®, Esperase ^®, Everlase® ^®, Maxapem ^®, Maxatase ^®, Op timase Purafect ^® OxP or Savinase ^®. Usually proteases are used in an amount of 0.00001 to 1.5 wt .-% and particularly preferably from 0.0001 to 0.75 wt .-%, each based on the total weight of the organic composition.

Also, lipases can be used as a functional component according to the second variant of the method according to the invention. They serve to remove firmly adhering greasy soil. Lipases are thus a bio-alternative to surfactants and can support the cleaning action of the surfactants in the range from 0.0001 to 1% by weight, based on the total weight of the organic composition. Suitable lipases can be obtained from plants (for example, Rhizinusarten), microorganisms and animal sources, as in For example, pancreatic lipases. Commercially available lipases are, for example, Lipolase ^®, Lipomax® ^{®, ®} and Lipozym Lumafast® ^®.

The The above-mentioned enzymes may optionally be used with any other enzymes are combined to improve the cleaning performance of the Detergent used, organic composition continues to increase improve. Further suitable according to the invention Enzymes are cellulases, hemicellulases, peroxidases, reductases, Oxidases, ligninases, cutinases, pectinases, xylanases, phenol oxidases, Lipoxygenases, tannases, pentosanases, malanases. Glucanases, arabinosidases and any mixtures of these enzymes.

at this second variant of the invention Method, the n-nonyl ester is preferably in the function of Surfactants added to the detergent, it being preferred in this case in that the n-nonyl ester is present in an amount of 0.001 to 40% by weight, more preferably from 0.01 to 30% by weight, more preferably from 0.1 to 20% by weight, and most preferably from 1 to 10% by weight, each based on the total weight of the organic composition, is used.

When Additives, which according to this second variant the method according to the invention in the process step ic), more particularly, n-nonyl ester various surfactants, builders, solvents, Hydrophobic components, phase separation agents, thickeners, Polymers, soil release agents, solubilizers, hydrotropes, such as sodium cumenesulfonate, octylsulfate, butylglucoside, Butylglycol, emulsifiers, such as gallus soap, gloss-drying additives, Cleaning agents, antimicrobial agents or disinfectants, Antistatic agents, preservatives, such as glutaraldehyde, bleach systems, Perfumes, fragrances, dyes, opacifiers or skin protection products, the amount of such Additives usually not exceeding 12% by weight, based on the total weight of the organic composition.

• 3. Gemäß einer dritten Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionelle Komponente um einen Abbinder und bei der organischen Zusammensetzung um einen Klebstoff.

An overview of the additives contained in detergents, on the amounts in which they are added to the detergents and on the manner of producing a detergent from the abovementioned components in the sense of process step ii) of the inventive method for producing an organic composition including the DE 101 06 712 A1 be removed.

• 3. According to a third variant of the method according to the invention, the functional component is a binder and the organic composition is an adhesive.

The chemical composition of the binder contained in the adhesive Depends on the type of setting by the adhesive he follows. So it can be a physically setting adhesive, for example, a hot melt adhesive containing, for example Ethylene-vinyl acetate copolymers, polyamides or polyesters as binders a solvent-containing wet adhesive, including For example, polymeric vinyl compounds, polymethylmethacrylate or natural and synthetic rubber as a binder to a contact adhesive, including for example, polychloroprenes or butadiene-acrylonitrile rubber as a binder, a dispersion adhesive, including, for example Polyvinyl acetate, vinyl acetate copolymers, polyacrylates, polyvinylidene chloride, Styrene-butadiene copolymers, polyurethanes, polychloroprene or rubber latexes as a binder, a water-based adhesive, including, for example Glutin glue, such as skin glue or fish glue, glues based on plant Natural products, such as starch, methylcellulose or casein glue, or PVAL adhesives as a binder, containing a pressure-sensitive adhesive for example, polyacrylates, polyvinyl ethers or natural rubber as a binder, or a plastisol, including, for example PVC and plasticizer as a binder, act.

Farther It may be the adhesive and a chemically curing Adhesive, for example a cyanoacrylate-based adhesive, containing, for example, cyanoacrylic acid ester as a binder, a methyl methacrylate-based adhesive, including, for example Methacrylic acid methyl ester as a binder, an anaerobic hardening Adhesive containing, for example, diacrylic acid ester of diols as a binder, a radiation-curable adhesive containing for example, epoxy acrylates or polyester acrylates as binders, a phenol-formaldehyde resin-based adhesive including, for example Phenols and formaldehyde as a binder, a silicone-based adhesive, includes, for example, polyorganosiloxanes as binders, a Polyimide-based adhesive, including, for example, aromatic Tetracarboxylic anhydrides and aromatic diamines as binders, an epoxy resin adhesive including, for example, oligomers Diepoxide and polyamines or polyamidoamines as Abbinder, or a Polyurethane-based adhesive, including, for example, di- and optionally trifunctional isocyanates and polyols as binders act.

The Concentration of Abbinder in the adhesive depends on the type of adhesive used, but is usually in a range of 10 to 100 wt .-%, particularly preferably of 20 to 90 wt .-% and more preferably from 30 to 80 wt .-%, each based on the total weight of the adhesive.

at this third variant of the invention Method, the n-nonyl ester is preferably in the function of Solvent, a consort or in the Function of a surfactant added to the adhesive, it being in this Case is preferred that the n-nonyl ester in an amount of 0.001 to 40 wt .-%, particularly preferably from 0.1 to 30 wt .-%, even more preferably from 1 to 20% by weight, and most preferably from 3 to 10 wt .-%, each based on the total weight of the organic Composition, is used. Especially when used of the n-nonyl ester as a solvent, for example in solvent-containing Wet adhesives may increase the concentration of the n-nonyl ester, if appropriate also above the aforementioned concentration ranges.

