EP0714287A1

EP0714287A1 - Hair treatment agents

Info

Publication number: EP0714287A1
Application number: EP94926170A
Authority: EP
Inventors: Jörg KAHRE; Kurt Seidel; Winfried Emmerling; Joachim-Kurt Foitzik
Original assignee: Henkel AG and Co KGaA
Current assignee: Henkel AG and Co KGaA
Priority date: 1993-08-19
Filing date: 1994-08-10
Publication date: 1996-06-05
Also published as: CZ45796A3; WO1995005157A1; JPH09501663A; DE4327700A1; PL313079A1

Abstract

Described are hair-treatment agents designed to remain on the hair, the agents being improved in many respects by virtue of the fact that they contain an additional component consisting of alkyl polyglycosides. Particularly worthy of mention are their hair-fixing and stabilizing properties.

Description

"Hair treatment lunos ittel"

The invention relates to the agent for the treatment of hair that remains on the hair.

The care of the hair is an important part of human body care. There are a number of products for different purposes. For cleaning the hair, tenside-containing, aqueous agents are usually used, which are rinsed off again after a brief action on the hair and scalp. Hair rinses primarily serve to improve the hair properties according to other hair treatment methods; they too usually only remain on the hair for a short time and are then rinsed off. Permanent dyeing and shaping of hair are also treatment methods in which the corresponding agents are removed from the hair by rinsing after an exposure time, which is usually in the range of up to about 30 minutes.

However, a number of other hair treatment agents remain on the hair.

Such means are, for example

Hair sprays for fixing the hairstyle,

Hair fixers, blow dryer waves and hair gels, which serve to temporarily shape the hairstyle, and hair lotions.

It is known from a large number of publications to use nonionic surfactants of the alkylpolyglycoside type in hair treatment compositions. The publications EP 337 354, EP 398177, EP 502 304 and EP 504 791 may be mentioned as examples. However, these publications only disclose hair treatment agents such as shampoos, rinses and permanent waving agents which are rinsed off after a short exposure time. None of these documents indicates that alkylpolyglycosides have advantageous effects on the hair if they are contained in agents which remain on the hair. It has now surprisingly been found that agents remaining on the hair can be improved in their effectiveness in several ways by adding alkyl polyglycosides to these agents. The alkyl polyglycosides have a self-strengthening effect, stabilize the hairstyle hold after drying and can increase the effect of other components on the hair due to their wetting properties.

The invention therefore relates to hair treatment compositions for remaining on the hair in the form of an aqueous, aqueous / alcoholic or alcoholic preparation containing conventional cosmetic ingredients, characterized in that they are an alkyl polyglycoside of the general formula (I)

R0- (Z) _x (i)

in which R stands for an alkyl radical with 6 to 22 carbon atoms, Z for a mono- or oligosaccharide and x for a number from 1.1 to 5, or its adduct with 1 to 10 molecules of ethylene oxide and / or propylene oxide.

The agents according to the invention can be, for example, hair sprays, hair fixers, blow dryer waves, hair gels, hair treatments, hair conditioning agents and hair lotions.

The alkyl polyglycosides according to formula (I) are characterized by the following parameters:

The alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. I-octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. When using so-called "oxo alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.

The alkyl glycosides which can be used according to the invention can contain only one specific alkyl radical R. Usually these connections but manufactured from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the respective working up of these compounds.

Particularly preferred are those alkyl polyglycosides in which R consists essentially of CQ and Cio alkyl groups, essentially from C12 and Ci4 alkyl groups, essentially from CQ to Ciö alkyl groups or essentially from Z 2 to C 1 alkyl groups consists.

Any mono- or oligosaccharides can be used as sugar building block Z. Sugar with 5 or 6 carbon atoms and the corresponding oligosaccharides are usually used. Examples of such sugars are glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allos, altrose, mannose, gulose, idose, talose and sucrose. Preferred sugar components are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.

The alkyl polyglycosides which can be used according to the invention contain an average of 1.1 to 5 sugar units. Alkyl glycosides with x values from 1.1 to 2 are preferred. Alkyl glycosides in which x is 1.1 to 1.4 are very particularly preferred.

