CS220563B1 - Photographic material on the basis of silver halide emulsions - Google Patents

Description

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OEJIACTB ΠΡΜΜΕΗΕΗΚΗ M30EPETEHMH H30ÓpeTeHze KacaeTCH $ £ OTorpai írqecKoro MaTepzana to ochobs rsno-znocepeópzHux SMyzLczfi, κοτορυζ conep &amp; zT well zpafeeĚ Mepe onzHCBeTonyBCTBKTejiLHuft rajiooocepeópHHufi sejiaTZHOBuft cnoz of no KpaiiHeií Mepe ojhíh oóecnBenuBaeMufí ZNZ BUMUBaeMuft φζζΒτροκρΒΟΖτβηΒ. XAPAKTEPMCTHKA H3BECTHHX ΤΕΧΗΡΓΊΕΟΜΧ PBIIEHHfl K3BecTH0 BHeceHze opraHznecKZX KpaczTejieíi b φοτοΓρΒφζηθοκπε Ma-c Tepzanu nentio npenoTBpameHza opeojiaoTpajseHZH from / bristles pacoeHHzz.Tanze KpaczTenz b najiBHezmeM odo3HaneHHue $ zjiLTpoKpaczTejiaMz, nOJDKHU ΖΜΘΤΒ BUCOKyiO 3KCTZHKHZI0, TOHHO COOTBeTCTBynuyiO £ 3ΗΗ0Κněmí npHMe.HeHHH of ηοπκΗυ óutb όυοτρο, from óe3ocTaTonHO HeoópaTZMOynejizeMu. JlanBine TpeóyeTcz xopoiíiaa BonopacTBopzMocTB of xopomaHctokkoctb npz xpaHeHzz Kaz b zanecTBe βοληηογο pacTBopa, τηκ zb KanecTBe οοοτηβηοΑ nacTz φοτοΓρηφζΗθοκζχ cnoeB. Jlajiume Heoóxo-ZJímo φοτοΓρπφζηεοκΒΗ HeaKTZBHOCTB, T.e. nonζΗΒρρρββ non non non non non non non non non non non non non non non non non non nonJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠΠ Czο czx nop z3BecTHue CBeTonorjiaTZTejrz βηποηηηιοτ stz TpeóoBaHZHtojibko nacTZHHO. OcoóeHHo cjiohho 0Ka3U3aeTCH óe30CTaT0HH0e yza-jieHze HPH Kpaítee kopotkom BpeweHZ oópaóoTKZ from / zjiz zcnojiB3O3aHzzTazzx oópaóaTUBaniizx Β3ήη, κοτορυε msjio bjizhiot Ha pa3pyineHzeφζζΒτροκρθοζτβηεζ.Οτο othocztch ocoóeHHo κ φζζΒτροκραοζτεζΗΜ, onzcaHHUM b onzcanzz Ζ300ρθτθηζη κ naTeHTy BejiBrzz 431,272, b £ BHKJia COM onzcaHzz z3oópeTeHza κ aznenTOBazHoz 33ηβκθ ΦΡΓ 1447 813 b onzcanzz Z30ÓpeTeHZH κ naTeHTy CIII 3 091 3 S ZB onzcanzz Z30dpeTeHZH κ naTeHTy PJLP 109 455. Β Ηβκοτορπχ cnynaHX, πρκ dojiBinoM KOjnrcecTBe odpadoTaHHoro MeTepn-Ajia, nponcxoOTT HaKoiuiemie HepaspymeHHoro $ HJiLTpoKpacnTejia-b rotates paóaTHBawix BaHHax, HTO b nocnencTBHH MeñiaromeMy λο-0Κρ3Ή1ΗΒΒΗΧΚ) ΟΤΟΜΒΤ φΟΤΟΜΒΤθρΚΘΛΟΒ, HaíIDUMep, TapTpa3KH (Color-In-dex K2 19 140). XE Camo othochtch κ τθμ KpaciíTejiHM, κοτορπβTOJILKO OÓpaTKMO nepeBOJXHTCB B ÓSCIIBeTHyiO φορΜγ (HanpHMep, TPX $ e-HHJIMeTaHOBHe KpaCHTeJIH, OKHC3ΗΗΗθ Β ΟΠΗΟΒΗΗΗ Η300ρθΤΘΗΙΙΗ to K-I Tehty 0paHlíHH 017102 h Color-Index N * 42,685). MaTepnaJiH, co-nepxanme Tanne KpacHTejm, οκβ3ηβηιοτοη nocjie odpadoTKH decixBeTHH-mh, ho odpa3yioT KpacnTejiL οπητβ npn xpaHemm npoHBJieHHoro MaTepiia-jia, Tan οτο B03HHKaeT HexejiaTejiBHO Bxjwoe oKpainHBaHne MaTepna-Jia.