The Additives, which according to this third variant the method according to the invention in the process step ic) are dependent on the Nature of the respective adhesive. In particular, be considered Fillers, such as chalk, natural ground or precipitated calcium carbonates, calcium magnesium carbonates (dolomite), Silicates such as aluminum silicates, barite or magnesium aluminum silicates, talc and reinforcing fillers such as Russian, in particular Russian, Channel Russian, Gas Russian, Furnacerusse or mixtures thereof, plasticizers or plasticizer mixtures, Catalysts (in the case of chemically setting adhesives), stabilizers as well as solvents. The amount of such additives depends on the type of adhesive and is usually not more than 50 wt .-%, based on the total weight of the organic composition.

• 4. Gemäß einer vierten Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionellen Komponente um ein Paraffin, insbesondere ein Paraffinwachs, und bei der organischen Zusammensetzung um einen Entschäumer.

An overview of adhesives provides among others the publication "Glue / Adhesives" of the Fonds der Chemischen Industrie in the Verband der Chemischen Industrie eV, 2001 ,

• 4. According to a fourth variant of the method according to the invention, the functional component is a paraffin, in particular a paraffin wax, and the organic composition is an antifoam.

The paraffin provided as a functional component in the fourth variant of the process according to the invention in process step ib) generally represents a complex mixture without a sharp melting point. For characterization, its melting range is usually determined Differential thermal analysis (DTA) as in "The Analyst" (1962), 420 , described, and / or its solidification point. This is the temperature at which the wax passes from the liquid to the solid state by slow cooling. Paraffins with less than 17 carbon atoms are not useful according to the invention, their proportion in the paraffin wax mixture should therefore be as low as possible and is preferably below the limit which can be measured with conventional analytical methods, for example gas chromatography. Preferably, waxes are used which solidify in the range of 20 ° C to 70 ° C. It should be noted that even at room temperature appearing paraffin wax mixtures may contain different proportions of liquid paraffin. In the case of the paraffin waxes which can be used according to the invention, the liquid fraction at 40 ° C. is as high as possible, without already being 100% at this temperature. Particularly preferred paraffin wax mixtures have at 40 ° C a liquid content of at least 50 wt .-%, in particular from 55 wt .-% to 80 wt .-%, and at 60 ° C, a liquid content of at least 90 wt .-%. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ° C, preferably down to at least 60 ° C. It should also be ensured that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 ° C and atmospheric pressure vaporizable fractions. According to the invention Paraffin waxes can be obtained for example under the trade names Luna Flex ^® from fillers and Deawax ^® DEA Mineralöl AG. The amount of paraffin in the defoaming organic composition is preferably in a range of 50 to 99% by weight, more preferably 60 to 95% by weight, and most preferably 70 to 95% by weight, respectively based on the total weight of the organic composition. However, if carrier materials are added to the defoamer, the proportion of paraffin can also be significantly below the above-mentioned concentration ranges.

at this fourth variant of the invention Method, the n-nonyl ester is preferably in the function of Solvent or in the function of a surfactant added to the defoamer, it being preferred in this case in that the n-nonyl ester is present in an amount of 0.001 to 20% by weight, particularly preferably from 0.1 to 10% by weight, more preferably from From 1 to 8% by weight and most preferably from 2 to 7% by weight, respectively based on the total weight of the organic composition used becomes.

The additives which can be provided in process step ic) according to this fourth variant of the process according to the invention may be, for example, silicone oils and their blends with hydrophobicized silica, or other defoaming compounds such as bisamides. Also may contain carrier materials in the defoamer which preferably have a granular structure and consist of water-soluble or water-dispersible, surfactant-free compounds, in particular of inorganic and / or organic salts, which are suitable for use in detergents and cleaners. Examples of water-soluble, inorganic support materials are in particular alkali metal carbonate, alkali metal borate, Alkalialumosilikat and / or alkali metal sulfate, while as organic support materials such as acetates, tartrates, succinates, citrates, carboxymethylsuccinates and the alkali metal salts of aminopolycarboxylic acids, such as EDTA, hydroxyalkane and Aminoalkanpolyphosphonate in question, such as 1 Hydroxyethane-1,1-diphosphonate, Ethylendiaminotetramethylenphosphonat and Diethylentriaminpentamethylenphosphonat can be used. The use of film-forming polymers, such as polyethylene glycols, Polyvinalalkoholen, polyvinylpyrrolidones, polyacrylates and cellulose derivatives as support materials is conceivable. The amount of such additives is usually not more than 25 wt .-%, based on the total weight of the organic composition. However, carrier materials can also be used in a significantly higher concentration.

• 5. Gemäß einer fünften Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionellen Komponente um ein Öl, vorzugsweise um einen Kohlenwasserstoff mit 20 bis 35 Kohlenstoffatomen (Schmieröl), und bei der organischen Zusammensetzung um eine Schmierstoffformulierung.

As an example of a defoamer, which can be prepared according to the fourth variant of the method according to the invention, be in WO 1997/034983 In particular, the disclosure of this document with respect to the method for producing an antifoam from the provided in the steps 1a, 1b and 1c) components in the sense of the method step ii) is hereby incorporated by reference and part of the disclosure of the present invention forms.

• 5. According to a fifth variant of the process according to the invention, the functional component is an oil, preferably a hydrocarbon having 20 to 35 carbon atoms (lubricating oil), and the organic composition is a lubricant formulation.

at the oil contained in the lubricant formulation can it is a raffinate, which by separation of the in oil naturally present hydrocarbons with 20 to 35 Carbon to obtain a hydrocracking oil (HC synthesis oil), which by cracking petroleum ingredients, the more have been obtained as 35 carbon atoms, or in order synthetic hydrocarbons, which by cracking act of petroleum constituents of less than 12 carbon atoms to gases such as ethene buten and the subsequent Synthesis of hydrocarbons with 20 to 35 carbon atoms obtained from these gases.

