DE1000992B - Process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances - Google Patents

Process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances

Info

Publication number
DE1000992B
DE1000992B DEC11609A DEC0011609A DE1000992B DE 1000992 B DE1000992 B DE 1000992B DE C11609 A DEC11609 A DE C11609A DE C0011609 A DEC0011609 A DE C0011609A DE 1000992 B DE1000992 B DE 1000992B
Authority
DE
Germany
Prior art keywords
rubber
chlorosulfonated polyethylene
substances
production
composite bodies
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEC11609A
Other languages
German (de)
Inventor
Helmut Prante
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Continental AG
Original Assignee
Continental Gummi Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Gummi Werke AG filed Critical Continental Gummi Werke AG
Priority to DEC11609A priority Critical patent/DE1000992B/en
Publication of DE1000992B publication Critical patent/DE1000992B/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Description

Verfahren zur Herstellung von Verbundkörpern aus chlorsulfoniertem Polyäthylen und Kautschuk oder kautschukähnlichen Stoffen Die Erfindung betrifft ein Verfahren zur Herstellung von Verbundkörpern aus chlorsulfoniertem Polyäthylen und Kautschuk oder kautschukähnlichen Stoffen, die insbesondere für Fußboden- oder Wandbeläge Verwendung finden. Process for the production of composite bodies from chlorosulfonated Polyethylene and rubber or rubber-like materials The invention relates to a process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances, especially for flooring or Find wall coverings use.

Beim Verbinden von Mischungen, die chlorsulfoniertes Polyäthylen enthalten, mit Kautschukmischungen mittels Vulkanisation erhält man häufig infolge des abgesättigten Charakters des Polyäthylens eine schlechte oder keine gegenseitige Haftfestigkeit der beiden Schichten. When joining blends containing chlorosulfonated polyethylene contain, with rubber mixtures by means of vulcanization one often obtains as a result the saturated character of polyethylene is bad or not mutual Adhesion strength of the two layers.

Es wurde nun gefunden, daß sich eine einwandfreie Haftung von chlorsulfoniertem Polyäthylen am Kautschuk oder kautschukähnlichen Stoffen erzielen läßt, wenn der Mischung mit chlorsulfoniertem Polyäthylen Benzoesäure und/oder Salicylsäure zugesetzt wird und sodann die beiden Schichten zusammenvulkanisiert werden. Im allgemeinen wird man Benzoesäure der Verwendung von Salicylsäure vorziehen, weil bei Anwendung der Benzoesäure bessere Ergebnisse hinsichtlich der Haftfestigkeit erhalten werden. Als Kautschukmischungen können beliebige natürliche oder synthetische Kautschukarten verwendet werden. Zur Hersltellung von schwer brennbaren Fußboden- und Wandbelägen, wie sie beispielsweise für den Schiffsbau oder in bestimmten handwerklichen oder industriellen Betrieben in Frage kommen, wird man solchen Mischungen, die auf 2-Chlorbutadien-Kautschuk aufgebaut sind, den Vorzug geben, weil sie schwer brennbar sind. Diese Mischungen haben ferner den Vorteil, daß sie sich von den übrigen Kautschukmischungen durch eine besonders gute Haftfestigkeit an dem chlorsulfonierten Polyäthylen auszeichnen. Aus preislichen Gründen verwendet man hierbei ein Regenerat von 2-Chlorbutadien-Kautschuk. Durch den Aufbau dieser Verbundkörper wird es möglich, diese ohne Schwierigkeinen fortlaufend auf einer automatischen Vulkan;isationsmaschine zu vulkanisieren und eine aiisgezeichnetze Haftfähigkeit zwischen den beiden elastomeren Schichten zu erzielen. It has now been found that proper adhesion of chlorosulfonated Polyethylene on rubber or rubber-like substances can be achieved if the Mixture with chlorosulfonated polyethylene, benzoic acid and / or salicylic acid added and then the two layers are vulcanized together. In general Benzoic acid will be preferred to salicylic acid because of its application of benzoic acid, better results in terms of adhesive strength can be obtained. Any natural or synthetic types of rubber can be used as rubber mixtures be used. For the production of flame-retardant floor and wall coverings, as they are for example for shipbuilding or in certain craft or industrial plants come into question, one will get such mixtures based on 2-chlorobutadiene rubber should be preferred because they are flame-retardant. These mixes also have the advantage that they stand out from the rest of the rubber compounds a particularly good adhesive strength to the chlorosulfonated polyethylene. For reasons of price, a regenerated 2-chlorobutadiene rubber is used here. The construction of these composites makes it possible to do so without difficulty to vulcanize and continuously on an automatic vulcanizing machine an indicated adhesiveness between the two elastomeric layers achieve.

PATENTANSPROCHE 1. Verfahren zur Herstellung von Verbundkörpern aus chlorsulfoniertem Polyäthylen und Kautschuk oder kautschukähnlichen Stoffen, insbesondere für Fußboden- oder Wandbeläge, dadurch gekennzeichnet, daß der Mischung, die chlorsulfoniertes Polyäthylen enthält, Benzoesäure und/oder Salicylsäure zugesetzt wird und daß die beiden Schichten anschließend zusammenvulkanisiert werden. PATENT CLAIM 1. Process for producing composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances, in particular for floor or wall coverings, characterized in that the mixture, the chlorosulfonated Contains polyethylene, benzoic acid and / or salicylic acid is added and that the both layers are then vulcanized together.

Claims (1)

2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß als Kautschukmischung eine solche aus einem Regenerat von 2-Chlorbutadien-Kautschuk verwendet wird. 2. The method according to claim 1, characterized in that the rubber mixture one made from a regenerated 2-chlorobutadiene rubber is used.
DEC11609A 1955-07-27 1955-07-27 Process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances Pending DE1000992B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEC11609A DE1000992B (en) 1955-07-27 1955-07-27 Process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC11609A DE1000992B (en) 1955-07-27 1955-07-27 Process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances

Publications (1)

Publication Number Publication Date
DE1000992B true DE1000992B (en) 1957-01-17

Family

ID=7015022

Family Applications (1)

Application Number Title Priority Date Filing Date
DEC11609A Pending DE1000992B (en) 1955-07-27 1955-07-27 Process for the production of composite bodies from chlorosulfonated polyethylene and rubber or rubber-like substances

Country Status (1)

Country Link
DE (1) DE1000992B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3342789A (en) * 1962-07-31 1967-09-19 Exxon Research Engineering Co Composition comprising chlorinated butyl rubber and a curing system
FR2537106A1 (en) * 1982-08-20 1984-06-08 Dunlop Ltd IMPROVED CARRIER BELT

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3342789A (en) * 1962-07-31 1967-09-19 Exxon Research Engineering Co Composition comprising chlorinated butyl rubber and a curing system
FR2537106A1 (en) * 1982-08-20 1984-06-08 Dunlop Ltd IMPROVED CARRIER BELT

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