DD294635A5 - CLEANING, ODOR-RELATED AND CLEANING AGENTS FOR MOBILE TOILET FACILITIES - Google Patents
CLEANING, ODOR-RELATED AND CLEANING AGENTS FOR MOBILE TOILET FACILITIES Download PDFInfo
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- DD294635A5 DD294635A5 DD34097390A DD34097390A DD294635A5 DD 294635 A5 DD294635 A5 DD 294635A5 DD 34097390 A DD34097390 A DD 34097390A DD 34097390 A DD34097390 A DD 34097390A DD 294635 A5 DD294635 A5 DD 294635A5
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- cleaning
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- mobile toilet
- quaternary ammonium
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- 238000004140 cleaning Methods 0.000 title description 12
- 239000012459 cleaning agent Substances 0.000 title description 2
- VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 10
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims abstract description 9
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 8
- VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical compound NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 6
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 claims abstract description 5
- WWJLCYHYLZZXBE-UHFFFAOYSA-N 5-chloro-1,3-dihydroindol-2-one Chemical compound ClC1=CC=C2NC(=O)CC2=C1 WWJLCYHYLZZXBE-UHFFFAOYSA-N 0.000 claims abstract description 4
- KGEKLUUHTZCSIP-UHFFFAOYSA-N Isobornyl acetate Natural products C1CC2(C)C(OC(=O)C)CC1C2(C)C KGEKLUUHTZCSIP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001940 [(1R,4S,6R)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Substances 0.000 claims abstract description 4
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 4
- 229940116411 terpineol Drugs 0.000 claims abstract description 4
- 239000001716 (4-methyl-1-propan-2-yl-1-cyclohex-2-enyl) acetate Substances 0.000 claims abstract description 3
- -1 alkali metal chlorate Chemical class 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- 238000009434 installation Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002304 perfume Substances 0.000 abstract description 5
- 239000003513 alkali Substances 0.000 abstract description 4
- 239000000975 dye Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 4
- 239000002562 thickening agent Substances 0.000 abstract description 3
- 238000004332 deodorization Methods 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 239000000645 desinfectant Substances 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 229960000686 benzalkonium chloride Drugs 0.000 description 4
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002855 microbicide agent Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Natural products CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical class Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 231100001228 moderately toxic Toxicity 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229940070805 p-chloro-m-cresol Drugs 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 231100001068 severe skin irritation Toxicity 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Die Erfindung betrifft Mittel fuer mobile Toilettenanlagen, welche aus einer Kombination aus Chloracetamid, einer mikrobizid wirksamen quaternaeren Ammoniumverbindung, Alkalichlorat, Terpinol, Terpineol und/oder Isobornylacetat, eines nichtionogenen Tensids, eines Gemisches aus Mono- und Dialkylpolyglykolphosphonsaeureester und Wasser, gegebenenfalls Farbstoffen, Parfuemoelen und/oder Verdickungsmitteln bestehen. Die erfindungsgemaeszen Mittel eruebrigen eine mechanische Zerkleinerung und weisen verbesserte Anwendungseigenschaften hinsichtlich der Nebenwirkungen beim individuellen Einsatz auf.{Mittel; mobile Toilettenanlagen; Chloracetamid; quaternaere Ammoniumverbindung; Alkalichlorat; Terpinol; nichtionogenes Tensid; Tensidgemisch}The invention relates to means for mobile toilet facilities, which consists of a combination of chloroacetamide, a microbicidally active quaternary ammonium compound, alkali chlorate, terpinol, terpineol and / or isobornyl acetate, a nonionic surfactant, a mixture of mono- and Dialkylpolyglykolphosphonsaeureester and water, optionally dyes, perfume oils and / or thickeners exist. The compositions according to the invention eliminate mechanical comminution and have improved application properties with regard to side effects in individual use. mobile toilet facilities; chloroacetamide; quaternary ammonium compound; alkali chlorate; terpinol; nonionic surfactant; surfactant mixture}
Description
1Γ0 OiI η = 16 bis 181Γ0 OiI η = 16 to 18
m = 7 bis 9m = 7 to 9
Ιί2 = E1 , KΙί 2 = E 1 , K
im Verhältnis 3:1 bis 1:3 (Phosphortensid) und Wasser, gegebenenfalls darüber hinaus Hilfsstoffen wie Farbstoffen, Parfümölen und/oder Verdickungsmitteln, bestehen.in the ratio of 3: 1 to 1: 3 (phosphorus surfactant) and water, optionally further excipients such as dyes, perfume oils and / or thickeners exist.