In addition to these oils, bio-oils obtained from renewable raw materials may also be present in the lubricant formulation, in particular bio-oils from the HETG, HEPG, HEPR or HEES group (VDMA 24568 ISO standard 15380 ) can be used. The HETG group includes triglycerides, such as rapeseed oil, while the HEPG group comprises polyglycols. The HEES group includes synthetic esters, in particular TMP esters (trimethylpropane esters, also called oleic esters or trioleate). The HEPR group includes liquids consisting mainly of polyalphaolefin (PAO) and related hydrocarbons.

The The amount of oil in the lubricant formulation is preferably in a range of 50 to 99 wt .-%, particularly preferably in one Range of 60 to 95 weight percent and most preferably in one range from 70 to 90 wt .-%, each based on the total weight of organic composition. However, if the lubricant formulation can also be used for cooling, it can also have large amounts of water, in which case the oil content in the lubricant formulation also clearly lie below the aforementioned concentration ranges can.

at this fifth variant of the invention Method, the n-nonyl ester is preferably in the function of Solvent or in the function of a surfactant added to the lubricant formulation, in which case it preferred is that the n-nonyl ester in an amount of 0.001 to 40 wt .-%, particularly preferably from 0.1 to 30 wt .-%, even more preferably from 1 to 20% by weight, and most preferably from 2 to 10 wt .-%, each based on the total weight of the organic Composition, is used.

• 6. Gemäß einer sechsten Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionellen Komponente um ein Farbmittel und bei der organischen Zusammensetzung um einen Lack oder um eine Farbe. Dabei wird unter einer „Farbe" im Sinne der vorliegenden Erfindung eine nicht glänzende, offenporige Beschichtung mit einem hohen Farbstoff- und Pigmentanteil, aber nur einen geringen Bindemittelgehalt verstanden, während unter einem „Lach" eine Zusammensetzung zum Beschichten von Oberflächen aus Holz, Metall, Kunststoff oder mineralischem Material verstanden wird, die im Vergleich zu einer Farbe einen höheren Bindemittelgehalt aufweist.

The additives which can be provided in process step ic) according to this fifth variant of the process according to the invention may be, in particular, surface-active, oil-improving or oil-protecting additives. Surface-active additives include detergents, dispersants, high-pressure or wear protection, corrosion and rust protection, and friction-changing additives. The oil-improving additives change the properties of the oil in terms of viscosity, pour point and elastomers, for example, seals. The oil-protecting additives cause aging protection of the oil, deactivating metal particles and preventing the oil from foaming. Even finely ground solids, such as Teflon (PTFE), ceramic oxides or molybdenum disulfide compounds can be added as an additive. If the lubricant composition is also to be used as a coolant, it may also be water in Amounts of up to 95% by weight, more preferably in amounts of up to 90% by weight, in which case the lubricant composition is preferably in the form of an emulsion.

• 6. According to a sixth variant of the method according to the invention, the functional component is a colorant and the organic composition is a lacquer or a color. For the purposes of the present invention, a "color" is understood to mean a non-shiny, open-pored coating with a high proportion of dye and pigment, but only a low binder content, while a "laugh" means a composition for coating surfaces of wood, metal, Plastic or mineral material is understood, which has a higher binder content compared to a color.

The colorant may be an inorganic or an organic colorant, which colorants may be water-soluble or water-insoluble. In particular, inorganic or organic, preferably powdered pigments are suitable. Pigments differ from dyes in that they are insoluble in their application media. Suitable inorganic pigments and their methods of preparation can G. Buxbaum; "Industrial Inorganic Pigments", 1st ed., Pp. 85-107; VCH Verlagsgesellschaft mbH, Weinheim, 1993 . G. Buxbaum; "Industrial Inorganic Pigments", 1st ed., Pp. 114-117; VCH Verlagsgesellschaft mbH, Weinheim, 1993 such as G. Buxbaum; "Industrial Inorganic Pigments", 1st ed., Pp. 124-131; VCH Verlagsgesellschaft mbH, Weinheim, 1993 be removed. The disclosure of these references relating to inorganic pigments is hereby incorporated by reference and forms part of the disclosure of the present invention. Suitable organic pigments and their method of preparation can in particular W. Herbst and K. Hunger; "Industrial Organic Pigments"; 2nd edition, pp. 4-11; VCH Verlagsgesellschaft mbH, Weinheim, 1995 . W. Herbst and K. Hunger; "Industrial Organic Pigments"; 2nd edition, p 462; VCH Verlagsgesellschaft mbH, Weinheim, 1995 . W. Herbst and K. Hunger; "Industrial Organic Pigments"; 2nd edition, pp. 482-485; VCH Verlagsgesellschaft mbH, Weinheim, 1995 . W. Herbst and K. Hunger; "Industrial Organic Pigment"; 2nd ed., P. 503; VCH Verlagsgesellschaft mbH, Weinheim, 1995 such as W. Herbst and K. Hunger; "Industrial Organic Pigments"; 2nd edition, pp. 567-569; VCH Verlagsgesellschaft mbH, Weinheim, 1995 be removed. Suitable classes of organic colorants (oriented on the main body of the colored structural unit) are nitroso, nitro, monoazo, disazo, trisazo, stilbene, diphenylmethane, triaryl methane, xanthene, acridine, quinoline, thiazole, Indamine, azine, oxazine, thiazine, lactone, phthalocyanine colorants called.

These Colorants can be used in varnish or in color in quantities a range of 0.001 to 40 wt .-%, particularly preferably in amounts in a range of 0.01 to 30 wt.%, more preferably in Amounts in a range of 0.01 to 30 wt .-% and most preferred in amounts ranging from 0.1 to 10% by weight, based in each case on the total weight of the organic composition.

at this sixth variant of the invention Method, the n-nonyl ester is preferably in the function of Solvent or in the function of a surfactant added to the paint or paint, in which case it is preferred that the n-nonyl ester in an amount of 0.001 to 40 wt .-%, especially preferably from 0.1 to 30% by weight, more preferably from 1 to 20 Wt .-% and most preferably from 2 to 10 wt .-%, each based on the total weight of the organic composition used becomes.