HejiocTaTOHHaH pacTBopHMOCTL μηογοηηολθηηηχ KpacHTejiefí πρηβολητ

TaKxe κ TpyjmocTHM lime nx npHMeHemm. B Tex cnynaHx, Korna Heod- XOJCHMO BHCOKOe OKpamHBaHHe, dOJIBinoe KOJIHHeCTBO ΒΟΛΗ, Heodxojuwioemin pacTBopeHHH puοΒτροκρηοκτβτΐΗ; OHa ΠρΗΒΟΛΗΤ, κροΜθ τογο, κ ocasjieHJíHM β sejiaTHHOBOM cjioe, KOTopne MeinaioT odec-iBeHHBaHHio. Tanne HenocTaTKu BHCTynaioT Tom Korn n3-3a .cjihui-kom y3K0fí odjiacra πογλολθηηη mzjiBTpoKpacHTeJiefi HeodxomiMo npn-ΜΘΗΗΤΒ CMSCB H3 ΤρθΧ HJUT dOJIBIIierO HHCJia KpaCHTeJieíí, HTOdH OXBa-thtb bcio φ, οτοΓρβφΗΉβοκίϊ BasHyio odJiacTt cneKTpa. B Tarax cjiynaHxcjhihikom ce ^ eKTHBHoe norjiomeHne cjienyeT οήήτβτβ ηθλοοτβτκομ. Τηκκμη BemecTBaMH hbjihkztch, Hanpimep, KpacHTejien corjiacHo omicaHnio H3odpeTeHHH κ naTeHTy Ohio 3,316,091, BHKJianHOMy onHcaHHio H30dpe τθηηη κ-HeaKiienTOBaHHoft 3affBKe ΦΡΓ I 522 427, BHKannHOMy onxcaHHioH3odpeTeHHH κ HeaKiienTOBaHHOfi 3aHBKe ΦΡΓ 2,262,794, BHKJiajmoMyoriHcaHHio. H3odpeTeHKH HeaKiienTOBaHHOí κ * · I 33Ηβκθ ΦΡΓ 472,789, OMI-CaMV H3odpeTSHHH κ naTeHTy CUIA 3560214 h onzcamno H30dpeTeHKHκ 3K0H0MimecK0My naTeHTy Γ, Π, Ρ 109455, κοτορπβ c ηβ3ββηηει.ώϊ He-ΛΟΟΤΒΤΚΒΜΗ, KpOMe ΤΟΓΟ, OdJianaiOT HH3K0ÍÍ BOnopaCTBOpHMOCTLIO. M3-3acjihihkom y3K0S cneKTpajiBHofí odnacTii norjiomeHHH kx Hano πρκμθηητβΒ ΟΤΗΟΟΗΤΘΗΒΗΟ. djIBIHHX Κ0ΛΗΉΘ0ΤΒ3Χ, HTOdH OdekneHKTB ΛΟΟΤΒΤΟΗΗΟΘnpenoTBpameHHe opeojia. IIosTOMy jierxo nocTnraeTCH BepxHHH rpa-HHIia paCTBOpKMOCTH. - 3 - ·

HejiocTaTKOM μηογοηηολθηηηχ KpacHTeJieg ηβ ^ ϊηθτοη jjajiee TpynoeMKoenojiynemie ία H3 jioporax κ Tpyjmo £ OCTynHHX hcxoihhx BemecTB, htoΠρΚΒΟβΗΤ K BHCOKOft CTOHMOCTH.

IW I430EPETEHMH

H 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 K K K K K K K K K

H3JI0KEHHE CyiHHOCTH H30EPETEM B OCHOBe H30ÓpeTeHHH JieHHT 3a £ aha HaííTH JUia 003 £ ΗΗΚΗ B SLiyjILCIÍ-OHHHX n / r · SeJiaTXHOBHX CJIOHX C BUCOKOg TUIOTHOCTLK) OKpaneHHOrOMaTepaajia, Jierao nojiynaeMue, xoponio paCTBopHMHe η όκοτρο odecuBe-HHBaeMHe φοΒτροχρΗοχτθΛΗ mni cMecH KpacHTejiefi, κοτορκθ c bhcokoíísKCTXHKUKeg noímomasoT cbst b bo3Mosho óoJiMieK Hacra bhjwoií by-JiacTH cneKTpa.