Anwendungsgebiet der ErfindungField of application of the invention
Die Erfindung betrifft neue keimreduzierende, geruchstilgende und reinigende Mittel für mobile Toilettenanlagen, welche erst nach mehreren Stunden bzw. Tagen in das öffentliche Abwassernetz entleert werden.The invention relates to novel germ-reducing, odor-controlling and cleaning agent for mobile toilet facilities, which are emptied only after several hours or days in the public sewer network.
Charakteristik des bekannten Standes der TechnikCharacteristic of the known state of the art
Zur Beseitigung von Fäkalien in mobilen Toilettenanlagen sind verschiedene Verfahren bekannt, die auf physikalischen Grundoperationen bzw. der Anwendung chemischer Mittel basieren.For disposal of feces in mobile toilet facilities, various methods are known which are based on basic physical operations or the application of chemical agents.
In der DE-PS 2406311 wird beispielsweise eine mobile Toilettenanlage mit einem luftdichtverschließbaren Fäkalienbehälter beschrieben, in dem mittels Vakuum die Flüssigkeit aus den Exkrementen entweder bei Normaltemperatur oder durch Erwärmen verdampft wird. Eine weitere Methode besteht im Verbrennen der Exkremente mittels einer Heizspirale und dem Ableiten der Verbrennungsgase über eine Filteranlage durch ein Gebläse ins Freie, wie sie in der DE-OS 3014244 beschrieben wird.In DE-PS 2406311, for example, a mobile toilet system is described with an airtight sealable Fäkalienbehälter in which by means of vacuum, the liquid is evaporated from the excrement either at normal temperature or by heating. Another method consists in burning the excrement by means of a heating coil and the discharge of the combustion gases through a filter system by a blower into the open, as described in DE-OS 3014244.
Diese Verfahren haben den Nachteil, daß sie technisch aufwendig und mit einem erheblichen Energieeinsatz verbunden sind, wodurch ihre Anwendbarkeit in Wohnwagen, Haus- und Segelbooten erheblich eingeschränkt ist.These methods have the disadvantage that they are technically complex and associated with a significant use of energy, whereby their applicability in caravans, houseboats and sailboats is considerably limited.
Günstigere Lösungsvarianten bestehen in einer Kombination von physikalischen Methoden und chemischen Mitteln.Cheaper solutions exist in a combination of physical methods and chemical agents.
In der US-PS 3374490 wird beispielsweise eine Toilettenanlage mit Auffangbehälter beschrieben, in den ein. Desinfektionsmittel dosiert wird und eine mechanische Zerkleinerung erfolgt.In US-PS 3374490, for example, a toilet system is described with a collecting container in the one. Disinfectant is metered and a mechanical comminution takes place.
Zur Verwendung in chemischen Desinfektionsmitteln sind verschiedene mikrobizide Wirkstoffe und Wirksto'!kombinationen bekannt.Various microbicidal agents and Wirksto '! Combinations are known for use in chemical disinfectants.
Neben Chlor, Chlorabspaltern, Phenolen und dessen Derivaten, Aldehyden, wie beispielsweise Formaldehyd und Formaldehydabspaltern, ist der Einsatz von Alkoholen, Sauerstoffabspaltern, wie Peressigsäure, sowie oberflächenaktiven Verbindungen, wie quaternären Ammoniumverbindungen und amphoteren Tensiden, prinzipiell möglich (K. H. Wallhäuser, „Sterilisation, Desinfektion und Konservierung", 2.Aufl. 1978, S.337ff.).In addition to chlorine, chlorine donors, phenols and its derivatives, aldehydes, such as formaldehyde and Formaldehydabspaltern, the use of alcohols, Sauerstoffabspaltern, such as peracetic acid, and surface-active compounds, such as quaternary ammonium compounds and amphoteric surfactants, in principle possible (KH Wallhäuser, "sterilization, disinfection and Conservation ", 2nd edition 1978, p.337ff.).