• 7. Gemäß einer siebten Variante des erfindungsgemäßen Verfahrens handelt es sich bei der funktionellen Komponente um eine Haar- oder Hautpflegesubstanz und bei der organischen Zusammensetzung um eine kosmetische Zubereitung.

The additives which can be provided in process step ic) according to this sixth variant of the process according to the invention may in particular be binders, such as vegetable oils, coniferous gum rosin, casein from milk, alkyd resin, polyurethane resin or epoxy resin, solvents, such as water , Ethanol, citrus peel oil, white spirit, water or glycol ethers, thixotropic agents, antioxidants, viscosity regulators, skin and foam inhibitors, leveling agents, UV absorbers, extenders, preservatives or binders. The amount of additives to be used can vary widely. This is especially true for the binder and solvent, depending on whether it is a paint or a color.

• 7. According to a seventh variant of the method according to the invention, the functional component is a hair or skin care substance and the organic composition is a cosmetic preparation.

Examples of hair and / or skin care substances are in particular 18-β-glycyrrhetinic acid from liquorice root extract (Gylcyrrhiza glabra), preferably in a purity of> 99% pure substance in the extract, aescin in horse chestnut (Aesculus hippocastanum), allantoin, aloe vera ( containing mainly sugars, anthraquinones and minerals such as zinc), amino acids such as alanine, arginine, serine, lysine, ammonium glycyrrhizate from licorice root extract, preferably in a purity of almost 100% pure in the extract, chamomile extract (Matricaria recutita) apigenin, Arnica, in particular Arnica montana or Arnica chamissonis, Asiaticoside and Madecassoside in the Cen tella asiatica extract, Avenaanthramide from oat extract (Avena sativa), avocadol, azulene from chamomile extract (Matricaria recutita), biotin (vitamin H), bisabolol from chamomile extract (Matricaria recutita), brown algae extract (Ascophyllum nodosum) , Chlorogenic acid in water extract of the Japanese honeysuckle (Lonicera japonica), coenzyme Q10, creatine, dexpanthenol, disodium glycyrrhizate from liquorice root extract, preferably in a purity of almost 100% pure substance in the extract, extract of red algae (Asparagopsis armata), birch flavonoids Extract (Betula alba), flavonoids, vitexin in the extract of passionflower (Passiflora incarnata), flavonoids, vitexin in linden extract (Tilia platyphyllos), ginkgo flavone glycosides and terpene lactones in ginkgo extract (Ginkgo biloba), ginsenosides in ginseng extract (Panax ginseng), glycogen, grapefruit extract, witch hazel extract from virgin witch hazel (hamamelis virgiana), honey, isoflavone glycosides in clover extract (Trifolium pratense), St. John's wort extract (Hypericum perforatum), jojoba oil, lecithin, corn oil (Zea mays), evening primrose oil, niacinamide, oenotheine B in willowherb (Epilobium angustifolium) extract, oleuropein in olive extract (Olea europea), phytocohesin (sodium beta -Sitosterolsulfat), plankton extract (Tetraselmis suecica, spirulina and others), polyphenols, catechins from the extract of grape seeds (Vitis vinifera), polyphenols, green tea catechins (Camellia sinensis), marigold extract (Calendula officinalis), rosmarinic acid in Melissa extract (Melissa officinalis), sandalwood oil, β-glucans from oats (Avena sativa), stearylglycyrrhetinic acid (stearyl ester of 18-β-beta glycyrrhetinic acid), sterols, sitosterol in stinging nettle extract (Urtica dioca), sweet almond oil (Prunus dulcis), Vitamin C and its esters, vitamin E and its esters, wheat germ oil zinc gluconate / magnesium aspartate / copper gluconate, as well as zinc sulfate or zinc oxide and proteins or protein derivatives, such as For example protein hydrolysates (for example collagen, keratin, silk protein or wheat protein hydrolysates) are mentioned.

These Hair and / or skin care substances can be used in the cosmetic Preparations in quantities ranging from 0.001 to 40% by weight, more preferably in amounts ranging from 0.01 to 30% by weight, even more preferably in amounts ranging from 0.01 to 30% by weight and most preferably in amounts ranging from 0.1 to 10 wt .-%, each based on the total weight of the organic Composition, be included.

at this seventh variant of the invention Method, the n-nonyl ester is preferably in the function of Solvent or in the function of a surfactant added to the cosmetic preparation, it being in this case preferred is that the n-nonyl ester in an amount of 0.001 to 40 wt .-%, particularly preferably from 0.1 to 30 wt .-%, even more preferably from 1 to 20% by weight, and most preferably from 2 to 10 wt .-%, each based on the total weight of the organic Composition, is used.

Suitable additives which can be provided according to this seventh variant of the process according to the invention in process step ic) are, for example Schrader, K., "Basics and Formulations of Cosmetics", 2nd edition, 1989, pages 728-737 . Domsch, A., "the cosmetic preparations", publishing house for chemical industry (H. Ziolkowsky, Ed.), 4. Edition, volume 2 sides 212-230, 1992 or Johnson, DH, "Hair and Hair Care," New York, 1997, pages 65-104 , refer to. The additives may be used in the usual amounts known to those skilled in the art, in particular in amounts of 0.1 to 10.0 wt .-%, based on the total weight of the organic composition.

