CZ45796A3

CZ45796A3 - Hair care preparation

Info

Publication number: CZ45796A3
Application number: CZ96457A
Authority: CZ
Inventors: Jorg Kahre; Kurt Seidel; Winfried Emmerling; Joachim Kurt Foitzik
Original assignee: Henkel Kgaa
Priority date: 1993-08-19
Filing date: 1994-08-10
Publication date: 1996-07-17
Also published as: EP0714287A1; WO1995005157A1; JPH09501663A; DE4327700A1; PL313079A1

Abstract

Described are hair-treatment agents designed to remain on the hair, the agents being improved in many respects by virtue of the fact that they contain an additional component consisting of alkyl polyglycosides. Particularly worthy of mention are their hair-fixing and stabilizing properties.

Description

BACKGROUND OF THE INVENTION Hair care is an important part of human body care. There are a number of different uses for this. For hair washing, this is usually done with aqueous surfactants containing rinsing agents, which are rinsed off after a short period of exposure to hair and scalp. Rinsing agents are mainly used to improve hair properties by other hair care methods; also these resources o1 · " 1-remain on the hair only for a short time and then rinse. Also, permanent hair dyeing and hair styling are methods of hair care in which, after a period of action, usually within about 30 minutes, the corresponding hair is removed from the hair by rinsing.

In contrast, many other hair care products remain. Such compositions are, for example, 2o-hair sprays to strengthen the hair, hair hardeners, hair gels, and hair gels to temporarily shape the hair, and hair lotions. Many publications disclose the use of non-ionic surfactants of the 25 alkylpolyglycoside type in hair care compositions. EP 337 354, EP 398 177, EP 502 304 and EP 504 791 are examples of these. However, these publications only disclose hair care compositions such as shampoos, rinse agents and sustained formulations which, after a short period of action rinse. However, it is not pointed out in any of these publications that the beneficial effects of alkylpolyglycosides on hair develop when they are contained in compositions that remain on the hair.

It has now surprisingly been found that the effects of the compositions remaining on the hair can be improved in several respects by adding alkyl polyglycosides. Thus, alkylpolyglycosides alone have the effect of strengthening and stabilizing the hair after drying, and by their wettable properties may increase the effect of other ingredients on the hair.

SUMMARY OF THE INVENTION Accordingly, the present invention provides hair care compositions which remain on the hair, in the form of condoms. uo. an aqueous / alcoholic or alcoholic composition comprising conventional cosmetic ingredients comprising an alkylpolyglycoside of formula (I) 20 RO- (Z) "(I) wherein R is an alkyl radical of 6 to 22 carbon atoms Z is mono or uiiyosachariu represents a number of 1.1 to 5, or a condensation product thereof with 1 to 10 molecules of ethylene oxide and / or propylene oxide. For example, the composition of the invention may be hair sprays, hair hardeners, waving agents, hair gels, hair treatments, hair conditioners and hair lotions. The alkyl polyglycides of formula (I) are characterized by the following parameters: 5 The alkyl radical R contains from 6 to 22 carbon atoms and can be both straight and branched. Preferred are linear linear and 2-branched branched aliphatic residues. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl. If so-called "oxo alcohols" are used as starting materials, compounds with an even number of carbon atoms in the alkyl chain predominate.

The alkylglycosides used according to the invention may contain only one particular alkyl radical R. However, these compounds are usually prepared from starting materials such as natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures 15 corresponding to the starting compounds or their processing in the production.

Particularly preferred are such alkyl polyglycosides in which R is essentially composed of:

C 8 and C 10 alkyl groups, 20 - C 12 and C 11 alkyl groups, C 3 to C 16 alkyl groups or

C 12 -C 18 alkyl groups.