The alkoxylated homologs of the alkyl polyglycosides mentioned can also be used according to the invention. These homologues can contain an average of up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit. These products also usually do not represent uniform compounds, but instead have a corresponding homolog distribution depending on the selected ethoxylation process. Such alkoxylated compounds can be obtained, for example, by using ethoxylated fatty alcohols for the synthesis of the alkyl polyglycosides. Within the framework of the teaching according to the invention, however, the use of the non-alkoxylated compounds is preferred. The alkyl polyglycosides are preferably contained in the agents according to the invention in an amount of 0.1 to 6% by weight, based on the total agent. Furthermore, it has been shown that amounts between 2 and 4% by weight are particularly good are advantageous.

The agents according to the invention are formulated on an aqueous, aqueous-alcoholic or alcoholic basis. Ethanol and / or isopropanol are preferably used as alcohols. For the specialist, the selection of the basis results from the general specialist knowledge in accordance with the product to be formulated.

In addition to the alkyl polyglycosides, the agents according to the invention can contain all of the cosmetic ingredients customary for these agents. The selection of the other constituents is essentially determined by the type of agent.

Hair sprays according to the invention are predominantly formulated as alcoholic or aqueous-alcoholic solutions. The alcohol is usually contained in amounts of 40 to 95% by weight, based on the overall preparation. Amounts of 50 to 70% by weight are preferred.

The hair spays according to the invention can contain alcohol as the only solvent. However, other solvents can also be present in amounts of up to 60% by weight, based on the entire preparation. Suitable solvents are, for example, water, linear and branched alkanes with 5 to 7 C atoms and ketones with 3 to 6 C atoms. Water, n-pentane, n-heptane, acetone and 3-methyl-3-methoxy-butanol are preferred solvents. Water and n-heptane, each in amounts up to about 30% by weight, in particular up to 20% by weight, are particularly preferred.

Furthermore, the hair sprays according to the invention contain 0.5-10% by weight of a film former as an essential component. The known natural resins, synthetic resins and synthetic polymers can be used as film formers, which are soluble in the chosen solvent and leave a coating on the hair after the solvent has evaporated. Preferred film formers according to the invention are nonionic, amphoteric, zwitterionic and anionic polymers.

Suitable nonionic polymers are, for example:

Vinylpyrrolidone / vinyl acetate copoly ere, as they are sold for example under the trademark Luviskol ^R (BASF). Luviskol ^R VA 64, Luviskol ^R VA 73 and Luviskol ^R VA 37 are preferred nonionic polymers; Luviskol ^R VA 37 is particularly preferred.

Vinyl pyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymers, as are available, for example, under the name Copoly er VC-713 (ISP).

Polyvinylpyrrolidones, as are available, for example, under the names Luviskol ^R K 30 and Luviskol ^R K90.

Oligomers and polymeric silicones, such as polydimethylsiloxanes, polymethylphenylsiloxanes and ethoxylated siloxanes, such as are available, for example, under the names Dow Corning ^R 344 Fluid, 345 Fluid, 556, 190, 193, 200, 244, 245 and 1401.

Suitable amphoteric polymers are, for example, the octyl acry1 amide / methyl methacrylate / tert available under the names Amphomer ^R and Amphomer ^R LV-71 (Delft National). Butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers.

Suitable zwitterionic polymers are, for example, the polymers disclosed in German patent applications DE 39 29 973, DE 21 50 557, DE 28 17 369 and DE 3708 451. Acrylamidopropyltrimethylammonium chloride / acrylic acid copolymers and their alkali and ammonium salts are particularly preferred zwitterionic polymers. Other suitable zwitterionic polymers are methacroylethylbetaine / methacrylate copolymers, which are commercially available under the name Amersette ^R (Amerchol). Anionic polymers suitable according to the invention include:

Vinyl acetate / crotonic acid copolyers, such as are commercially available, for example, under the names Resyn ^R (National Starch), Luviset (BASF) and Gafset ^R (ISP). Luviset ^R CA-66 is a particularly preferred anionic polymer.

Vinyl pyrrolidone / vinyl acrylate copolymers, available, for example, under the trademark Luviflex (BASF). A preferred polymer is the vinyl pyrrolidone / acrylate terpolymers available under the name Luviflex ^R VBM-35 (BASF).

Vinyl acetate / butyl maleate / isobornyl acrylate copolymers as available under the trademark Advantage ^R (ISP). Advantage ^R CP is a preferred polymer.

