CS231255B1 - Method of depositing of copper layers on glass surface - Google Patents
Method of depositing of copper layers on glass surface Download PDFInfo
- Publication number
- CS231255B1 CS231255B1 CS807476A CS747680A CS231255B1 CS 231255 B1 CS231255 B1 CS 231255B1 CS 807476 A CS807476 A CS 807476A CS 747680 A CS747680 A CS 747680A CS 231255 B1 CS231255 B1 CS 231255B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- solution
- depositing
- copper layers
- glass surface
- apa apa
- Prior art date
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims 3
- 229910052802 copper Inorganic materials 0.000 title claims 3
- 239000010949 copper Substances 0.000 title claims 3
- 239000011521 glass Substances 0.000 title claims 3
- 238000000034 method Methods 0.000 title claims 3
- 238000000151 deposition Methods 0.000 title claims 2
- 239000000243 solution Substances 0.000 claims 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 1
- 206010070834 Sensitisation Diseases 0.000 claims 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000007747 plating Methods 0.000 claims 1
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 claims 1
- 230000008313 sensitization Effects 0.000 claims 1
- 239000001476 sodium potassium tartrate Substances 0.000 claims 1
- 235000011006 sodium potassium tartrate Nutrition 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 235000011150 stannous chloride Nutrition 0.000 claims 1
- 239000001119 stannous chloride Substances 0.000 claims 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims 1
- 101710134784 Agnoprotein Proteins 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 description 1
- 238000000136 cloud-point extraction Methods 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Chemically Coating (AREA)
- Surface Treatment Of Glass (AREA)
Description
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b) .AglTO^ 10 γ/η bohu r) -ágNOj ΌΠΗρΤβ . 10-30 γ/η β 50$ 3THHOBOM JĎW yjiyHMHiw h yoKopeHHH npoqeooa aKT2BnpoBaHBHnpejyiaraeTCH πρημθηητβ ropsHne pacTBopa 33οτηοκηοηογοcepeópa (TeMnepaiypa pacTBopoB - 50-90°C). ΒρβΜΗ aKTHBHpOBaHHB COCTaBJIfleT 0,5-5 MHHyT.
MejmeHiie ποΒβρχΗοοτΗ hsjísjíhh hpobohht H3 pacTBopaee coneS npn TeMnepaType 30-60°C.
Ilocjie HaHeceHHH μθπηογο hokphthh H3ji;eJiHe npoMHBaiOT -bojíoh: h oyniaT.
OjiHaKO ηρΗΜθΗθϋΗβ yKa3aHHoro cnocoóa HaHeceHHH Me^ηογο ποκρκτΗΗ Ha noBepxHocTL CTeKJia He π03Β0Λπβτ nojiyqaTB - 3 - OTačOiHue 3epKajiBHHe AByxcTopoHHne MeaHue ποκρητηη,hq noasatomiiecH QKHCJiíwmefjiy ae&CTBHK) bhqiuhqíž cpesu.
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IlGcraBJíQHHafl nejiB socTHraercs ιθμ, ψγο b m3B6gthomcnocoóe HaHeceHMH μθτιηογο ποκρητηη Ha ποβθρχηοοτβCTeKJia nyiejá cescHÓOH3am!H ee pacTBopoM xjiopncioroOHOBa, aKTHBHpoBaHHfl paciBopoM a3oiHOKHCJioro cepetípa nμθαηθηηη npn TeMnepaiype 30-65°C , ceHcntíon3aiyiio ocy-mecTBJísioT b 0,0005-0,0007 Bec.^ boahom pacTBope xmopne- Q Toro ojiOBa, aKTHBupoBaHne - b 0,005-0,15 Bec.% pacTBopea3OTHOKHCJioro cepetípa npn TeMnepaiype noBepxsocTn 30-6Q°ca nocjie μθαηθηηη ποβθρχηοοτβ CTeKJia otípatíaTHBaíOT0,0001-0,5 Bec.% pacTBOpOM CTatíOH3aTopa.
