CS261089B1 - Raw mixture for white decorative ceramic dye stuff production - Google Patents

Raw mixture for white decorative ceramic dye stuff production Download PDF

Info

Publication number
CS261089B1
CS261089B1 CS871461A CS146187A CS261089B1 CS 261089 B1 CS261089 B1 CS 261089B1 CS 871461 A CS871461 A CS 871461A CS 146187 A CS146187 A CS 146187A CS 261089 B1 CS261089 B1 CS 261089B1
Authority
CS
Czechoslovakia
Prior art keywords
oxide
traces
white decorative
cerium
preparation
Prior art date
Application number
CS871461A
Other languages
Czech (cs)
Slovak (sk)
Other versions
CS146187A1 (en
Inventor
Pavol Hlodak
Stefan Kovacik
Stefan Varga
Ladislav Sarvas
Original Assignee
Pavol Hlodak
Stefan Kovacik
Stefan Varga
Ladislav Sarvas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pavol Hlodak, Stefan Kovacik, Stefan Varga, Ladislav Sarvas filed Critical Pavol Hlodak
Priority to CS871461A priority Critical patent/CS261089B1/en
Publication of CS146187A1 publication Critical patent/CS146187A1/en
Publication of CS261089B1 publication Critical patent/CS261089B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

Zlepšenie pretavenosti bielych dekoračných keramických farieb a dosiahnutie vysokého· stupňa bělosti sa dosiahne dodržením hmotnostného zastúpenia jednotlivých komponentov surovinovej zmesi, a to: 52 až 77 % frít obsahujúcich 10 až 30 % oxidu křemičitého, 45 až 70 % oxidu olovnatého, 8 až 25 % oxidu boritého, stopy — 7 % oxidu hlinitého, stopy — 6 °/o oxidu vápenatého, stopy — 2 % oxidu horečnatého, stopy — 3 % oxidu draselného, stopy — 3 pere. oxidu sodného, stopy — 3 % oxidu zinočnatého·; 23 až 48 % cérového preparátu. Cérový preparát musí obsahovat minimálně 90 % oxidu céričitého. Cérový preparát možno v zložení nahradit do výšky 68 % jeho hmotnostného obsahu technicky čistým oxidom cíničitým. Biela dekoračná keramická farba sa uplatní pri dekorácii obkladových materiálov spotrebnej keramiky, umeleckej keramiky, a pod.Improvement of white decorative refinement ceramic colors and achieving a high · the degree of whiteness is achieved by adherence weight representation of the individual raw material components, namely: 52 up to 77% of flakes containing 10 to 30% oxide silica, 45 to 70% lead oxide, 8 to 25% boric oxide, traces - 7% alumina, traces of - 6 ° / o calcium oxide, traces - 2% magnesium oxide, traces - 3% potassium oxide, traces - 3 pen. sodium oxide, trace - 3% oxide · zinc; 23-48% cerium preparation. The cerium preparation must contain at least 90% of cerium oxide. Cereal preparation can be replaced in height 68% of its weight content technically pure tin dioxide. White decorative ceramic color is used for decoration consumer ceramic lining materials artistic ceramics, and the like.

Description

Vynález sa týká zloženia surovinovej zmesi pre výrobu bielej dekoračnej keramickej farby, ktorá po* nanesení na glazúru a po výpale má vytvárať vysokobiely a přetavený dekor. Keramická dekoračná farba připravená zo surovinové] zmesi sa vypaluje pri teplote 940—1 000 °C.The invention relates to a composition of a raw material composition for the production of a white decorative ceramic paint which, when applied to the glaze and after firing, is intended to produce high-white and remelted decor. The ceramic decorative paint prepared from the raw material mixture is fired at a temperature of 940-1000 ° C.

Doteraz používané biele dekoračně keramické farby sú připravované z komerčně vyrábaných zmesi na báze Zr/Si a Zr/Ce. Dekoračně keramická farba sa zamiefa spolu s rozrábacím médiom na požadovaná jemnost Povrch vypálenej keramickej farby možno charakterizovat pri dostatočnej bělosti, ako nie vždy dobré přetavený a u dobře pretavenej keramickej farby je belosť nedostatočná.The white decorative ceramics used hitherto are prepared from commercially produced mixtures based on Zr / Si and Zr / Ce. The decorative ceramic paint is targeted together with the cutting medium for the desired fineness. The surface of the fired ceramic paint can be characterized with sufficient whiteness than not always good remelting, and in a well remelted ceramic paint the whiteness is insufficient.

