DE102007035622B4 - Lid for a furnace for receiving molten metal, in particular metal, and furnace for receiving molten material - Google Patents

Abstract

Cover (1) for a furnace (10) for receiving molten material (S), in particular metal, with at least one layer (4, 4 '') formed of a material, the coefficient of thermal conductivity of which is greater than that of steel, the cover having a the inner cover surface (3) facing the melt (S) and the outer cover surface (2) facing away from the melt (S) and the layer (4, 4 '') closer to the inner cover surface (3) than to the outer cover surface (2 ), wherein a surface (4 ') of the at least one layer (4, 4' ') at least partially forms an inner cover surface (3), wherein the material forming the layer (4, 4' ') is copper, characterized in that the copper is applied by plating to a lid base (5) and the entire inner lid surface (3) is formed by the copper layer.

Description

The invention relates to a lid for a furnace for receiving molten metal, in particular metal, and a furnace for receiving molten material, in particular metal, with a crucible which can be filled with melted material and with a lid for closing the crucible.

In the production or processing, especially post-treatment, of steel, it is usually necessary to convert the steel by heating in a liquid phase. Due to the high melting point of metal in general, high temperatures are associated with it. Therefore, appropriate crucibles and possibly lids were developed for this temperature regime.

The lid is usually removable from a crucible and is used during melting of the steel for the restraint and targeted removal of gases resulting from the melting process, as well as for the effective utilization of the supplied melting energy. The cover prevents a large part of the energy supplied from escaping upwards unused.

Such lids and crucibles are generally used in electric arc furnaces for the production of molten metals and ladle furnaces, generally for the aftertreatment of molten metals. A lid for an electric arc furnace generally comprises at least one central opening for the introduction of graphite electrodes and a peripheral opening provided with a suction system for removing gases, volatile burned-on parts and powders.

The present invention addresses a problem encountered in handling molten metals. Here, for example, crude steel is post-treated such that a desired alloy composition of the steel is set within narrow limits. Part of the aftertreatment of this crude steel is the addition of aggregates in the molten steel, which sometimes cause violent reactions of the melt. These violent reactions of the liquid steel to the aggregates produce splashes or drops of liquid metal which leave the melt. These splashes meet u. a. also on the lid of the oven.

Such problems are also known in the production of molten metal by arc furnace. Here, a flushing process is performed in the electric arc furnace to equalize the temperature of the metal bath. Through the interaction of this rinsing process with one or more arcs or arcs present in the arc furnace, processes also occur which cause splashes or drops of liquid metal to leave the metal bath. These also get u. a. to the lid of the arc furnace.

The splashes of liquid metal on the lid cool off on the inner surface of the oven lid. They weld with the furnace lid and bake firmly against the inner wall of the furnace lid. The process that splashes or drops of liquid metal get to the inner wall of the furnace lid, is - as described above - not uncommon when dealing with molten metal. Therefore, there is an increase of the caking on the inside of the furnace lid by further splashes or drops from the molten metal. At some point, these caking reaches a level that interferes with the process management for the production of the steel. In particular, these lead to problems when opening and closing the furnace in the supply of new metal.

A cooled cover for electric arc furnaces or ladle furnaces, which has this problem is, for example, from the European patent specification EP 1 062 469 B1 known.

The DE 4235662 A1 describes a heat or arc protection on wall and lid cooling elements for electric arc furnaces. It is on pipes, reversing flaps and sheets made of steel an overlay welding of good thermal conductivity and not or only partially magnetic material, eg. As copper, applied to prevent cracking of the wall and lid cooling elements.

The invention has for its object to provide a lid for a furnace for receiving molten material and a furnace for receiving melt, in which such caking can be reduced or avoided altogether.

The object is achieved with a cover of the type mentioned above in that the cover has at least one layer formed of a material whose heat conduction coefficient is greater than that of steel, wherein the cover has an inner lid surface facing the molten material and an outer ceiling surface facing away from the molten material and the layer is disposed closer to the inner lid surface than to the outer lid surface, wherein a surface of the at least one layer at least partially forms an inner lid surface, wherein the material forming the layer is copper, and wherein the copper is applied to a lid body by plating and the entire inner lid surface is formed by the copper layer.