Any mono or oligosaccharides can be used as the sugar component Z. Usually 5 or 5 sugars are used. 6 carbon atoms, 25 as well as the corresponding oligosaccharides. Examples of such sugars are glucose, fructose, galactose, arabinose, ribose. xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose. Preferred components are glucose, fructose, galactose, arabinose and sucrose; glucose is particularly preferred. - 4 -

The alkylpolygiycosides of the invention contain on average 1.1 to 5 sugar units. Preferred are alkyl glycosides having x values of from 1.1 to 2. Especially preferred are alkyl glycosides with x values of from 1.1 to 1.4. According to the invention, alkoxylated homologs of said alkyl polyglycosides can also be used. These homologues may on average contain up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit. Also, these products are usually not uniform compounds but exhibit, depending on the method, ethoxylation corresponding to the distribution of homologs. For example, such alkoxylated compounds can be obtained by using ethoxylated fatty alcohols for the synthesis of alkyl polyglycosides. However, non-alkoxylated compounds are preferred according to the invention. Alkylpolygiycosides are preferably present in the compositions of the invention in an amount of from 0.1 to 6% by weight, based on the total composition. Furthermore, it has been found to be particularly advantageous: amounts between 2 and 4% by weight.

The compositions of the invention are preferably based on 20 aqueous, aqueous / alcoholic or alcoholic bases. The alcohols used are preferably ethanol and / or isopropyl alcohol. The choice of the base results from the general knowledge in the art according to the assembled product.

In addition to the alkyl polyglycosides, the compositions of the invention may be used

.1. _. - L i * A 4 η I t! I i 14 III LI. Γ *. _. . _ Γ * '. Λ Λ Λ ousanje vsecty pryyi means unusual cosmetic ingredients. Typically, the selection of additional components is determined by the type of resource.

The hair sprays of the invention are predominantly composed of alcoholic or aqueous-alcoholic solutions. Typically, the alcohol is present in amounts of from 40 to 95% by weight, based on the total composition. Preferably, from 50 to 70% by weight is used.

The hair sprays of the invention may contain alcohol as the sole solvent. However, additional 5 solvents may also be present in amounts of up to 60% by weight of the composition as a whole. Suitable solvents are, for example, water, straight or branched C 5 -C 7 alkanes and C 3 -C 6 ketones. Preferably, water, n-pentane, n-heptane, acetone and 3-methyl-3-methoxybutanol are used. Especially preferred are water and n-heptane, each in amounts up to about 30% by weight, especially up to 20% by weight.

The hair sprays of the present invention further comprise 0.5-10% of a film-forming agent as a necessary component. As fuming agents, known natural resins, synthetic resins and synthetic polymers can be used which are soluble in the chosen solvent and leave a coating on the hair after evaporation of the solvent. Preferred film-forming agents according to the invention are amphoteric, zwitterionic and anionic polymers.

Suitable nonionic polymers are, for example: 20 Vinylpyrrolidone / vinyl acetate copolymers, sold under the trade name Luviskol® (BASF), for example. Preferred nonionic polymers are Luviskol® VA 64. Luviskol® VA 73 and Luviskol® VA 37. Luviskol® VA 37 is particularly preferred.

Vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcapro-lactam terpolymers, such as those available under the name Copolymer VC-713 (ISP).

Polyvinylpyrrolidone, available, for example, under the names Luviskol® K30 and Luviskol® K90.

Oligomeric and polymeric silicones such as polydimethylsiloxane, polymethylphenylsiloxane and ethoxylated siloxanes are available, e.g., under the designation Dow Coming®344 Fluid, 345 Fluid, 556, 190, 193, 200, 244, 245 and 1401.

Suitable amphoteric polymers include, but are not limited to, octalacrylamide / methyl methacrylate / t-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers under the names Amphamer® and Amphomer® LV-71 (Delft National).

Suitable zwitterionic copolymers are, for example, those disclosed in DE 39 29 973, DE 21 50 557, DE 28 17 369 and DE 37 08 451. The acrylamido-propyltrimethylammonium chloride / acrylic copolymers and their alkali and ammonium salts are zwitterionic polymers. particularly preferred. Other suitable zwitterionic polymers are methacroyl ethyl betaine / methacrylate copolymers, commercially available under the name Amersette® (Amerchol).

Suitable anionic polymers according to the invention include:

Vinyl acetate / crotonic acid copolymers available, for example, under the names Resyn® (National Starch), Luviset® (BASF) and Gafset® (ISP). A particularly preferred anionic polymer is Luviset® CA-66.