CorjiacHo H3odpeTeHHio, sahana peuiaeTcn τθμ, hto b MaTepnane HaOCHOBe raJiooocepedpHHHX SMyjiLcnn coflepzHTCH no KpanHeS Mepe b0ΛΗ0Μ 3MyJIBCH0HH0M BCDOMOraTeJILHOM cjioe no Kpa &amp;

r is 03HaHax) T: R, εΣ = - CH 3, -C 2 H 5, C 2 H 4 -Ck; E 2 = H, Cff; - 4 -

IIpezMymecTBo 'oodpeTeHO coctoht b πρημθηθηο no KpažHeň MepeB OÍHOM. SMyjIBCHOHHOM ΙΜΗ ΟΜΟΓΒΤΠΟΜΟΓΒΤβΗΒΗΟΜ CJIOe KpaCHTemen OH ΟΜβ-cn KpacHTeneii reMynn c ο ο ο ο ο ρ ρ ο n n n ame ame ame ame ame ame ame a a a a a a a p p p p p p p p p p p p p p p p p p.

OcodeHHoe npenMymecTBO H3odpeTeHHH it HTO well Kpaiteen Mepe b online HOM SMyJILCHOHHOM OH ΒΟΠΟΜΟΓΒΤβηΒΗΟΜ CJIOe COAepJKHTCfl CMeCB KpaCH-Temes, CORMACH H3odpeTeHHio, οοοτβθτοτβθηηο rewards žopMyme b κο-τοροδ 3aMecTHTemn R2 pa3nnHHn 3aMecTHTemH η r, r1, r3 onjiHaKO- 9 h bh. B cjiynae, ecmn r = C35T, kpacnTemn normamajoT bo Bcen 3onHon n KpacHon odmacTHx cneKTpa, b cmynae, ecmn r2 = H, b ciiHeíi n donBinei naTcn 3emeHon odmacTmx; ομθοβκι KpacnTemen c-R2 = H nR 2 = Cn AocTHraeTCH neficTByiomaH 3ainnTa no BceMy cneKTpy βοημογο cBeTa. Tanne CMecn ημθιοτ ocodeHHne npenMymecTBa nmn 3amnTHHx cmo-ββ προτηΒ opeoma OTpaKeHHH. Πο coctohhhio τθχηηκη, HTodn ηοοτηηΒ cpaBHHTemBHyio 3aiiHTy, Hano πρημοηητβ CMecn H3 3nmn 4 KpacnTemež, hto BmeneT 3a codon 3HanHTemi> Hoe noBHmeHne pacxona KpacnTemen n cooTseTCTByiomHe 3to ocHOBaTemBHoe npenMymecTBO KoacnTemefi, CORMACH H3odpeTeHHio, ocHOBUBaeTcm Ha that HTO npn 3aMemeHnn = CN B03HHKaeT ηθοηη- Makha cobhkh daToxpoMHun ΐξΒθτοΒοη cnBHr η normomeHne sthx well CNX nop ηθοβθοτηηχ KpacnTemet nonomoeTCH b τβκομ nneanBHOM BH-_ 9 no nomameHneM aHanonraioro KpacnTemn c R c = E , ητο βοοηηκβθτ

- 5 - HenpepiffiHoe nornomeHme no Bcefi bhjwioS odnacTH cnen-Tpa.

CymecTBeHHoe npeHMymecTBO H3odpeTeHnn coctoht b bhcokoíí peammoH-although cnocoóHocTH 3thx KpaciiTenefí, κοτορβπ npoHBnneTCH b about him duct-pom oóeciXBennBaHiíK NPN pH 10 h b b HeodpaTHMOM npeBpameHHH dec-nBeTHirií προηγκτ YSE npn Hedonámom conepxamm cynB $ aTa B Waste-THBajoumx BaHHax. 3thm οηη ηβηο πρβΒοοχοηητ npyrae KnaccH KpacnTe-Ne CSC okcohojih n Tos TpnčbemuíMeTaHOBEie xpac groundling, κοτορκβ oxo-th ÓLicTpo OÓeciíBemiBaioTcn him b κκοηοίί odnacra 3HaneKZtt pH óhknpeBpamajoTCH odpaTHo b oKpameHHyio popwy.

Ho cpaBHemra c η3βθοτηημι <pnnBTpoKpacnTenflMZ H3 miacca deH3mnn-ΑθΗΟΒΚΧ KpacHTenefi sth KpacnTenn h hx nponyKTH ii en en en en en en 3 H H X X X X. HoSTOMY £ OCTHraeTCH de3-ocTaTOHHoe βημηββηηθ h HCKnicrqaeTCH modon Bnn odpaTHoro nnn ocTa-TOHHoro OKpamnBaHKH, our npn chjilho nydmimx odpadaTHBaioiicax βηη-Hax c epsεηΒΗΗΜ conepsamieM cynBgĎHTa. C 3Τ0ΐί tohkh 3pefflLH Kpacmrenn, cornac H3odpeTemno, ocodeHHO npe-BocxonHT KpacnTenn no onucaHino H30dpeTeHH.fi κ naTeHTy CIILA. 3 316 091, KOTopue n3-3a hbho οοτβτοηηογο OKpainHBaHHH He γολητοη nnn μητβ-pnanoB what οκοροοτΗοδ wasteoraož.