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Hnace ΠρΗΒβββΗΗ ΚΟΗΚρβΤΗΗΘ ΠρΗΜβρΗ ΒΗΠΟΛΗβΗΗΗ flaHHO-ΓΟ Η300ρβΤΘΗΗΗ· ΠρΗΜθρ I. 1. CTQKJiHHHyio nJiacinHKy HarpeBaioT β BO3aymsoM τβρ-Mociaie so TeMnepaiypH 30°C. 2. Harpeiya nmacTHHKy norpyacaíOT Ha 25 cen b paoTBop,coflepaíamHH £nCl2 -2H20 0,0005 Bec.% 3. 3aTeií nJiacTHHKy norpyaaioT Ha 25 ees b pacTBop, co^epsamnii AgNOj 0,005 Bec.^o. 4. AKTHBnpoBaHHys) nJiacTHHKy norpysaioT Ha 15 mhh bnpeaBapmejiiHO HarpeTEň so 30°C pacTBop, H3 κοτοροτοBeayT MeaHeHne. - 4 - 5· IIocjiq M0Tajuin3auo nnacTUHRy norpyataioT Ha 5gqkb pacTBop, GoaepjsamMií HaipMH 3TMJiaH3MaMHHTeTpayiccycHoiíKHGJIOTE B ΚΟΛΗΗΘΟΤΒΘ 0,5 BQG.% (cTaÓHJIM3aiíHfl). 6. CTaóHJiH3HpoBaHHyío MesHyio iuiacTHHKy npoMHBaíOT.BOSOS h cyinaT b TeqeHHe 2 MHHyi lípu TeMneparype I00°Cnpn βΤΜΟΟφβρΗΟΜ flaBJíeHHH. ΠρΗΜθρ 2· 1. Cocys ftBioapa HarpeBaíOT b B03ayniHQM TepMociaTeflo leidnepaTypu 55°C. 2. íIorpyacaioT ero Ha 10 οβκ b paciBop, coaepscamo Φ SnClg ·2Η^0 0,001 Βθθ·%· 3· Cocya norpyjsaiOT Ha 15 οθκ b pacTBop, coflepsamOAgLT%0,09 Bec.%. 4. IIorpyaaiDT ero Ha 10 MHHyT, b npeaBapmejihao Ha-rpaTHíí ao 40 °C paciBop μθ^ηθηκη. 5. IIOGJie MaiajuiH3amiH cocya norpyncaioT Ha I5ceK bpacTBop, coflepataiuHH Kajinií Haipufí βηηηοκηολμη b Kojwqe-GiBe 0,001 Bec./o.
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Jiy HaxoflMicfl b npesejiax 5,5-7,5 κγ/cm2. 3epKaJiBHoa Mea-Hoe ποκρΗΤΗβ c κοΒφφίΐινίθΗΤοω oipaaeHHH co ctopohu Meiaji-Jia 81-84% Λ-Jifl cB6Ta c ajimhoS bojihu 640 -750 hm ημθθτlojimoy ot 0,1 #o 0,3 mkm η Ooaee. LIpanidymecTBO πρημθηθηηη βοαηογο pacTBopaSnCl2 .2^0 no cpaBHeHHK) c khcjimm hjih lueaoqHhiM ero pacIBOpOM COCTOHT B TOM, qTO npH 3I0M HCKJIiOqaeTCH nOCJie-syioman οτμμβκθ ceHCHČHJiH3HpoBaHHOíí noBepxHociH ot hohob.ΒΒΘΛΘΗΗΜΧ SJíaKTpOJIHTOB (qeJioqB,KHCJiOTa). ΟαηοβρθμθηηοG 3THM flOGTHraeTCH paBHOMepHafl CeHCHÓOM3aiUJfl προοτοϋ HCJIOfflHOH φορΜΜ Ο’ΕΘΚΛΗΗΗΟίί ΠΟΒβρΧΗΟΟΤΗ,qTO Tpy^HO ,ΖξΟΟΤΗΓ-HyTB fla;sa πρκ HeosHOKpaTHOH οτμμβκθ noBepxHocTH ot khcjio-ro hjih mejioqHoro pacTBopa (ocočeHHO BHyipeHHHX noBepx-Hociefl). 1 - 5 - ΙΙρΗΜθρΗ ΠρΗΜΘΗΗΘΜΗΧ Β flSHHGM ΟΠΟΟΟΟβ paOTBGpOBM8SHQHHH, ΠΡΜ C00THQUI6HHH ΚΟΜΠΟΗΘΗΤΟΒ,B8C.%:
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- 6 - páTi ωβΤδΟΗΘδΙΙΗΚ) SOnOJlHMTeJIiHUM ΒΈθβθΗΗΘΜ npOlíeCGa ΤβρΜΟ-GTaiiipOBaHHfl M3fleJIHfl. 3. Πθ3ΒΟ7ΙΗΘΤ IWJiyqHTB 3epKaJIBHIil3 MeTaJIJlMHeGKMQ ΠΟΚΡΗ-ths, MueioinHe xopomyio asre3Mio κ HanocHMOii ποΒθρχΗοοτΗ, 3aGH9T npílMQHSHHfl ΗΗ3Κ0Κ0ΗΙΐ6ΗΐρΗρ0Β3ΗΗΗΧ BOflHMX paCIBOpOBΧΛΟΡΗΟΓΟ OJIOBa H a30TH0KHGJI0r0 GQpeÓpa. 4. OipaaaiejiBHafl cnocodnocTB mq^hex μθηοκ, nojiyneH-hhx no npeaJiaraeMoisy cnocočy, b oóJiacTH ajihh bojih640-750 mm cjieflyioiuafl: а) CO CTOpOHU ΜθβΗΟΓΟ ΠΟΚρΜΤΗΑ CTeKJI0M3SeJIMfl 81- 84%; б) CO GTOPOHM np03paqHOM nOflJIO&KH ΟΤβΙϋΙΟΗ33βΟΗ 82- 86%. 5. ΜΗ0Γ0Κρ3ΤΗ0 HCn0JIB30BaTB ΠρΗΜΘΗΗΘΜϋίί 3ΚΤΗΒΗρθ—BaHHfl noBepxHOGTH pacTBop a3OTHOKHCJioro cepeópa. 6. Ι53Γοτοβητβ τθρΜοο» coflepsamníí cocy# flBioapa, MeiaJi-.JIM 3 H po Ba H HUS Ηβ£0ρ0Γ00Τ0ΑΙ1{ΜΜ MeiaJUIOM (MQflBiO) , KOTOpafi no cbohm τθηιιο H3 o jihuhohhhm GBoficiBaM ΗΘ yciynaei TepMOcy,coflepsameMy cocy/t flsioapa, Me'TajuiH3HpoBaHHHK GepeópoM. Πρκ 3T0M Boja, oiaioinafl TeMneparypy +95°C, 3ajioaeMafl b lep-mog, coflQpisamnii cocys ^Bioapa oóbqmom 0,25 ji, npn Teanepa-iype BHeiuneíi cpe^a +I5°C qepe3 12 qacoB HMeei Teanepa-Typy +66° -70°C. - 7 -
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1. Cnocoó HaHecenHfl μθ^ηογο ποκρύτηΗ Ha nosepx-HOCTB GT6KJI3 nyTGM CQHCHÓHJIH3ail,HH ΘΘ paCTBOpOM XJIOpUC-ΤΟΓΟ- OJIOBa, aKTHBHpOBáHHfl paCTBOpOM a30TH0KHGJI0r0 ce-peópa h ΜθΛΗόΗΗΗ npn reiínepaiype paciBopa 30-65°C, ot-JIHHaiOlUHiÍGS ΤβΜ, Í1O C HeJIBíO ΠΟΒΗΙΠΘΗΗΗ CTaÓOBHOCTLI #ByX-GTOpOHHerO 3βρΚ8ΛΒΗ0Γ0 ΠΟΚΡΗΤΗΗ, CeHCHÓHJIH3amiIQ ocyme-gtbjihiot b 0,0005-0,007 Bec.^ bo^hom pacTBope xjiophcτο-γο ojioBa, aKTHBHpoBaHHe - b 0,005-0,15 Bec.fo pacTBopea3OTHOKHCJioro cepeópa npH Teianepaiype noBepxHocTH . 30-6Q°C, a nocJie μθαηθηηη ποβθρχηοοτβ cTeoa oópaóaTu- ® BatoT 0,0001-0,5Bec.^ pacTBopoM cTaÓOH3aTopa. 2. Cnocoó no n.I, ouinnaiomnňcíi τθμ, hto ποβθρχηοοτβcieKJia oópaóaTHBaioi pacTBopoM Kajinn Haipun βηηηοκηολογο,HaTpHfl 3TOeHflHaMHHTeTpayKCyCHOKHC Jioro , ΒΤΟθΗΟδΜΟ-iQTpayKcycHOH khchotoh, φορωβΛΗΗΟΜ, TpHSTanojiaMMHOM hjihnponHJIOBblM ΟΠΜρΤΟΜ . MCTOnHHKH ΗΗφορΜΗΠ,ΗΗ, ΠρΗΗΗΤΗθ BO BH0M3HH6 ΠρΗ3KcnepTH3e: I. Ty II-72I7 M0.302.000Ty, 08.02.78. ( 2. lilazKaycKac M.M. h Ap. XnMunecKafl MeTajuin3annn nJiacTMacc, ;'Xhmhh'’, 1977, c.51-72, 95-101 -g-
AHHoiamiH M30ÓpeTeHHe OTHOCHTCfl K ΟΤδΚΟΛΒΗΟΗ Η BaKyyMHOŽíΠρΟΟΟΘΗΗΟΟΤΗ, Iip6HMyiH6CTB0HHO ΠρΗ np0H3B0aCTBe TOBa-poB HapoflHoro noipeÓJieHHH, HanpHMep, TepMocoB.