Vinylpyrrolidone / vinyl acrylate copolymers available, for example, under the trade name Luviflex® (BASF). The preferred polymer is a vinylpyrrolidone / acrylate terpolymer, available under the name Luviflex® VBM-35 (BASF).

Vinylacetatebutylameate / isobornyl acrylate copolymers available under the trade name Advantage® (ISP). The preferred polymer is Advantage® CP. - 7 -

Copolymers of methyl vinyl ether / maleic anhydride and their esters, available, for example, under the name Gantrez® (ISP). The preferred anionic polymer is Gantrez® ES 225.

Terpolymers of acrylic acid / ethyl acrylate / N-tert-butylacrylate amide, available e.g. under the name Ultrahoid; (BASF).

Particularly preferred are nonionic polymers such as Luviskol VA 37 and anionic polymers such as Luviflex VBM 35 and Ultrahold ®8.

According to the invention, compositions with a film-forming content of 1-7, in particular 3-7% by weight, are preferred. Further, the hair sprays of the invention may comprise a propellant. Based on the known problems of CFCs, propellants such as propane-butane, pentane, N 2 O, dimethyl ether, carbon dioxide, nitrogen and air are preferred. Particularly preferred propellants are nitrogen. CO2 and air. Propellant-free compositions which can be sprayed with known mechanical devices are also particularly preferred within the scope of the invention. Particularly suitable for spraying such compositions are, for example, the dispensers described in EP-A1-401060. 20 Other components of the hair spray according to the invention are, for example, perfuming oils, amines, especially fatty amines, preservatives such as small amounts of paraffins and surfactants. , in particular nonionic and cationic surfactants.

The hair hardeners, waving agents and hair gels of the invention are preferably formulated as water-alcoholic liquids. The proportion of alcohol in the solvent is usually between 5 and 50%, with between 10 and 30% being preferred. The alcohol component used is preferably ethanol or isopropyl alcohol.

Hair hardeners, waving agents, and hair gels may additionally contain a natural or synthetic polymer as the film-forming agent. In recent years, the use of synthetic polymers has been established against the use of natural polymers such as bleached or partially saponified shellac.

As synthetic polymers, the above nonionic, amphoteric, zwitterionic and anionic polymers can be used. The following types have been found to be suitable as cationic polymerizates:

Quaternized cellulose derivatives available under the name Celquat® and Polymer JR®. Preferred quaternary cellulose derivatives are Celquat H 100, Celquat L 200 and Polymer JR®400.

Quaternized guar derivatives available under the names Cosmedia Guar® and Jaguar®. Preferred guar derivatives are, for example, Cosmedia Guar® C-261 and Jaguar® C 13-S.

Copolymers of vinylpyrrolidone with quaternized derivatives of diaicylaminoacrylate and methacrylate, such as diethylsulphate quaternized vinylpyrrolidone / dimethyla methacrylate copolymers. Such compounds are available under the names Gafquat ® 734 and Gafquat ® 755.

Copolymers of vinylpyrrolidone with vinylimidazolium methochloride. offered under the name Luviquat®.

Polymer dimethyldiallylammonium salts and their copolymers with acrylic and methacrylic acid esters and amides. Examples of such cationic polymers are the commercially available Merquat®100 products (poly (dimethyldiallylammonium chloride)) and Merquat®550 (dimethyleniallylammonium chloride-acrylamide copolymer). * 9 -

Particularly suitable for the compositions of the invention are compounds of the "Gafquat" type.

Other preferred constituents of hair hardeners, dye formulations and hair gels are small amounts of substances, such as 5, preferably cationic, nonionic or zwitterionic surfactants, more or less alcohols such as glycols or polyglycols, preservatives, fatty and oily components such as ethoxylated glycerides, amines for neutralizing the anionic groups of the polymerization as well as perfuming oils and dissolving aids. 10 Hair treatments and hair conditioners are generally water based. They may contain as additional folders:

Polymers, in particular non-ionic and zwitterionic polymers of the aforesaid type.

Surfactants, especially cationic and nonionic, such as, for example, quaternary ammonium salts and fatty alcohol ethoxylates, polyols and glycerides.