KpacHTemí, cornacHO H30dpeTeHHio, H3-3a Ha3BaHHHx npmniH ocodeHHOποηχοηΗΤ nnn odecnenuBaHHH τβκηχ ΦοτογρβΦηήθοκηχ MaTepnanoB, yκοτορκχ BcnencTBne Kpafee κοροτκοΓΟ BpewieHU odpadoTKH η / πηκ ββηη, conepsaaiHx cynBtfca Mano, npHMeHeHHe npyrnx φπηΒτροκρΗΟΗτθπθδHeB03M0SH0 Can B03M0SH0 nHUJB B HH3KHX ΚΟΗΙίθΗΤρβΙίΗΗΧ. JNHMymecTBO Kpacctin, cornac H3odpeTHH10, cocto-JTT B HX xopomies BOnopaCTBOpiIMOCTH, ocodeHHO HX andMMHHiHHX conen.

Tax kok ohh odnanamT, Kpowe τογο, bucokoh skcthhklw ^, mosho no-cthhb bkcokoK iwothocth φκηΒτροκρηοΗτθηθΗ npn He'3HamiTenBHoz Ha-rpy3Ke Βοηοκ nonHBHoro pacTBopa. Kpowe τογο, ohh npenoTBpanazoTocasneme κρκοτεηηοΒ KpacHTena b cnoe npn bhcokok KOHneHTpanxn

CL

- 6 - Π0 CpaBHeHHIO C H3BeCTHHMH eeH3mimeHOBHMK KpaCHTeJIBMH HBHO JyHH-Hyio pacTBopKMocTL Ó iar on on on oe oe oe ox ox ox ox ox ox po po po po.

OcoóeHmM npenMymecTBOM ηβληθτοη προοτοβ cnocoó nojiyqeHHH Kpacn — Tejiíi, coiviacHO H30ÓpeTeHHK>, H3 oóqe.nocTynHwc h nemeBHX hcxo, hhbixBemecTB. O

KpacHTejm RNE 03HanaeT R = H, nojiynaioT KOHneHcainieíí οοοτβθτ-, CTByWIX n JÍIiaJIKIUiaMIIH0ÓeH3aJIBT: C erHJÍ0B COOTBeTCTBynUZMH HHpa30-b jioHaMH cnnpTOBOM m bojíhom pacTBopax b npncyTCTBini aneTaTaaMMOHHH b KanecTBe κοηλθηοθιβιοηηογο cpencTBa. IIoJiytieHJie KpacxTejieft CR2 = OW onucano b oimcamui H30ÓpeTeHHHκ naTeHTy Γ Ρ £ 131 178. nonynemiH CMecH south X3 ítnyx KpacnTejieft, corjiacHo oómefó áopwiyne, κοτορυθ pa3janai0TCH tojilko 3aMecTHTejieR b = H mu qi hcxojíhhm BenjecTBOM cjiysHT KpacxTejiL c R = H jxjuíKpacHTejin CR2 = Cn. IIorjiameHiie oóonx KpacHTejie® β3βημηο nonoji-HH30TCH onTHMaJILHHM 0Opa30M H OXBaTHBaiOT BCIO φβρβφΙΙΉΘΟΚΗ BaS-Hyio oOjiacTt ot 400 wt. ΚΟΗΘΗΗΟ, He3aBHCHM0 OT 3Τ0Γ0 ΜΟΗΗΟ03ΜΟΗΗΟ ΠρΚΜΘΗΒΗΗβ CMeCH ΠΟ Kpaft-Heft Mepe H3 οαηογο KpacHTejia, corjiacHo H3odpeTeHHio, c npyrHMHOpraHHHeCKHMH $ HJI3TpOKpaCiíTeJLHMH.

Ha ocHOBe iuupoKOft oónacTn noímoineHHH ηη3Β3Ήηηθ KpacHTejm ocoóeHHonoBxojyrr jyiH πριιμθηθηηη b cneimaJiBHHX BcnoMoraTejiBHHX cjiohx julhnpejIOTBpamSHIIH opeona, OCOÓeHHO JVIH ΠρΗΜβΗΘΗΗΗ B ZeJiaTZHOBHX CJIOHX, HaXOJÍWíXCH Ha OÓpaTHOŽ CTOpOHe mieHKZ B-CJIOHX Ha3HBaeMHXNC TCLK. CBoScTBa KpacnTejieft CMeceíi, and τβκηθ nx conepsnumix φοτοΓρβφΗ · HecKHX MaTepnajioB, ormcHBaioTCH b coienywix npnwepax no cpaBHe-HHK3 C H3BeCTHHMH ni ni T T T T T T T.