UejiB H30ópeieHHB - noBbímeHHe οτθΟηλβηοοτη aByxciopoHfíero 3θρΚ3ΛΒΗ0Γ0 ΠΟΚρΗΤΗΗ.
IlocraBJíeHflaH ηθλβ aocToaeTCfl Teti, ητο ceHCH<5HJiH3a-iíhio ocymecTBJífliOT b 0,0005-0,007 Bec.% βο^ηομ paciBopeXJIOpHGTOrO OJIOBa, QKTHBHpOB3HH6 - B 0,005-0,15 BeC.fopacTsopa a3OTHOKHCJioro cepeópa πρκ TeMnepaiype noBepx-hocth 3Q-60°C, a nočně μθαηθηο ποβθρχηοοτη cTeoa oó-paóaTUBasoT 0,0001-0,5 Bec.% pacTBopoM ciaóHJiH3aTopa. Η300ρθΤβΗΜδ MO&eT HaÉTH ΠρίωβΗβϋΗβ íipH MQTaJIJIM3ai],HMGiSKJiHHHEx cocysos TepMOca ^Bioapa, a Tarase npn npoH3-BOsoiBe paAHOSJíeKTpoHHtix npnóopoB h pe<pieKTopHUx jiaMn.
Claims (2)
- Předmět vynálezu1. Způsob nanášení měděných vrstev na povrch skla jehosenzibilizací roztokem chloridu cínatého, aktivací roztokemdusičnanu stříbrného a poměřováním při teplotě roztoku JOaž 6J °C, vyznačující se tím, že za účelem zvýšení stabilityoboustranné zrcadlové vrstvy se senzibilizace provádí ve vodnémroztoku o hmotnostní koncentraci 0,005 až 0,007 % aktivacev roztoku dusičnanu stříbrného o hmotnostní koncentraci 0,005až 0,15 % při teplotě povrchu JO až 60 °C a po pomědění sepovrch skla zpracuje roztokem stabilizátoru o hmotnostní kon-centraci 0,0001 až 0,5 %·
- 2. Způsob podle bodu 1, vyznačující se tím, že se povrchskla zpracovává roztokem vínanu sodno-draselného, sodné solikyseliny ethylendiamintetraoctové, kyseliny ethylendiamih-tetraoctové, formalínem, triethanolaminem nebo propylalkoholem. 4
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU792849301A SU1036697A1 (ru) | 1979-12-20 | 1979-12-20 | Способ нанесени медного покрыти на поверхность стекла |
| BE0/205949A BE890335A (fr) | 1979-02-28 | 1981-09-14 | Procede d'obtention d'un revetement brillant en cuivre sur une surface de verre et objets en verre traites conformement audit procede |
| BE890335 | 1981-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS231255B1 true CS231255B1 (en) | 1984-10-15 |
Family
ID=27158721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS807476A CS231255B1 (en) | 1979-12-20 | 1980-11-05 | Method of depositing of copper layers on glass surface |
Country Status (4)
| Country | Link |
|---|---|
| BG (1) | BG35806A1 (cs) |
| CS (1) | CS231255B1 (cs) |
| DD (1) | DD160879A3 (cs) |
| SU (1) | SU1036697A1 (cs) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2675808C1 (ru) * | 2018-10-29 | 2018-12-25 | Федеральное государственное бюджетное учреждение науки Институт химии твердого тела Уральского отделения Российской академии наук | Способ получения фотокаталитически активной пленки |
-
1979
- 1979-12-20 SU SU792849301A patent/SU1036697A1/ru active
-
1980
- 1980-11-04 BG BG8049544A patent/BG35806A1/xx unknown
- 1980-11-05 CS CS807476A patent/CS231255B1/cs unknown
- 1980-11-11 DD DD80225113A patent/DD160879A3/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BG35806A1 (en) | 1984-07-16 |
| DD160879A3 (de) | 1984-06-13 |
| SU1036697A1 (ru) | 1983-08-23 |
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