Thickeners such as agar-agar, guar gum, alginates and xanthan gum as well as cellulose ether.

Perfume oils, dimethylisosorbide and cyclodextrins. Auxiliary solubilizers such as ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, the same as ethoxylated fatty alcohols.

Dyes. PH adjusters such as acid 25 citrate / sodium citrate buffer. Active substances such as panthenol, allantoin, glucose, gluconates, maleic acid and pyrrolidone dicarboxylic acids, as well as their salts. Light-protecting substances. 5 - Consistency agents, such as sugar esters, polyol esters or polyol alkyl ether.

Degreasing agents such as polyethoxylated lanolin derivatives and fatty acid alkanolamides.

Complexing agents such as EDTA, NTA and phosphonic acids. 10 - Swelling and penetrating agents such as glycerin, propylene glycol monoethyl ether, carbonates, bicarbonates, guanidine, urea and primary, secondary and tertiary phosphates. Hazardous substances such as latex.

Pearlescent agents such as ethylene glycol mono- or distearate 15 - Propellants such as propane-butane, N, O, dimethyl ether and air.

Antioxidants.

Usually, the hair waters of the invention are based on an aqueous-alcoholic basis. In addition to water, they preferably contain between 20 and 70% of 20 ethanol and / or isopropyl alcohol. As a rule, all other components are in small amounts, i.e. in amounts of soil, in particular below 2% by weight, based on the hair water as a whole. Preferred hair lotions according to the invention contain as further components plant extracts, vitamins and / or anti-dandruff agents. -11 -

Suitable plant extracts are, for example, extracts of needles leaves, roots and / or flowers of brindles, conifers, nettles, valerian, chamomile, lemon balm, etc.

Vitamins are preferably vitamins A, 8, C and 5 E, in particular vitamins A and E. Examples of corresponding slouco-vitamins are vitamins A and E, α-tocopherol nicotinate and α-tocopherol succinate.

As anti-dandruff agents, soluble compounds of the corresponding effect are preferably used. Examples of such compounds are those marketed under the tradename Octopirox® (CTFA designation: Piroctone Olamine) and Natrium, respectively. Magnesium-Omadine®.

Other preferred hair water components are components such as menthol, camphor, ethoxylated glycosides, panthenol, allantoin, bisabolol, nonionic polymers such as polyvinylpyrrolidone, small amounts of surfactants, especially nonionic or cationic 15, such as quaternary ammonium compounds, propylene glycol and perfume oils. Further, it has proven advantageous if the compositions of the invention additionally contain protein hydrolysates or derivatives thereof.

Protein hydrolysates are mixtures of products that are obtained by acidic, basic or enzymatically catalyzed protein degradation,

The corresponding proteins may originate from both animal and plant sources. - 12 -

According to the invention, e.g.

Collagen Hydrolysates (CTFA designation: Hydrolyzed Animal Protein, Hydrolyzed Animal Collagen and Soluble Animal Collagen). Preferably, hydrolyzates of bovine collagen may be used. Hydrolysates may also be in the form of salts such as sodium or ammonium. Known commercial products are, for example, Dehylan®ET 40 (Henkel), Promosis® Silk 1000 Q (Interorgana), Collapuron® N (Henkel). Nutrilan®V 37908 and Nutrilan®! (Griinau), Gelita-ol®C and CS (Deutsche Gelatine Fabriken Stoess & Co), as well as Lexein LP 170 and Lexein®X-350 (Inolex).

Collagen condensates condensates. The collagen derivatives may also be used in accordance with the invention in the form of their condensates with organic acids, in particular fatty acids or mixtures of fatty acids. Preferred acids are oleic, myristic, undecylene, coconut and abietic acids. The condensation products may also produce x forms of salts, especially sodium, potassium and triethanolamine. Such condensation products are also designated by CTFA Oleoyl Hydrolyzed Animal Protein, Myristoyl Hydrolyzed Animal Protein, TEA Abietoyl Hydrolyzed Animal Collagen, Potassium Undecylenoyl Hydrolyzed Animal Collagen, and TEA Coco Hydrolyzed Animal Collagen.