• I) das Bereitstellen einer thermoplastischen Zusammensetzung, erhältlich nach dem vorstehend beschriebenen Verfahren gemäß der ersten Variante;
• II) das Erhitzen der thermoplastischen Zusammensetzung auf die Glasübergangstemperatur des thermoplastischen Polymers oder auf eine Temperatur oberhalb der Glasübergangstemperatur des thermoplastischen Polymers;
• III) die Herstellung eines Formkörpers aus der im Verfahrensschritt II) hergestellten, erhitzten, thermoplastischen Zusammensetzung.

A contribution to the solution of the abovementioned objects is also provided by a method for producing a shaped body, comprising the method steps:

• I) providing a thermoplastic composition obtainable by the above-described process according to the first variant;
• II) heating the thermoplastic composition to the glass transition temperature of the thermoplastic polymer or to a temperature above the glass transition temperature of the thermoplastic polymer;
• III) the production of a shaped article from the heated, thermoplastic composition prepared in process step II).

in the Step I) of the inventive method for Production of a molded article is first a Inventive thermoplastic composition provided, this provision preferably by a Process according to the first variant of the invention Procedure takes place.

Then, in process step II), the thermoplastic composition is heated to the glass transition temperature of the thermoplastic polymer or at a temperature above the glass transition temperature of the thermoplastic polymer. In this connection, it is again preferred that heating the thermoplastic composition to a temperature in a range of 5 degrees below the glass transition temperature (Tg) to 100 ° C above the glass transition temperature of the thermoplastic polymer used, more preferably to a temperature in a range of 1 degree below the glass transition temperature (Tg) to 50 ° C above the glass transition temperature of the thermoplastic polymer used, and most preferably to a temperature in a range of 1 degree above the glass transition temperature (Tg) to 20 ° C above the glass transition temperature of the thermoplastic polymer used, wherein However, here too the upper limit of the temperature range is essentially limited by the decomposition temperature of the thermoplastic polymer used.

in principle can process steps I) and II) at the same time or be carried out one behind the other. A simultaneous Implementation of method steps I) and II) is, for example then useful if the thermoplastic composition by means of a melt mixing process is produced. Here it may be be advantageous, which presented by the melt blending Herge To transfer composition directly into a shaped body. A successive implementation of the method steps I) and II) is useful, for example, if the thermoplastic Composition produced by a dry mixing process is or if the thermoplastic composition by means of a melt mixing process is prepared, but not immediately subjected after the formation of the formation of a shaped body is special rather first according to the Process step v) is cooled.

in the Process step III) of the process according to the invention for the production of a shaped body is from the in the process step II), heated thermoplastic composition Molded body. As a method for producing a Moldings are in particular the injection molding, extrusion molding, compression molding, layer forming, lamination molding, die forming, vacuum forming and Transfer forms into consideration, wherein the injection molding is particularly is preferred.

Farther it corresponds to an embodiment of the invention Process for producing a thermoplastic molding, that in at least one further process step IV) at least a partial region of the shaped body obtained in process step III) serves as a molding blank and in its mass cross-section is reduced compared to. At the mass cross section acts it is the cross section of a region of the molding, the solid from the thermoplastic invention Compound consists. For example, in containers or containers the mass cross section represents the thickness of a wall of these containers or container dar. In more thread-like or strand-shaped Moldings, the mass cross-section represents the thickness of these Threads or strands. For more flat Forms such as plates, layers, webs, films or foils represents the Mass cross section the strength of these flat structures dar. For the reduction of the mass cross section are basically all methods known and suitable to the person skilled in the art for this purpose. This includes, for example, stretching in one or two directions, Pulling in one or two directions, spinning or blowing, the each preferably at elevated temperatures, in which the inventive thermoplastic Composition so soft or even liquid is that one Stretching, pulling, spinning or blowing can be done. The subarea, in which the cross-sectional reduction is made preferably at least 50% and most preferably at least 80% of that in step III) obtained from. Generally this is done Stretching or drawing, if from the obtained in step III) shaped body Fiber is to be obtained. In the production of films can on the one hand the pulling or stretching in one or more dimensions respectively. Thus, the running of an extruder web with a higher compared to the exit velocity from the extruder Speed to be pulled on a roll. Should on the other hand a Containers or containers are received, so will except stretching, pulling and spinning, especially blowing in step IV) used. Here, the mass cross-section reduction takes place by applying a gas pressure. The gas pressure is generally like this chosen that the most at least on glass transition temperature heated thermoplastic composition of the product obtained in step III) Shaped body can be stretched. In general, the Elongation through the use of a final shape of the molding having Limited shape. So can be next to containers like Freezer boxes, trays and food packaging such as fruits, vegetables or meat and medicines as tablets, Capsules, suppositories or powders also containers for Make fluids. These liquid containers can be used alongside for cosmetic liquids or pharmaceutical industry in the food industry, preferably in the beverage industry also as reusable containers such as PET or PLA bottles. It still possible that two or more of the process steps I) to IV) by further Procedural steps are supplemented and / or at least temporally overlapping run. This applies in particular to the process steps III) and IV).

Farther can be inventively besides bottles also produce other shaped bodies. These include Ein- and Reusable containers, such as plates, bowls, pots or cups, and cutlery such as knives, forks or spoons. Especially are the biodegradable invention thermoplastic compositions for these applications.

• a) das Bereitstellen eines Gutes und eines Formkörpers, insbesondere einer Folie, wobei der Formkörper erhältlich ist durch das vorstehend beschriebene Verfahren;
• b) das mindestens teilweises Umgeben des Gutes mit dem Formkörper.

A contribution to the solution of the objects mentioned at the outset continues to be provided by a method for the production of a packaged good comprising as method steps:

• a) providing a good and a shaped body, in particular a film, wherein the shaped body is obtainable by the method described above;
• b) at least partially surrounding the goods with the molding.

at the material provided in process step a) is preferably a pharmaceutical, a personal care product, an agricultural aid, an adhesive, a building material, a dye or a food.

The at least partially surrounded of the goods, for example, by the in DE-A-103 56 769 described method carried out.