Methyl vinyl ether / maleic anhydride copolymers and their esters, as are available, for example, under the name Gantrez ^R (ISP). Gantrez ^R ES 225 is a preferred anionic polymer.

Acrylic acid / ethyl acrylate / N-tert-butyl acrylamide terpolymers, which are sold, for example, under the name Ultrahold ^R 8 (BASF).

Nonionic polymers such as Luviskol VA 37 and anionic polymers such as Luviflex VBM 35 and Ultrahold ^R 8 are particularly preferred.

Agents with a film former content of 1-7, in particular 3 to 7,% by weight are preferred according to the invention.

Furthermore, the hair sprays according to the invention can contain blowing agents. Because of the known CFC problem, it is preferred to use blowing agents such as propane-butane mixtures, pentane, N2O, dimethyl ether, carbon dioxide, nitrogen and air in the formulation as hairspray. Nitrogen, CO2 and air can be particularly preferred blowing agents. Propellant-free preparations which can be sprayed with the known mechanical devices are also particularly preferred agents in the context of the teaching according to the invention. Particularly suitable for spraying such agents are, for example, dispensers which are described in European patent application EP-Al-401060.

Further components for hair sprays according to the invention are, for example, perfume oils, amines, in particular fatty amines, preservatives and small amounts of paraffins and surfactants, in particular nonionic and cationic surfactants.

Hair setting agents, hair dryer shafts and hair gels according to the invention are preferably formulated as aqueous-alcoholic solutions. The alcohol content of the solvent is usually between about 5 and 50%, with contents between 10 and 30% being preferred. Ethanol or isopropanol is preferably used as the alcohol component.

Hair setting agents, blow dryer shafts and hair gels can contain a natural or synthetic polymer as a film-forming agent as a further component. In the course of the last few years, the use of synthetic polymers has prevailed over the use of natural polymers, such as, for example, decolorized or partially saponified shellac.

The above-mentioned nonionic, amphoteric, zwitterionic and anionic polymers can be used as synthetic polymers. Cationic polymers, preferably of the following structure types, have also proven to be suitable:

quaternized cellulose derivatives, as are commercially available under the names Celquat ^R and Polymer JR ^R. The compounds Celquat H 100, Celquat L 200 and Polymer JR ^R 400 are preferred quaternized cellulose derivatives.

quaternized guar derivatives, as are commercially available under the names Cosmedia Guar ^R and Jaguar ^R. Preferred guar derivatives are, for example, Cosmedia Guar ^R C-261 and Jaguar ^R C 13-S. Copoly ere of vinylpyrrolidone with quaternized derivatives of dialkylaminoacrylate and methacrylate, such as vinylpyrrolidone-dimethylaminomethacrylate copolymers quaternized with diethyl sulfate. Such compounds are commercially available under the names Gafquat ^R 734 and Gafquat ^R 755.

Copolymers of vinyl pyrrolidone with vinyl imidazolium methochloride, such as those offered under the name Luviquat ^R.

Polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid. The products obtainable under the names Merquat ^R 100 (poly (dimethyldiallylammonium chloride)) and Merquat ^R 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers.

Compounds of the "Gafquat" type are particularly suitable for the agents according to the invention.

Preferred further components for hair fixers, hair dryer and hair gels are small amounts of, preferably cationic, nonionic or zwitterionic, surfactants, polyhydric alcohols such as glycols or polyglycols, preservatives, fat and oil components such as ethoxylated glycerides, amines for neutralizing anionic Groups of the polymers as well as perfume oils and solubilizers.

Hair treatments and hair conditioning agents according to the invention are generally formulated on an aqueous basis. They can contain as further components:

Polymers, in particular nonionic and zwitterionic polymers of the types mentioned above, surface-active compounds, in particular cationic and nonionic, such as quaternary ammonium salts and fatty alcohol, polyol and glyceride ethoxylates, Thickeners such as agar agar, guar gum, alginates and xanthan gum and cellulose ether,

Perfume oils, dimethyl isosorbide and cyclodextrins,

Solubilizers, such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol and ethoxylated fatty alcohols, dyes,

Substances for adjusting the pH, such as citric acid / sodium citrate buffer,

Active ingredients such as panthenol, allantoin, glucose, gluconates, maleic acid and pyrrolidone carboxylic acids and their salts, light stabilizers,