By thermal conductivity, also called thermal conductivity, a material constant is understood to mean the unit W / Km, which is usually given for solids at 20 ° C. Preferably, the layer has a thermal conductivity coefficient greater than 100 W / Km. For example, aluminum would be suitable for this purpose. The layer can also be composed of several partial layers, wherein at least one partial layer according to the invention has a thermal conductivity coefficient which is greater than that of steel. The layer can be arranged arbitrarily on or within the lid or even form the entire lid.

The inventive design of the lid ensures that the heat from the liquid metal splashes, which reach the inner lid surface, is dissipated faster. Ideally, the heat removal from the liquid metal splash, which has reached the inner lid surface, takes place so rapidly by means of the layer according to the invention that welding of the metal drop to the inner lid surface is completely avoided.

The positive effect of reducing the welding of the metal drop with the inner lid surface already occurs when the lid has a layer of a material whose heat conduction coefficient is larger than that of steel. However, it is preferable to use a material which not only has a heat conduction coefficient larger than that of steel, but also has the property that metal spatters from the molten metal are poorly adhered to this material. As a result, on the one hand the heat is dissipated quickly from the metal droplets and thus prevents welding of the droplet with the inner lid surface, on the other hand, the metal drops are easy to remove from the layer or fall during cooling possibly even for the day - such as by the influence of gravity and / or Shakes of the furnace - from. However, it is already sufficient that the lid has a layer having a heat conduction coefficient larger than that of steel. As a result, the baking to the inner lid surface can already be reduced and possibly completely prevented.

Steel usually has a coefficient of thermal conductivity of 40 to 60 W / Km, depending on its composition. Thus, to improve the dissipation of thermal energy from the inner lid surface to the outer lid surface, any material which has a higher coefficient of thermal conductivity than steel is suitable.

In particular, it is advantageous that the thermal conductivity coefficient of the material is greater than that of steel, at least in a certain temperature range, preferably in a specific temperature range which occurs when handling molten metal melts, in particular in a temperature range of approximately 1100 ° C. (degrees Celsius). ) up to 1500 ° C.

The lid has an inner lid surface facing the molten material and an outer lid surface facing away from the molten material, wherein the layer is disposed closer to the inner lid surface than to the outer lid surface. The closer the material is placed to the inner lid surface with the higher coefficient of thermal conductivity over steel, the faster the heat can be dissipated from the liquid metal spatter. By arranging the at least one layer within the lid or on the lid, the thermal property and thus the heat dissipation behavior of the lid can be improved.

A surface of the at least one layer at least partially forms the inner lid surface. By means of such an arrangement, the thermal energy exhibited by the liquid metal splash is removed as quickly as possible from the metal splash. This leaves the least time for a possible welding process between metal drops and inner lid surface. As a result, the best possible result is generally achieved with regard to the prevention of caking.

The material forming the layer is applied to a lid body by plating. The plating may be done during the furnace lid manufacturing process. Alternatively, this can also be carried out for furnace cover already in operation. In this respect, the advantages of the invention can also be made available later for already running plants. As plating is referred to in metalworking the application of a higher quality - in the present case, the higher valence in the higher coefficient of thermal conductivity - metal layer on another material, usually also metal. In this case, the most insoluble possible connection between the metal layer and the underlying and / or overlying material is created. The connection between the material and the metal is achieved by temperature and pressure. Practically, the plating is implemented by a variety of techniques, such. B. by rolling metal foils on a metal body or by welding, casting, dipping, blasting or electroplating process. Nowadays, plating is done mostly by roll-welding plating.

The material forming the layer is copper here. Copper can be through, for example Apply plating very well to steel. Further, copper has a heat conduction coefficient which is about 8 times greater than that of steel, ie, about 400 W / Km. In addition, liquid metal drops of steel have poor adhesive properties on copper. Copper can therefore be used particularly advantageously as a layer or plate to prevent caking of liquid metal splashes on an inner lid surface. Preferably, the lid has a layer of a material whose heat conduction coefficient is substantially not less than that of copper.