In der DE-OS 3815456 sind desinfizierende Mittel zur Oxydation, Entkeimung und Desodorierung beschrieben, deren Wirkung auf einer Mischung aus Chlorlösung und Chloroxiden bzw. deren Salzen beruht.In DE-OS 3815456 disinfecting agent for oxidation, sterilization and deodorization are described, the effect of which is based on a mixture of chlorine solution and chlorine oxides or their salts.
Zur Anwendung in Stuhldesinfektionsmitteln ist jedoch die Wirkstoffauswahl auf Grund der spezifischen Wirkbedingungen begrenzt. Für derartige Einsatzfälle werden als mikrobizide Wirkstoffe Chlor, Chlorabspalter, Phenole und Phenolderivate und Aldehyde verwendet. Desinfektionsmittel auf der Basis ven Phenolen, Phenolderivaten und Aldehyden besitzen ein breites mikrobizides Wirkungsspektrum, sind jedoch mit allergisierenden, geruchsbelästigenden und toxischen Nebenwirkungen beiFor use in stool disinfectants, however, the choice of active ingredient is limited due to the specific conditions of action. For such applications are used as microbicidal agents chlorine, chlorine, phenols and phenol derivatives and aldehydes. Disinfectants based on phenols, phenol derivatives and aldehydes have a broad microbicidal spectrum of activity but are associated with allergenic, offensive and toxic side effects
ihrer Anwendung verbunden, was ihren Gebrauch insbesondere bei der individuellen Anwendung durch Nichtfachleute ,their use, especially their use by non-professionals,
einschränkt.limits.
Quartäre Ammoniumverbindungen und Amphotenside besitzen erhebliche Wirkungslücken, und ihre Wirksamkeit nimmt in Kontakt mit Eiweißen und organischen Stoffen aller Art stark ab. Sie sind deshalb zur alleinigen Anwendung nicht geeignet und werden meist in Kombination mit Aldehyden verwendet, die die bereits beschriebenen Nachteile besitzen.Quaternary ammonium compounds and amphoteric surfactants have significant gaps in their effectiveness, and their effectiveness decreases sharply in contact with proteins and organic substances of all kinds. They are therefore not suitable for sole use and are usually used in combination with aldehydes which possess the disadvantages already described.
Eine weitere Möglichkeit zur Behandlung von Abwässern ausToilettenanlagen ohne zwingende mechanische Zerkleinerung der Fäkalien wird in der DE-OS 1517711 beschrieben, nach eier dem Abwasser zur Aufspaltung von Zellulosesubstanz Ätzkali zugesetzt wird. Dieser Zusatz bewirkt jedoch nur eine begrenzte Keimreduzierung und Geruchstilgung. Außerdem besteht die Gefahr der Korrosion und Verätzung.Another way to treat wastewater from toilet facilities without compulsory mechanical comminution of feces is described in DE-OS 1517711, after eggs the wastewater for the decomposition of cellulose substance caustic potash is added. However, this additive causes only a limited germ reduction and odor removal. There is also the risk of corrosion and corrosion.
Ziel der ErfindungObject of the invention
Ziel der Erfindung sind hochwirksame keimreduzierende und geruchstilgende Mittel mit spezifischer Reinigungswirkung für mobile Toilettenanlagen, welche eine mechanische Zerkleinerung erübrigen sowie verbesserte Anwendungseigenschaften hinsichtlich der Nebenwirkungen beim individuellen Einsatz aufweisen.The aim of the invention are highly effective germ-reducing and odor-controlling agents with specific cleaning action for mobile toilet facilities, which eliminate the need for mechanical comminution and have improved application properties with regard to the side effects in individual use.
Darlegung des Wesens der ErfindungExplanation of the essence of the invention
Der Erfindung liegt die Aufgabe zugrunde, keimreduzierende und geruchstilgende Mittel mit spezifischer Reinigungswirkung auf der Basis einer Kombination aus mikrobiziden Wirkstoffen, fäkalienverflüssigenden sowie reinigenden Substanzen zu entwickeln.The invention has for its object to develop germ-reducing and odor-controlling agent with specific cleaning action on the basis of a combination of microbicidal agents, fäkalienverflüssigenden and cleaning substances.
