CS206889B1 - l-metakryloyloxy-2-(4-/3-chlcú'propionyl/fenoxy)etán a spfisob jeho přípravy - Google Patents
l-metakryloyloxy-2-(4-/3-chlcú'propionyl/fenoxy)etán a spfisob jeho přípravy Download PDFInfo
- Publication number
- CS206889B1 CS206889B1 CS434479A CS434479A CS206889B1 CS 206889 B1 CS206889 B1 CS 206889B1 CS 434479 A CS434479 A CS 434479A CS 434479 A CS434479 A CS 434479A CS 206889 B1 CS206889 B1 CS 206889B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- preparation
- ethane
- phenoxy
- chlorpropionyl
- methacryloxy
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 4
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 title claims 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 6
- CEXQWAAGPPNOQF-UHFFFAOYSA-N 2-phenoxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC1=CC=CC=C1 CEXQWAAGPPNOQF-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- INUNLMUAPJVRME-UHFFFAOYSA-N 3-chloropropanoyl chloride Chemical compound ClCCC(Cl)=O INUNLMUAPJVRME-UHFFFAOYSA-N 0.000 claims description 2
- -1 3-chloropropionyl Chemical group 0.000 claims 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HBZVNWNSRNTWPS-UHFFFAOYSA-N 6-amino-4-hydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C(O)C2=CC(N)=CC=C21 HBZVNWNSRNTWPS-UHFFFAOYSA-N 0.000 description 1
- BXBCUFDIDOYHKM-UHFFFAOYSA-N C(C(=C)C)(=O)OCCOC1=CC=C(C=C1)C(CCCl)=O Chemical compound C(C(=C)C)(=O)OCCOC1=CC=C(C=C1)C(CCCl)=O BXBCUFDIDOYHKM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
Vynález sa týká novej zlúčeniny l-metakryloyloxy-2-(4-/3-chlo'rpropionyl/fenoxy)etánu vzorca
Cl - ch2 -
- CSC - C = 0¾ CHj a apesob jeho přípravy.
Spfisob přípravy novej zlúčeniny» ktorá nie je známa z líteratúry, je založený na tom, že l-metakryloyloxy-2-fenoxy-etán aa acyluje chloridom kyaeliny /3-chlo'rpropionove j za přítomnosti bežvodého chloridu hlinitého.
Uvedená zlúčenina má použitie ako monomér pre přípravu avetlocitlivých polymérov a polymérnych aenzibilizátorov.
Příklad
12»3 g /i-chlorpropionylchloridu v 20 ml sírouhlíka ea přidá za chladenia (O °C) a miešania ku 15,5 g chloridu hlinitého v 20 ml sírouhlíka. Potom za chladenia a miešania sa přidá 20 g l-metakryloyloxy-2-fenoxyetánu v 20 ml sírouhlíka. Po přidaní všetkého 1-metakryloyloxy-2-fenoxyetánu sa reakčná zmes mieša pri teplote miestnosti ešte 30 minút. Potom sa reakčná zmes Opatřené vyliala na zmes l’adu a kyseliny chlorovodíkovéj a po rozložení sa
206 889
208 889 extrahovala chloroformom. Chloroformová vrstva sa 4-krát premyla vodou. Chloroform aa vákuovo odpařil a viakozny produkt po pretřepaní stuhol. Rozpustil sa v benzéne a pustil cez vrstvu silikagélu (3 cm x 5 cm). Potom sa benzén odpařil. Látka sa rozpustila v éteri a vy mrazovala sa pri -70 °C. Po vysušeni sa získala bisla krystalická látka s t.t. 85,5 až 87 °C a výtažku 66 56.
Claims (2)
1. l-metakryloxyloxy-2-(4-/3“Chlórpropionyl/fenoxy)etán vzorca
2. Spdsob přípravy zlúčeniny podl’a bodu 1, vyznačujúci sa tým, že l-métakryloyloxy-2-fenoxyetán sa acyluje chloridom kyseliny β-chlorpropiónovej za přítomnosti bezvodého chloridu hlinitého.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS434479A CS206889B1 (cs) | 1979-06-25 | 1979-06-25 | l-metakryloyloxy-2-(4-/3-chlcú'propionyl/fenoxy)etán a spfisob jeho přípravy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS434479A CS206889B1 (cs) | 1979-06-25 | 1979-06-25 | l-metakryloyloxy-2-(4-/3-chlcú'propionyl/fenoxy)etán a spfisob jeho přípravy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS206889B1 true CS206889B1 (cs) | 1981-07-31 |
Family
ID=5385961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS434479A CS206889B1 (cs) | 1979-06-25 | 1979-06-25 | l-metakryloyloxy-2-(4-/3-chlcú'propionyl/fenoxy)etán a spfisob jeho přípravy |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS206889B1 (cs) |
-
1979
- 1979-06-25 CS CS434479A patent/CS206889B1/cs unknown
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