Advantageously, to avoid caking of liquid metal splashes on the inner lid surface of the lid can also be used a layer which consists of a material which is formed as a ductile metallic, in particular nickel-containing, matrix with embedded hard material particles, in particular carbon nanotubes. This layer also has a high and widely adjustable thermal conductivity or a high heat transfer coefficient. Among other things, the thermal property of the material or of the layer depends on which material is used as matrix and on the type and proportion of the hard material particles used in the layer. In particular, it is advantageous to use a nickel-containing matrix with embedded carbon nanotubes. Here, the thermal conductivity of the layer can be adjusted by adjusting the concentration of Carbonnanotubes in the matrix over a wide range and thus the thermal properties. In addition, this material has a high mechanical and thermal resistance and is therefore well suited for use in a high temperature region, such as occurs in the production of steel.

In an advantageous embodiment of the invention, the inner lid surface is at least partially cylindrical and / or conical. These are particularly easy to produce forms for the inner lid surface. In particular, a conical cover surface has the advantage that due to the conical shape of the inner cover surface, the metal drops sprayed onto this part of the inner cover surface are easier to detach. Because here usually a larger force component acts perpendicular to the inner lid surface than in a cylindrically shaped lid surface. In the latter case, the lid surface is usually oriented parallel to the weight force acting on the metal drop.

It is particularly advantageous if the inner cover surface is at least partially smooth. Ie. At least in some sections, there are no structures on the inner cover surface which allow metal drops to settle there and deposit them permanently. A substantially smooth lid surface thus helps to prevent caking by the metal drops striking the inner lid surface find as little support as possible to deposit there. As a result, an automatic drop of the metal drops striking the inner lid surface can be improved. This is particularly important for furnace lid in pipe-gap-pipe construction. In this case, it is advantageous to use iron pipes which compensate the topographical structures of the pipe-gap-pipe construction in such a way that the inner cover surface is at least partially substantially smooth. In addition, a layer according to the invention can be deposited. Also, the tubes used may be made of a material whose thermal conductivity coefficient is greater than that of steel, and preferably not smaller than that of copper.

In a further advantageous embodiment, the lid has a wall thickness between 8 mm and 16 mm. In particular, in a combination of a conventional cover made of steel in conjunction with a layer of a material with a higher thermal conductivity of steel, the heat dissipation from the interior of the furnace is limited by the wall thickness, in particular by the wall thickness of the steel portion of the lid. Due to different thermal material constants of the material used and the steel, there is a different temperature of steel and material. This is particularly problematic at the interface between the material used and the steel. Because here, due to the temperature difference, the formation of stresses can occur, which can cause the steel layer to come off the material layer or plate. Since the introduced into the top wall heat output by the metal bath when handling molten metal can be influenced only slightly, limited by the temperature differences thermal stresses at the interface the usable wall thickness. The temperature differences are, however, caused by the respective thicknesses of the steel used and the material used. A faultless operation for existing in metal baths heat outputs of the lid, d. H. Avoiding the degeneration of the interface between the lid body and the material can be ensured only for a top wall thickness which is between 5 mm and 20 mm, preferably between 8 mm and 16 mm.

In an advantageous embodiment of the invention, the lid has a cooling device for discharging heat coupled into the inner lid surface. By means of this cooling device, it is possible to remove the heat carried out from the metal bath. It is to Make sure that the cooling device is designed such that sufficient for the cooling of the lid heat output can be dissipated. In particular, the cooling device can be formed as a closed water cooling device, which is advantageously traversed by water, which has a flow velocity of at least 3 m / s. Such a selected flow rate within the closed water cooling device allows sufficient dissipation of heat energy.

Alternatively or in combination, the cooling device can also be designed as a spray water cooling device. In this case, the outer lid surface is sprayed by appropriately distributed nozzles with spray water to ensure the heat dissipation. Also advantageously, a cooling device designed as a surge water cooling device can be provided. From this preferably occurs water at a flow rate of at least 3 m / s. This meets the outer lid surface and is then derived from this.

By said cooling means can be ensured that for the caking further reducing cooling provides a sufficiently large heat dissipation. Ie. the heat dissipated by the metal drops through the layer is dissipated as quickly as possible to the cooling device. As a result, a large temperature difference between the inner lid surface and cooling device remains, so that an efficient heat dissipation is ensured.

The object underlying the invention is also achieved by a furnace of the type mentioned, wherein the lid and / or crucible have a layer formed from a material, the heat transfer coefficient is greater than that of steel. In this case, the said to claim 1 applies in an analogous manner. Due to the improved heat dissipation for lid and oven, there is no welding of metal splashes from the melt with the respective furnace limitations. The caking is thus reduced or avoided and thus the disadvantages occurring in this context.