Consistency enhancers such as sugar esters, polyol esters or polyol alkyl ethers, superfatting agents such as polyethoxylated lanolin derivatives and fatty acid alkanolamides,

Complexing agents such as EDTA, NTA and phosphonic acids,

Swelling and penetration substances such as glycerol, propylene glycol monoethyl ether, carbonates, hydrogen carbonates, guanidines, ureas and also primary, secondary and tertiary phosphates, opacifiers such as latex,

Pearlescent agents such as ethylene glycol ono and distearate, blowing agents such as propane-butane mixtures, N2O, dimethyl ether and air, and antioxidants.

Hair lotions according to the invention are usually formulated on an aqueous-alcoholic basis. In addition to water, they preferably contain between 20 and 70% ethanol and / or isopropanol. All other components are usually only in small amounts, i.e. in amounts below 5, in particular below about 2% by weight, based on the total hair tonic.

Hair lotions preferred according to the invention contain plant extracts, vitamins and / or antidandruff active ingredients as further constituents.

Examples of suitable plant extracts are the extracts of leaves, needles, roots and / or blossoms of birch, coniferous trees, nettles, baldrian, witch hazel, lemon balm, etc. Vitamins of the A, B, C and E groups, in particular vitamins of the A and E groups, are preferably used as vitamins. Examples of corresponding compounds are vitamin A and vitamin E acetate and palmitate, α-tocopherol nicotinate and α-tocopherol succinate.

Soluble compounds with a corresponding action are preferably used as antidandruff active ingredients. Examples of such compounds are the products commercially available under the trademark 0ctopirox ^R (CTFA name: Piroctone Olamine) and sodium or magnesium Omadine ^R.

Further preferred constituents of hair lotions are components such as menthol, camphor, ethoxylated glycerides, panthenol, allantoin, bisabolol, nonionic polymers such as polyvinylpyrrolidone, small amounts of tensides, preferably nonionic or cationic surfactants, such as quaternary ammonium compounds, propylene glycol and Perfume oils.

Furthermore, it has proven to be advantageous if the agents according to the invention additionally contain protein hydrolyzates or their derivatives.

Protein hydrolyzates are product mixtures that are obtained by acidic, basic or enzymatically catalyzed breakdown of proteins (proteins).

The corresponding proteins can come from both animal and vegetable sources.

For example, the following can be used:

Collagen hydrolyzates (CTFA names: Hydrolyzed Animal Protein, Hydrolyzed Animal Collagen and Soluble Animal Collagen). Hydrolyzates based on bovine collagen may be preferred. The hydrolysates can also be in the form of salts, for example as the sodium or ammonium salt. Known commercial products are, for example Dehylan ^R ET 40 (Henkel), product mois ^R Silk 1000 Q (Interorgana) Collapuron ^R N (Henkel), Nutrilan ^R V 37908 and Nutrilan ^R I (Grunau), Gelita Sol ^R C and CS ( German gelatine factories Stoess & Co) as well as Lexein LP 170 and Lexein ^R X-350 (Inolex).

Ko11aqenhvdrolvsat condensates. According to the invention, collagen hydrolyzates can also be used in the form of their condensates with organic acids, in particular fatty acids or fatty acid mixtures. Preferred acids are oleic acid, myristic acid, undecylenic acid, coconut fatty acid and abietic acid. The condensation products can also be in the form of salts, in particular sodium, potassium and triethanolamine salts. Such condensation products also carry the CTFA names Oleoyl Hydrolyzed Animal Protein, Myristoyl Hydrolyzed Animal Protein, Oleoyl Hydrolyzed Animal Collagen, Potassiu Coco Hydrolyzed Animal Protein, TEA Abietoyl Hydrolysed Animal Collagen, Potassium Undecylenoyl Hydrolyzed Animal Collagen and TEA Coco Hydrolyzed Animal Collagen .

Commercial products include Lamepon ^R LP0, Lamepon 4 SK, Lamepon ^R UD, Lamepon ^R 460, Lamepon ^R PA TR, Lamepon ^R ST 40 and Lamepon ^R S (Grünau) as well as Lexein ^R A 240, Lexein ^R S 620 and Lexein ^R A 520 (Inolex).