Uvedené nedostatky odstráňuje biela dekoračná keramická farba připravená zo surovinové]' zmesi podfa vynálezu, ktorej podstatou je, že pozostáva hmotnostně z 52— —77 % frít obsahujúcich 10—30 % SiCU, 45—70 % PbO, 8—25 % B2O3, stopy — 7 θ/ο A12O3, stopy — 6 % CaO, stopy — 2 % MgO, stopy — 3 % K2O, stopy — 3 % Na2l0, stopy — 3 % ZnO a z 23—48 % cenového preparátu obsahujúceho* hmotnostně minimálně 90 % CeO3 a ako zvyšok oxidy prvkov vzácných zemin a nečistoty.These drawbacks are overcome by the white decorative ceramic paint prepared from the raw material composition according to the invention, which consists of 52-77% by weight of frits containing 10-30% SiCU, 45-70% PbO, 8-25% B 2 O 3 , trace - 7 θ / ο A1 2 O 3 , trace - 6% CaO, trace - 2% MgO, trace - 3% K 2 O, trace - 3% Na 2l 0, trace - 3% ZnO up to 23—48 % of a pricing preparation containing at least 90% CeO 3 by weight and, as a remainder, rare earth oxides and impurities.

Obsah cérového preparátu možno nahradit v zložení až do výšky 68 % jeho obsahu technicky čistým SnO2. Frity sa zamiefajú spolu s prídavkom cérového preparátu, resp. s prídavkom cérového preparátu a technicky čistého SnO3 na požadovaná jemnost. Mletie prebieha spolu s nosným médiom pri obsahu sušiny nad 55 %. Po zomletí a dosiahnutí optimálnych Teologických vlastností je keramická farba vhodná na nanášanie.The content of cerium preparation can be replaced in the composition up to 68% of its content by technically pure SnO 2 . The frits are mixed together with the addition of the cereal preparation, respectively. with the addition of cerium preparation and technically pure SnO 3 to the required fineness. The grinding is carried out together with the carrier medium at a dry matter content above 55%. After grinding and achieving optimal theological properties, the ceramic paint is suitable for application.

Dodržaním zloženia surovinovej zmesi pre výrobu bielej dekoračnej keramickej farby podfa vynálezu získáme bielu dekoračnú keramičku farbu, výpalom ktorej dosiahneme dokonale hladký, přetavený a vysokobiely povrch naneseného dekoru. Biela dekoračná keramická farba připravená zo* surovinovej zmesi podfa vynálezu je vhodná na všetky druhy glazur, ktoré sú na báze SiO2 a B2O3.By adhering to the composition of the raw material composition for the production of the white decorative ceramic paint according to the invention, we obtain a white decorative ceramic paint by firing to obtain a perfectly smooth, melted and high white surface of the applied decor. The white decorative ceramic paint prepared from the raw material mixture according to the invention is suitable for all types of glazes which are based on SiO 2 and B 2 O 3 .

Příklady konkrétnej přípravy a použitia bielej dekoračnej keramickej farby. Příklad 1Examples of particular preparation and use of white decorative ceramic paint. Example 1

Hmotnostně zloženie surovinovej zmesi pre výrobu bielej dekoračnej keramickej farby:Weight composition of raw material mixture for production of white decorative ceramic paint:

frita zloženiafrit composition

SiO2 — 24,69 %,SiO 2 - 24.69%,

PbO — 53,48 «/o,PbO - 53.48 «/ o,

BoO3 — 9,01 %,BoO 3 - 9.01%,

CaO — 4,9 %,CaO - 4.9%,

A12O3 - 5,86 %,A1 2 O 3 - 5.86%,

Na2O — 0,47 %,Na 2 O - 0.47%,

K2O — 1,59 % 76 % cérový preparát 24 %K 2 O - 1,59% 76% cereal preparation 24%

Navážené suroviny sa mefú s monopropylénglykolom na zvyšok 0,1 % na site 0,063. Hmotncstný obsah sušiny je 66,5 %. Nanášanie je realizované sietotlačou cez šito* 62 T 100 mikrónovej okatosti. Odekorované výrobky sa vypafujú pri teplote 950 °C v tunelovej muflovej peci. Doba výpalu je 22 hodin.The weighed raw materials are measured with monopropylene glycol to a residue of 0.1% on a sieve of 0.063. The dry matter content was 66.5%. Application is performed by screen printing through a 62 T 100 micron mesh screen. The peeled products are fired at 950 ° C in a tunnel muffle furnace. The firing time is 22 hours.