In an advantageous embodiment of the invention, the lid and crucible have a common closing surface and the layer is arranged in the region of the closing surface on the lid and / or crucible. In this case, it is ensured, in particular in the critical region of the closing surface, that no or only a reduced amount of caking is produced, which can cause problems when opening and closing the lid. Stove stops to remove the caking are thereby reduced or eliminated completely.

In an advantageous embodiment of the invention, a surface of the layer at least partially forms the inner lid surface and / or crucible surface. As a result, it is ensured in a particularly advantageous manner that both the furnace side and the cover side a fastest possible removal of heat from striking the respective inner surfaces metal splashes is possible. The welding of metal drops with the respective inner surface is avoided. In particular, this makes it possible for the splashes to automatically fall back from the inner crucible surface and / or inner cover surface into the metal bath.

In a preferred embodiment of the invention, the furnace comprises a cooling device for cooling the furnace. This ensures that the heat which has been improved by means of the layer is removed from the interior of the crucible efficiently, for example, from the outer lid surface and / or outer crucible surface. The cooling device for the furnace can be designed analogously to the statements already made above.

Further advantages of the invention will become apparent from the following embodiments, which are explained in more detail with reference to the schematic drawings. Show it:

1 a schematic cross-sectional view of a furnace with lid and crucible and layer applied thereto,

2 possible layer arrangements for the lid or crucible,

3 a lid for a ladle furnace in pipe-gap-pipe construction with layer according to the invention.

1 shows a cross-sectional view of a furnace 10 , The oven 10 has a lid 1 as well as a crucible 11 on. The oven 10 is shown in the closed state, ie cover 1 and crucibles 11 form a closed volume. In the crucible 11 molten melt S is present. The melt S is formed as molten steel. Above the liquid steel is a slag S '. Furthermore, metal drops emerging from the steel bath are shown. These meet at least partially an inner surface 13 respectively. 3 of the crucible 11 or the lid 1 , That would be the oven 10 in 1 formed in accordance with the prior art, which would be on the inner surface 13 respectively. 3 of the crucible 11 or the lid 1 striking metal drops at the respective position with the inner surface 3 of the crucible 11 or the lid 1 weld. It would be difficult to remove metallic caking, which in time with weight and increase in volume. If the caking exceeds a certain extent or a certain limit mass or certain extent, then it is necessary to remove these caking with great effort. However, this is at the in 1 not shown required arrangement.

The lid 1 includes an outer lid surface 2 and an inner lid surface 3 , Furthermore, the lid shows 1 a lid body 5 on. On the lid body 5 a copper cladding is applied. The copper cladding is in 1 with the reference number 4 Mistake. The copper cladding has a surface facing the melt S 4 ' on. This forms sections of the inner surface 3 of the lid 1 , The copper cladding is smooth and has a heat transfer coefficient of about 400 W / Km.

The copper plating ensures that when metal drops from the melt S on the copper plating 4 Meet, this dissipates the heat from the metal drop so quickly that no welding process between the inner lid surface 3 and metal drops occur. In addition, one points to the copper cladding 4 struck metal drops only a slight adhesion to the copper cladding 4 on. The cooled metal drop then hangs relatively loosely on the copper plating 4 and usually falls off on cooling off. However, this is at least due to a avoided welding process between the inner lid surface 3 and a metal drop easily removable.

To dissipate the heat dissipated from the metal drop as quickly as possible, has the lid 1 a cooling device 7 on. The cooling device 7 includes one in the lid 1 built multi-chamber system, which is traversed by coolant, especially water. The flow rate of the water is more than 3 m / s in the exemplary embodiment. Due to such a high flow rate, the heat dissipated from the metal drops can be sufficiently fast through the cooling device 7 be dissipated. Furthermore, the in 1 illustrated lid 1 a wall thickness 6 which is 12 mm. In this wall thickness, not shown spray water cooling or splash water cooling can be provided, which the outer lid surface 2 Cools from above. Furthermore, the oven can 10 one in 1 not shown cooling device for the crucible 11 exhibit. For copper plating 4 on the inner crucible surface 13 the design is analogous to the execution of the copper cladding 4 on the inner lid surface 1 possible.

