CS274093B1 - Admixture into lubrications for glass fibres' surface treatment - Google Patents
Admixture into lubrications for glass fibres' surface treatment Download PDFInfo
- Publication number
- CS274093B1 CS274093B1 CS504389A CS504389A CS274093B1 CS 274093 B1 CS274093 B1 CS 274093B1 CS 504389 A CS504389 A CS 504389A CS 504389 A CS504389 A CS 504389A CS 274093 B1 CS274093 B1 CS 274093B1
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- CS
- Czechoslovakia
- Prior art keywords
- fibers
- lubrications
- admixture
- surface treatment
- glass fibres
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- 239000003365 glass fiber Substances 0.000 title claims description 6
- 238000005461 lubrication Methods 0.000 title abstract description 6
- 238000004381 surface treatment Methods 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 7
- 239000000835 fiber Substances 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- YFHNDHXQDJQEEE-UHFFFAOYSA-N acetic acid;hydrazine Chemical compound NN.CC(O)=O YFHNDHXQDJQEEE-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- -1 oxypropylenes Chemical group 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Description
Vynález ea týká prieady na zníženie laplvoetl filmotvorných látok, do lubrlkácií na úpravu skláněných vlákien.The present invention relates to a primer for reducing laplosetting film formers to glazing fibers.
K povrchové] úpravě eklenených vlákien našli Široká uplatnenie ako filmotvorné látky rožne syntetické e prirodné makroaolekulárne látky, najčastejšie vo formě roztokov a disperzi! či emulzii.For the surface treatment of green fibers, wide use as film-forming substances has been found in various synthetic and natural macro-molecular substances, most often in the form of solutions and dispersions! or emulsion.
Výroba vlákien, či už na principe JednoetupňoveJ alebo dvojstupňové] technologie, spočívá v spájani elementárnych vlákien, «pravidle o počte 200 až 2000 vlákien, do prameňe lubrikáciou a navinutím ne cievky, tzv, kokčny. Pri sušeni kokónov, najčastejšie pri teplotách 110 až 140 °C alebo za normálně] teploty, filmotvorné látky epájajú Jednotlivé elementárne vlékna do celistvého prameňa. V priebehu tohto procesu aa vSak z dovodu lepiváβtl filmotvorných látok neepájejú len vlákna d· pramsňa, ala dochádza aj k vzájoranésu zlepóvaniu prameňov v clevka. Tento Jav sposobuje, žo pri epracovani clavok sa pramene odvíjajú a určitým odporom, ktorý sposobuje neúplné epracovanie cievok a tiež negativno vplýva na textllné vlastnosti, zvlášť pri výrobě zosúkane] prladze. Riešenie tohto problému za použitia látok, minerálnych či syntetických olejov (čs, autorské osvedčenie č. 2S7 484) nie je univerzálně, predovšetkým z dovodu zvýšenia povrchového odporu skloněných vlákien, čo ea negativné projevuje při epracovani vlákien z dovodu zvýšenia elektrostatického náboje,The production of fibers, either on the principle of single-stage or two-stage technology, consists in joining the elementary fibers, the rule of 200 to 2000 fibers, into the strand by lubricating and winding the coil, the so-called coke. When drying the cocoon, most often at temperatures of 110 to 140 ° C or at normal temperature, the film-forming substances adhere to the individual elementary strands into an integral strand. In the course of this process, and because of the adhesive of the film-forming substances, not only the strands of the strand are bonded together, but there is also an increased bonding of the strands into the funnel. This phenomenon causes the strands to unwind when the studs are reworked, and with some resistance, which causes incomplete reworking of the bobbins and also negatively affects the textile properties, especially in the production of the twisted yarn. The solution to this problem by using substances, mineral or synthetic oils (MS, author's certificate No. 2S7 484) is not universally, especially because of the increase in the surface resistance of the inclined fibers, which also has a negative effect on the processing of the fibers due to the electrostatic charge.
Zietili eme, že tieto problémy je možná účinné riešif použitím zlúčenín podle vynálezu. Podstata vynálezu epočiva v tom, že ββ používajú segmentové polyméry etylónoxldu a propylónoxidu a koncovými oxypropylónovými eegmentaml, ktoré obsahujú 15 ež 70 % hmotnosti polyetoxeméru v molekule, o priemernej molekulové] hmotnosti 400 až 3500, ako priaady na zníženie lepivosti filmotvorných látok do lubrikácii na úpravu povrchu skleněných vlákien.It has been found that these problems can be effectively solved by using the compounds of the invention. The principle of the invention is that ββ uses segmental polymers of ethyloneoxide and propyl oxide and terminal oxypropylone eegmentaml containing 15 to 70% by weight of a polyetoxomer per molecule, with an average molecular weight of 400 to 3500, as additives to reduce the tackiness of film forming agents to lubricate glass fiber surface.