Cationized hydrolysates of calcium, such as, for example, the product on the market under the name Lamequat ^R L (CTFA name: Lauryldi onium hydroxypropylamino hydrolyzed animal protein; Grünau) can also be used according to the invention.

Elastin-Hvdrolvsate (CTFA name: Hydrolyzed Animal Elastin). Examples of elastin hydrolyzates which can be used according to the invention are the products sold under the names Nutrilan ^R Elastin E 20 (Henkel) and Gelita ^R Gelastin (Deutsche Gelatine Fabriken Stoess & Co). Bovine elastin hydrolysates may be preferred.

Condensation products of elastin hydrolysates with fatty acids such as lauric acid (CTFA name: Lauroyl Hydrolyzed Animal Elastin) can also be used. Crolastin ^R AS (Croda) is a corresponding market product. Keratin hydrolysates (CTFA name: Hydrolyzed Animal Keratin) represent a further group of protein hydrolysates to be used according to the invention. Examples of branded products are Nutrilan ^R Keratin W (Henkel), Kera- pro ^R S (Diedrichs), Promois ^R WK H (Seiwa Oil & Chemetics) and Kerasol ^R (Croda).

Other proteins whose hydrolysates can be used according to the invention are wheat proteins, milk proteins, protein proteins, silk proteins, almond proteins, soy protein and proteins from animal skins. Corresponding sales products are, for example, Gluadin ^R AGP (Henkel), products of the DiaMin ^R series (Diamalt), Lexein ^R X-250 and Lexein ^R MP (Inolex), Crotein ^R A, Crotein ^R C, Crotein ^R ASC and Crotein ^R 0 ( Croda), Gelita ^R Flex S 50 (Deutsche Gelatine Fabrik Stoess & Co) and Hydrosilk ^R 10000 (Croda).

These protein hydrolyzates can also be reacted with organic acids or acid mixtures such as myristic acid, oleic acid, coconut fatty acid or abietic acid to give condensates which can be used according to the invention. Examples of corresponding commercial products are Lexein ^R A 200 (Inolex), Lamepon ^R P0-TR, Lamepon ^R PA-K, Lamepon ^R S-MV and Lamepon ^R S-TR (Grünau) and Crotein ^R CCT (Croda).

Quaternized products of such protein hydrolyzates are available, for example, as Lexein ^R QX 3000 (Inolex), Crotein ^R Q (Croda) and Croquat ^R WKP (Croda).

The application also relates to the use of the agents according to the invention for treating hair, and to a method for treating hair, in which such an agent is applied to the hair and remains thereon. Examples:

I. Measurements

1.1 Examination of the film picture ability

The investigations were carried out according to the by P. Busch in Ärztel. Cosmetol. 19 (1989), 33, or 306-308. For this purpose, a lock of hair was attached to a measuring head and stretched with the help of a hanger. After loosening, the curl carried out a free, damped oscillation, the parameters stretching, initial amplitude and damping being recorded and evaluated. The following results were obtained (the details of the components are in% by weight of active substance):

Components: Bl VI

- Cetyltrimethylammonium chloride 1, 0 1, 0

- Polyvinylpyrrolidone - 2.0

- alkyl glucoside with = C8--16 ^and dx = 1.4 6.0 -

- ethanol 0.0 30.0

- water ad 10 100 ad 100

Stretching at 15% rel. Moisture and combed streak [J] 0.79 0.40

Initial amplitude [N] 4.6 3.9

Damping maximum with combed

Locke [1 / s] 1.47 0.94

The results show that with an amount of about 6% by weight customary for nonionic surfactants, a greater setting effect is achieved than with a usual amount of nonionic polymer of about 2% by weight. 1.2 "Curl retention" studies

In the curl retention tests, the unhinging behavior of a strand of hair was determined using the following method:

A strand of hair (approx. 9 inches long, approx. 2 g mass) was moved in 10 g of the preparation to be examined for 30 seconds. The strand was then removed from the preparation and adhering preparation was removed by pulling the strand through between the thumb and index finger. The tress was then brushed out until resistance was no longer felt and rolled up onto a medium-sized hair roller overnight. The following morning the winder was removed and the length of the streak was measured. The strand was then brought into a climatic chamber, the relative humidity of which was kept at a value between 60 and 70% by a saturated solution of ammonium chloride and potassium nitrate. After 6 hours, the length of the tress was then measured again.