ΠyΕΡ OCyiIIECTBJEEHHH H30EPETEHHH

Πριιμθρ I

CpaBHHBaioTCH KpacHTejm, cooTBeTCTBywie coctohhhio tsxhukh (Taon.I, - 7 - She I - 8) n, corjiacHo κ3θόρθΤ6Ηΐιιο, (Tadji. I, Her 9-12), and Tan-z cmscL · wx KpacnTejieft, corjiacHo H3odpeTeHnro, OTHocHTejiLHOcneKTpaJiLHoro norjiomeHHH, EH (pI> y3HOHHoro ποβθβ, θηηη h odecuBeniiBa eMOCTH-b. φοτοΓρΗφκΗβοκκχ BaHHax. C οτοϋ uejiLio íodaBJíJWT BonHue pacTBopu KpacnTejiefi I-I2 10% by κ Homo pacTBopy οΟηηηο # zejiaTHHH b Tanowo xojnraecTBe, HTO nocjie no-Ha jiHBa deciiBCTHHa HocHT.ejiB H3 APET pejuímosH h cyinraa nojiyqx-JEHCL CJIOH φΐυίηΤρΟΒ, KOTOpHe B CBOBM COOTBeTCTByDIHeM ManciiMyMeΠΟΓΗΟΠίθΗΗΗ Π0ΚΒ3ΗΒ3Ι0Τ OBTHMaJILHyB IUIOTHOCTB, paBHyiO I 0. T0JI-uíhhh cjioeB cocTaBJíHKT 6PN 3HaHeHHe zejiaTHHOBoro pacTsopa Pash pH 5.2 to 0.2. B KanecTBe nydnmero BemecTBa nodaBJíHKT Ha We destroy 100 mji 10 $ -ro pacTBopa zejiaTHHU 6 mji 5 ^ ro bouhobo pacTBopaHaTpneBoft cojh I, 3-KHxjiop-5-rnjipoKCH-CHM-TpHa3HHa from 0.75 mji5% -ro pa 9th cjioh nccjienyioTCH cJienyiomHM odpa3ow: a) OnpenejieHHe MancHMyMOB norjiomeHHH, and Tarase οπτημβηβηηχ iuiot-HOCTea npn 450, 500, 530, 560 of 650 wt.

JlaHHLie cM0Tpn Tadn. 2 d) OnpenejieHne ρηΦΦ ^ ηοηηογο noBeneHHH rivet 10 HHHyTHoro KOH TaKTHpoBaHHH c HenydJieHHM zejiaTHHOBHM cjioeM, HadyxmeM b He-CTHJBipOBaHHOa ΒΟβΘ (TOJUIÍHHa CJIOH 50 pM), B ΚΗΗΘΟΤΒΘ ΠρΗΘΜΗΟΓΟcjioh h onpenejieHHe IJA $ AYH; njspyiaiqeií npn τηκηχ ycjioBHHX hojihB% OT HCXOUHOfí IUIOTHOCTH , KHK OTHOCHTeJILHaH Mep CKOPOCTH, HH <$ y í ní (Tadn. 2). b) OiipeneneHHe ckopocth odeciiBeHHBaHHH b I $ -om pacTBope NaOH, I $ -om pacTBope í ^ sOg, and Tarase b nowadaysM mnKcaze OPBO 308z b npoHBHTejiHX .OPBO 40 from A 82. (cp. "OPBO-peiienTu", H3namie 1978 r .)

We hate cocTasjíeHH b Tadn. 3. r) OnpeneneHHe οοτητοηηογο oKpainHBaHKH HCKyccTBeHHO CTapesinxxnpod npz 50 ° C H 30% -OŮ ΟΤΗΟΟΗΤΘΠΒΗΟΗ BJiaZHOCTH, 5 CyTOK no- - 8 - CJie ΠρΜΘΗΘΜίΟΚ ΉΙΚΗΘ3ΉΙΚΗΘ THHa "IlaKOHOJBlT"

60 ceK. npoHBJiemie, OPBO A 82, 27 ° C30 ceK. nyowift (Smccas (MP 329 / MH), 20 ° C30, nMoMHBKa, 20 ° C (coctsb BaHH cp. "OPBO-penenTu", H3naHne 1978 r.)