Toto použitie týchto zlúčenín Je založené na empirlckom zlatěni, že uvedené polyméry, ktoré obsahujú na koncových segmentech oleofilné oxypropylénové jednotky, znižujú lepivost filmotvorných látok, Týmto ea odlišujú od etylónoxld-propylánoxidových polymérov připravovaných tak,' že hydrofilné segmenty eú na koncoch polyméru (Blažej A. a kol.: Tenzidy, ALFA Bratislava 1977 str. 92).This use of these compounds is based on empirical gold that said polymers, which contain oleophilic oxypropylene units at the end segments, reduce the tackiness of the film-forming substances, thereby distinguishing them from the ethylone-propylene oxide polymers prepared by hydrophilic eu segments at the ends of the polymer. et al .: Surfactants, ALFA Bratislava 1977 p. 92).
Výhoda riešenia podlá vynálezu epočiva hlavně v tom, že vymedzená skupina polymérov nislsnže výrazné znižuje lepivost, ala aj nezhoršuje elektrostatické vlastnosti eklenených vlákien a sú prakticky zdravotně aj ekologicky minimálně závadné. Skloněné vlákna je možná používat pře výstuž plastov bez negativného vplyvu na zlepšenie sdhézie, Z dovodu, že celý rad týchto zlúčenín Je nerozpustný vo vodě. Je ich možné aplikovat do vodných lubrlkečných kompozici! buď vo formě emulzii či kololdných roztokov ze použitia či už róznych tenzidov, emulgátorov, hydrofllných vo vodě rozpustných polymérov, mazadiel a pod. Zníženie lepivosti skloněných prameffov vo formě kokónov sposobuje, že vlékne sa z cievok Íahko odvíjajú, čo má kladný dopad na textllné epracovanie a zníženie sklovláknltého odpadu.The advantage of the solution according to the invention is, in particular, that the defined group of polymers is noticeably low in tack, but does not deteriorate the electrostatic properties of the yarns, and is practically harmless in terms of health and ecology. The inclined fibers may be used to reinforce the plastics without adversely affecting the improvement, since many of these compounds are insoluble in water. They can be applied to aqueous lubricant compositions! either in the form of emulsions or colloidal solutions from the use of either different surfactants, emulsifiers, hydrophilic water-soluble polymers, lubricants and the like. Decreasing the stickiness of the inclined strands in the form of cocoon makes it easy to pull from the reels, which has a positive impact on textile processing and reduction of glass fiber waste.
Vynález je ďalej objasněný formou príkladov, v ktorých zloženie je uvádzané v hmotnostně] koncentrácli*The invention is further elucidated by way of examples in which the composition is given by weight of concentrate
Přiklad 1Example 1
Ako přisedá do lubrikácii se použili následovně segmentové polyméry etylénoxidu a propylénoxldu s koncovými oxypropylé novými eegmentaml:Segmented polymers of ethylene oxide and propylene oxide with terminal oxypropylenes of new eegmentam were used as sits for lubrication:
A - polymér o priemernej molekulové] hmotnosti 500 e 20 % polyetoxeméruA - a polymer having an average molecular weight of 500 to 20% of a polyetoxomer
B - polymér o priemernej molekulové] hmotnosti 1 200e 50 % polyetoxeméruB-polymer having an average molecular weight of 1,200 and 50% of a polyetoxomer
C - polymér o priemernej molekulové] hmotnosti 3 500 s 65 % polyetoxeméruC-polymer having an average molecular weight of 3,500 with 65% polyetoxomer
Základná lubrlkácia obsahovala 10 % polyvinylacetátové] disperzie (sušina 50 %) plastifikovanej 20 % dibutylftalátu, 0,5 % aromatického diallanu na báze ftalanhydridu a 3-aminopropyltrietoxysilan (sušina 50 %), 0,4 % 12,5 % emulzie acetátu amlnoamldu na báze dietyléntriaminu e kyselinou olejovou, 0,05 % uvedených segmentových polymérov etylenoxlCS 274093 Bl du a propylenoxldu a zbytok do 100 % vody. Pri připrava roztokov segmentových polymérov aa poatupovalo tak, že před ich přidáním do vody ae emulgovali na koloidnó roztoky zmieSaním a uvedeným acetótom aminoamidu. Lubrikécie ae použili na úpravu skloněných vlákien z E-ekla o priamernej hrúbke 13 pm. Upravené aklanené vlákna vo forma kokónov aa vyeuSili pri teplote 125 °C a použili k výrobě aekaných vlákien. Voči Standartu, t.j. bez uvedených segmentových polymérov v lubrikácii, aa kokóny skleněných