Erfindungsgemäß wird die Aufgabe gelöst durch eine Kombination ausAccording to the invention the object is achieved by a combination of
2 bis 6 Gewichtsanteilen in % Chloracetamid2 to 6 parts by weight in% chloroacetamide
6 bis 14 Gewichtsanteilen in % einer mikrobizid wirksamen quaternären Ammoniumverbindung mit der Grundstruktur der n-Alkyldimethyl-benzyl-ammoniumchloride6 to 14 parts by weight in% of a microbicidally active quaternary ammonium compound having the basic structure of the n-alkyldimethylbenzylammonium chlorides
0,2 bis 2 Gewichtsanteilen in % Alkalichlorat0.2 to 2 parts by weight in% alkali chlorate
2 bis 6 Gewichtsanteilen in % Terpinol, Terpineol und/oder Isobornylacetat2 to 6 parts by weight in% terpinol, terpineol and / or isobornyl acetate
0,3 bis 3 Gewichtsanteilen in % eines nichtionogenen Tensids aus der Gruppe der Polyoxyethylen-Addukte 0,1 bis 1 Gewichtsanteilen in % eines Gemisches aus Mono- und Dialkylpolyglykolphosphonsäureester der Formel0.3 to 3 parts by weight in% of a nonionic surfactant from the group of polyoxyethylene adducts 0.1 to 1 parts by weight in% of a mixture of mono- and Dialkylpolyglykolphosphonsäureester of the formula
R1O 0 m"R 1 O 0 m "
p 2ηΛ1βp 2ηΛ1β
E2O X0H n = 1β bis 18 E 2 O X 0H n = 1β to 18
m = 7 bis 9 ρ -im = 7 to 9 ρ -i
P, = R , IIP, = R, II
im Verhältnis 3:1 bis 1:3 (Phosphortensid).in the ratio 3: 1 to 1: 3 (phosphorus surfactant).
Gegebenenfalls werden Hilfsstoffe wie beispielsweise Farbstoffe, Parfürnöle und/oder Verdickungsmittel zugefügt. Der Restanteil ist Wasser. Als quaternäre Ammoniumverbindungen der angegebenen Grundstruktur (Quat) eignen sich beispielsweise Dimethylbenzylalkylammoniumchlorid mit Alkyl = C11 bis C14 (Benzalkoniumchlorid) und Dimethylbenzylacetamidododecylammoniumchlorid(Methalkoniumchlorid).Optionally, adjuvants such as dyes, perfumes and / or thickening agents are added. The remainder is water. Suitable quaternary ammonium compounds of the stated basic structure (quat) are, for example, dimethylbenzylalkylammonium chloride with alkyl = C 11 to C 14 (benzalkonium chloride) and dimethylbenzylacetamidododecylammonium chloride (methalconium chloride).
Als Alkalichlorat ist Natrium- bzw. Kaliumchlorat einsetzbar. Aus der Gruppe der Polyoxyethylen-Addukte werden vorzugsweise Alkylphenylpolyoxyethylenoxid-Addukte mit Alkyl = C8 bis Cu und 6 bis 15EO-Einheiten sowie oxethylierte Fettalkoholgemische der Kettenlänge C9 bis Ct8 mit 8 bis 15EO-Einheiten verwendet.As alkali chlorate sodium or potassium chlorate can be used. From the group of polyoxyethylene adducts preferably Alkylphenylpolyoxyethylenoxid adducts with alkyl = C 8 to Cu and 6 to 15EO units and ethoxylated fatty alcohol mixtures of chain length C 9 to Ct 8 are used with 8 to 15EO units.
Die erfindungsgemäßen Mittel ermöglichen bereits in geringen Konzentrationen die gewünschte Kombination von Wirkungen.The agents according to the invention enable the desired combination of effects even at low concentrations.
Sie gewährleisten eine hohe keimreduzierende, geruchstilgende und oberflächenreinigende Wirkung sowie eine ausreichende Zersetzung der Exkremente in einem Zeitraum von 24 bis 96 Stunden mit geringen toxikologischen bzw. ökotoxikologischen Nebeneffekten, wobei diese Eigenschaften die Wirkung der Einzelkomponenten beträchtlich übertreffen, was für das Vorliegen eines synergistischen Effektes durch die erfindungsgemäße Kombination spricht.They ensure a high germ-reducing, odor-controlling and surface-cleaning effect and a sufficient decomposition of the excrements in a period of 24 to 96 hours with low toxicological or ecotoxicological side effects, these properties considerably exceed the effect of the individual components, indicating the presence of a synergistic effect the combination according to the invention speaks.