The "curl retention" value CR is then defined as:

% CR = (LL _t ): (LL ₀ ) + 100%

With:

L: total length of hair strand (9 inches)

L ₀ : length of the strand of hair before storage in the climatic chamber

L Length of the strand of hair after storage in the climatic chamber

The following results were obtained (the components are in% by weight):

Components: B2 V2 V3

Propylene glycol 2.0 2.0 2.0

Dehyton ^R AB 30 ¹ 4.0 4.0 4.0

Alkyl glucoside with R = Ci2-16 ^unc * x = ^1.4 6.0 - -

Polyvinylpyrrolidone - 2.0 - - water ad 100 ad 100 ad 100

% CR 71.4 73.9 44.6

1 fatty amine derivative with betaine structure (approx. 30% active substance in water; CTFA name: Coco-Betaine) (HENKEL)

The results show that almost the same setting effect is achieved with the alkyl glucoside as with a film-forming polymer.

II. Foππulierunqsbeispiele

All figures are in% by weight.

1. Hair fixer

Plantaren ^R 2000 ² 12.0

Dehyquart ^R A3 4.0

Ethanol 30.0

Water ad 100

² alkyl glucoside with R = Cβ-16 ^{and x = 1} , ⁴ (50% active substance) (HENKEL)

3 cetyltrimethylammonium chloride (25% active substance in water; CTFA name: Cetrimonium Chloride) (HENKEL)

2. Hair fixer

Plantaren ^R 2000 6.0

Polyvinyl pyrrolidone 2.0

A 4.0 Dehyquart ^R

Ethanol 30.0

Water ad 100

3. Styling gel (pH 5.6) Plantar ^R 1200 ⁴ 0

Carbopol ^R 98θ5 60.0

Propylene glycol 3.0

Eumulgin ^R HRE 40 ⁶ 2.0

Sodium hydroxide solution (10%) 3.0

Trilon ^R B ⁷ 0.2

Water ad 100

⁴ alkyl glucoside with R = Ci2-16 ^and x = l » ⁴ (approx. 50% active substance; CTFA name: Lauryl polyglycose) (HENKEL)

⁵ polyacrylic acid (GOODRICH); 2% solution in water

6 hardened castor oil + 40 E0 (CTFA name: PEG-40 Hydrogenated Castor Oil) (HENKEL)

⁷ ethylenediaminotetraacetic acid tetra sodium salt (40% active substance in water; CTFA name: Tetrasodium EDTA) (BASF)

4. Hair tip fluid

Plantaren ^R 2000 4.0

Carbopol ^R 980 60.0

Propylene glycol 3.0

Eumulgin ^R HRE 40 2.0

Sodium hydroxide solution (10%) 3.0

Panthenol 0.5

Trilon ^R B 0.2

Water ad 100

5. Pump spray

Plantaren ^R 1200 6.0

Propylene glycol 2.0

Dehyton AB 30 4.0

Water ad 100 6. Pump spray

Plantaren ^R 1200 4.0

Luviskol ^R VA 64 ⁸ 3.0

Propylene glycol 2.0

Dehyton AB 30 4.0

Water ad 100

⁸ vinyl pyrrolidone-vinyl acetate copolymer (60:40) (approx. 50% active substance in water) (HENKEL)

7. Aerosol hair spray

Plantaren ^R 1200 4.0

Polyvinylpyrrole idon 1.0

Propylene glycol 2.0

Ethanol ad 100

8. Hair tonic

Plantaren ^R 1200 3.0

Nicotinic acid adenyl phosphate 0.05

0ctopirox ^R ^ 0.5

Perfume oil q.s.

Dye q.s.