Příklad 2Example 2

Hmctnostné zloženie surovinovej zmesi pre výrobu bielej dekoračnej keramickej farby:Weight composition of raw material mixture for production of white decorative ceramic paint:

frita zloženiafrit composition

SiO2 — 13,58 %,SiO 2 - 13.58%,

PbO — 60,39 Ψο,PbO - 60.39 ,ο,

BaO3 — 23,13 %,B and O 3 - 23.13%,

A12O3 - 0,54 o/o,A1 2 O 3 - 0.54 o / o

CaO - 0,21 %,CaO - 0.21%,

MgO — 0,21 %,MgO - 0.21%,

ZnO — 1,94 % 55 % cérový preparát 45 %ZnO - 1.94% 55% cereal preparation 45%

Navážené suroviny sa mefú s monopropylénglykolom na zvyšok 0,1 % na site 0063. Hmotnostný obsah sušiny je 66,5 %. Nanášani-e, teplota, doba a miesto výpalu ako v příklade 1.The weighed raw materials are treated with monopropylene glycol to a residue of 0.1% on sieve 0063. The dry matter content is 66.5%. Application, temperature, time and place of firing as in Example 1.

Příklad 3Example 3

Hmotnostně zloženie surovinovej zmesi pre výrobu bielej dekoračnej keramickej farby:Weight composition of raw material mixture for production of white decorative ceramic paint:

frita zloženiafrit composition

SiO2 — 13,68 %,SiO 2 - 13.68%,

PbO — 60,39 %,PbO - 60.39%

B2O3 - 23,13 θ/ο,B 2 O 3 - 23.13 θ / ο,

A13O3 - 0,54 0/0) A1 3 O 3 - 0.54 (0/0 )

CaO — 0,21 o/o,CaO - 0.21 o / o,

MgO - 0,21 «/o,MgO - 0,21 «/ o,

ZnO — 1,94 o/o 70% cérový preparát 15 % technicky čistý oxid cíničitý 15 %ZnO - 1.94 o / o 70% cerium preparation 15% technically pure tin oxide 15%

Navážené suroviny sa mefú s monopropylénglykoiom na zvyšok 0,1 o/o na site 0063. Hmotnostný obsah sušiny je 66,5 °/o. Nanášanie, teplota, doba a miesto výpalu akoi v příklade 1.The weighed raw materials are measured with monopropylene glycol to a residue of 0.1 o / o on sieve 0063. The dry matter content is 66.5%. Application, temperature, time and place of firing as in Example 1.

Povrch vypálenej bielej dekoračnej keramickej farby vytvorenej zo surovinovej zmesi podfa vynálezu sa javí ako dokonale hladký a vysokobiely.The surface of the fired white decorative ceramic paint formed from the raw material composition of the invention appears to be perfectly smooth and high white.

Biela dekoračná keramická farba zo surovinovej zmesi podfa vynálezu sa osvědčila v prevádzkových skúškach pri dekorácii obkladačiek. Uplatní sa pri dekorácii obkladových materiálov, ako aj inej spotrebnej keramiky, umeleckej keramiky a pod.The white decorative ceramic paint of the raw material composition according to the invention has proven itself in operational tests for the decoration of tiles. It is used for decoration of cladding materials as well as other consumer ceramics, art ceramics and the like.