Die Anwendung kann in Mengen von 20 bis 200ml der erfindungsgemäßen Kombination auf einen 10-l-Toilettenbehälter erfolgen, wobei Verdünnungen der o.g. Mengen auf 500 bis 1000ml Wasser empfohlen werden.The application may be made in amounts of 20 to 200 ml of the combination of the invention to a 10-liter toilet bowl, with dilutions of the o.g. Quantities to 500 to 1000ml of water are recommended.
Ausführungsbeispieleembodiments
Zusammenstellung der Vergleichsprodukte und der erfindungsgemäßen MittelCompilation of the comparison products and the agents according to the invention
Tabelle 1: bekannte Vergleichsprodukte VTable 1: known comparative products V
Nr. WirkstoffkombinationNo combination of active ingredients
V1 Formaldehyd (30%ig)V1 formaldehyde (30%)
V 2 Glutaraldehyd(20%ig) V3 p-Chlor-m-kresol (20%ig) V4 Benzalkoniumchlorid (15%ig)V 2 glutaraldehyde (20%) V3 p-chloro-m-cresol (20%) V4 benzalkonium chloride (15%)
V 5 Chloracetamid (6%ig)V 5 chloroacetamide (6%)
V6 Chloracetamid/Benzalkoniumchlorid (im Gewichtsverhältnis 1.-2,5; 20%ig)V6 chloroacetamide / benzalkonium chloride (in weight ratio 1.-2.5, 20%)
Die Vergleichsmuster enthalten neben dem Wirkstoff übliche Hilfsstoffe wie Tenside, Lösungsvermittler, Parfümöle und Wasser. Tabelle 2: erfindungsgemäße Mittel EThe comparison samples contain, in addition to the active ingredient, customary auxiliaries, such as surfactants, solubilizers, perfume oils and water. Table 2: Compositions E of the invention
C A BenzalkoniumchloridC A benzalkonium chloride
Q £ MethalkoniumchloridQ £ methalconium chloride
TE & TerpinolTE & terpinol
T = TerpineolT = terpineol
I & IsobornylacetatI & isobornyl acetate
K & KaliumchloratK & potassium chlorate
N = NatriumnitratN = sodium nitrate
A & AIkYl-(C8 bis C13)-phenylpolyoxyethylenoxidaddukt mit 6 bis 15EO-EinheitenA & AIkYl- (C 8 to C 13 ) -phenylpolyoxyethylenoxidaddukt with 6 to 15EO units
F £ oxethyliertes Fettalkoholgemisch mit C9 bis C18 mit 8 bis 15 EO-EinheitenAcetoxyated fatty alcohol mixture with C 9 to C 18 with 8 to 15 EO units
Die Mengenangaben sind in Gewichtsanteilen in %.The quantities are in parts by weight in%.
Die Mittel enthalten neben den angegebenen Wirkstoffen Hilfsstoffe wie Farbstoffe und Parfümöle und Wasser.The agents contain adjuvants such as dyes and perfume oils and water in addition to the specified active ingredients.
Beispiel 2 Prüfung der WirksamkeitExample 2 Testing the effectiveness
Die Prüfung erfolgt praxisanalog, indem eine bestimmte Präparatmenge der Vergleichs- bzw. erfindungsgemäßen Mittel (gemäß Beispiel 1) in einen 1-l-Behälter gegeben wird. Danach wurde mit 100ml H2O verdünnt und 500ml Exkremente dazugegeben. Der Erfolg der Behandlung wurde nach 96 Stundan beurteilt.The test is carried out in a manner similar to practice by placing a specific amount of the comparative or inventive compositions (according to Example 1) in a 1 liter container. Then it was diluted with 100ml H 2 O and 500ml excrement added. The success of the treatment was assessed after 96 hours.
Beurteilt werden der Keimgehalt, die Desodorierung sowie hinsichtlich der Reinigungswirkung die Verflüssigung des Inhaltes und die Reinigung von Oberflächen.The bacterial content, the deodorization and, with regard to the cleaning effect, the liquefaction of the contents and the cleaning of surfaces are assessed.
