CS266992B1 - Glass for glass fibre - Google Patents
Glass for glass fibre Download PDFInfo
- Publication number
- CS266992B1 CS266992B1 CS882847A CS284788A CS266992B1 CS 266992 B1 CS266992 B1 CS 266992B1 CS 882847 A CS882847 A CS 882847A CS 284788 A CS284788 A CS 284788A CS 266992 B1 CS266992 B1 CS 266992B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- glass
- molar concentration
- oxide
- asbestos
- concentration
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 21
- 239000003365 glass fiber Substances 0.000 title claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 11
- 239000000395 magnesium oxide Substances 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 239000010425 asbestos Substances 0.000 abstract description 8
- 229910052895 riebeckite Inorganic materials 0.000 abstract description 8
- 239000004568 cement Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 2
- 229910052708 sodium Inorganic materials 0.000 abstract description 2
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 238000007496 glass forming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910018967 Pt—Rh Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/001—Alkali-resistant fibres
- C03C13/002—Alkali-resistant fibres containing zirconium
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Podstatou riešenia je sklo pre skleně né vlákno, ktoré obsahuje v molárnej koncentrácii 7 až 8 % ZrC>2, 14 až 15 % Na2O, 4,6 až 6,0 % CaO, 2,5 až 3,5 % BaO, 3 až 5 % MgO, 0,5 až 2,0 % T1O2 a 64 až 68 % S1O2. Molárna koncentrácia CaO v skle je vyššia ako molárna koncentrácia MgO a molárna koncentrácia MgO je vyššia ako molárna koncentrácia BaO. Výhodou riešenia je zníženie energetickej náročnosti taviaceho procesu a tiež náhrada azbestu skleně nými vláknami v azbestocementových výrobkoch.The essence of the solution is glass for glass fiber which contains it in molar concentration 7 to 8% ZrC 2, 14 to 15% Na 2 O, 4.6 up to 6.0% CaO, 2.5 to 3.5% BaO, 3-5% MgO, 0.5-2.0% T102 and 64-68% SiO2. The molar concentration of CaO in the glass is higher as MgO molar concentration and molar concentration MgO concentration is higher than molar BaO concentration. The advantage of the solution is reducing the energy intensity of the melter process as well as replacement of asbestos glass fiber in asbestos cement products.
Description
Vynález sa týká zloženia skla pre skleněné vlákno vhodné najma na výstuž cementových kompozitov a ako náhrada azbestu v azbestocementových výrobkooh. 'The present invention relates to a glass fiber composition suitable for reinforcing cementitious composites and as a substitute for asbestos in asbestos-cement products. '
Pre sklo vhodné na výrobu skleněného vlákna je dčležitá viskozita a teplota liquidus, teda vlastností, ktoré charakterizujú tvarovatelnosť skloviny na vlákna. Teplota tvarovania skloviny na vlákno je charakterizovaná teplotou pri viskozitě skloviny rovnajúcej sa 100 Pa.s. Pre sklo vhodné na výrobu skleněného vlákna je potřebné, aby teplota tvarovania bola vyššia ako teplota liquidus, najvýhodnejŠie aspoň o 40 °C.Viscosity and temperature of the liquidus are important for glass suitable for the production of glass fiber, a property that characterizes the formability of glass into fibers. The fiber forming temperature of the glass is characterized by a temperature at a glass viscosity of 100 Pa.s. For glass suitable for the production of glass fiber, it is necessary that the forming temperature be higher than the liquidus temperature, most preferably at least 40 ° C.
Pri výrobě skleněného vlákna vhodného na výstuž cementových kompozitov a ako náhrada azbestu v azbestocementových výrobkoch sa v súčasnosti najčastejšie použiva sklo charakterizované chemickým zložením v hmotnostnej koncentrácii 62,8 % oxidu křemičitého, 14,8 % oxidu sodného, 5,6 % oxidu vápenatého a 16,8 % oxidu zirkoničitého, ktorého teplota tvarovania skloviny na vlákno je 1 300 °C.In the manufacture of glass fiber suitable for reinforcing cementitious composites and as a substitute for asbestos in asbestos-cement products, glass characterized by chemical composition at a concentration of 62.8% by weight of silica, 14.8% by weight of sodium, 5.6% by weight of calcium and , 8% zirconium dioxide, the glass forming temperature of which is 1300 ° C.
Nevýhodou skla uvedeného zloženia je vysoká energetická náročnost na tahanie skloviny do vlákna, zapříčiněná vysokou teplotou tvarovania.A disadvantage of the glass of this composition is the high energy consumption of drawing glass into the filament due to the high molding temperature.