• A) das Bereitstellen einer durch Lebewesen verzehrbaren Substanz, beispielsweise eines Nahrungsmittels oder eines Arzneimittels, sowie eines n-Nonylesters, welcher erhältlich ist durch Reaktion einer n-Nonylalkohol-Komponente mit einer weiteren Komponente, welche mit der n-Nonylalkohol-Komponente unter Bildung eines n-Nonylesters zu reagieren vermag;
• B) das mindestens teilweises Umgeben der durch Lebewesen verzehrbaren Substanz mit dem n-Nonylester.

A contribution to the solution of the abovementioned objects is also provided by a method for coating substances which can be consumed by living beings, comprising as method steps:

• A) the provision of an organism-consumable substance, such as a food or a drug, and an n-nonyl ester, which is obtainable by reaction of an n-nonyl alcohol component with another component, which with the n-nonyl alcohol component to form a n-nonyl ester is able to react;
• B) at least partially surrounding the organism-consumable substance with the n-nonyl ester.

The Provision of the n-nonyl ester is preferably carried out according to the process step ia) of the initially described method for producing a organic composition.

The at least partially surrounding the substance consumable by living things With the n-nonyl ester, for example, take place such that the consumable substance and the n-nonyl ester in suitable mixing devices mixed with each other, in particular the Patterson-Kelley mixer, DRAIS turbulence mixer, Lödigemischer, Ruberg mixer, Screw mixer, plate mixer and fluidized bed mixer and continuously working vertical mixer, in which the polymer structure by means of rotating knife is mixed in fast frequency (Schugi mixer), be considered as mixing devices. Should the n-nonyl ester not be liquid at the mixing conditions, so this is Component before or during mixing with the by Subjects eatable substance to a temperature above the melting temperature to heat the n-nonyl ester. In addition to the use of the above The mixing devices described may at least partially surround the substance consumable by living things with the n-nonyl ester too be done by, for example, that consumable by living things Substance presented in a fluidized bed mixer and the n-nonyl ester in liquid form on the substance consumable by living beings is sprayed on.

• α) ein thermoplastisches Polymer, wobei die Zusammensetzung eine thermoplastische Zusammensetzung ist;
• β) ein Enzym, wobei die Zusammensetzung ein Waschmittel ist;
• γ) einen Abbinder eines Klebstoffes, wobei die Zusammensetzung ein Klebstoff ist;
• δ) ein Paraffin, wobei die Zusammensetzung ein Entschäumer ist;
• ε) ein Öl, wobei die Zusammensetzung eine Schmierstoffformulierung ist;
• ζ) ein Farbmittel, wobei die Zusammensetzung ein Lack oder eine Farbe ist; oder
• η) eine Haar- oder Hautpflegesubstanz, wobei die Zusammensetzung eine kosmetische Zubereitung ist,

wobei der n-Nonylester vorzugsweise durch das eingangs beschriebene Verfahren zur Herstellung eines n-Nonylesters, umfassend die Verfahrensschritte ia1), 1a2), 1a3) und gegebenenfalls 1a4), erhalten wurde.The use of at least one n-nonyl ester, which is obtainable by reacting an n-nonyl alcohol component with a further component which reacts with the n-nonyl alcohol component to form an n-nonyl ester, also contributes to the solution of the abovementioned objects capable of being included as an additive in a composition as a functional component

• α) a thermoplastic polymer, wherein the composition is a thermoplastic composition;
• β) an enzyme, the composition being a detergent;
• γ) a binder of an adhesive, the composition being an adhesive;
• δ) a paraffin, the composition being a defoamer;
• ε) an oil, the composition being a lubricant formulation;
• ζ) a colorant, the composition being a lacquer or a color; or
• η) a hair or skin care substance, the composition being a cosmetic preparation,

wherein the n-nonyl ester is preferably obtained by the process described above for the preparation of an n-nonyl ester, comprising the process steps ia1), 1a2), 1a3) and optionally 1a4).

The Invention will now be closer by way of non-limiting examples explained.

EXAMPLE 1: Preparation of oleic acid n-nonyl ester

31.6 g of pelargonic acid (0.2 mol, ^Emery® 1203) and 150 ml of methanol were placed in a glass flask and concentrated with 3 g of conc. Sulfuric acid added. The mixture was refluxed for 4 hours. Thereafter, 3.5 g of anhydrous sodium carbonate were added and the excess alcohol distilled off. The pelargonic acid methyl ester was distilled off in vacuo (p about 16 mbar) at 95-100 ° C.

29.2 g of the pelargonic acid methyl ester thus obtained was mixed with 6 wt .-% Kupferchromit-Kataly added and stirred in an autoclave at 230 ° C and a hydrogen pressure of 250 bar for 4 hours. Thereafter, the catalyst was filtered off and the filtrate distilled in vacuo. The boiling point was about 113 ° C at 26 mbar, the yield was 79%.

Of the approach described above for the preparation of n-nonanol was repeated several times.

346.9 g of the thus obtained n-nonanol and 421 g of technical oleic acid (EDENOR TiO5) were placed in a flask with distillation bridge submitted and mixed with 0.38 g of tin (II) oxalate (Fa. Fluka). The Reaction mixture became 150 ° C within 3 hours heated to 220 ° C. Thereafter, a vacuum was applied slowly and after a further 2 hours at 220 ° C (acid number the reaction mixture = 1.0) became the excess distilled off n-nonanol in vacuo. It was cooled to 90 ° C and filtered.

EXAMPLE 2: Preparation of stearic acid n-nonyl ester

It were 347 g of n-nonanol (prepared analogously to Example 1) and 409 g technical stearic acid (EDENOR ST1) in a flask with Stirred and submitted with 0.38 g of tin (II) oxalate (Company Fluka). The reaction mixture was within After that was heated for 3 hours from 150 ° C to 220 ° C slowly applied vacuum and after another 3 hours at 220 ° C. (Acid value of the reaction mixture = 0.5) was the excess distilled off n-nonanol in vacuo. It was cooled to 90 ° C and filtered.