Keimgehalt: 0 = keine oder geringe KeimreduzierungGerm content: 0 = no or little germ reduction
1 = deutliche Keimreduzierung1 = significant germ reduction
2 = ausreichende Keimreduzierung2 = sufficient germ reduction
3 = sehr gute Keimreduzierung Desodorierung: 0= keine Desodorierung3 = very good germ reduction deodorization: 0 = no deodorization
1 = geringe Desodorierung1 = low deodorization
2 = befriedigende Desodorierung2 = satisfactory deodorization
3 = gute Desodorierung Verflüssigung des Inhaltes: 0 = keine Verflüssigung3 = good deodorization Liquefaction of the contents: 0 = no liquefaction
1 = teilweise Verflüssigung1 = partial liquefaction
2 = befriedigende Verflüssigung Reinigung von Oberflächen: 0 = keine Reinigung2 = satisfactory liquefaction Cleaning of surfaces: 0 = no cleaning
1 = befriedigende Reinigung1 = satisfactory cleaning
2 = gute Reinigung2 = good cleaning
Beispiel 3: Ergebnisse der WirksamkeitExample 3: Results of the efficacy
menge gehalt rierung des Inhaltes von Oberflächenamount of content of surfaces
(ml)(Ml)
1 = gering toxisch1 = low toxicity
2 = mittelmäßig toxisch2 = moderately toxic
3 = toxisch Hautverträglichkeit: 0 = keine Hautschäden3 = toxic Skin compatibility: 0 = no skin damage
1 = leichte Hautreizung1 = slight skin irritation
2 = mittelmäßige Hautreizung2 = mediocre skin irritation
3 = starke Hautreizung Geruchsbelästigung: 0 — nichtoderkaum belästigend3 = severe skin irritation Odor nuisance: 0 - non-odor annoying
1 = leicht belästigend1 = slightly annoying
2 = mittelmäßig belästigend2 = moderately annoying
3 = starkbelästigend3 = very annoying
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD34097390A DD294635A5 (en) | 1990-05-25 | 1990-05-25 | CLEANING, ODOR-RELATED AND CLEANING AGENTS FOR MOBILE TOILET FACILITIES |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD34097390A DD294635A5 (en) | 1990-05-25 | 1990-05-25 | CLEANING, ODOR-RELATED AND CLEANING AGENTS FOR MOBILE TOILET FACILITIES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD294635A5 true DD294635A5 (en) | 1991-10-10 |
Family
ID=5618700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD34097390A DD294635A5 (en) | 1990-05-25 | 1990-05-25 | CLEANING, ODOR-RELATED AND CLEANING AGENTS FOR MOBILE TOILET FACILITIES |
Country Status (1)
| Country | Link |
|---|---|
| DD (1) | DD294635A5 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2727289A1 (en) * | 1994-11-30 | 1996-05-31 | Derives Resiniques Terpenique | DISINFECTING COMPOSITION CONSISTING OF AT LEAST ONE TERPENIC ALCOHOL AND AT LEAST ONE BACTERICIDAL ACID SURFACTANT, AND USE OF SUCH SURFACTANTS |
| GB2317563A (en) * | 1996-09-26 | 1998-04-01 | Peter Jowett | Herbicidal and algicidal composition comprising a thickened aqueous solution of a herbicidal chlorate |
| EP1083214A3 (en) * | 1999-08-11 | 2003-05-21 | drom fragrances international KG | Composition, especially suitable for toilet freshener |
-
1990
- 1990-05-25 DD DD34097390A patent/DD294635A5/en not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2727289A1 (en) * | 1994-11-30 | 1996-05-31 | Derives Resiniques Terpenique | DISINFECTING COMPOSITION CONSISTING OF AT LEAST ONE TERPENIC ALCOHOL AND AT LEAST ONE BACTERICIDAL ACID SURFACTANT, AND USE OF SUCH SURFACTANTS |
| WO1996016548A1 (en) * | 1994-11-30 | 1996-06-06 | Action Pin | Disinfecting or antiseptic composition including at least one terpene alcohol and at least one bactericidal acidic surfactant, and use thereof |
| GB2317563A (en) * | 1996-09-26 | 1998-04-01 | Peter Jowett | Herbicidal and algicidal composition comprising a thickened aqueous solution of a herbicidal chlorate |
| EP1083214A3 (en) * | 1999-08-11 | 2003-05-21 | drom fragrances international KG | Composition, especially suitable for toilet freshener |
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| Date | Code | Title | Description |
|---|---|---|---|
| A5 | Published as prov. exclusive patent | ||
| ENJ | Ceased due to non-payment of renewal fee |