vlákien podstatné IahSie připravovali na aekanle,' čo zlepšuje pracovně podmienky, a znížil ea podiel neapracovaného vlákna.Basic lubrication contained 10% polyvinyl acetate] dispersions (dry matter 50%) plasticized 20% dibutyl phthalate, 0.5% aromatic diallan based on phthalic anhydride and 3-aminopropyltriethoxysilane (dry matter 50%), 0.4% 12.5% ammonium amide acetate emulsion diethylenetriamine e with oleic acid, 0.05% of said segmented polymers of ethylene oxide / CS 274093 Bl and propylene oxide, and the remainder to 100% water. In the preparation of the segment polymer solutions aa, they were emulsified into the colloidal solutions by mixing with said aminoamide acetate prior to their addition to water. Lubricants ae were used to treat the inclined fibers of E-ekl with a direct thickness of 13 µm. The treated aclanted fibers in the form of a cocoon aa were dried at 125 ° C and used to produce leaked fibers. In relation to the Standard, i. without said segmental polymers in lubrication, and a glass fiber cocoon was substantially prepared on the aekanle, which improves the working conditions, and reduced the unprocessed fiber content.
Přiklad 2Example 2
Základná lubrikácia ea skladala z 10 % aduktu na báze epoxidovéJ živice o prlemarneJ molekulovej hmotnoati 380, dietyléntriaminu a dietanolamínu v molárnom pomere 1:0,3(1 (auSino 50 %), 0,3 % kyseliny octovej, 0,3 % kyseliny boritej, 2,2 % mazadla na báze monopropylónglykolu, 0,5 % kopolyméru oxiranu a mataloxiranu a.mastnými alkoholml, 1 % segmentového polyméru etylénoxidu a propylónoxidu a koncovými oxypropylénovými aagmentami o priemer nej molekulovej hmotnoati 1200 a 50 % polyetoxaméru a zbytok do 100 % vody. Postup přípravy uvedenaj lubrikécie spočívá v tom, že prialuSnó množstvo aduktu opoxidovaj živice ae zmieše a kyselinou octovou, segmentovým polymérom etylénoxidu a propylónoxidu a po zriadani vodou přidá do hlavného množstva vody potrebnej k príprave lubrikácia. Ostatně zložky aa prldajú priamo do lubrikaónej vody. Lubrikécie aa použila na úpravu skláněných vlákien o priemernej hrúbke 9 jim,1 použitých k výrobě tkenln pre elektropriemysel či obalovanie rozných vodičov, Sklovlóknitý hodváb Je epracovatelný, nelepí a lahko aa odvija pri textllnom spracovaní, čo umožňuje Jeho efektlvne epracovanie.The base lubrication ea consisted of a 10% adduct based on epoxy resin with a molecular weight of 380, diethylenetriamine and diethanolamine in a molar ratio of 1: 0.3 (1 (auSino 50%), 0.3% acetic acid, 0.3% boric acid) 2.2% monopropylone glycol based lubricant, 0.5% oxirane / mataloxirane copolymer and fatty alcohols, 1% segmented polymer of ethylene oxide and propyl oxide and terminal oxypropylene agglomerates with an average molecular weight of 1200 and 50% polyetoxamer and the remainder to 100% water The process for preparing said lubricant comprises mixing an additional amount of the opoxic resin adduct and mixing it with acetic acid, a segmented polymer of ethylene oxide and propyl oxide, and, after water has been added, to the main amount of water required to prepare the lubricant. aa used to treat glass fibers with an average thickness of 9 µm, 1 used to make for the electrical industry or for the coating of various conductors.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS504389A CS274093B1 (en) | 1989-08-30 | 1989-08-30 | Admixture into lubrications for glass fibres' surface treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS504389A CS274093B1 (en) | 1989-08-30 | 1989-08-30 | Admixture into lubrications for glass fibres' surface treatment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS504389A1 CS504389A1 (en) | 1990-08-14 |
| CS274093B1 true CS274093B1 (en) | 1991-04-11 |
Family
ID=5394527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS504389A CS274093B1 (en) | 1989-08-30 | 1989-08-30 | Admixture into lubrications for glass fibres' surface treatment |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS274093B1 (en) |
-
1989
- 1989-08-30 CS CS504389A patent/CS274093B1/en unknown
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| Publication number | Publication date |
|---|---|
| CS504389A1 (en) | 1990-08-14 |
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