Vyššie uvedenú nevýhodu odstraňuje sklo pre skleněné vlákno podlá tohoto vynálezu, ktorého podstatou je, že v molárnej koncentrácii obsahuje 7 až 8 % oxidu zirkoničitého, až 15 % oxidu sodného, 4,6 až 6,0 % oxidu vápenatého, 2,5 až 3,5 % oxidu bárnatého, až 5 % oxidu horečnatého, 0,5 až 2,0 % oxidu titaničltého a 64 až 68 % oxidu křemičitého, pričom molárna koncentrácia oxidu vápenatého v skle je vyššia ako molárna koncentrácia oxidu horečnatého a molárna koncentrácia oxidu horečnatého je vyššia ako molárna koncentrácia oxidu bárnatého.The above-mentioned disadvantage is eliminated by the glass fiber glass according to the invention, which consists in that it contains 7 to 8% zirconium oxide, up to 15% sodium oxide, 4.6 to 6.0% calcium oxide, 2.5 to 3 in molar concentration. 5% barium oxide, up to 5% magnesium oxide, 0.5 to 2.0% titanium dioxide and 64 to 68% silica, the molar concentration of calcium in the glass being higher than the molar concentration of magnesium oxide and the molar concentration of magnesium oxide is higher than the molar concentration of barium oxide.
Zníženie energetickej náročnosti pri spracovaní skla na vlákno sa dosiahne vzájomnou kombináciou obsahu oxidu bárnatého, vápenatého a oxidu horečnatého v skle, čím sa zníži teplota tvarovania pod 1 200 °C pri zachovaní dostatočného rozdielu 40 °C medzi teplotou tvarovania a teplotou liquidus a súčasne sa získá zo skla skleněné vlákno s dobrou alkalivzdornostou.Reducing the energy intensity of glass processing into a fiber is achieved by combining the barium, calcium and magnesium oxide contents of the glass together, thereby reducing the forming temperature to below 1200 ° C, while maintaining a sufficient 40 ° C difference between the forming temperature and the liquidus temperature. Glass fiber glass with good alkalinity.
Podstata vynálezu je objasněná příkladným chemickým zložením skla v molárnej koncentrácii 7,3 % oxidu zirkoničitého, 14,8 % oxidu sodného, 5,1 % oxidu vápenatého, 3,2 % oxidu horečnaté ho, 2,6 % oxidu bárnatého, 1,6 % oxidu titaničltého a 65,4 % oxidu křemičitého, ktorého teplota tvarovania je 1 195 °C, teplota liquidus 1 154 °C a odolnost voči alkáliám podía ČSN 70 0533 je 10,2 mg/(100 cm2).The principle of the invention is illustrated by the exemplary chemical composition of glass at a molar concentration of 7.3% zirconia, 14.8% sodium oxide, 5.1% calcium oxide, 3.2% magnesium oxide, 2.6% barium oxide, 1.6%. % of titanium dioxide and 65.4% of silica having a forming temperature of 1195 ° C, a liquidus temperature of 1154 ° C and an alkali resistance according to CSN 70 0533 of 10.2 mg / (100 cm 2 ).
Výhoda skla pre skleněné vlákno vhodné najma na výstuž cementových kompozitov a ako náhrada azbestu v azbestocementových výrobkoch spočívá v znížení energetických nárokov na výrobu skleněných vlákien v dčsledku zníženia teploty tvarovania skloviny na vlákno, čím sa súčasne predlžuje životnost Pt-Rh pecí, v ktorých sa sklovina spracováva.The advantage of glass for glass fiber, suitable especially for reinforcing cementitious composites and as a substitute for asbestos in asbestos-cement products, is the reduction of energy requirements for glass fiber production due to lowering the glass forming temperature to fiber, thereby extending the service life of Pt-Rh furnaces processes.
Použitie alkalivzdorných skiel a skleněných vlákien odolávajúcich alkalickému prostrediu umožní širší rozvoj priemyslu vyrábajúceho kompozitné materiály zo sklovláknitou výstužou. Ďalšou přednostou je možnost náhrady azbestu v azbestocementových výrobkoch skleněnými vláknami, čím sa vylúčia karcinogénne účinky preukázané u azbestu a azbestových výrobkoch.The use of alkali-resistant glass and alkali-resistant glass fibers will allow for a wider development of the fiberglass reinforced composite industry. A further advantage is the possibility of replacing asbestos in asbestos-cement products with glass fibers, thus avoiding the carcinogenic effects shown in asbestos and asbestos products.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS882847A CS266992B1 (en) | 1988-04-27 | 1988-04-27 | Glass for glass fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS882847A CS266992B1 (en) | 1988-04-27 | 1988-04-27 | Glass for glass fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS284788A1 CS284788A1 (en) | 1989-05-12 |
| CS266992B1 true CS266992B1 (en) | 1990-01-12 |
Family
ID=5366766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS882847A CS266992B1 (en) | 1988-04-27 | 1988-04-27 | Glass for glass fibre |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS266992B1 (en) |
-
1988
- 1988-04-27 CS CS882847A patent/CS266992B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS284788A1 (en) | 1989-05-12 |
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