Ehjio οηθηθηο ocTaTOHHoe oKpaiiixBaHxe b% ot xcxojxhoS ujiotho-cth nocjie npoxosmeHHH Ha3BaHHoft oópáóoTKH (TaóJi. 4a) N-Jie night nonoJiHHTejiBHoS npoMKBKH Bonoíí what 3HaneHneM pH = 4.0 (TaÓJi. 4o) Π3 jiaHHHX mohho cnexaTL cjienyiomee pěaioMe: linden OAHHaKOBLix ocTaJiLHLix CBOftcTBax , KpacKTexn, corxacHO X3oópe-Temw, npeBocxo £ HT KpacHTejm, cooTBeTCTByromze coctohhiíio TexHHKH, no · cnenywM nyHKTaM: - BcjiencTBne bhcokoS θκοτηηκιβιη HeoóxonHMoe KOjnnecTBO KpacHTe-Jlff JW βΟΟΊΉΗΘΗΗΗ CpaBHKMOČI lUIOTHOCTH -MSJIO. B3TMM KpaCHTe-jm, corjiacHoOppeTemno, hmho nioBocxoflHT KpacnTexn Ih7. Πο 3T0My nyHKTy Kpacn-Tejm, cornacHo x3odpeTeHXK3, hbho npeBocxojyiT Bce Kpacnmemn, cooTBeTCTBywie coctohhhk τθχηχκη (κρομθ 5). Yke CMecnio BByxKpacHTejieíí moz3 co3naTB iκοοκρο iwothoctb no Bceft odjiacTZ cneKTpa. Πο cKopocra ®í (p $ y3ini KpacxTejni, cormacno n30dpeTeHKio, npeBoexo-BCE npyrne xpacHTejm (κροΜθ 6). - Πο cKopocTH oóeciíBeHXBaHHBL e> HM HaTpneM, cyjiLžxTOM pa3xnn n-hhmx cpoTorpažnnecKKMn βθηηεμη KpacHTSJíB 9 cornacHo K3odpeTe-hxb, npesocxojniT bcs npyrae KpacnTejni c KpacxTejiHMH, Cornac-ΗΟ Z30ÓpeTeHHD, Cpa3HHMH JDCHB KpacxTejm 1x2. nocxe CKOPOCT-hok oópaóoTKx (60 prizes). tojibko KpacHTejm, corxacno H3odpeTeHXD - 9 - η KpacHTejiL 7 npaKTHnecKH He ποκβ3ηββιοτ ηηκηκογο οοτβτοηηογοOKpaiUHBaHHH Η ΗΗΚΒΚΟΓΟ OÓpaTHOrO OKpaiíIKBaHHíT πρκ KHCJIHX 3 ha -ΗΘΗΗΗΧ pH.

KpacHrejiH, coiviacHO n3odpeTemno, jjocTzraioT otjutihux cbohctb Kpa-CHTejieft, cooTBeTCTBywa coctohkkio τθχηηκιϊ, tojilko no. ITpXMep 2 'JUa npOBepKH φΟΤΟΓρΒφΧΉβΟΚΟβ aKTHBHOCTH nOÓaBJIJTOT CpaBHHMHe noonTunecKOíí iltiothocth KOJinnecTBa KpacHTeneii 9 h II κ AgBr / j nAgCI / Br BMyjBcnflM, ceHCHdnjm3npoBaHHHM no-pa3HOMy. JUs θτοη izennAoóaBJunoTCH 5 mt KpacHTejin 9 ht 10 mt KpacHTejiH II κ sMyjiBCHHM, πρκΒθΛθΗΗΗΜ b TadJi. Fifth Hocne nodaBJíeHnn nonxo &amp; WRO cMamiBaTejEHh 2 vr 5% -ro Bojmoro pacTBopa HaTpneBOg cojih jníxnop 1,3-5-RNI-poKcn-CNM-b Tpna3HHa nanecTBe nydnTejiH sMyjiLCHH nojniBaeTCH HaHocxTejiL H3 TpnaneTaTa nejnnoji03H, cyuiHTcn, 3acBenKBaeTCH 3a-CTY neHHaTHM onTircecKHM kjihhom h 5 mhh. npoHBJíHeTCH b npoHBHTejie OPBO 40 amino HHCTpyianni ΟΡΒΟ I 100 (cp. OPBO-penenTu "ΒοΗΒφβΗ1978). hahhh noKa3HBaeT None 5. 9 KpacHTejiB He noKa3HBaeT'HHKaKOft žoTorpaánmecKoft βκτκβηοοτη, KpacnTejiL II BH3EBaeT tojil-co B o £ Hom CJiynae HedojiLinne noTepn HyBCTBHTejiBHocTH , κοτορυεjyiH ÓojiBWHOTBa npaKTiraecKHX npHMeHemiií: He HMe &amp; T 3Ηβηθηηη. - ΊΟ -

Tadjnma I

KpacHTejiL

KpacHTejit I: khcjiothhíí dpyKCHH, Color-Index $ 42 685 2: Tp ^ emuíMeTaHOBUíí KpacnTejiB gpopMyjm

H HOCH2CH2 hoch2ch2

.ch2ch2oh

CH2CH2OH

CL

KpacHTejiL

KpaczTejii »\ t

KpacHTejiL

KpacHTejiL corjiacHO oiracaHHio H3oópeTemiH k naTeHTy $ paHHHH I 017 102 3: on -I- [4 ’-cyjit $ o $ eHiuiJ -3-MeTHJinnpa30Ji0H- (5) -