UUUUU II * I *! ΑΛΙ Λ Λ Λ? | A AA nn) JiUuu / iy jawu ιιαρι. ivc / ui t I * Λ Λ rt í3 > A LCIIII ^ pUl ΙΌ'-Γ

Cl / J i

Lamepon®UD, Lamepon®460, Lamepon®PA TR, Lamepu® :; AND; 40 and Lamepon ® S (Grunau), as well as Lexein ® A240, Lexein ® S 620 and Lexex ® A 520 (Inolex). - 13 -

According to the invention, cationized collagen hydrolysates can also be used, such as the commercial product Lamequat® L (CTFA designation: Lauryldimonium Hydroxypropylamino Hydrolyzed Animal Protein; Grunau).

Elastin boron (CTFA: Hydrolyzed Animal

Elastin). Examples of commercially available elastin hydrolysates are Nutrilan ® Elastin E 20 (Henkel) and Gelita ® Gelastin (Deutsche Gelatine Fabriken Stoess & Co). Bovine elastin hydrolysates may be preferred.

Condensation products of elastin hydrolyzates with fatty acids such as lauric acid (CTFA designation: Lauroyl Hydrolyzed Animal Elastin) may also be used. The corresponding market product is Crolastin®AS (Croda).

Keratin Hydrolyzate (CTFA designation: Hydrolyzed Animal

Keratin) represent another group of protein hydrolysates useful in the invention. Examples of branded products are Nutrilan® Keratin W (HenkeJ), Kerapro® S (Dietiu, Promois® WK H (Seiwa Oil & Chemetics) and Kerasol® (Croda).

Other proteins whose hydrolysates can be used according to the invention are wheat proteins, milk proteins, egg white proteins, silk proteins, almond, soy and animal skin proteins. Corresponding commercial products are, for example, Gluadin®AGP (Henkel), DiaMin® (Diamalt), Lexein®X-250 and Lexein®MP (Inolex), Crotein® A, Crotf3® and ®C, Crotein®ASC and Crotein® products 0 (Croda). Gelita®Flex S 50 (Deutsche Gelatine Fabriken Stoess & Co) and Hydrosilk® 10000 (Croda).

Also, these protein hydrolysates can react with organic acids or mixtures of acids such as myristic, oleic, coconut or abietic acid to form condensates useful in the invention. Examples of such commercial products are Lexin®A 200 (Inoilex), Lamepon®PO-TR, Lamepon®PA-K, Lamepon®S-MV and Lamepon®S-TR (Grúnau) and Crotein®CCT (Croda). s Quaternized products of such protein hydrolysates are available, for example, under the names Lexein® QX 3000 (Inolex), Crotein® Q (Croda) and Croquat® WKP (Croda). The invention also relates to the use of the composition according to the invention for hair care, as well as to a method of hair care in which such a composition is applied to the hair and remains there. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS I. Measurements 15 1.1

The tests were carried out according to the method described in P. Busch, Arztl. Kosmetol. 19 (1989), 33, respectively. 306-308. For this purpose, the strand of hair was always attached to the measuring head and straightened with a trowel. After release, the strand performed loose, muted swings, while the parameters stretch, initial amplitude, and damping were registered and evaluated. The following results were obtained (composition data always in% by weight of active substance): - 15 -

Components: B1 V1-ethyltrimethylammonium chloride 1.0 1.0 5-Polyvinylpyrrolidone-2,0-alkylglucoside with R = C3.i6 ax = 1.4 6.0 -ethanol 30.0 30.0 -water ad 100 ad 100 io 15% rel. humidity and piled strand [mJ] 0.79 0.40 Initial amplitude [mN] 4.6 3.9 Maximum damping in piled strand [1 / s] 1.47 0 M 15 Results show that at approximately 6% w / w, conventional for non-ionic surfactants, it achieves a greater firming effect than with a conventional amount of non-ionic polymer of about 2% by weight. 20 1.2 Curl retention tests The curl retention tests have determined the behavior of the suspended hair strand as follows:

A strand of hair (approximately 23 cm long, approximately 2 g in weight) was moved for 10 seconds in 10 g of the preparation to be examined. Then the strand was removed from the solution and the pinched preparation was removed by stretching - 16 - between the thumb and forefinger. Then the strand was ripped up, no longer resisting, and shot overnight on a medium-sized curler. The following morning the curler was removed and the spring length was measured. Then the strand was transferred to a climatic chamber where it was kept at a relative humidity of between 60 and 70% with a saturated ammonium chloride and potassium nitrate solution. After 6 hours, the length of the strand was measured again.