Between lid 1 and crucibles 11 is the closing area 12 arranged. This refers to the contact surface of the lid 1 and crucibles 11 in the closed state. At least in the area, ie near, the closing surface 12 it is convenient, the copper-plated layer 4 for lids 1 and crucibles 11 each on the inner surface 3 respectively. 13 provided. This ensures that there is always a simple opening and closing of the oven 10 remains possible. In particular, it comes in the area of the closing surface 12 through the copper plating 4 not to a caking of metal drops, which causes the opening and closing of the oven 10 not hindered.

Preferably, contrary to the illustration in FIG 1 no horizontal projection of the closing surface 12 in the oven interior available. Either this supernatant is chamfered and then goes over, for example, a vertical wall section of the crucible. As a result, deposition of metal drops on a horizontal projection is avoided. The metal drops can simply be returned to the melt S by means of the bevel. Alternatively it can be provided that in order to avoid deposits of metal drops on a projection of the closing surface 12 the cover-side closing surface and the crucible-side closing surface are substantially exactly overlapping each other in their dimensions.

To prevent the caking by metal drops ejected from the melt, it is also possible to provide a layer system with a plurality of layers, in particular a multiple plating. Preferably, at least a majority of the layers used have a thermal conductivity greater than that of steel, and in particular not less than that of copper. Preferably, the layers are arranged in a multi-layer system such that, at an interface of the partial layers within a layer system, in each case that layer has the higher thermal coefficient, which is arranged closer to the interior of the furnace.

The representation of the gas suction devices, the aggregate addition devices and the electrodes was in 1 omitted, since these are not essential to the present invention.

By the in 1 shown arrangement of a copper plate 4 on a lid body 5 as well as on a crucible body 11 ' It is possible, the caking of leaked from the melt S metal drops on the inner surfaces 3 respectively. 13 from lid 1 and crucibles 11 to avoid. If the entire inner lid surface 3 of the lid 1 plated by means of copper, so that at no point the inner surface 3 of the lid 1 Caking occurs.

Furthermore, it is particularly advantageous to have such copper claddings 4 also at least in the area of the closing surface 12 for the crucible 11 provided. It can then only caking close - depending on the extent of copper plating 4 - form on the melt surface. However, these hinder the melting or conditioning process of the melt S usually insignificant.

2 shows a variety of possibilities, such as a layer 4 for a lid 1 or a crucible 11 can be arranged so that the heat dissipation from an inner surface 3 to an outer surface 2 can be improved. The case that the layer 4 forms the entire lid or crucible is not shown here. However, this possibility is not excluded, but it will probably rarely be used due to cost reasons.

The layer arrangements are associated with a lid body 5 described, but are not limited to a lid body. Rather, these are analogous to for crucible body 11 applicable.

The two left-lying segments of the 2 show a layer 4 with a higher coefficient of thermal conductivity than steel on a lid body 5 , A section of the layer surface 4 ' at the same time forms the inner surface 3 of the lid or crucible.

In the middle segment 5 a layer is shown by the lid body 5 is enclosed. Will the thickness of the lid body 5 , which of the inner surface 3 facing, kept low, so here is a significant improvement in heat dissipation towards the outer surface 3 given.

The second from the right-lying segment has a lid body 5 on which partially the outer surface 2 forms. Towards the inner surface 3 closes a first layer 4 and a second layer 4 '' at. The layers 4 and 4 '' lie one above the other, adjacent to each other and may have a same coefficient of thermal conductivity or a different coefficient of thermal conductivity. These layers 4 . 4 '' can therefore be formed in particular from different materials. However, preferably, both materials have a coefficient of thermal conductivity greater than that of steel, and preferably not less than that of copper. Alternatively, different layers can also be arranged next to each other, so that the respective layer has the best possible thermal properties and / or adhesion properties for a certain area within the lid or crucible and, if necessary, a cost reduction in the provision of the lid and / or crucible can be achieved.

In particular, it is advantageous if the first layer 4 and the second layer 4 '' have different optical properties, in particular in the visible spectral range. This makes it possible to easily identify when the first layer is worn and possibly re-accumulated with caking. In such a case, then a renewal of the worn layer can be provided. This principle is also transferable to a multilayer system.