?, 6 1 Π 8 9? 6 6 Π 8 9

Claims (2)

PREDMETSUBJECT 1. Surovinová zmes pre výrobu bielej dekoračnej keramickej farby vyznačujúca sa tým, že sa skládá hmotnostně z 52—77 % frít obsahujúcich 10—30 % oxidu křemičitého, 45—70 % oxidu olovnatého, 8—2'5 % oxidu boritého, stopy — 7 % oxidu hlinitého, stopy — 6 % oxidu vápenatého, stopy — 2 % oxidu horečnatého, stopy — 3 % oxidu draselného, stopy — 3 % oxidu sodného, stopy — 3 % oxidu zinočnatého a z1. Raw material mixture for the production of white decorative ceramic paint, characterized in that it consists of 52-77% frits containing 10-30% silica, 45-70% lead oxide, 8-2.5% boron oxide, traces - 7% alumina, traces - 6% calcium oxide, traces - 2% magnesium oxide, traces - 3% potassium oxide, traces - 3% sodium oxide, traces - 3% zinc oxide and VYNALEZUWe claim: 23—48 % cérového preparátu obsahujúceho hmotnostně minimálně 90 °/o oxidu céričitého a ako zvyšok oxidy prvkov vzácných zemin a nečistoty.23-48% of a cerium preparation containing at least 90% by weight of cerium oxide and, as a remainder, rare earth oxides and impurities. 2. Surovinová zmes pre výrobu bielej dekoračnej keramickej farby podía bodu 1, vyznačujúca sa tým, že cérový preparát je nahrazen do výšky 68 % jeho obsahu technicky čistým oxidom cíničitým.2. Raw material mixture for the production of white decorative ceramic paint according to claim 1, characterized in that the cereal preparation is replaced up to 68% of its content by technically pure tin oxide.
CS871461A 1987-03-05 1987-03-05 Raw mixture for white decorative ceramic dye stuff production CS261089B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CS871461A CS261089B1 (en) 1987-03-05 1987-03-05 Raw mixture for white decorative ceramic dye stuff production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CS871461A CS261089B1 (en) 1987-03-05 1987-03-05 Raw mixture for white decorative ceramic dye stuff production

Publications (2)

Publication Number Publication Date
CS146187A1 CS146187A1 (en) 1988-06-15
CS261089B1 true CS261089B1 (en) 1989-01-12

Family

ID=5349054

Family Applications (1)

Application Number Title Priority Date Filing Date
CS871461A CS261089B1 (en) 1987-03-05 1987-03-05 Raw mixture for white decorative ceramic dye stuff production

Country Status (1)

Country Link
CS (1) CS261089B1 (en)

Also Published As

Publication number Publication date
CS146187A1 (en) 1988-06-15

Similar Documents

Publication Publication Date Title
CN106277793B (en) A kind of glaze of high temperature gold colored glaze face brick, brick and preparation method thereof
EP0402007B1 (en) Glass composition for use in glazes
US7892997B2 (en) Glaze compositions
RU2060233C1 (en) Frit
CN105198217B (en) It is a kind of to be used for throwing vitreous brick production entirely, beneficial to the ground-coat enamel of ceramic ink color development
EP2000443B1 (en) Metallic glaze composition
CN111253072A (en) Ceramic glaze with good wear resistance and high hardness and preparation method thereof
CN107098588B (en) A kind of transparent glass-ceramics glaze and its preparation method and application
CN110330313A (en) A kind of Dehua lard white ware porcelain and preparation method thereof
CN108298818A (en) Enamel ceramics mica titanium perlatolic glaze and its glaze slip preparation method and application
GB2068933A (en) Lead free glazes for alumina bodies
CN115124244A (en) Transparent frit, crystalline wear-resistant glaze, glazed brick and preparation method thereof
CN112299718A (en) Magnesium aluminate spinel wear-resistant printing glaze and preparation method and application thereof
US20050130824A1 (en) Transparent tile glaze
JPS565348A (en) Color ceramic and color frit composition for automobile glass plate
JPH0374177B2 (en)
CS261089B1 (en) Raw mixture for white decorative ceramic dye stuff production
SU967978A1 (en) Glaze
JPS565349A (en) Color ceramic and color frit composition
CN1023698C (en) Formula for making porcelain glaze with Ti-containing slag
GB2301100A (en) Glass flux composition
SU1004285A1 (en) Opacified glaze
SU1031927A1 (en) Brown ceramic pigment
SU1222645A1 (en) Mat glaze
FR2531700A1 (en) Crystal pptn. glazing compsn.