EXAMPLE 3: Preparation of a thermoplastic composition

In A 15 kg Henschel mixer is charged with 6 kg of polyethylene terephthalate (PET SP04 from Catalana de Polimers). The mixed wall temperature was 40 ° C. Furthermore, 0.5 wt .-% of the example 2 n-nonyl ester prepared as Fromwennmittel added. Subsequently was the material on a granulator (ZSK 26Mcc) with plug screw granulated.

to Production of moldings from the thermoplastic composition was a fully hydraulic injection molding machine with a hydraulic clamping unit type Gattenfeld HM800 / 210 used. The maximum closing force is 800 kN, the screw diameter is 25 mm. As a trial tool a tool with a tapered, rectangular core was used. For the determination of the demolding force was a Kraftinessdose with a maximum measuring range of 2 kN attached to the ejector rod. The predrying of the molding compound was carried out at about 225 ° C. for about 4 hours. It was one opposite one Mold release-free molding significantly improved demoulding with the thermoplastic composition according to the invention observed.

EXAMPLE 4: Preparation of a detergent

0.2 ew .-% zinc ricinoleate (Tego ^® Sorb Conc 50 from Goldschmidt), 1 wt .-% of sodium citrate, 0.1 wt .-% of the compound obtained in Example 1 n-nonyl ester as defoamers, 1 wt .-% of boric acid, 7.5% by weight of glycerol, 1% by weight of ethanol, 4% by weight of C ₁₂ -C ₁₆ -alkyl glycoside, 8% by weight of soap, 8% by weight of C ₁₂ -C ₁₄ -fatty alcohol + 1.3 EO sulfate sodium salt, 1% by weight Acusol 120 (15%, methacrylic acid (stearyl alcohol-20-EO) ester-acrylic acid copolymer from Rohm & Haas), 0.5% by weight Dequest 2066, amylase, Protease and water were mixed to obtain a detergent.

EXAMPLE 5: Preparation of an adhesive

According to the teaching of DE-A-199 57 351 From a polypropylene glycol with Mn = 880 and diphenylmethane diisocyanate a high molecular weight diisocyanate was prepared, from which then the monomeric MDI was removed so far that a residual monomer content of 0.1% resulted. From 100 parts of a polyol mixture for a standard polyurethane hot melt adhesive (QR 6202, Henkel) with an average OH number of 32.5 and 76.5 parts of the above high molecular weight diisocyanate, a hot melt adhesive was prepared. In addition, 5% by weight of the n-nonyl ester prepared in Example 2 was added.

EXAMPLE 6: Preparation of defoamer

4.0 wt .-% paraffin with a solidification point after DIN ISO 2207 of 45 ° C, a liquid content at 40 ° C of about 66 wt .-% and a liquid content at 60 ° C of about 96 wt .-%, 1.2 wt .-% bisamide, 3 wt .-% sodium carbonate, 58 , 7 wt% sodium sulfate, 21.4 wt% sodium silicate, 2.1 wt% cellulose ether, 4.8 wt% of the n-nonyl ester obtained in Example 1, and water are mixed to form an aqueous slurry , which according to the method of European Patent EP 625 922 was spray-dried with superheated steam.

EXAMPLE 7: Preparation of defoamer on n-nonyl ester basis

1.2% by weight of bisamide, 3% by weight of sodium carbonate, 58.7% by weight of sodium sulfate, 21.4% by weight of sodium silicate, 2.1% by weight of cellulose ether, 8.8% by weight of the obtained in Example 1 n-nonyl ester and What This is mixed to form an aqueous slurry, which according to the method of European Patent EP-A-0 625 922 was spray-dried with superheated steam.

EXAMPLE 8: Preparation of a textile auxiliaries

To 995 g of a textile lubricant consisting of 78.5% by weight of i-butyl stearate, 5% by weight of oleyl / cetyl alcohol 5 mol of EO, 2.2% by weight of coconut fatty acid monoethanolamide 4 mol of EO, 0.8% by weight % Oleic acid, 6% by weight of the n-nonyl ester obtained in Example 2, 6% by weight of secondary fatty alcohol, 7 moles of EO (Tergitol 15S7, manufacturer: Union Carbide) and 1.5% by weight of water were added with stirring ( maximum stirring speed of an overhead stirrer with propeller stirrer) at 20 ° C 5 g of the according to Example 1b of DE-A-39 39 549 given polymer emulsion. After 30 seconds, the polymer emulsion had dispersed evenly and a clear solution had formed. Thereafter, the stirring speed was reduced as much as possible and the textile lubricant was heated to 60 ° C to accelerate the dissolution of the polymer particles.

EXAMPLE 9: Preparation of a varnish

Man mixed 736 g of demineralized water, 4 g of a 70 wt .-% solution of stearic acid isodecyl ester in C ₁₂ H ₂₆ (mixture of isomers), 10 g of sodium nitrobenzenesulfonate, 5 g of tetrasodium ethylenediaminetetraacetic acid, 100 g of urea, 25 g of sodium bicarbonate, 100 g of DI.1, 20 g of Fluorescent Brightener CI 230 submitted. 5 g of the n-nonyl ester obtained in Example 1 were added as a defoamer and stirred for 60 seconds with a high-speed stirrer at 2000 rpm.

EXAMPLE 10: Preparation of a Cosmetic formulation

• – 5,0 g der in der EP-A-1 485 061 mit der Formel (I) gekennzeichneten Verbindungen, in der R' für Methyl und R jeweils für eine Butyloctanoyl-Rest (C₁₂) steht,
• – 5,0 g Emulgator Dioctylether (Cetiol OE, Firma Cognis),
• – 0,6 g Emulgator Cetylstearylalkohol + 20-EO (Eumulgin B2, Firma Cognis),
• – 0,1 g Creatin.