The "curl retention value" 1 is then defined as; io% CR = (L * Lt): (L - U) + 100%, where L: Total length of hair strand (23 cm) U: Length of strand strand before placing in climatic chamber L ,; The length of the hair strand after being placed in a climatic chamber 15

The following results were obtained (composition data always in% by weight of active substance);

Folders; B2 V2 V3 -propyleneglycol 2.0 2.0 2.0 -Dehyton®AB 301 4.0 4.0 4.0-alkylglucoside with R = C 12-ie ax = 1,4 6,0 - - -polyvinylpyrrolidone - n, z - u - ad 100 ad 100 ad 100% CR 71,4 73,9 44,1 - 17 - 1 Fatty amine derivative with betaine structure (approximately 30% active substance in water; CTFA; Coco-Betaine ) (Henkel). The results show that with alkylglucoside almost stiffening effects are obtained as with film-forming polymers. II. Formulation Examples All data are in% by weight. 10 1. Hardener 12,0 4,0 30,0 ad 100

Plantaren® 2000 Dehyquart® A3 15 Ethanol Water 2 Alkylglucoside with R = Ca-is ax = 1.4 (50% active) (Henkel) 3 Cetyltrimethylammonium chloride (25% active in water; 20 CTFA: Cetrimonium Chloride) (Henkel ). 2. Hair hardener 25

Plantaren® 2000 Polyvinylpyrrolidone 6.0 2.0 - 18 - - 18 - 4.0 30.0 ad 100

Dehyquart® A

Ethanol

Water 3. Styfing-gel (pH 5.6)

Plantaren® 12004 4.0

Carbopol® 9805 60.0 io Propylenglyko! 3.0

Emulgin® HRE 4QS 2.0

Sodium hydroxide (10%) 3.0

Trilon®B7 0.2

Water ad 100

1S1 Alkylglucoside with R = Ci2-i2 and x = 1.4 (about 50% active; CTFA: Lauryl Polyglycose) (Henkel) 5 Polyacrylic acid (Goodrich); 2% solution in water 6 Solidified castor oil + 40 EO (CTFA; PEG-40 2o Hydrogenated Castor Oil) (Henkel) 7 Sodium ethylenediaminetetraacetic acid (40% active in water; CTFA; Tetrasodium EOTA) (BASF) - 19 - 4. Hair End Liquid

Plantaren® 2000 5 Carbopol® 980 Propylene Glycol Emulgin® HRE 40 Sodium Hydroxide (10%) Pathenol to Trilon®B Water 4.0 60.0 3.0 2.0 3.0 0.5 0.2 ad 100 5. Mechanical Sprayer

Plantaren® 1200 Propylene glycol Dehyton AB 30 Water 6.02.0 4.0 ad 100 20 6. Mechanical rc ^ p, <> ·. '· &Gt; , -u, i

Plantaren® 1200 4.0 25 Luviskal®VA 643 3.0 2.0 4.0 ad 100

PropylengJykof Dehyton AB 30 Water 3 Vinylpyrrolidone-vinyl acetate copolymer (60:40) (about 50 active ingredients in water (Henkel) 7. Aerosol hair spray

Plantaren® 1200 4.0

Polyvinylpyrrolidone 1.0

Propylene glycol 2.0

Ethanol ad 100 8. Hair water

Plantaren® 1200 3.0

Nicotinic acid adenyl phosphate 0.05

Octopirox®3 0,5

Perfume Oil qs

Dye qs

Ethanol 40.0

Water ad 100 9 Hydroxy-4-methyl-6 monoethanolamine salt (2 < 4 >; 4 ' -trinomethylpentyl) -2-pyridone (Hoechst) 9. Hair treatment