. TpHMeTHHOKCOHOJI corjiacHO onncaHmo n3odpeTeHHH κ naTeHTy EeJiL Mn 431,272, npHMep 3 4: DNC-l- [4 '-cyjiLČO (£ eHHnJ -3-MeTHjmnpa3OJiOH- (5) - neHTaMeTHHOKCOHOJi corjiacHO onncaHHio H3odpeTeHHio Bejitrnn 272npnMep 431 4 5: dne- THodapdnTypoBaH KncjioTa —PΘΗΤ3Μ6ΤΗΗ0Κ00— HOJijmcnepcnH cepedpHHOft cojm b sejiainne cornacHO BHKJianHOMy oimcaHHio H3odpeTeHnH κaKuenTOBaHHOft 3asBKe ΦΡΓ I 447 813 6: TapTpa3HH, Color-Index Je 19 140

KpacHTejiL 7

corjiacHo omicaHHK) H30ópeTemíH κ naTeHTy CÍUA2 072 908

KpacHTejiL 8:

corjiacHo onHcamw H3oópeTeHHH κ naTeHTy CIHA3 316 091

KpacHTejm, corjiacHo H3oÓpeTeKKio, oómež: čbopMyjm

, b κοτορκχ

'CL

KpacHTejiB 10: R, R ^ = CHg,

! ι

KpacHTejit II: R 1, R 2 = CH 3, R 2 = CH, R 3 = J / k i

KpacHTeJiL 12: r, rj SO2 Na -CHg-CH2-CH, R2 = CR, R3 =

SO4

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W 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 —1—1 1 — I 1—1 I — 1 VV ν

CQ 00 a «aaaaaaa ► — 1 aa 03 0) K gg 0) 03 (r- *« 03 03 03 03 03 03 H 03 * - «§ 03 O § 03 03 0) o 03 03 OO LO LO m OO LO oo O o Η-1 CHANGE CO CQ A 1 1-1 in 1—1 in 1-1 In 1-1 in

? Ll Η 0 tí tí tí ll ll ll ll ll ll ll ll ll ll ll ll ll tí tí tí - - - - - - - - - - - - - - - - - -

Honor Α C0 ο «W03 03 03 03 a .a ο C Ο LO COΑ

I 03 0303Ε- <S 03 03 Ό honor 03 03

X Α «Γ * J? 03 e-5 00 Α a a «« κ «and S Ρ 03 03 03 03 03 § § 03 03 03 03 03 C0 I — t Ο Ο Ο Ο ν ω ω ω ω

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aaaaa 1Ή a <^ ja 1 — taa 03 and lp-4 g * rt G3 03 * t— <03 03 03 03 03 o 03 st · ^ o o 03 03 03 03 03 o 03 o LO LO oO LO LO OOOO — V v co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co 3 Ό

X E- <

o and CX ca X CX EH O X HO ω X e- · sa t; H Ξ> ^, 3 O OJ o * -7— · ► «and X • to CD x — X. t x x x x 0 x k x x x x x x x x x x x x x x x x x x x x x x x x 03 m .Ei cd OO a> S h h r-r r r r r r XX »CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD CD * * CD 5 X oo-<X ca OX go X 3 X o H-4bM three ►w4 kM X 1—4 CD O t =? .—, CD J · and X * - <£ 3 U 2 1—1 X • e— <HM E- * XOO φ Ό X X CD s Ό and O and k £ e 2 CD X> = ί mo OX ca o ca XXX »=: • XX 03 X '' Z * '' X ω E- ·> -Oj CM OOO LO O Oi — io

M CM 00 LO O

CM

X re X X> x X o o x ^ z x ^ z o io o ‘Λ2 O O 1-1 1—1 CM 1-1 00 1-1 V CM V O O O Μ Μ Η-1 l · -1

X X • X X X o o X V_Z x ^ z o CM LO CM o o CM o CM 1—1 CO 1-1 o V CM o o o o

O O CM CM CM X ν 'X> what about 1 - 1 by 1 - 1 CM + i-ι σ> -4

Tarínnua 5 í »

CM cd g o b

X ec! 3 o 3 &amp; £ 0 as what

CM

PS

PS

EH

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PS 3 as E- Ǥ &amp;

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PS 3 a; r-ť

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O

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ΦΟΓΜΥΜ H30EPETEHR3 I. ÍOTorpa ínecKHň MaTepnaji ^ Ha ^ οοηοβθ rajion ocepedpmHX 3MyjiBcnftno KpaiíHeň Mepe as ra ^ ^ HHM OHjzocepedpHHHM ^ ejiaTUHoblím cjioeM, κοτορυίί conepsuT well KpaítHefi Mepe · ojhih deH3mraneH0B £ IFI-Kpacn Tenby QTJiimaiomHňcH τθμ, HTO well Kpatoeíi Mepe b οληομ eMyjiL -ciiohhom Hjm BcnoMoraTejiBHOM cjioe conepcKUTcn no Kpaiteeft Mepeojuih KpacHTejiL odme &amp; $ opMyjm