An O / W emulsion was prepared whose oil phases had the following composition:

• - 5.0 g in the EP-A-1 485 061 compounds of the formula (I) in which R 'is methyl and R is in each case a butyloctanoyl radical (C ₁₂ ),
• 5.0 g of emulsifier dioctyl ether (Cetiol OE, Cognis),
• 0.6 g of emulsifier cetylstearyl alcohol + 20 EO (Eumulgin B2, Cognis),
• - 0.1 g creatine.

Of the The composition thus obtained was 5% by weight of that in Example 1 n-nonyl ester obtained.

EXAMPLE 11: Preparation of Boron Mulling

It became a conventional Kalkspülung from 7.6 g prehydrated bentonite, 1.15 g ferrochromolignosulfonate, 2.3 g slaked lime, 0.38 g starch and 0.76 g NaOH. This Kalkspülung were 5 wt .-% of the obtained in Example 1 n-nonyl ester added.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

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• - DE 10070770 C [0015]
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• WO 1997/034983 A [0067]
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Cited non-patent literature

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• - W. Herbst and K. Hunger; "Industrial Organic Pigment"; 2nd edition, page 503; VCH Verlagsgesellschaft mbH, Weinheim, 1995 [0073]
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• Johnson, DH, Hair and Hair Care, New York, 1997, pp. 65-104 [0080]
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Claims (20)

Process for the preparation of an organic composition, which is a functional component selected from Group consisting of a thermoplastic polymer, an enzyme, a binder, a paraffin, an oil, a colorant and a hair or skin care substance, including as process steps: i) providing ia) one n-nonyl ester as an additive, which is available through Reaction of an n-nonyl alcohol component with another component, which with the n-nonyl alcohol component to form an n-nonyl ester to be able to react, ib) the functional component, as well possibly ic) at least one further additive; ii) the mixing of the n-nonyl ester, the functional component and optionally the at least one further additive. The method of claim 1, wherein the further Component, which with the n-nonyl alcohol component to form a n-nonyl ester, a mono-, di-, tri-, Tetra- or polycarboxylic acid with more than four carboxyl groups, a derivative such a carboxylic acid or a mixture from such a carboxylic acid and a derivative thereof Carboxylic acid is. The method of claim 2, wherein the carboxylic acid is selected from the group consisting of adipic acid, Trimellitic acid, terephthalic acid and azelaic acid or a mixture of at least two of them. The method according to one of the preceding claims, wherein the additive is in an amount ranging from 0.001 to 40 wt .-%, based on the composition is used. The method according to one of the preceding claims, wherein the n-nonyl alcohol component to at least 80 wt .-%, based to the n-nonyl alcohol component, obtained from pelargonic acid becomes. The method of claim 5, wherein the pelargonic acid is obtained from oleic acid. The process of any one of the preceding claims, wherein the n-nonyl alcohol component contains less than 10% by weight, based on the n-nonyl alcohol component, C ₈ and C ₁₀ alcohols. The method according to one of the preceding claims, wherein the n-nonyl ester is an alkoxylated n-nonyl ester with 2 to 30 ether repeating units. The method according to one of the preceding claims, wherein the functional component is a thermoplastic polymer is and as a composition of a thermoplastic composition is obtained. A method for producing a shaped body, including the process steps: I) providing a thermoplastic composition obtainable by the method according to claim 9; II) heating the thermoplastic composition to the glass transition temperature of the thermoplastic polymer or at a temperature above the glass transition temperature the thermoplastic polymer; III) Preparation of a molded article from the heated, thermoplastic produced in process step II) Composition. The method of claim 10, wherein in another Process step IV) at least a portion of the in process step III) obtained in its mass cross-section compared with process step III) is reduced. The method according to one of claims 10 or 11, wherein the shaped body is selected from a Group consisting of a container, a foil, a Fiber or at least two of them. A method for producing a packaged goods containing as process steps: a) the provision of goods and a shaped article obtainable by a process according to any one of claims 10 to 12; b) the at least partially surrounding the goods with the molding. A method of coating by living things edible substances, including as process steps: A) the provision of a substance consumable by living things as well as an n-nonyl ester which is obtainable by reaction an n-nonyl alcohol component with another component which with the n-nonyl alcohol component to form an n-nonyl ester to be able to react; B) at least partially surrounding the organism-consumable substance with the n-nonyl ester. Use of at least one n-nonyl ester obtainable by reacting an n-nonyl alcohol component with another component which is capable of reacting with the n-nonyl alcohol component to form an n-nonyl ester as an additive in a composition comprising as a functional component α) a thermoplastic polymer, wherein the Zusam composition is a thermoplastic composition; β) an enzyme, the composition being a detergent; γ) a binder of an adhesive, the composition being an adhesive; δ) a paraffin, the composition being a defoamer; ε) an oil, the composition being a lubricant formulation; ζ) a colorant, the composition being a lacquer or a color; or η) a hair or skin care substance, wherein the composition is a cosmetic preparation. The use of claim 15, wherein the additive in an amount in a range of 0.001 to 40 wt .-%, based on the composition, is used. The use according to claim 15 or 16, wherein the n-nonyl alcohol component to at least 80 wt .-%, based on the n-nonyl alcohol component, is obtained from pelargonic acid. The use of claim 17, wherein the pelargonic acid is obtained from oleic acid. The use according to any one of claims 15 to 18, wherein the n-nonyl alcohol component contains less than 10% by weight, based on the n-nonyl alcohol component, of C ₈ or C ₁₀ alcohols. The use according to any one of claims 15 to 19, wherein the n-nonyl ester is an alkoxylated n-nonyl ester with 2 to 30 ether repeat units.