Stenol®161810 0.8

Gatarol®M 30 M11 0.4

Glucquat® 10012 0.6

Dehyquart®A 1.5

Piantaren®1200 2.4

Acrylamidopropyl-trimethylammonium chloride / acrylic copolymers (3: 1 molar ratio), neutralized with NaOH (polymer P1 according to OE 39 29 973 0.2

Water ad 100, Q CT6 / C 13 fatty alcohol (Henke!) 11 Myristyl- (3 EO) -myristate (CHEM-Y) 12 N, N-dimethyl-N-dodecyl-N (methylglucoside + 10 EO 2 hydroxypropyl) ammonium chloride ( designated CTFA: Lauryl Methy Gluceth — 10 Hydroxypropyl Dimonium Chloride) (Amerchol) - 22-10.

Stenal®1618 with Myritol® 31873 Texapon®K 14 S14 0.8 1.4

Plantaren®1200 0.8

Luviquat®HM 55215 1.2

Water ad 100 10 13 Fatty acid triglyceride (CTFA: Caprylic Capric Triglyceride) (Henkel) 14 Sodium lauryl methyl ether sulfate (approximately 28% active, designated CTFA: Sodium Myreth Sulphate) (Henkel) 15 13 Vinyl pyrrolidone-vinylimidazolium methochloride copolymer (20% active in water; CTFA: Polyquaternium 16) (BASF) 11. For care of damaged hair 30

Plantaren @ 1200 0.5

Lamequat®Li0 0.8

Nutrilan®! 50'7 1.6

Cetiol @ J 600'3 0.5 35 Copheroi®125019 0.2 - 23 - Glycerin 5.0

Ethanol 10.0

Dye, preservative, water at 100 s 16 Cationized collagen hydrolyzate (approximately 35% active substance; CTFA designation Lauryldimonium Hydroxypropyl Hydrolyzed Collagen (Henke!) 17 Collagen hydrolyzate (approximately 50% active; CTFA designation: i Hydrolyzed Collagen) (Henke! ) 18 Olyl erucate ester (CTFA designation: Oleyl Erucate) (Henkel) 19 Da-tocopheryl acetate (approximately 92% active substance, CTFA designation: Tocoferyl Acetate (Henkel Corp.) is 20 Dodecyl alcohol preparation + 7 EO, isoparaffin and polyacrylamide (designation CTFA: Polyacrylamide (and) C13-14-Isoparaffin (anthra-Laureth-7) (Henkel) The formulation has a pH of about 7.

Represents: .. i

Dr. ZDENKA KARřtfOVé 20

Claims

4 - 24 - 4 - 24 -

s 10 15 20

in the form of an aqueous, aqueous-alcoholic or alcoholic preparation containing conventional cosmetic components and, in addition, an alkylpolyglycoside of formula (I) RO- (Z) x (I) wherein R is an alkyl radical of 6 to 22 carbon atoms, Z is mono- or oligosaccharide, x is a number from 1.1 to 5, or a condensation product thereof with 1 to 10 ethylene oxide and / or propylene oxide molecules, further comprising a film-forming polymer.

Composition according to claim 1, characterized in that in formula (I) Z represents glucose and x represents a number between 1.1 and 2, in particular a number between 1.1 and 1.4.

A composition according to any one of claims 1 or 2, characterized in that it comprises from 0.1 to 6% by weight of the alkyl polyglycoside, based on the total composition.

A composition according to any one of claims 1 to 3, characterized in that it is an amphoteric, zwitterionic or anionic polymer.

5. A composition according to any one of claims 1 to 4 wherein the composition is a hair spray. 25 -25.

Composition according to any one of claims 1 to 4, characterized in that the composition is a hair hardener, a dye preparation or a hair gel.

7. A composition as claimed in any one of claims 1 to 6 which comprises a further surfactant, a group of nonionic and cationic surfactants. 10

Composition according to any one of claims 1 to 7, characterized in that it comprises a protein hydrolyzate or a protein hydrolyzate derivative.

Use of the compositions according to any one of claims 1 to 8 for hair care. 15

10. A method of hair care, characterized in that the composition according to any one of claims 1 to 10 is applied to the hair and remains there. Represents Or. ZDENKA ROBElZOUá

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