RH-RJ-CH3 HJIH CgHg

Hj 6 C 8 H 11 C 11;

Cn;

3HannT Clí ΛοποηΗΐιτβηΒΗο

o coox X = H, li, K, NH4 -1S - 2. 3. ΦοτοΓρθφϊϊΉβοκίϊίί waTepnaji no nyHKTaM I n 2, oTjmnajomniícH τθμ, coflepsiiTCfl ομθοβ H3 m ^ yx KpacHTejiefi, b kotoooSTe-jm OTjnmaioTCH 33 μθοτητθλθμ r ^ n 3aMecTHTejiH r, rhh rnpb-HH. 4. HOT ami orp ec T T HS T T T T T,, I 3 y y y y y y y y y y y y y y y y y y y y y y y y y y y y y y. 5. ΦοτοΓρΒφϋΉθοκηδ MaTepnam no nyHKTaM 1-4; "13-

AHHOTAW

OoTorpa ^ zzecKzíí MaTepzaoi Ha οοηοβθ rajioznocepedpHHBLX SMyzBczňC HJIbTpOKpaCHTeJLHMH M3oópeTeHne Kacaercn $ $ $ oTorpa znecKoro MaTepzaza, κοτορυ # Ββρζζτ no co-KpafíHen Mepe onzH CBeTonyBCTBZTejiBHHň ranoznocepedpa-HBifl cjioS h no KpaňHeň Mepe ολκή όυοτρο odeczBenzBaeMuíí of žernoBHMHBaeMUfi $ HJIBTpOKpaCHTeJIB.

UejiB H30ÓpeTeHHH - yzynmeHze pe3K0CTHHX cbočctb npz decnpodzeMHOňodpadoTn from npz οήθηβ κοροτκοΜ βρθμθηζ odpadoTnz. B οοηοβθH3oópeTeHTLH JiezKT 3azana, ηβζτζ xopomo pacTBopzMBíe from npazHe dn-οτρο 0óecitBeHH3aeMHe mzzBTponpacKTezz, noTopne BczencTBze Bzconoňbhctzhhzzz of mzponoň odzacTz norzaiijeHXH yze HPH hz3kzx noHzeHTpa-zzax oóecnenHBafOT οπτζμβζβηοθ npenoT3pameHze opeoza.

Oto zocTzraeTca ζθζμμμμpppppppezezezezezezezezezezezezezezezezezezezezezezez:

B npejmOHTHTeJIBHOň ώορΜΘ ΖΟΠΟΖΗβΗΖΗ ΠρΖΜβΗΗβΤΟΗ ομθοβ Z3 ZByx9 npaczTezen, pa3zznajomzxcH τοζβκο 3aMecTZTezeM R. 2

KpaczTezz c R = CN mocraraioT ManczMywa πογζολθηζη> 600 wt.

KpaczTezz πρζΜΟΗίποτ γζββηβγμ odpa3OM mna onpamzBaKZH odpaTHBrxsejiaTZHOBBEX caoeB zza Φοτοτθχηζηθοκζχ from zpyrzx nepKo-de ^ zx waTepzanoB. Ho Tanze βο3μοζηο zx πρζμθηθηζθ &amp; zynη yzynmeHzn opeozapaCCeHHZH B 31, 'yZBCZOHHBK CZOHX.

Claims (5)

OBJECT OF THE INVENTION What is claimed is: 1. A photographic material based on halogen-silver emulsions comprising at least one halogen-silver gelatin layer comprising at least one benzylidene dye, characterized in that it comprises at least one dye of the general formula in at least one emulsion or aid layer. where S and r! is CH 2, C 2 H 5 or C 8 H 11 CN, R 2 is H or CN, is a group of the formula X 0 ^ S ^ 2 3 and when R is CN, then R is a group of formula COOX or NH wherein X is H, Na, 4 -24 2. Photographic material according to claim 1, characterized in that it comprises a mixture of two dyes corresponding to said general formula. 3. The photographic material of claim 1, wherein said photographic material comprises a mixture of two dyes in which the different R &lt; 13 &gt; meanings and R, R &amp; R &apos; 4. Photographic material according to claim 1, characterized in that it comprises a mixture of at least one dye of said formula and other organic dyes. 5. A photographic material as claimed in any one of claims 1 to 4, wherein the colorant comprises in the layer on the opposite side of the photographic material. Recognized by the invention on the basis of the results of an expert review by the Office of Invention and Patenting, Berlin, DD.