In the far right segment of the 2 is another possible arrangement of the layer 4 played. Here is the layer 4 at least partially the outer surface 2 whereas the lid body 5 at least partially forms the inner surface. Depending on the thicknesses used, all of these can be found in the in 2 Layer segments shown shown segments can be used.

3 shows a lid 1 for an electric arc furnace in pipe-gap-pipe construction. The lid 1 has a cylindrically shaped part and a conical part. The conical part of the lid can be assigned an angle of inclination α. The shell portion surface of the conical part of the lid 1 is through pipes 7 and 8th educated. These are the pipes 7 around cooling tubes, in which water to cool the lid 1 to be led. Between the cooling pipes 7 are iron pipes 8th arranged, which ensure that through the pipes 7 and 8th formed inner lid surface is formed as smooth as possible. This ensures that metal drops due to the structure of the inner surface due to the pipe-gap-pipe construction 3 in the conical part of the lid 1 deposit to a reduced extent.

On this pipe construction of the conical part of the lid is in 3 no layer, in particular copper cladding, applied, which prevents caking of metal droplets or syringes from the melt. However, this may differ from the in 3 shown embodiment, in order to use the advantages of the invention for this cover part. In addition, by using a thicker copper plating for the inner surface of the in 3 shown conical lid part, the structure of the inner lid surface 3 be further smoothed.

The cylindrical part of the lid 1 consists of a lid body 5 , which is traversed by cooling chambers through which cooling water flows, and which part of a cooling device 7 are. The inner surface 3 the cylindrical part of the lid 1 is through a surface 4 ' a copper plate 4 educated. This extends in particular into the area around the closing surface 12 , As a result, a caking of metal particles in the vicinity of the closing surface 12 prevents, whereby the opening and closing of the oven or the removal and placement of the lid 1 on the crucible can be difficult.

Claims (13)

Cover ( 1 ) for a furnace ( 10 ) for receiving molten material (S), in particular metal, with at least one layer formed from a material ( 4 . 4 '' ), the heat conduction coefficient of which is greater than that of steel, wherein the cover has an inner cover surface facing the melt (S) ( 3 ) and the melt (S) facing away from the outer lid surface ( 2 ) and the layer ( 4 . 4 '' ) closer to the inner lid surface ( 3 ) than on the outer lid surface ( 2 ), wherein a surface ( 4 ' ) of the at least one layer ( 4 . 4 '' ) at least in sections an inner lid surface ( 3 ), wherein the layer ( 4 . 4 '' ) forming material is copper, characterized in that the copper by plating on a lid body ( 5 ) is applied and the entire inner lid surface ( 3 ) is formed by the copper layer. Lid according to claim 1, characterized in that the inner lid surface ( 3 ) is at least partially smooth. Lid according to claim 1 or 2, characterized in that the inner lid surface ( 3 ) is at least partially cylindrical and / or conical. Lid according to one of claims 1 to 3, characterized by a wall thickness ( 6 ) between 8 mm and 16 mm. Lid according to one of claims 1 to 4, characterized by a cooling device ( 7 ) for discharging into the inner lid surface ( 3 ) coupled heat. Lid according to claim 5, characterized in that the cooling device ( 7 ) is designed as a closed water cooling device, in particular a forced circulation cooling device. Lid according to claim 5, characterized in that the cooling device ( 7 ) is designed as a spray water cooling device. Lid according to claim 5, characterized in that the cooling device ( 7 ) designed as a surge water cooling device. Lid according to claim 8, characterized in that the outlet flow speed of the water emerging from the surge water cooling device is at least 3 m / s. Oven ( 10 ) for receiving molten material (S), in particular metal, with a crucible (S) fillable crucible ( 11 ) and with a lid ( 1 ) according to one of claims 1 to 9 for closing the crucible ( 11 ). Oven according to claim 10, characterized in that the crucible is a layer formed of a material ( 4 . 4 '' ), whose heat conduction coefficient is greater than that of steel. Oven according to claim 11, characterized in that cover ( 1 ) and crucibles ( 11 ) a common closing surface ( 12 ) and the layer ( 4 . 4 '' ) in the area of the closing surface ( 12 ) on lid ( 1 ) and / or crucibles ( 11 ) is arranged. Oven according to one of claims 10 to 12, characterized by a cooling device ( 7 ) for cooling the furnace ( 10 ).

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