Ethanol 40.0

Water ad 100

9 hydroxy-4-methyl-6 (2,4,4-trimethylpentyl) -2-pyridone, monoethanolamine salt (HOECHST) 9. Hair treatment

Stenol 1618 ¹⁰ 0.8

Gatarol ^R M 30 M ¹¹ 0.4

Glucquat ^R 100 ¹² 0.6

Dehyquart ^R A 1.5

Plantaren ^R 1200 2.4

Acrylamidopropyltrimethylammonium chloride / acrylic acid (3: 1 molar ratio) copolymer, neutralized with NaOH

(Polymer P1 according to DE 3929973) 0.2 water ad 100

¹⁰ Ci6 / Ci8 fatty alcohol (HENKEL)

¹¹ myristyl (3 E0) myristate (CHEM-Y)

¹² N, N-dimethyl-N-dodecyl-N (methyl glucoside + 10 E0-2-hydroxypropyl) ammonium chloride (CTFA name: Lauryl Methyl Gluceth — 10 hydroxypropyl di onium chloride (AMERCH0L)

10. Hair treatment

Stenol 1618 2.0

Myritol ^R 318 ¹³ 0.8

Texapon K 14 S ¹⁴ 1.4

Plantaren ^R 1200 0.8

Luviquat ^R HM 552 * 5 1.2

Water ad 100

13 Fatty acid triglyceride (CTFA name: Caprylic Capric Triglyceride) (HENKEL) ⁴ lauryl myristyl ether sulfate, sodium salt (approx. 28% active substance; CTFA name: Sodium Myreth Sulfate) (HENKEL) 15 vinyl pyrrolidone-vinyl imidazolium methochloride copolymer (20%

Active substance in water; CTFA name: Polyquaternium 16) (BASF)

11. Repair care

Plantaren ^R 1200 0.5

Lamequat ^R Ll6 g _f 8

Nutrilan ^R I 50 * 7 1.6

Cetiol ^R J 60θl ⁸ 0.5

Copherol ^R 125θl9 0.2

Glycerin 5.0

Sepigel 305 ²⁰ 3.0

Ethanol 10.0 dye, preservative, water ad 100

16 cationized collagen hydrolyzate (approx. 35% active substance; CTFA name: Lauryldimonium Hydroxypropyl Hydrolyzed Collagen (HENKEL)

17 collagen hydrolyzate (approx. 50% active substance; CTFA name: Hydro¬ lyzed Collagen) (HENKEL)

1 ⁸ Erucic acid oleylester (CTFA name: Oleyl Erucate) (HENKEL)

19 D-α-tocopheryl acetate (approx. 92% active substance; CTFA name: Tocopheryl Acetate) (HENKEL CORP.)

20 Preparation from dodecyl alcohol + 7E0, isoparaffin and polyacrylamide (CTFA name: Polyacryla ide (and) C13-14-isoparaffin (and) Laureth-7) (HENKEL)

The preparation had a pH of approx. 7.

Claims

Patent claims

1. Hair treatment agent for remaining on the hair in the form of an aqueous, aqueous / alcoholic or alcoholic preparation containing conventional cosmetic ingredients, characterized in that it is an alkyl polyglycoside of the general formula (I)

^R 0- (Z) _X (i)

in which R stands for an alkyl radical with 6 to 22 carbon atoms, Z for a mono- or oligosaccharide, x for a number from 1.1 to 5, or its adduct with 1 to 10 molecules of ethylene oxide and / or propylene oxide.

2. Composition according to claim 1, characterized in that in formula (I) Z stands for glucose and x for a number between 1.1 and 2, in particular for a number between 1.1 and 1.4.

3. Agent according to one of claims 1 or 2, characterized in that the alkyl polyglycoside is contained in an amount of 0.1 to 6 wt .-%, based on the total agent.

4. Agent according to one of claims 1 to 3, characterized in that the agent is a hairspray.

5. Agent according to one of claims 1 to 3, characterized in that the agent is a hair set, a hair dryer or a hair gel.

6. Agent according to claim 4 or 5, characterized in that the agent additionally contains a polymer.

7. Composition according to claim 6, characterized in that it is a nonionic, amphoteric, zwitterionic or anionic Polyme¬ risat.

8. Composition according to one of claims 1 to 7, characterized in that it contains a further surfactant selected from the group of nonionic and cationic surface-active compounds.

9. Agent according to one of claims 1 to 3, characterized in that the agent is a hair tonic.

10. Composition according to claim 9, characterized in that it contains an active ingredient selected from the group consisting of plant extracts, vitamins and anti-dandruff active ingredients.

11. Agent according to one of claims 1 to 10, characterized in that it contains a protein hydrolyzate or protein hydrolyzate derivative.

12. Use of an agent according to any one of claims 1 to 11 for the treatment of hair.

13. A method of treating hair, characterized in that an agent according to one of claims 1 to 11 is applied to the hair and remains on the hair.